Showing 50 of 25357 papers

Chalcone Glycosides of Licorice – Glycyrrhiza glabra L.

V. I. LITVINENKO
1964 SovietRxiv: ru-196401.90267

This study examines two flavonoid pigments isolated from the roots and rhizomes of licorice, Glycyrrhiza glabra L., designated L-7 and L-8. Using chromatographic isolation, physicochemical characterization, spectral analysis, enzymatic hydrolysis, molecular rotation comparisons, and ultraviolet irra…

On a New Application of the Fixed Point Principle in the Theory of Operators in a Space with an Indefinite Metric

Unknown
1964 SovietRxiv: ru-196401.90137

The paper develops an application of the Schauder-Tikhonov fixed-point theorem to bounded operators on a Hilbert space equipped with an indefinite metric. It proves that, under positivity and compactness assumptions on the off-diagonal part of an operator, there exists an invariant maximal nonnegati…

Binding Energy of Hypertriton in the Case of a Nonlocal Interaction

I. Sh. Vashakidze, G. A. Chilashvili
1964 SovietRxiv: ru-196401.90060

The paper studies the binding energy of hypertritium using a nonlocal factorizable interaction model for the three-body system. Assuming Gell-Mann global symmetry, the authors relate hyperon-nucleon potentials to nucleon-nucleon parameters and formulate coupled integral equations that include possib…

Measurement of the capacitance of a platinum electrode in sodium acetate solutions with additions of methanol and 1,3-butadiene

Unknown
1964 SovietRxiv: ru-196401.90021

This study examines whether electrochemical additive dimerization involving methyl radicals and 1,3-butadiene proceeds homogeneously in solution or through interaction with acceptor molecules adsorbed on a platinum anode. The authors measured polarization behavior and double-layer capacitance from p…

Study in the Field of Mixed Block Polyarylates

Unknown
1964 SovietRxiv: ru-196401.89889

This study examines the modification of polyarylates, high heat resistant aromatic polyesters whose poor solubility and limited elasticity can hinder processing. Mixed block polyarylates were synthesized by polycondensation of aromatic dicarboxylic acid chlorides and diatomic phenols with hydroxyl t…

THE GROUND STATE OF TWO-ELECTRON ATOMS AND IONS

A. M. Ermolaev, G. B. Sochilin
1964 SovietRxiv: ru-196401.89749

This paper develops a variational approach for the nonrelativistic ground states of two-electron atoms and ions that explicitly incorporates the singular behavior of the wave equation near particle collisions, following Fock’s expansion. The authors construct trial functions with logarithmic and pol…

On the Synthesis of Circuits Correcting Contact Opening

Unknown
1964 SovietRxiv: ru-196401.89688

The paper studies the synthesis complexity of contact circuits that remain functionally correct when a fault source causes openings of contacts, a case left open in earlier work on self-correcting circuits for short circuits. Using a modification of Lupanov’s circuit construction, the argument parti…

A Rapid Method for Determining the Number of Carbon and Hydrogen Atoms in Molecules of Gaseous Compounds

I. A. Revel’skii, R. I. Borodulina, T. M. Sovakova, V. G. Klimova
1964 SovietRxiv: ru-196401.89662

This paper presents a rapid gas chromatographic method for determining the number of carbon and hydrogen atoms in molecules of gaseous compounds, including low-boiling and halogen-containing substances for which conventional elemental analysis is difficult. The method uses sequential chromatographic…

Catalytic transformations of cyclododecane in the presence of platinized carbon

E. S. Balenkova, A. Yu. Alybina, T. I. Avdeeva, S. I. Khromov,
1964 SovietRxiv: ru-196401.89514

Cyclododecane was examined as a boundary case between medium and large cyclanes to determine whether it follows the catalytic transformation patterns previously observed for eight- to ten-membered rings. The authors synthesized cyclododecane, passed it over 5% platinized carbon at 300 degrees in hyd…

Variational Method for Unbounded Domains

Unknown
1964 SovietRxiv: ru-196401.89475

This paper develops a variational method for the first boundary-value problem for self-adjoint elliptic equations in unbounded domains, focusing on the half-space and avoiding prior summability restrictions on the boundary data. The argument replaces ordinary lower boundedness of the quadratic funct…

Detection of Free Hydroxyl in a Rarefied Hydrogen Flame by Electron Paramagnetic Resonance

V. P. BALAKHNIN, Yu. M. GERSHENZON, Academician V. N. KONDRAT’EV,
1964 SovietRxiv: ru-196401.89444

This paper reports electron paramagnetic resonance detection of free hydroxyl radicals in a rarefied hydrogen, oxygen flame, motivated by the role of OH, H, and O atoms in chain branching and propagation. A quartz reactor and resonator arrangement was used to place active centers in the microwave el…

Migration of Free Valence in Stabilized Olefin Radicals under the Action of Light

V. I. Tupikov, S. Ya. Pshezhetskii
1964 SovietRxiv: ru-196401.88993

This study examines whether light-induced migration of free valence, previously observed in stabilized polymer radicals, also occurs in radicals formed in ordinary olefin molecules. The authors generated radicals in several n-olefins by gamma irradiation at liquid nitrogen temperature, exposed the s…

FINITE GROUPS WITH DISPERSIVE SECOND MAXIMAL SUBGROUPS

Unknown
1964 SovietRxiv: ru-196401.88968

This paper classifies finite nonsolvable groups in which every second maximal subgroup has an invariant 2-complement, using recent structural results on groups of odd order, groups with dihedral Sylow 2-subgroups, and minimal simple groups. The main theorem shows that such groups are precisely certa…

Polymerization of cis- and trans-piperylene under the influence of coordination catalytic systems

E. N. KROPACHEVA
1964 SovietRxiv: ru-196401.88862

This paper examines the polymerization and copolymerization of cis and trans piperylene with butadiene under coordination catalytic systems based on organoaluminum compounds with cobalt or titanium chlorides. Using chromatographic isomer analysis, labeled butadiene, glass-transition data, and crysta…

On Operators in the Second Quantization Representation

F. A. BEREZIN
1964 SovietRxiv: ru-196401.88844

This paper studies operators in Fock space represented in normal form by creation and annihilation operator distributions satisfying Bose or Fermi canonical relations. It proves that every bounded operator admits such a normal representation, relates this representation to matrix kernels through ass…

The crystal structure of $\mathrm{K}$-fluoroberyllate $\mathrm{K}_2\mathrm{BeF}_4(\mathrm{Ba}_2\mathrm{SiO}_4)$

Table 1
1964 SovietRxiv: ru-196401.88787

This paper reports a single-crystal X-ray determination of the structure of potassium fluoroberyllate, K2BeF4, used as a lightened structural analogue of the cement silicate Ba2SiO4, whose small crystal size had hindered direct study. Rotation photographs and zero-layer scans with Mo K alpha radiati…

Study of the Mechanism of Cyclohexane Dehydrogenation over Holmium Oxide Using Radiocarbon $\mathrm{C}^{14}$

Unknown
1964 SovietRxiv: ru-196401.88740

The study examines the mechanism of cyclohexane dehydrogenation over holmium oxide, with particular attention to whether benzene is formed directly from cyclohexane or consecutively through cyclohexene. Mixtures of cyclohexane and radiocarbon-labeled cyclohexene were passed over holmium oxide at 560…

HOMOGENEOUS CATALYSIS IN THE HETEROLYTIC CHLORINATION OF UNSATURATED COMPOUNDS

Yu. A. SERTUCHEV, Academician of the Academy of Sciences of the Ukrainian SSR E. A. SHILOV
1964 SovietRxiv: ru-196401.88714

This study examines the strong solvent dependence and homogeneous catalysis of heterolytic chlorine addition to unsaturated compounds such as allyl chloride, tolane, and beta-chloroallyl chloride. Kinetic measurements in aprotic and proton-donor media show that chlorine addition is initiated or acce…

Reaction of phosphonitrile chloride trimer with aromatic dioxy compounds

S. M. ZHIVUKHIN, V. V. KIREEV, N. V. AULOVA, L. T. GERASIMENKO
1964 SovietRxiv: ru-196401.88682

This study examines the reaction of phosphonitrile chloride trimer with resorcinol and hydroquinone in a 1:1 molar ratio under varying solvent, temperature, and tertiary amine conditions. Reaction progress was followed by hydrogen chloride determination, while products were characterized by elementa…

Low-energy deuterons and tritons in the photodisintegration of $\mathrm{Li}^6$

Academician of the Academy of Sciences of the Ukrainian SSR A. P. Komar, E. D. Makhnovsky
1964 SovietRxiv: ru-196401.88627

This study examines low-energy charged particles produced in the photodisintegration of lithium-6 irradiated with bremsstrahlung photons up to 35 MeV. Using thick nuclear emulsions in a magnetic-field chamber, the authors identify deuterons, tritons, and protons from track ranges and magnetic deflec…

Transannular Electronic Effects in the Ferrocenyl Nucleus. Dissociation Constants of Substituted Ferrocenecarboxylic Acids

S. P. GUBIN, K. I. GRANDBERG, E. G. PEREVALOVA, Academician A. N. NESMEYANOV
1964 SovietRxiv: ru-196401.88538

This study examines transannular electronic effects in the ferrocene nucleus through potentiometric determination of dissociation constants for heteroannularly substituted ferrocenecarboxylic acids in aqueous ethanol. Correlation of the acid strengths with substituent constants, together with eviden…

Secondary Structure of Nucleoside Diphosphate Sugars. Hydrogenation of Uridine Diphosphate Glucose and Its Synthetic Analogs

Corresponding Member of the Academy of Sciences of the USSR N. K. KOCHETKOV, É. I. BUDOVSKII,
1964 SovietRxiv: ru-196401.88506

This study examines whether nucleoside diphosphate sugars, particularly uridine diphosphate glucose and synthetic analogs, possess a fixed secondary structure stabilized by intramolecular hydrogen bonds. The authors compare the kinetics of catalytic hydrogenation over rhodium on alumina for nucleosi…

Influence of the structure of some nitrobenzene derivatives on the catalytic reduction of the nitro group

A. V. Finkelshtein, Z. M. Kuzmina
1964 SovietRxiv: ru-196401.88497

This study examines how the nature and position of substituents in nitrobenzene derivatives affect catalytic reduction of the nitro group over skeletal nickel. Nitrobenzene and several ortho, meta, and para substituted derivatives were hydrogenated in ethanol at 20 degrees Celsius and atmospheric hy…

Effect of the Cathode Surface State on the Nature of the Electrochemical Reaction

Z. A. SOLOV'EVA, A. T. VAGRAMYAN
1964 SovietRxiv: ru-196401.88444

This paper examines how the surface state of a chromium cathode affects competing electrochemical reactions in chromic acid electrolytes. Using potential oscillograms, product observations, and controlled changes such as pre-immersion, variation of trivalent chromium and sulfuric acid content, and m…

On the Theory of Photoconductivity in Thin Semiconductor Layers

Academician of the Academy of Sciences of the Uzbek SSR É. I. ADIROVICH
1964 SovietRxiv: ru-196401.88416

The paper develops a theoretical treatment of photoconductivity in thin semiconductor layers under high illumination, where quasineutral bipolar diffusion applies and recombination occurs both through local centers and directly between bands. By reducing the governing diffusion and recombination equ…

Atmospheric Processes as a Mechanism of the Influence of Solar Activity on Tectonic Phenomena

A. D. SYTINSKII
1964 SovietRxiv: ru-196401.88264

This paper examines a proposed mechanism linking solar activity, atmospheric circulation, variations in the Earth’s angular velocity, and seismic phenomena. Building on earlier statistical work, it argues that corpuscular solar streams may alter planetary atmospheric processes, thereby changing atmo…

Some Features of Infrared Absorption Spectra of Vanadyl Compounds with Carboxylic Acids

V. T. KALINNIKOV, V. V. ZELENTSOV, M. N. VOLKOV, S. M. SHOSTAKOVSKII
1964 SovietRxiv: ru-196401.87962

This paper examines infrared absorption spectra of vanadyl carboxylates, including formate, benzoate, iodobenzoate, acetate homologs, and chloroacetate derivatives, in relation to their structural and magnetic properties. Comparing antisymmetric carboxylate stretching frequencies and vanadyl stretch…

Reaction of ester amides and ester chloroanhyd

Unknown
1964 SovietRxiv: ru-196401.87961

This paper examines the reactions of diacetyl with selected etheramides of phosphorous acid and with diethyl chlorophosphite, extending earlier work on additions of trivalent phosphorus esters to conjugated systems. The authors synthesize and characterize the resulting products by elemental analysis…

Stability in Liebmann's Theorem

Unknown
1964 SovietRxiv: ru-196401.87880

This paper proves a quantitative stability result for Liebmann’s rigidity theorem for the sphere. For a convex n-dimensional surface whose Gaussian curvature satisfies 1 minus epsilon less than or equal to K less than or equal to 1 plus epsilon, the author establishes linear estimates for the radius…

Design of Semistructures

Unknown
1964 SovietRxiv: ru-196401.87787

The paper studies projections of semilattices, understood as isomorphisms between the lattices of their subsemilattices, and formulates analogues of classification and rigidity problems known for groups, semigroups, and modules. It introduces weak isomorphisms, homogeneous completely isolated subsem…

On Entire Functions Bounded on the Real Axis

Unknown
1964 SovietRxiv: ru-196401.87643

The paper studies sharp growth estimates for entire functions of finite exponential type that are bounded by different constants on the negative and positive real semi-axes. Using a Phragmén, Lindelöf argument in the half-planes, it proves that if \(|f(x)| \leq A\) for \(x0\), then \(|f(re^{i\varphi…

On High-Frequency Pulsations during Solid Propellant Combustion

Corresponding Member of the Academy of Sciences of the USSR K. I. Shchelkin
1964 SovietRxiv: ru-196401.87597

This paper examines high-frequency pulsations during the combustion of solid fuel in a cylindrical grain cavity, focusing on the coupling between acoustic oscillations in the gas and elastic surface waves in the solid propellant. It develops frequency-matching conditions for gas acoustic modes and s…

On Chebyshev Approximation of a Continuous Function by a Polynomial under Constraints on the Coefficients

1.** The algorithm presented here for solving the problem of finding
1964 SovietRxiv: ru-196401.87561

This paper presents an algorithm for Chebyshev approximation of a continuous function by a linear polynomial in prescribed continuous functions when the coefficients may be subject to continuously specified convex constraints. The problem is reduced, by introducing an auxiliary variable, to a linear…

Silacyclobutanes. Strength of the $\mathrm{Si}$ – $\mathrm{C}$ bond of the silacyclobutane ring and synthesis of new silacyclobutane derivatives

Unknown
1964 SovietRxiv: ru-196401.87552

This study examines the reactivity of the Si-C bond in the silicacyclobutane ring and explores substitution reactions of 1-chloro-1-methylsilicacyclobutane as routes to new derivatives. Using 1,1-dimethylsilicacyclobutane, the authors test reactions with hydrochloric acid, hydrogen chloride, water, …

Investigation of the stepwise mechanism of $\beta$-nitrostyrene reduction in

L. Kh. Freidlin, E. F. Litvin, V. M. Chursina
1964 SovietRxiv: ru-196401.87540

This study examines the stepwise catalytic reduction of beta-nitrostyrene on palladium black in a strongly acidic acetic acid and sulfuric acid medium, a reaction relevant to the synthesis of phenethylamines and related nitrogen compounds. Using polarographic analysis for nitrostyrene, oxime, and ni…