Showing 50 of 25357 papers

Effect of Water on the Course of Butadiene Polymerization in the Presence of Complex Cobalt Catalysts

I. Yu. Kirchevskaya, Academician S. S. Medvedev
1964 SovietRxiv: ru-196401.73434

This study examines how small additions of water affect butadiene polymerization in benzene using a cobalt chloride pyridine complex with diisobutylaluminum chloride. Using carefully dried, oxygen-free apparatus and dilatometric kinetic measurements, the authors varied initial water and cobalt conce…

On the Applicability of the Limit Theorem of Order $p>0$ to a Nonhomogeneous Markov Chain with Two States

An inhomogeneous Markov chain is considered in the form of a sequence of series of random variables
1964 SovietRxiv: ru-196401.73418

The paper studies sums of binary random variables forming an inhomogeneous two state Markov chain and asks when a central limit theorem together with convergence of absolute moments of order p is applicable. It introduces quantities describing products of transition differences and variances, then f…

On the Dependence of Ion Adsorption on the Potential of Platinum

V. E. KAZARINOV, N. A. BALASHOVA
1964 SovietRxiv: ru-196401.73388

This study examines how the adsorption of cesium and sulfate ions on platinum depends on electrode potential, with emphasis on the structure of the electrical double layer and behavior at high anodic potentials. Using radiolabeled sulfuric acid and cesium sulfate solutions, the authors measured ion …

On the Conditions for the Destruction of the Primary Film during Aluminum Oxidation in Neutral Solutions

Unknown
1964 SovietRxiv: ru-196401.73376

This study examines the conditions under which the primary oxide film on aluminum is destroyed during oxidation in neutral potassium chloride solutions. Electrode potentials of aluminum were measured over time at 20, 25, 28, and 30 °C across concentrations from 0.001 N to near saturation, and the re…

Electron diffraction study of the molecular structure of $\alpha$-pinene oxide

Academician B. A. Arbuzov, V. A. Naumov, N. V. Alekseev
1964 SovietRxiv: ru-196401.73364

This study determines the gas-phase molecular structure of alpha-pinene oxide by electron diffraction, following earlier proton magnetic resonance evidence for a specific conformation. Electron-diffraction patterns of the vapor were recorded at two nozzle-to-plate distances and two accelerating volt…

Lower Bounds by the Sieve Method in Algebraic Number Fields

Unknown
1964 SovietRxiv: ru-196401.73319

The paper develops a modification of the sieve method that extends lower-bound results from the rational integers to arbitrary algebraic number fields, overcoming limitations caused by the weaker known zero-free region for Dedekind zeta-functions. The argument uses a zero-density estimate for zeros …

Synthesis of New Rare-Earth Element Silicates

Corresponding Member of the Academy of Sciences of the USSR N. A. TOROPOV, I. A. BONDAR
1964 SovietRxiv: ru-196401.72776

This paper reports a stage in a systematic investigation of rare earth silicates, focusing on the synthesis and characterization of new europium silicates and the growth of single crystals of several rare earth silicate compounds. Using phase diagram studies, coprecipitated stoichiometric mixtures, …

Continua with the fixed point property

Unknown
1964 SovietRxiv: ru-196401.72733

This paper studies fixed point properties of one-dimensional acyclic continua, in connection with a problem of P. S. Aleksandrov concerning arbitrary continuous self-maps. It proves that a continuum has the fixed-point property if it can be epsilon-mapped onto finite trees so that inverse images of …

Radiation of a Point Charged Particle Moving Along the Axis of a Semi-Infinite Circular Waveguide

G. V. Voskresenskii, B. M. Bolotovskii
1964 SovietRxiv: ru-196401.72494

The paper analyzes electromagnetic radiation produced when a point charge moves along the axis of a semi-infinite circular waveguide, either entering or leaving its open end. The field is represented by a Hertz vector split into the field of a uniformly moving charge in free space and an unknown fre…

On a Problem of Synthesis of Controlled Systems

L. S. GNOENSKII
1964 SovietRxiv: ru-196401.72469

The paper studies the synthesis of linear automatic control systems subject to bounded disturbances, with the objective of minimizing the maximum accumulated error at a fixed terminal time. It considers systems in which a variable gain coefficient may be chosen from a bounded class of piecewise cont…

Isomerization of the n-propyl radical

Yu. G. BUNDEL, Academician O. A. REUTOV
1964 SovietRxiv: ru-196401.72226

This study examines hydrogen-migration isomerization of the n-propyl radical in liquid-phase peroxide decompositions, using isotopic labels to detect small amounts of rearranged product. Butyryl peroxides labeled with deuterium or tritium in the alpha position were decomposed in carbon tetrachloride…

On the Interaction of Acid Esters with Alkyllithiums

Unknown
1964 SovietRxiv: ru-196401.72170

This study examines anomalous reactions of acid esters with lithium alkyls, focusing on the proposed role of beta-keto esters as intermediates in ketone formation. By replacing ether or tetrahydrofuran with n-hexane to slow the reaction and reduce competing alkoxide-mediated condensation, the author…

A difference method for solving Stefan-type problems for a quasilinear parabolic equation with discontinuous coefficients

Unknown
1964 SovietRxiv: ru-196401.72033

This paper studies two-phase and one-phase Stefan-type free-boundary problems for quasilinear parabolic equations with discontinuous spatial coefficients and nonlinear boundary conditions, including radially symmetric cylindrical and spherical cases after transformation. It constructs an implicit fi…

A universal bicompactum of given weight and given dimension

Unknown
1964 SovietRxiv: ru-196401.71976

The paper proves the existence, for every infinite cardinal weight and every natural dimension n, of a compact Hausdorff space of that weight and dimension n that contains a topological image of every completely regular space of weight at most that cardinal and dimension at most n. The argument cons…

Estimates for the Spectrum of Normal Operators

Unknown
1964 SovietRxiv: ru-196401.71972

This paper extends estimates for eigenvalues obtained from a quotient of a trial vector and its image to arbitrary normal operators in Hilbert spaces of functions or sequences. It proves that if the pointwise ratio of Af to f has its values in a disk, exterior disk, or half-plane on the Riemann sphe…

Changes in the phase composition of glass-ceramics under exposure to $\gamma$ rays

S. M. BREKHOVSKIKH, L. M. LANDA, N. I. CHUBKINA
1964 SovietRxiv: ru-196401.71822

This study reports an observed effect of gamma irradiation on the phase composition of lithium aluminosilicate glass-ceramics. Transparent glass-ceramic samples containing beta-eucryptite were irradiated with Co-60 gamma rays at doses from 10^2 to 10^5 r, and their phase changes were examined by X-r…

Study of the Kinetics of Hydrolysis of Certain $\mathrm{N}$-Glycosides

B. N. Stepanenko, V. A. Ignatyuk-Maist­renko, M. G. Chentsova
1964 SovietRxiv: ru-196401.71712

This study examines the relative stability of the N-glycosidic bond in p-carboxyphenyl glycosylamines containing D-glucose, D-galactose, D-xylose, and L-arabinose residues. To avoid uncertainties associated with polarimetric measurements and possible tautomerism, the authors developed a colorimetric…

Liquid-phase oxidation of carbon monoxide

Academician of the Academy of Sciences of the Kazakh SSR D. V. SOKOLSKII
1964 SovietRxiv: ru-196401.71497

This study examines the liquid phase oxidation of low concentrations of carbon monoxide using acidic palladium and copper salt solutions, motivated by analogies with platinum group catalyzed olefin oxidation. Experiments in a flow reactor at 20 to 60°C varied carbon monoxide concentration, gas flow,…

Synthesis of $\alpha,\alpha'$-difluoro-$\alpha,\alpha'$-dialkylethylenes using organolithium compounds

T. V. Talalaeva, O. P. Petrii, G. V. Timofeyuk, A. V. Zimin,
1964 SovietRxiv: ru-196401.71457

This paper describes the synthesis of symmetrical and unsymmetrical alpha,alpha-prime-difluoro-alpha,alpha-prime-dialkylethylenes using aliphatic and aromatic organolithium compounds with tetrafluoroethylene or trifluoroolefin precursors. The authors examine how reaction temperature and the structur…

On Thermodiffusion Fractionation of Polymer Solutions

L. M. SHULPINA
1964 SovietRxiv: ru-196401.71427

This paper examines thermodiffusion fractionation of polymer solutions, focusing on polyisobutylene in heptane and on the limitations imposed by high molecular weight. Using a vertical thermodiffusion column, the authors compare concentration and intrinsic-viscosity changes over time and relate them…

Open mappings of proximity spaces

Unknown
1964 SovietRxiv: ru-196401.71366

This paper introduces and studies several classes of mappings for proximity spaces intended to parallel open, closed, and preclosed mappings in topology. It defines proximally open, weakly open, regular, almost regular, and almost factor mappings, establishes characterizations in terms of closeness,…

On the Classical Solvability of Diffraction Problems for Equations of Elliptic and Parabolic Types

O. A. Ladyzhenskaya, V. Ya. Rivkind, N. N. Ural’tseva
1964 SovietRxiv: ru-196401.71334

The paper studies classical solvability of diffraction problems for second order elliptic and parabolic equations with coefficients having jump discontinuities across interfaces between media. It formulates model boundary and initial boundary value problems with continuity of the solution and conorm…

Preparation and Reactions of Pentafluorophenyl- and Heptafluoronaphthylmagnesium Chlorides

Corresponding Member of the Academy of Sciences of the USSR N. N. VOROZHTSOV, Jr., V. A. BARKHASH, N. G. IVANOVA,
1964 SovietRxiv: ru-196401.71326

Pentafluorophenylmagnesium chloride was prepared from pentafluorochlorobenzene by an entrainment reaction with ethylene bromide in ether, providing a more accessible route to pentafluorophenyl derivatives than routes based on bromo or iodo precursors. Its reactions with water, carbon dioxide, iodine…

On the Statistical Theory of Nonequilibrium Processes in Plasma (Accounting for Nonlinear Wave Interaction in Kinetic Equations)

Unknown
1964 SovietRxiv: ru-196401.70958

This paper develops kinetic equations for nonequilibrium plasma processes that include nonlinear wave interactions, considering both the case of vanishing mean fields governed by correlations of random phase-density and field fluctuations, and the limiting Vlasov case with neglected correlations. Th…

Mechanisms for Reproducing Parabolic and Hyperbolic Curves

Unknown
1964 SovietRxiv: ru-196401.70895

The paper develops the kinematic theory of three related six-link mechanisms for generating algebraic curves of parabolic and hyperbolic type. Using geometric relations among sliders, levers, and fixed guides, it derives equations for the paths traced by selected mechanism points, including third-or…

On the Nature of the Catalytic Activity of Platinum in Hydrogen Oxidation

Yu. A. BALOVNEV, Corresponding Member of the Academy of Sciences of the USSR S. Z. ROGINSKY,
1964 SovietRxiv: ru-196401.70868

The paper investigates the catalytic activity of exceptionally clean platinum surfaces in the oxidation of hydrogen, addressing conflicting earlier interpretations that attributed activity either to clean platinum or to gas-activated and contaminated surfaces. Using ultrahigh-vacuum preparation, cle…

Investigation of certain strength characteristics of the chemical bond in $\mathrm{Ti}_6\mathrm{O}$ and $\mathrm{Ti}_3\mathrm{O}$ compounds formed from $\alpha$-solid solutions of the titanium–oxygen system

I. I. Kornilov, V. V. Glazova
1964 SovietRxiv: ru-196401.70818

This study examines strength-related characteristics of chemical bonding in titanium-oxygen alloys in the alpha-titanium solid-solution range, with particular attention to the compounds Ti6O and Ti3O formed during prolonged annealing. Alloys containing 0 to 32 atomic percent oxygen were prepared, an…

Application of Electron Microscopy and X-ray Analysis Methods for the Study of Glass-Ceramic Materials

I. I. Kitaigorodsky, M. D. Beus, M. V. Artamonova
1964 SovietRxiv: ru-196401.70724

This paper examines the use of electron microscopy and X-ray phase analysis for studying glass-crystalline materials, with emphasis on controlling glass crystallization in sitall production. Using carbon and platinum-carbon replicas of etched fracture surfaces together with powder X-ray diffraction,…

Transmission of Electronic Effects of Substituents in Aromatic Systems through the Azomethine Group

V. I. Minkin, Yu. A. Zhdanov, E. A. Medyantseva
1964 SovietRxiv: ru-196401.70688

This study examines how substituent electronic effects are transmitted through azomethine-containing bridges in aromatic Schiff bases and related quaternized compounds. Acid ionization constants were measured potentiometrically for several substituted phenolic series, and the results were correlated…

On the Reaction of Simple Vinyl Ethers with Nitrosyl Chloride

K. A. OGLOBLIN, V. P. SEMENOV
1964 SovietRxiv: ru-196401.70675

The paper investigates the addition of nitrosyl chloride to three simple vinyl ethers, methylisopropenyl, methylpropenyl, and methyl-alpha-phenylvinyl ethers, in order to assess the effect of electron-donating methoxy substitution on reactivity and product formation. Low-temperature reactions in eth…

A new method for the synthesis of pyrazolines. Condensation of tertiary acetylenic chlorides with hydrazine

B. V. Ioffe, D. D. Tsitovich
1964 SovietRxiv: ru-196401.70604

This paper reports a preparative synthesis of previously unknown 5,5-dialkyl-substituted delta-2-pyrazolines by condensation of tertiary acetylenic chlorides with anhydrous hydrazine. The reaction affords liquid nitrogenous products of composition CnH2nN2 in moderate yields, and their structures are…