Showing 50 of 25357 papers

Conduction band structure of $\mathrm{GaP}$

Unknown
1964 SovietRxiv: ru-196401.64759

The paper reexamines the conduction-band structure of gallium phosphide, motivated by discrepancies between the accepted model with a direct transition near 2.55 eV and compositional evidence suggesting higher direct-transition energies. Using transmission and reflection measurements on plane-parall…

Nuclear quadrupole resonance in orpiment

I. N. Pen’kov, I. A. Safin
1964 SovietRxiv: ru-196401.64695

This study reports additional nuclear quadrupole resonance measurements of As-75 nuclei in natural orpiment, As2S3, using a pulsed quadrupole echo method at 77 and 300 K on cleavage fragments, polycrystals, and powders from two deposits. The spectra consistently contain two equal-intensity lines, in…

Interaction of Thiourea with Organic Sulfides, Disulfides, and Sulfenyl Chlorides in an Acidic Medium

B. V. KOPYLOVA, Corresponding Member of the Academy of Sciences of the USSR R. Kh. FREIDLINA
1964 SovietRxiv: ru-196401.64684

This study examines the reaction of thiourea with organic sulfides, disulfides, and sulfenyl chlorides in acidic media, extending earlier work on analogous reactions of ethers. Experiments with tert-butyl, n-butyl, isobutyl, and phenyl sulfur compounds show that sulfides may give either S-alkylisoth…

Temperature changes of the long period in oriented polymers

Yu. A. ZUBOV, D. Ya. TSVANKIN, G. S. MARKOVA, Academician V. A. KARGIN
1964 SovietRxiv: ru-196401.64597

Small-angle X-ray scattering was used to examine temperature-dependent changes in the long period of highly oriented low-pressure polyethylene fibers during repeated heating and cooling between room temperature and about 116 degrees C. The first heating cycle produced irreversible structural changes…

Study of longitudinal wave velocities in rock samples at pressures up to 20,000 kgf/cm $^2$

M. P. VODAROVICH, A. I. LEVYKIN, N. E. GALDIN
1964 SovietRxiv: ru-196401.64372

This study investigates longitudinal elastic wave velocities in igneous and metamorphic rock samples under pressures up to 20,000 kg/cm², extending earlier laboratory measurements relevant to seismic interpretation of the Earth’s crust and upper mantle. The authors used a high-pressure apparatus wit…

Temperature Dependence of Double-Layer Capacitance in Molten Oxides

O. A. ESIN, A. I. SOTNIKOV, Yu. P. NIKITIN
1964 SovietRxiv: ru-196401.64351

The study examines the temperature dependence of electrical double layer capacitance at the interface between liquid carbon saturated iron and molten calcium aluminosilicate or aluminate electrolytes at 1300 to 1600 degrees Celsius. Using alternating current polarization and frequency extrapolation …

Asymptotic Properties of the Trace of the Spectral Function of a Self-Adjoint Elliptic Differential Operator of Second Order

Unknown
1964 SovietRxiv: ru-196401.64220

The paper studies the high energy asymptotic behavior of the trace of the spectral function for a self-adjoint second order elliptic differential operator in Euclidean space with uniformly elliptic coefficients and nonnegative potential. Since known pointwise asymptotics for the spectral function ar…

Generation of High-Velocity Gas Jets

A. E. VOITENKO
1964 SovietRxiv: ru-196401.64182

The paper describes an explosive-driven device for producing high-velocity gas jets and strong shock waves by accelerating a metal plate against a gas-filled compression chamber with an outlet diaphragm. Experiments using photochronographic measurements show that gas acceleration occurs mainly in th…

On the jump in the critical alternating current of a superconducting solenoid in helium upon passing through the $\lambda$ point

V. V. Sychev, V. B. Zenkevich, V. V. Andrianov, V. A. Al'tov
1964 SovietRxiv: ru-196401.64146

This paper investigates how the critical alternating current of superconducting solenoids changes with temperature when cooled through the helium lambda point. Solenoids wound from a niobium titanium based superconducting alloy were tested at 50 Hz in liquid helium, using brass and fluoroplastic for…

On the Theory of Flows in Sea Straits

Unknown
1964 SovietRxiv: ru-196401.64097

This paper develops a theoretical model for steady currents and density distribution in a stratified sea strait of rectangular cross-section, driven by wind stress, longitudinal sea-level differences, and density gradients. Starting from simplified momentum and diffusion equations with constant turb…

On the mechanism of formation of hydrocarbons with a six-membered ring during the catalytic hydrocondensation of carbon monoxide with cyclopentene

Unknown
1964 SovietRxiv: ru-196401.63922

This paper examines the mechanism by which hydrocarbons containing a six-membered ring form during catalytic hydrocondensation of carbon monoxide with cyclopentene over a cobalt catalyst in the presence of hydrogen. To test an earlier hypothesis that methylenecyclopentane is an intermediate that sub…

Phase of the Second Harmonic of the Alternating Potential and Transfer Coefficients of Fast Electrochemical Reactions

Corresponding Member of the USSR Academy of Sciences V. G. Levich, B. M. Grafov, B. I. Khaikin
1964 SovietRxiv: ru-196401.63888

This paper proposes a method for determining the transfer coefficient of fast electrochemical oxidation, reduction reactions at low alternating-current frequencies. The authors analyze the phase shift of the second harmonic of the alternating electrode potential relative to a sinusoidal polarizing c…

ON ANGULAR LIMIT VALUES OF INTEGRALS OF CAUCHY TYPE

Unknown
1964 SovietRxiv: ru-196401.63824

This note studies angular limit values at a prescribed point of a simple rectifiable plane arc for Cauchy type integrals whose densities satisfy local estimates relative to a bounded nonnegative lower semicontinuous function. It introduces geometric measure quantities describing how the curve and th…

On the Mechanism of Radiolysis of Dilute Aqueous Nitrate Solutions

B. G. ERSHOV, A. K. PIKAEV, G. G. RYABCHIKOVA, and Academician Vikt. I. SPITSYN
1964 SovietRxiv: ru-196401.63621

This study examines the mechanism of gamma radiolysis in dilute aqueous sodium nitrate solutions, with attention to the roles of hydrated electrons, hydrogen atoms, hydroxyl radicals, oxygen, and pH. Product yields of nitrite, hydrogen peroxide, and hydrogen were measured in deaerated, air-saturated…

Stationary Resonant Regimes of Certain Rotational Motions

B. I. Morgunov
1964 SovietRxiv: ru-196401.63412

The paper studies rotational motions with one degree of freedom and slowly varying parameters when the small perturbation depends periodically on time. Using a resonant change of variables and averaging methods, it derives equations for stationary resonant regimes characterized by integer frequency …

Elastic Properties of Multicomponent Titanium Alloys with Molybdenum, Vanadium, and Niobium

S. G. Fedotov, O. K. Belousov
1964 SovietRxiv: ru-196401.63235

This study examines how molybdenum, vanadium, and niobium affect the elastic properties and phase behavior of multicomponent titanium alloys in Ti-Mo-V, Ti-Mo-Nb, Ti-V-Nb, and Ti-Mo-V-Nb systems. Alloys with fixed ratios of alloying elements were arc-melted, annealed or quenched, and compared throug…

EPR Spectra and Transmission of Substituent Effects in Anion Radicals of para-Nitrodiphenyls

L. S. DEGTYAREV, L. N. GANYUK, A. M. GOLUBENKOVA,
1964 SovietRxiv: ru-196401.63150

This study examines how para substituents affect electron-density distribution in anion radicals of substituted para-nitrobiphenyls and how insertion of a second benzene ring modifies transmission of substituent effects. Polarographic half-wave potentials and electron paramagnetic resonance spectra …

On the behavior of solutions to the first boundary value problem for some quasilinear parabolic equations

Unknown
1964 SovietRxiv: ru-196401.62996

The paper studies the long-time behavior of solutions to first boundary-value problems with zero boundary data for certain degenerate quasilinear parabolic equations, including one-dimensional nonstationary filtration type equations and a multidimensional analogue. Assuming existence of regularized …

On a Class of Non-Self-Adjoint Boundary Value Problems

N. G. ASKEROV, S. G. KREIN, G. I. LAPTEV
1964 SovietRxiv: ru-196401.62856

The paper studies a class of non-self-adjoint boundary-value problems in which the spectral parameter appears both in the differential equation and in the boundary condition, although the corresponding fixed-parameter operators and boundary conditions are self-adjoint. Using an abstract Hilbert spac…

Statistical Theory of Nonequilibrium Processes at the Metal–Solution Interface. Statistical Theory of the Nonequilibrium Double Layer

V. A. KIR’YANOV, Corresponding Member of the Academy of Sciences of the USSR V. G. LEVICH
1964 SovietRxiv: ru-196401.62851

This paper develops a statistical formulation of nonequilibrium processes at the metal electrolyte interface, focusing on the electrical double layer beyond the Gouy Chapman Stern approximation. Using generalized correlation functions and a Fokker Planck description of ionic motion, the authors deri…

Dissociation cross section of $\mathrm{H}_2^+$ ions from methane and n-butane at various electron energies

S. E. Kupriyanov, A. A. Perov
1964 SovietRxiv: ru-196401.62832

This study examines how the dissociation cross sections of H2+ ions formed by electron impact from methane and n-butane depend on the energy of the ionizing electrons. Using a double mass spectrometer with neon as the collision gas, the authors measured dissociation of 3.8 keV H2+ ions and compared …

Excitation of Triplet States of Naphthalene Molecules in Solid Solutions by Fast Electrons

M. V. ALFIMOV, N. Ya. BUBEN, A. I. PRISTUPA, V. N. SHAMSHEV
1964 SovietRxiv: ru-196401.62826

This study investigates whether naphthalene molecules in solid polymer solutions are excited to triplet states during irradiation by fast electrons, a process previously difficult to observe because of recombination luminescence. Using electron paramagnetic resonance at 100 K, the authors examined n…

Analytic Mappings and the Bergman Function

Unknown
1964 SovietRxiv: ru-196401.62790

This paper studies analytic mappings of bounded domains in complex Euclidean space through the variational characterization of the Bergman function. It defines a class of mappings normalized by the modulus of their Jacobian at a point and proves that the reciprocal infimum of the squared integral of…

Anticholinesterase Properties of $\mathrm{O}$ -Ethyl- $\mathrm{S}$ -Alkyl Methylthiophosphinates. Kinetics of Inhibition and Structure of the Active Surface of Cholinesterases

A. P. BRESTKIN, N. N. GODOVIKOV, E. I. GODYNA, Academician M. I. KABACHNIK,
1964 SovietRxiv: ru-196401.62713

This study examines how the size and branching of alkyl substituents in O-ethyl-S-alkylmethylthiophosphinates influence their inhibition of horse serum cholinesterase. A series of compounds bearing tert-butyl or isopropyl groups at different distances from the phosphorus atom was synthesized, and in…

On convolution-type equations on the half-line

R. D. Bantsuri, G. A. Dzhanashia
1964 SovietRxiv: ru-196401.62704

The paper studies convolution type integral equations on the half line with integrable kernel and right hand side, under the condition that the Fourier transform satisfies \(1-K(t)\neq 0\). By extending the equation to the whole line and applying Fourier transforms, the problem is reduced to a Wiene…

Determination of the Electron Affinity Energy of Copper, Silver, and Gold Atoms by the Surface Ionization Method

I. N. BAKULINA, N. I. IONOV
1964 SovietRxiv: ru-196401.62658

This paper determines the electron-affinity energies of copper, silver, and gold atoms using negative surface ionization on a heated polycrystalline tungsten filament. Molecular beams of the metals and potassium iodide were directed onto the filament, and negative ion currents were measured with a m…

On the Osmotic Theory of Solutions

F. M. Kuni
1964 SovietRxiv: ru-196401.62654

This note addresses the statistical mechanical formulation of the osmotic theory of solutions, in which the thermodynamics of a solution can be expressed through properties of the dissolved substances. For monatomic molecules with pairwise interactions, it derives expressions for the activity coeffi…

On the Theory of Topological Rings

V. I. ARNAUTOV
1964 SovietRxiv: ru-196401.62648

This paper studies the topological analogue of the Baer radical for associative Hausdorff topological rings, defining it by transfinite iteration from closures of sums of topologically nilpotent ideals. It establishes general characterizations and inclusion properties, including that the radical is …

Study of Elastic Wave Velocities in Ultramafic Rocks of the Monchegorsk Pluton under High Confining Pressure

E. I. BAYUK, N. E. GALDIN
1964 SovietRxiv: ru-196401.62600

This paper examines elastic wave velocities in ultrabasic rocks from the Monchegorsk pluton under hydrostatic pressures up to 4000 kg/cm², with the aim of improving interpretation of deep crustal and upper mantle seismic data. Using dynamic measurements on pyroxenites, peridotites, and related norit…

Generation of Ultrasound at a $p$ – $n$ Junction Made of a Non-Piezoelectric Material

Academician B. P. Konstantinov, A. A. Grinberg, A. A. Kastalsky,
1964 SovietRxiv: ru-196401.62489

The paper examines ultrasound generation at p-n junctions made from nonpiezoelectric semiconductors, proposing a mechanism based on the electrostatic attraction of ionized donors and acceptors in the space-charge region. A theoretical treatment derives the lattice deformation, radiated wave amplitud…

On the Induced Reactivity of Certain Compounds with a Conjugated System in Reaction with 1,1-Diphenyl-2-picrylhydrazyl

A. A. Berlin, V. A. Vonsyatskii
1964 SovietRxiv: ru-196401.62484

The study examines the induced reactivity of polymeric and monomeric compounds with conjugated systems toward 1,1-diphenyl-2-picrylhydrazyl in solution, with particular attention to the role of paramagnetic centers. Using electron paramagnetic resonance, spectrophotometry, chromatography, and ebulli…

THE POSSIBILITY OF X-RAY EMISSION FROM COSMIC RADIO SOURCES

Unknown
1964 SovietRxiv: ru-196401.62454

This paper estimates whether cosmic radio sources such as radio galaxies and supernova remnants can produce detectable X-ray emission in the 1 to 100 Å range. It develops approximate flux formulas for synchrotron X-rays from relativistic electrons, including internal and Galactic absorption, and app…

Mechanism of the Effect of Ultrasonic Vibrations on the Processes of Coagulation Structure Formation in Aqueous Clay Dispersions

S. P. NICHIPORENKO
1964 SovietRxiv: ru-196401.62446

This study examines how ultrasonic oscillations affect coagulation structure formation in aqueous dispersions of Cherkassy montmorillonite and palygorskite, montmorillonite clays. Using structural mechanical measurements, X-ray structural analysis, and electron microscopy, the authors relate changes…