Showing 50 of 25357 papers

Study of the Interaction of Antimony(III) Chlorides and Bromides with Alkali Elements of Similar Properties in Solutions of the Corresponding Hydrohalic Acids

G. V. Zimina, V. E. Plyushchev, S. B. Stepina
1965 SovietRxiv: ru-196501.78448

This study examines heterogeneous equilibria in quaternary systems containing potassium, rubidium, or cesium halides with antimony(III) chlorides or bromides in aqueous hydrochloric or hydrobromic acid. Solubilities were measured isothermally at 25 degrees C at several fixed acid concentrations, and…

On the Approximation of Periodic Functions in the Mean

Unknown
1965 SovietRxiv: ru-196501.78412

This paper studies analogues in \(L_p\) metrics of Favard-type inequalities relating the approximation of a periodic function by Fourier partial sums or trigonometric polynomials to the corresponding approximation of its derivative. It proves an \(L_p\) estimate for the deviation of a function from …

ON THE THEORY OF OPERATORS OF THE FORM $\dfrac{d}{dt}-A$

A. A. Dezin
1965 SovietRxiv: ru-196501.78357

This paper studies boundary value problems for operators of the form du/dt minus A in a Hilbert space, where A is an unbounded normal operator, with emphasis on constant coefficient differential operators on the torus. It analyzes scalar boundary conditions relating the values at t = 0 and t = a, es…

On the Summability of Fourier Series in Eigenfunctions of the Laplace Operator by Cesaro, Riesz, and Poisson–Abel Means

Unknown
1965 SovietRxiv: ru-196501.78327

This paper studies almost everywhere summability of Fourier series in eigenfunctions of the Laplace operator on an arbitrary multidimensional domain under boundary conditions yielding a complete orthonormal eigenfunction system. It proves that for every function in \(L_2(g)\), the eigenfunction expa…

Structure of Schiff Bases of $\mathrm{N}$-arylpyrrolines

Corresponding Member of the Academy of Sciences of the USSR A. P. Terent’ev,
1965 SovietRxiv: ru-196501.78307

This study examines the products formed in the reaction of alpha-(2-chloroethyl)-beta-chlorocrotonaldehyde with hydrochlorides of aromatic amines, focusing on the structure of Schiff bases of N-arylpyrrolines. The authors prepared a series of derivatives, separated principal and minor products by ch…

On the Causes of the Increased Yield of Phenol during the Radiolysis of Sulfuric Acid Aqueous Benzene Solutions Containing Ferrous Ions and Oxygen

Unknown
1965 SovietRxiv: ru-196501.78027

This study examines why phenol yields increase during radiolysis of aerated sulfuric acid aqueous benzene solutions containing ferrous ions. Using cobalt-60 gamma radiation and 0.9 MeV electrons, the authors measured the formation of ferric ions, phenol, and muconic dialdehyde as functions of ferrou…

THERMODYNAMICS OF HYDRATION OF ION EXCHANGERS

E. F. Nekryach, O. D. Kurilenko, A. V. Dumanskii
1965 SovietRxiv: ru-196501.78025

This study examines the thermodynamics of hydration of KU-2 sulfonic cation-exchange resin in H, K, Na, and Ca forms, using samples with 4% and 20% divinylbenzene cross-linking. Water vapor sorption isotherms, heats of wetting, and derived thermodynamic functions were used to estimate monolayer capa…

On the Behavior of Solutions to the Equations of Hydrodynamics as the Reynolds Number Passes Through a Critical Value

Unknown
1965 SovietRxiv: ru-196501.78021

This paper studies the behavior of solutions to the incompressible Navier-Stokes equations in a bounded domain as viscosity, equivalently the Reynolds number, passes through a critical value. The problem is reduced by expansion in eigenfunctions of the Stokes operator to an infinite system of ordina…

KINETICS OF REACTIONS IN MACROMOLECULES.

A. D. Litmanovich
1965 SovietRxiv: ru-196501.77935

This paper develops a simplified kinetic description for irreversible reactions occurring in polymer chains when the rate constant for a unit depends on whether zero, one, or two neighboring units have already reacted. Using a sequence-based representation of copolymer chain structure, the author re…

Properties of Equimorphisms at Infinity

Unknown
1965 SovietRxiv: ru-196501.77910

This note studies how equi-morphisms of hyperbolic spaces act on the sphere at infinity, especially with respect to tangency in the spherical Poincaré model. It proves that tangency of a curve in hyperbolic space to the sphere at infinity is invariant under equi-morphisms, using a characterization b…

Addendum to My 1933 Paper on the Correct Orientation of a Crystal

Corresponding Member of the Academy of Sciences of the USSR B. N. DELONE
1965 SovietRxiv: ru-196501.77705

This addendum clarifies Delone’s method for setting a crystal lattice by giving explicit rules for expressing the vectors of a crystallographic Bravais frame in terms of vectors obtained from an initial fundamental frame through Selling reduction. It specifies corrections to the reduction procedure,…

Study of the Process of Stereospecific Polymerization of Butadiene in an Aqueous Medium in the Presence of Rhodium Chloride by the Tracer Atom Method

B. D. Babitskii, V. A. Kormer, I. Ya. Poddubnyi,
1965 SovietRxiv: ru-196501.77627

This study examines the role of water in the stereospecific polymerization of butadiene in aqueous emulsion initiated by rhodium chloride, a reaction known to yield highly trans-1,4-polybutadiene but with an uncertain mechanism. Using tritiated water as an isotopic label, the authors measured radioa…

Application of a Quantum Paramagnetic Traveling-Wave Amplifier for Radio Astronomy Studies at a Wavelength of 8 cm

L. I. MATVEENKO, G. S. MISEZHNIKOV, M. M. MUKHINA,
1965 SovietRxiv: ru-196501.77544

This paper describes the use of a traveling-wave quantum paramagnetic amplifier in an 8 cm radio-astronomical radiometer to improve sensitivity at centimeter wavelengths. The authors present the amplifier and radiometer design, including a ruby active medium operated at liquid-helium temperature, me…

ON ONE CLASS OF POST CALCULI

M. I. Kratko
1965 SovietRxiv: ru-196501.77206

This note studies a class of Post calculi defined by productions of types I and IIa, motivated by their relation to formal languages, finite automata, and a conjecture of Büchi. After recalling definitions and known results on normal calculi and calculi with type Ia productions, it proves that every…

On the Mechanism of Inhibition of the Ethylene Polymerization Reaction over Chromium Oxide Catalysts

Yu. I. PECHERSKAYA, V. B. KAZANSKII
1965 SovietRxiv: ru-196501.77085

This study examines how common inhibitors affect ethylene polymerization on supported chromium oxide catalysts, focusing on pentavalent chromium ions identified as active centers. Using electron paramagnetic resonance spectra of activated chromaluminosilicate catalysts treated with water, butanol, b…

On an Effect Accompanying Nuclear Reactions in Single Crystals and Its Use in Various Physical Studies

Unknown
1965 SovietRxiv: ru-196501.77045

This paper examines an effect observed when nuclear reactions or charged-particle scattering occur in single-crystal targets, where the ordered arrangement of nuclei produces local distortions in angular distributions near crystallographic axes. The author develops estimates for the angular size of …

Local Structure of Darboux Surfaces

I. Kh. Sabitov
1965 SovietRxiv: ru-196501.77021

This note studies the local extrinsic geometry of the Darboux surfaces associated with an infinitesimal bending of a positively curved surface of class \(C^{n,\alpha}\). Using local coordinates, properties of the bending and rotation fields, and Stoilow’s theory of interior mappings, it analyzes the…

Decomposition of a Representation of a Reductive Lie Algebra into Representations of Its Regular Reductive Subalgebras of Maximal Rank

V. B. Mandelzweig
1965 SovietRxiv: ru-196501.76997

This paper studies the branching of an irreducible finite-dimensional representation of a complex reductive Lie algebra when restricted to a regular reductive subalgebra of the same rank. Using character identities, Kostant’s weight multiplicity formula, and finite difference operators applied to pa…

THERMAL ANALYSIS OF THE SODIUM BOROHYDRIDE—HYDRAZINE SYSTEM

G. A. EGORENKO, D. S. STASINEVICH, I. S. ANTONOV
1965 SovietRxiv: ru-196501.76507

Phase equilibria in the sodium borohydride, hydrazine system were investigated by differential thermal analysis over the range from minus 120 to 80 degrees C and from 0 to 85.5 wt.% sodium borohydride. The study identifies four solvated compounds, NaBH4·2N2H4, 2NaBH4·N2H4, NaBH4·N2H4, and NaBH4·6N2H…

Electron diffraction study of the molecular structure of trivalent nitrogen compounds. $\mathrm{N}$-dimethylaniline

Unknown
1965 SovietRxiv: ru-196501.76499

This study examines the vapor-phase molecular structure of N-dimethylaniline, with particular attention to the configuration of the trivalent nitrogen atom and the rotational arrangement of the dimethylamino group relative to the phenyl ring. Electron diffraction patterns were recorded at two camera…

Synthesis of $\mathrm{C}$-substituted unsaturated ketoses using the Wittig reaction

Yu. A. ZHDANOV, G. N. DOROFEENKO, L. A. UZLOVA
1965 SovietRxiv: ru-196501.76379

This paper explores the use of the Wittig reaction as a route to C-substituted carbohydrate derivatives that are difficult to obtain by organomagnesium methods, especially when functionalized aglycone fragments are required. Acetylated aldehydo forms of D-glucose, D-galactose, and D-mannose were con…

On the Convergence of Positive Functionals and Operators

M. A. KRASNOSEL′SKII, V. S. KLIMOV, E. A. LIFSHITS
1965 SovietRxiv: ru-196501.76190

This paper studies convergence criteria for sequences of positive linear functionals and operators in Banach spaces ordered by a cone, extending Korovkin-type results beyond spaces of continuous functions. It introduces smoothness points of a cone and saturated, uniformly saturated, and completely s…

ON THE MECHANISM OF RECOMBINATION OF RADICALS OF IRRADIATED PROTEINS IN THE PRESENCE OF OXYGEN

I. I. Sapezhinskii, N. M. Emanuel'
1965 SovietRxiv: ru-196501.76150

This paper examines the mechanism by which radicals in irradiated proteins recombine in the presence of oxygen, with particular attention to whether the process includes chain oxidative recombination rather than only direct peroxide radical termination. Casein and bovine serum albumin were gamma irr…

STIMULATED CURRENTS AND ELECTROLUMINESCENCE IN SUBLIMATED ZINC SULFIDE FILMS AT 77° K

A. G. Gol'dman, G. A. Zholkevich, N. P. Lazar
1965 SovietRxiv: ru-196501.76102

This paper reports measurements of stimulated conductivity and electroluminescence in sandwich cells made from sublimated zinc sulfide films at 77 K. The authors examine current-voltage and brightness characteristics under high applied voltage and after ultraviolet irradiation, finding that above a …

An experimental investigation of turbulent flow of electroconductive fluid in the pipe in parallel magnetic field

Unknown
1965 SovietRxiv: ru-196501.75988

This paper reports an experimental study of turbulent flow of an electrically conducting liquid in a pipe subjected to a longitudinal magnetic field, a configuration in which the field primarily affects velocity fluctuations through Joule dissipation. Using a gallium loop with stainless steel pipes …

Asymptotics of Classical Green’s Functions in the “Viscous Hydrodynamic Approximation”

B. I. Sadovnikov
1965 SovietRxiv: ru-196501.75922

This paper studies the asymptotic behavior of classical Green functions for a gas of elastic spheres, starting from a previously derived closed kinetic equation for the basic Green function. It first treats a short path regime by successive approximations, obtaining an explicit damped form and an as…

Polymorphism in Organic Molecular Crystals

Yu. V. Mnyukh, M. A. Tseneva
1965 SovietRxiv: ru-196501.75812

Polymorphic transformations in octahydroanthracene, orcin, and carbon tetrabromide are examined to determine whether the mechanism previously observed in n-dichlorobenzene is more general for organic molecular crystals. Using Laue X-ray photography and optical polarizing microscopy under controlled …

A new hysteresis effect in silicon $p$ – $n$ junctions

Academician of the Academy of Sciences of the Uzbek SSR É. I. ADIROVICH, P. I. KNIGIN, Yu. S. KOROLEV
1965 SovietRxiv: ru-196501.75742

This paper reports a hysteresis effect observed in the reverse current-voltage characteristics of diffusion silicon p-n junction photodiodes at sufficiently large voltages, both in darkness and under illumination. The authors describe steady-state and pulsed measurements at different temperatures an…

On Deformations of Fibered Spaces

Unknown
1965 SovietRxiv: ru-196501.75720

This paper constructs a complete holomorphic family of deformations of a holomorphic principal fiber bundle with compact base and complex structure group. Using differential forms with values in the adjoint bundle, the deformation problem is expressed through the integrability equation for a form of…

Investigation of the basicity of some heteropoly compounds by infrared spectroscopy

Academician Vikt. I. SPITSYN, S. A. BAKHCHISARAITSEVA, V. Ya. KABANOV
1965 SovietRxiv: ru-196501.75607

This study examines the basicity of phosphotungstic and silicotungstic heteropoly compounds by infrared spectroscopy, with particular attention to spectral evidence for oxonium ions and strongly hydrogen-bonded water. The authors prepared several acids and sodium or barium salts, recorded spectra in…

Analysis of the Experimental Activation Entropy of Carbon Oxide Hydrogenation Processes over a Nickel Catalyst

G. I. Golodets, V. M. Vlasenko, G. E. Yuzefovich
1965 SovietRxiv: ru-196501.75563

This paper analyzes the experimental entropy of activation for hydrogenation of carbon monoxide and carbon dioxide to methane on a nickel containing catalyst under conditions where side processes are negligible. Using transition state theory and reported kinetic data, the authors compare activation …

ON THE DEEP COLORATION OF THE ANIONIC FORMS OF CYCLOPENTENE-4-DIONES-1,3 AND INDANDIONES-1,3

È. Ya. Gren, G. Ya. Vanag
1965 SovietRxiv: ru-196501.75491

This paper examines why anionic forms of cyclopentene-4-dione-1,3 and indandione-1,3 derivatives show unusually deep coloration and long-wavelength absorption compared with typical beta-diketone anions. Using LCAO molecular orbital calculations in the Hückel approximation, the authors compare transi…