Showing 50 of 25357 papers

On the mechanism and sequence of addition of phosphorus trichloride and other chloranhydrides of phosphorus acids to propylene oxide

Corresponding Member of the Academy of Sciences of the USSR A. N. PUDOVIK, E. M. FAIZULLIN,
1965 SovietRxiv: ru-196501.88577

This study examines the mechanism and regioselectivity of the addition of phosphorus trichloride and phosphorus acid chlorides to propylene oxide, addressing conflicting earlier interpretations of the reaction products. Experiments with dried reagents, atmospheric moisture, added water, and triethyl…

On an Abstract Characterization of a Simple Projective Group of Type $PGL(2,K)$ over a Field $K$ of Characteristic $r\ne0{,}2$

Unknown
1965 SovietRxiv: ru-196501.88298

This paper gives an abstract characterization of simple projective groups of type PGL(2,K) over fields of nonzero characteristic not equal to 2, within the class of locally finite groups. It introduces 2-infinitely isolated subgroups, approximable elements, and almost regular elements, and proves th…

Continuous operation of a $\mathrm{GaAs}$ injection laser cooled by a flow of gaseous helium

M. N. Zargaryants, A. A. Kiselev, O. D. Kropotova, L. N. Kurbatov,
1965 SovietRxiv: ru-196501.88286

This paper reports an experimental method for achieving continuous operation of a GaAs injection laser by cooling the diode with a stream of gaseous helium. The authors discuss thermal constraints on continuous semiconductor laser emission, describe a Zn-diffused GaAs p-n junction diode mounted in a…

A New Method for Studying Thermal Diffusion in Gases

Unknown
1965 SovietRxiv: ru-196501.88150

This paper proposes an optical method for studying thermal diffusion in gas mixtures, based on changes in absorption or photoluminescence of molecular vapors when a foreign gas is added in a two-vessel cell with a temperature difference. The author interprets previously observed decreases in lumines…

ALKYLATION OF BENZENE BY A CARBONACEOUS SUBSTANCE OBTAINED FROM PROPYLENE ON SILICA GEL

A. P. Rudenko, D. È. Bodrina, A. A. Balandin, M. F. Rodicheva
1965 SovietRxiv: ru-196501.88101

This study examines whether carbonaceous deposits formed by propylene polycondensation on silica gel can alkylate benzene, and whether such behavior supports a demethanation stage in carbide formation. Flow experiments at 500 to 900°C compared propylene, benzene, their mixtures, and benzene passed o…

Tests, Unbiased Estimators, and Cotest Ideals

Academician Yu. V. LINNIK
1965 SovietRxiv: ru-196501.88082

The paper develops an analytic framework for similar randomized tests and unbiased estimation by treating precotests as functions whose expectations vanish on the null hypothesis. For dominated statistical families with holomorphic expectation images, it associates the null hypothesis with a cotest …

Specific Properties of Oxidation Catalysts and Their Bond Energies with Oxygen, Hydrogen, and Carbon Atoms

Unknown
1965 SovietRxiv: ru-196501.88064

This paper applies the energetic form of multiplet theory to oxidation catalysis, relating catalyst specificity to bond energies between the catalyst and oxygen, hydrogen, and carbon atoms or groups in reacting organic molecules. Using literature activation energies for oxygen isotope exchange, hydr…

Detonation burning of heterogeneous systems

V. E. GORDEEV, V. F. KOMOV, Ya. K. TROSHIN
1965 SovietRxiv: ru-196501.88054

This paper investigates detonation combustion in heterogeneous systems consisting of thin petroleum oil films on tube walls in gaseous oxygen at atmospheric pressure. Using high-speed photographic recording in steel tubes, the authors examine initiation by strong sources and by transfer from a prefo…

FREQUENCY CONDITIONS FOR ABSOLUTE STABILITY OF PULSE AUTOMATIC SYSTEMS WITH ONE NONLINEAR BLOCK

Yu. A. DMITRIEV
1965 SovietRxiv: ru-196501.87872

This paper studies absolute stability of discrete pulse automatic control systems with finitely many degrees of freedom and a single scalar nonlinear block, represented by a nonlinear difference equation. Under sector and slope restrictions on the nonlinearity and spectral assumptions on the linear …

Primary Ideals in Noncommutative Rings

V. A. Andrunakievich, Yu. M. Ryabukhin
1965 SovietRxiv: ru-196501.87808

This paper studies generalizations of primary ideals in associative noncommutative rings satisfying the maximal condition for two-sided ideals. It introduces an abstract notion of s-primarity defined through annihilators modulo an ideal, compares it with existing notions such as primary, simple, irr…

SYNTHESIS OF GARNETS WITH LARGE CATIONS

B. V. Mill'
1965 SovietRxiv: ru-196501.87712

This study examines the crystal-chemical limits for forming garnets that contain large cations in dodecahedral, octahedral, and tetrahedral positions. Guided by ionic-radius considerations, stoichiometric oxide and carbonate mixtures were fired in air and selected compositions were also tested hydro…

Equations of Mathematical Physics

G. N. Polozhii. EQUATIONS OF MATHEMATICAL PHYSICS.
1965 SovietRxiv: ru-196501.87622

This review examines G. N. Polozhii’s textbook on equations of mathematical physics, emphasizing its nontraditional organization and its systematic use of Green’s functions, delta-type source functions, potentials, and integral transformations across elliptic, parabolic, and hyperbolic equations. It…

On the Nonadditive Entropy of a Thermally Inhomogeneous System

V. S. Imshennik
1965 SovietRxiv: ru-196501.87388

This paper examines whether Carathéodory’s principle and the associated integrating factor for heat can be applied to thermally inhomogeneous systems, a question linked to claims that such systems possess nonadditive entropy. Using an ideal two-temperature electron-ion plasma as an example, the auth…

On the spontaneous transition from combustion to detonation in pure acetylene at low pressures

S. M. Kogarko, A. G. Lyamin, V. A. Mikhailov
1965 SovietRxiv: ru-196501.87366

This paper investigates whether combustion in pure acetylene can spontaneously transition to detonation at initial pressures near and below the previously accepted lower limit. Experiments were conducted in long steel tubes using weak spark initiation, thermocouple records of reaction-zone motion, a…

Low-Temperature Polarization Spectra of Porphine and Its Derivatives

Academician of the Academy of Sciences of the BSSR A. N. SEVCHENKO, K. N. SOLOV'EV,
1965 SovietRxiv: ru-196501.87212

This paper examines low-temperature fluorescence polarization spectra of porphine, chlorin, and octaethylporphine in frozen glassy solutions, with the aim of testing assignments of electronic-vibrational bands and the symmetry of active normal vibrations in porphyrin molecules. Using monochromatic e…

On the Existence of the $\mathrm{H}_5^+$ Ion in the Positive Column of a Hydrogen Glow Discharge at Elevated Pressure

Academician of the Academy of Sciences of the Uzbek SSR S. V. Starodubtsev, V. M. Knopov, S. L. Pozharov, I. G. Chernov
1965 SovietRxiv: ru-196501.87208

This paper reports a mass-spectrometric study of ions sampled from the positive column of a hydrogen glow discharge at elevated pressures. Using an anode sampling aperture and carefully cleaned apparatus, the authors detected the usual hydrogen ions together with a mass 5 ion assigned to the molecul…

On the Theory of Weighted Classes of Differentiable Functions of Several Variables and Its Applications to Boundary Value Problems for Elliptic Equations

Unknown
1965 SovietRxiv: ru-196501.86775

This paper studies weighted Sobolev type classes of differentiable functions of several variables in exterior domains, with weights of the form involving a radial factor satisfying an integral growth condition. It proves embedding theorems for these classes, extending earlier results for particular …

On the role of $\pi$-complexes in the coordination-ionic polymerization of butadiene

B. D. BABITSKII, V. A. KORMER, M. I. LOBACH, N. N. CHESNOKOVA
1965 SovietRxiv: ru-196501.86766

This paper examines the role of transition metal pi complexes in the stereospecific polymerization of butadiene, contrasting these systems with coordination anionic catalysts that require metal carbon sigma bonds. Using catalytic systems based on cobalt, nickel, vanadium, molybdenum, and related Lew…

Melting curve of selenium up to 45,000 kg/cm $^2$

E. Yu. TONKOV, I. E. PAUKOV
1965 SovietRxiv: ru-196501.86669

The study investigates the melting curve of high-purity selenium at pressures from 13,500 to 45,500 kg/cm², extending earlier measurements to determine whether behavior analogous to tellurium appears at higher pressure. Experiments were conducted using a six-punch high-pressure apparatus calibrated …

Limiting Cauchy Problem for First- and Second-Order Differential Equations with Unbounded Nonlinear Potential Operators

Ya. D. Mamedov
1965 SovietRxiv: ru-196501.86519

This paper studies limiting Cauchy problems at infinity for first and second order evolution equations in a Hilbert space with time dependent unbounded positive self-adjoint operators and nonlinear potential terms. Using Lyapunov-type energy functionals built from the operator square root and the no…

On Determining Cloud Cover Boundaries

Unknown
1965 SovietRxiv: ru-196501.86513

This paper formulates the determination of cloud boundaries in lee-side flow over an obstacle as a coupled free-boundary problem, rather than as a post-processing step applied to an everywhere adiabatic motion. It derives governing equations for steady two-dimensional incompressible flow with adiaba…

GENERALIZED EXTENSIONS OF UNBOUNDED OPERATORS

È. R. Tsekanovskii
1965 SovietRxiv: ru-196501.86414

The paper develops a framework for generalized extensions of unbounded operators using a Hilbert scale \(H_+ \subseteq H_0 \subseteq H_-\), where \(H_-\) is defined as the space of generalized elements dual to \(H_+\). For bounded operators from \(H_+\) to \(H_-\), it introduces a generalized adjoin…

Study of the EPR Spectrum of a Rarefied Hydrogen Sulfide Flame

Yu. M. Gershenzon, Academician of the Academy of Sciences of the Armenian SSR A. B. Nalbandyan,
1965 SovietRxiv: ru-196501.86303

This study applies electron paramagnetic resonance radiospectroscopy to a rarefied hydrogen sulfide flame in order to identify transient atoms and radicals relevant to the still uncertain oxidation mechanism of hydrogen sulfide. Using heated resonator and reactor arrangements that allowed the flame …

TRANSMISSION OF SUBSTITUENT EFFECTS

V. I. Zdanovich, Z. N. Parnes, D. N. Kursanov
1965 SovietRxiv: ru-196501.86277

This study examines whether substituent effects are transmitted with equal efficiency in cis and trans cinnamic acids. Dissociation constants of substituted cis and trans cinnamic acids, and of corresponding benzoic acids, were measured potentiometrically in 49% ethanol at 25 °C and analyzed using H…

ON THE ELEMENTARY THEORY OF CLASSICAL LIE ALGEBRAS

M. A. Taitslin
1965 SovietRxiv: ru-196501.86205

This note studies decision problems for elementary first-order theories of finite-dimensional Lie algebras in the language with addition and multiplication. Using structural facts about complex simple Lie algebras, root decompositions, and an effective interpretation of finite structures with two eq…

ON THE METHOD OF AVERAGING

A. N. Filatov
1965 SovietRxiv: ru-196501.86174

This paper extends the Bogolyubov averaging method from ordinary differential equations to systems of integro-differential equations with a small parameter and memory integral. Under boundedness, Lipschitz, and uniform averaging assumptions on the functions defining the system, it constructs an aver…

OPTICAL ANISOTROPY OF SEMIRIGID CHAIN MOLECULES

V. N. Tsvetkov
1965 SovietRxiv: ru-196501.86128

The paper examines how the optical anisotropy of semirigid chain molecules depends on chain flexibility and molecular weight, with implications for interpreting flow birefringence in polymer solutions. Using Langevin chain statistics together with Porod’s expression for the end-to-end distance of a …

The symmetry of elementary particles in the uniform group theory

Yu. V. Novozhilov, I. A. Terent'ev
1965 SovietRxiv: ru-196501.86109

This paper examines an extension of the Poincare group based on the nonuniform group P(SU6), proposed as a framework in which space-time and internal symmetry variables are treated jointly rather than as a direct product. The authors derive the commutation structure, construct the determinant invari…

STUDY OF THE STRUCTURE OF SOLUTIONS OF CRYSTALLIZING POLYMERS

V. A. Kargin, N. F. Bakeev, S. Kh. Fakirov, N. I. Nikanorova
1965 SovietRxiv: ru-196501.86081

This study examines whether supramolecular ordering in solutions of crystallizing polymers affects crystallization kinetics, using the induction period as an indicator of solution structure. A depolarized light method with crossed polarizers was applied to dilute fractionated linear polyethylene sol…

Total Synthesis of the Glyceride Base of Vegetable Oils and Animal Fats

V. N. Klykov, E. N. Zvonkova, G. G. Zapisochnaya, I. K. Sarycheva,
1965 SovietRxiv: ru-196501.85830

This paper reports synthetic approaches to the glyceride basis of vegetable oils and animal fats, focusing on higher fatty acids and triglyceride mixtures that reproduce natural lipid compositions. The authors describe syntheses of saturated and unsaturated fatty acids, preparation of more than 80 t…

On the Long-Term Strength of Highly Elastic Polymers

Unknown
1965 SovietRxiv: ru-196501.85750

The paper examines the applicability of Zhurkov’s fluctuation theory of strength to the long-term rupture of highly elastic polymers, where rubber lifetime under tension can show a complex, nonmonotonic dependence on deformation. It argues that the stress-concentration parameter should be treated as…

Coulomb Interaction of Electrons in a Thin Film

Unknown
1965 SovietRxiv: ru-196501.85721

This paper examines how Coulomb interactions affect the spectrum of free charge carriers in an idealized thin semiconductor film. The film is modeled as a plane dielectric layer with an electron gas confined by an infinite one-dimensional potential well, and the limiting case of a very thin, degener…

The Role of $n\to\pi^*$ Transitions in the Ionization and Decay Processes of Compounds

D. N. SHIGORIN, V. K. POTAPOV
1965 SovietRxiv: ru-196501.85678

This paper examines the role of electronic n to pi* transitions in ionization and fragmentation processes of molecules containing carbonyl chromophores, with particular attention to anthraquinone and fluorenone. Ionization curves and ion appearance potentials were measured by electron impact mass sp…

Application of the PMR Method to the Study of the Nature of the Titanium-Cyclopentadienyl Bond in Mono- and Dicyclopentadienyl Titanium Derivatives

Academician A. N. NESMEYANOV, E. I. FEDIN, P. V. PETROVSKII,
1965 SovietRxiv: ru-196501.85463

High-resolution proton NMR is applied to mono- and dicyclopentadienyl titanium derivatives to examine how substituents on titanium affect the nature of the titanium, cyclopentadienyl bond. The study compares chemical shifts for ring and alkoxy protons across chloro, alkoxy, acyloxy, and substituted …

INTRODUCTION OF AROMATIC AND HETEROCYCLIC RADICALS INTO FERROCENE. THE REACTION OF BROMOFERROCENE WITH ORGANOMAGNESIUM COMPOUNDS

A. N. Nesmeyanov, V. A. Sazonova, V. N. Drozd
1965 SovietRxiv: ru-196501.85379

The study examines the substitution of bromine in bromoferrocene by aromatic and heterocyclic groups through reactions with organomagnesium compounds in the presence of cuprous bromide and copper. Under nitrogen and heating after removal of ether, aryl and heteroaryl Grignard reagents gave phenylfer…