Showing 50 of 25357 papers

Isotope-Exchange Sorption of Tritium from Aqueous Solutions under Dynamic Conditions

V. V. Rachinskii, L. A. Lenskii
1965 SovietRxiv: ru-196501.13086

This paper develops a sorption dynamics treatment of tritium isotope exchange during filtration of tritiated water through porous hydrogen-containing media, considering water-saturated, dry, and partially saturated columns. Using equilibrium front-motion equations and isotope distribution coefficien…

Density theorem for finite functions in weighted classes

Unknown
1965 SovietRxiv: ru-196501.12998

The paper proves a density theorem for compactly supported smooth functions in weighted Sobolev-type classes on bounded and unbounded domains with simple boundary structure in the sense of Sobolev. It formulates boundary and growth conditions on the weights, including behavior near lower-dimensional…

X-RAY SPECTRAL DETERMINATION OF ATOMIC CHARGES IN NICKELOCENE AND NICKELOCINIUM

S. S. Batsanov, I. A. Ovsyannikova
1965 SovietRxiv: ru-196501.12918

This study addresses conflicting theoretical predictions for the charge on nickel in nickelocinium, and clarifies earlier X-ray spectral results for nickelocene. Nickel K-edge absorption spectra of nickelocene and nickelocinium triphenylborate were measured with high resolution, corrected for instru…

Nuclear magnetic resonance line shape of isolated groups of nuclei and intermolecular interaction in solids

Unknown
1965 SovietRxiv: ru-196501.12908

This paper examines how intermolecular interactions affect the nuclear magnetic resonance line shape of reorienting methyl groups in solids, where spectra of isolated nuclear groups are broadened by interactions between groups. Using measurements of the second and fourth moments and temperature-depe…

Study of Alkaloids of Corydalis gortschakovii and Corydalis pseudoadunca

Corresponding Member of the Academy of Sciences of the USSR S. Yu. Yunusov
1965 SovietRxiv: ru-196501.12849

This study examines the alkaloid composition of Corydalis gortschakovii and Corydalis pseudoadunca collected in the Zaalai Range. Total alkaloids were obtained by chloroform extraction and separated into phenolic and nonphenolic fractions, followed by crystallization, derivative formation, spectral …

Autocorrelation of Thermal Fluctuations in a Double Dilute Solution near Its Critical Point

I. R. Krichevskii, L. A. Rott, Yu. V. Tsekhanskaya
1965 SovietRxiv: ru-196501.12835

This paper examines thermal fluctuations and Brownian motion in binary dilute solutions near the liquid gas critical point, with emphasis on the autocorrelation and slow relaxation of composition fluctuations. Using Gibbs critical point conditions and Onsager’s interpretation of diffusion as driven …

Electron diffraction study of the molecular structure of $\Delta^3$-carene oxide

Academician B. A. Arbuzov, V. A. Naumov, L. F. Shpatruk
1965 SovietRxiv: ru-196501.12628

This study examines the molecular structures of the alpha and beta stereoisomers of Delta-3-carene oxide, whose interconversion requires rupture of a carbon-oxygen bond. Vapor electron diffraction patterns were measured and interpreted using radial distribution analysis and successive approximations…

On Ponomarev's Theory of Absolutes of Topological Spaces

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1965 SovietRxiv: ru-196501.12498

This note reformulates Ponomarev’s spectral theory of absolutes for paracompact spaces by giving a direct definition of “absolute” zero-dimensional projection spectra. It proves that every Ponomarev absolute is the space of a unique absolute spectrum, namely the maximal spectrum of that absolute, an…

Interaction of Dialkylamides of Dialkylphosphorous Acid with Aldehydes

V. P. EVDAKOV, L. I. MIZRAKH, L. Yu. SANDALOVA
1965 SovietRxiv: ru-196501.12326

The study examines the reaction of dialkylamides of dialkylphosphorous acid with aldehydes, a system that could plausibly yield several types of phosphorus-containing products by analogy with known reactions of phosphorous acid derivatives. Heating equimolar amidophosphites and aldehydes gave nitrog…

Surface and Intraglobular Silanol Groups of Silica Gels Obtained by the Hydrothermal Method

V. M. CHERTOV, D. B. DZHAMBAEVA, A. S. PLACHINDA, I. E. NEIMARK
1965 SovietRxiv: ru-196501.12110

This study examines the concentration of surface and intraglobular silanol groups in silica xerogels prepared from hydrogels subjected to hydrothermal treatment at varied temperatures and durations. Total structural water was determined by high temperature calcination, while surface hydroxyls were m…

On the temperature jump in polyatomic gases

Unknown
1965 SovietRxiv: ru-196501.12006

The paper examines temperature jump at a solid wall in polyatomic gases when different molecular degrees of freedom have unequal accommodation at the surface and slow internal relaxation. It divides the near-wall region into a kinetic layer and a wider relaxation zone, formulates separate heat-trans…

On the Existence and Uniqueness of Solutions to Certain Boundary Value Problems for Degenerate Second-Order Elliptic Equations

Unknown
1965 SovietRxiv: ru-196501.11967

This paper studies existence and uniqueness for boundary-value problems for second-order elliptic equations that degenerate on part of the boundary, with boundary conditions imposed only on the nondegenerate portion or supplemented by suitable nonhomogeneous data. Extending a method of Schechter, th…

INFRARED SPECTRA OF CARBON MONOXIDE ADSORBED ON RUTHENIUM, RHODIUM, AND PALLADIUM OVER A WIDE TEMPERATURE RANGE

Unknown
1965 SovietRxiv: ru-196501.11963

Infrared spectra were measured for carbon monoxide adsorbed on ruthenium, rhodium, and palladium between minus 150 and 120 degrees C at pressures near 10^-5 mm Hg and 1.3 mm Hg, in order to examine the proposed formation of both linear and bridged surface complexes on Group 8 metals. The spectra sho…

Flat wing in a hypersonic flow

Corresponding Member of the Academy of Sciences of the USSR G. G. CHERNYI
1965 SovietRxiv: ru-196501.11844

This paper develops an approximate formulation for hypersonic ideal-gas flow over the windward side of a flat wing at angle of attack. The governing conservation equations in the layer between the wing and the shock are transformed using a Legendre polynomial expansion across the layer, yielding a h…

On Nonlinear Equations of the First Kind

Corresponding Member of the Academy of Sciences of the USSR A. N. TIKHONOV
1965 SovietRxiv: ru-196501.11841

The paper develops regularization methods for nonlinear equations of the first kind with a continuous one-to-one operator between metric spaces, using a smoothing functional that combines data misfit with a quadratic norm penalty. Under compact embedding and Hilbert space convexity assumptions, it p…

Statistical Operator for Nonstationary Processes

Unknown
1965 SovietRxiv: ru-196501.11743

The paper constructs a statistical operator for nonstationary nonequilibrium processes by extending a previous local-integral-of-motion method. Using conservation laws for energy, particle number, and momentum, it defines time-dependent operators governed by slowly varying thermodynamic parameters a…

\(C^{1,\alpha}\)-Isometric Immersions of Riemannian Spaces

Unknown
1965 SovietRxiv: ru-196501.11575

This paper studies local isometric immersions of analytic Riemannian spaces into codimension one Euclidean space with prescribed Hölder regularity, focusing on whether classes \(C^{1,\alpha}\) can be universal beyond the analytic case. It formulates universality results and obstructions: Nash and Ku…

A PRIORI ESTIMATES AND SOLVABILITY OF GENERAL BOUNDARY VALUE PROBLEMS FOR GENERAL ELLIPTIC SYSTEMS WITH DISCONTINUOUS COEFFICIENTS

N. V. Zhitarashu
1965 SovietRxiv: ru-196501.11332

This paper studies general boundary value and conjugation problems for Douglis, Nirenberg elliptic systems with discontinuous coefficients on a bounded domain divided by an internal surface. It formulates the relevant Sobolev, Hölder, and Slobodetskii spaces, defines a joint covering condition combi…

Reactivity of Ambident Anions. Alkylation of Sodium Derivatives of Acetoacetic Ester and Acetylacetone with Triethyloxonium Borofluoride

T. A. MASTRYUKOVA, A. E. SHILOV, V. V. ABALAEVA, E. E. KUGUCHEVA,
1965 SovietRxiv: ru-196501.11223

This study examines how the strongly electrophilic alkylating agent triethyloxonium fluoroborate affects the ambident reactivity of sodium derivatives of acetoacetic ester and acetylacetone. Using ether-phase reactions under heterogeneous conditions, followed by thin-layer chromatography, gas-liquid…

Mössbauer Effect in Tin-Based Solid Solutions

L. A. ALEKSEEV, P. L. GRUZIN
1965 SovietRxiv: ru-196501.11193

This study applies the Mössbauer effect to determine recoil-free gamma absorption by tin-119 nuclei in pure tin and in disordered tin-based solid solutions containing bismuth, indium, cadmium, or antimony. By measuring resonance absorption spectra over 130 to 300 K for absorbers of varying thickness…

Mechanism of Methane Combustion at Elevated Temperatures

Academician of the Academy of Sciences of the Uzbek SSR N. V. Lavrov, I. G. Petrenko
1965 SovietRxiv: ru-196501.11057

This paper examines the mechanism of complete methane combustion at elevated temperatures, focusing on the elementary radical reactions leading to carbon dioxide and water vapor. Building on Semenov’s low-temperature oxidation scheme, the authors propose a high-temperature chain mechanism that inclu…

Local Activation of Anthracene during Paraffin Oxidation Inhibited by Tetracyanoethylene–Anthracene Mixtures

Unknown
1965 SovietRxiv: ru-196501.10932

This study examines the inhibition of thermooxidative processes in paraffin hydrocarbons by mixtures of anthracene and tetracyanoethylene, with attention to charge-transfer complex and adduct formation. Measurements of induction periods during oxidation of kerosene and ceresin at 180 °C showed that …

Catalytic Synthesis of para-Aminostyrene

A. A. ARTAMONOV, Academician A. A. BALANDIN, R. D. BODNARCHUK
1965 SovietRxiv: ru-196501.10873

This study addresses the preparation of para-aminostyrene, an important intermediate for polymers and organic synthesis, by catalytic conversion of para-aminoethylbenzene as an alternative to multistage low-yield methods. Para-aminoethylbenzene was passed over a mixed oxide catalyst at 560 to 640°C …

Parametric Method for Solving Fractional Programming Problems on Analog Computers

1°.** Consider the nonlinear programming problem
1965 SovietRxiv: ru-196501.10835

The paper presents a parametric method for solving a class of fractional programming problems with a convex numerator, positive denominator, convex inequality constraints, linear equalities, and bounded variables. The authors introduce an auxiliary convex function depending on a parameter, whose zer…

SYNTHESIS AND PROPERTIES OF π-ALLYLCARBONYL COMPLEXES OF IRON

A. N. Nesmeyanov, I. I. Kritskaya, È. I. Fedin
1965 SovietRxiv: ru-196501.10486

This paper reports the synthesis and characterization of several pi-allyl iron tricarbonyl complexes containing iodide, bromide, chloride, nitrate, and a 2-bromoallyl ligand, as well as a triphenylphosphine substitution product. The authors prepare these compounds by reactions of allyl halides with …

Photochemical Arylation of Triphenylphosphine with Diaryliodonium Tetrafluoroborates

O. A. Ptitsyna, M. E. Pudeeva, N. A. Belkevich,
1965 SovietRxiv: ru-196501.10335

This paper examines photochemical arylation of triphenylphosphine with diaryliodonium salts as a preparative route to triphenylarylphosphonium tetrafluoroborates. The authors irradiated acetone or methanol solutions of triphenylphosphine and substituted diaryliodonium tetrafluoroborides or chlorides…

THE GIBBS PHENOMENON

1. Introduce the notation:
1965 SovietRxiv: ru-196501.10157

This note studies the occurrence of the Gibbs phenomenon for triangular summation methods of trigonometric Fourier series whose multipliers are approximated by a function of k/n with small perturbations. It proves a lemma giving sufficient conditions in terms of the limiting integral associated with…

Study of organosilicon compounds containing $\mathrm{Si}$ – $\mathrm{Cl}$ and $\mathrm{C}$ – $\mathrm{Cl}$ bonds by nuclear quadrupole resonance

I. P. Biryukov, M. G. Voronkov, G. V. Motsarev,
1965 SovietRxiv: ru-196501.10097

This study applies pulsed nuclear quadrupole resonance at liquid nitrogen temperature to seven chloroalkylchlorosilanes containing both Si-Cl and C-Cl bonds, aiming to relate resonance frequencies to bond polarity and substituent effects. The measured chlorine resonance frequencies show near-linear …

Absorption and EPR Spectra of Quinones Adsorbed from the Gas Phase on the Surface of Oxides

V. Ya. LYUDIN, V. E. KHOLMOGOROV, Academician A. N. TERENIN
1965 SovietRxiv: ru-196501.10004

This study examines whether electron transfer from oxide surfaces to adsorbed quinone molecules can be detected under vacuum conditions. Benzoquinone and anthraquinone vapors were adsorbed on thermally treated ZnO, MgO, BaO, and silica gel, and the resulting species were investigated by diffuse refl…

Study of a Polymer Blend by Radiothermoluminescence

L. Yu. ZLATKEVICH, V. G. NIKOL’SKII, V. G. RAEVSKII
1965 SovietRxiv: ru-196501.09982

This study evaluates radiothermoluminescence as a method for assessing the homogeneity, glass-transition behavior, and practical stability of polymer mixtures. Mixtures of butadiene elastomers SKB and SKD were irradiated at low temperature and analyzed through glow curves during warming, with insuff…

On the Theory of Finite Matrices

Unknown
1965 SovietRxiv: ru-196501.09938

This paper develops comparison estimates for finite complex matrices using elementwise majorization, induced matrix norms, and logarithmic norms. It proves relations between spectral abscissa and the limiting behavior of the spectral radius, extends Perron type comparison arguments to real majorants…