Showing 50 of 25456 papers

Nomograms and tissues

Unknown
1963 SovietRxiv: ru-196301.79029

The paper studies the equivalence between rectifiability of webs and nomographic representability of functions of several variables by nomograms of aligned points. It formulates a web through an equation z equals phi of n variables and gives necessary and sufficient conditions for rectifiability in …

GAS MOTION BEHIND AN ASYMMETRIC PISTON

Let us consider the motion of a piston that moves according to the law
1963 SovietRxiv: ru-196301.78901

The paper analyzes gas motion behind a slightly asymmetric cylindrical or axisymmetric piston moving with constant speed in a gas initially at rest. It reformulates the gas-dynamic equations in coordinates adapted to the piston shape, introduces similarity variables, and treats the asymmetry as a sm…

Bimolecular Preassociation of Polyatomic Molecules

E. E. NIKITIN
1963 SovietRxiv: ru-196301.78780

This paper develops a theoretical description of bimolecular preassociation in polyatomic molecules, emphasizing the role of intramolecular vibrational energy redistribution after formation of a transient quasimolecular complex. Using nonstationary perturbation theory, the decay probability of an in…

On the Possibility of Directed Modification of the Course of Mineral Formation in the $\mathrm{CaO}$ – $\mathrm{Al}_2\mathrm{O}_3$ – $\mathrm{SiO}_2$ System

Unknown
1963 SovietRxiv: ru-196301.78672

This study examines whether mineral formation during firing in the CaO, Al2O3, SiO2 system can be deliberately redirected to favor the more active cement clinker phases C5A3 and C3S instead of C3A and C2S. The authors fired synthesized mineral mixtures and raw mixes with and without fluorine contain…

Quasi-Invariant Cores in Antagonistic Games

E. B. Yanovskaya
1963 SovietRxiv: ru-196301.78668

This paper studies infinite antagonistic games on the unit square with payoff kernels that may be unbounded, addressing conditions under which the upper and lower values over distribution strategies coincide. It introduces quasi-invariance of a kernel with respect to families of transformations of t…

Associative Superenvelope of a Lie Algebra and Its Infinite-Dimensional Representations in Spaces of Analytic Germs

P. K. RASHEVSKII
1963 SovietRxiv: ru-196301.78489

Rashevskii introduces the associative superenvelope of a complex Lie algebra as a completion of its universal associative envelope with respect to a countable system of norms on symmetrized formal series. The paper establishes multiplication estimates ensuring that this completion is a countably nor…

Free and bound excitons in $\mathrm{GaP}$ crystals

Corresponding Member of the Academy of Sciences of the USSR E. F. GROSS, N. S. KOCHEVA,
1963 SovietRxiv: ru-196301.78392

This paper reports low-temperature absorption, luminescence, and reflection studies of GaP crystals aimed at distinguishing free and bound exciton features and their coupling to lattice phonons. The authors identify step-like structures in the absorption spectrum at 77.3 K as indirect transitions to…

The Wittig Reaction in the Carbohydrate Series

N. K. KOCHETKOV, B. A. DMITRIEV
1963 SovietRxiv: ru-196301.78074

This paper examines the use of the Wittig reaction as a synthetic route for extending monosaccharide carbon chains and preparing 2,3-dehydro-2,3-dideoxy-aldonic acid derivatives. The authors show that unprotected reducing sugars, including arabinose, ribose, glucose, galactose, a heptose, and N-acet…

Ionization Rate of Hydrogen on Active Electrodes

M. B. KNASTER, M. I. TEMKIN
1963 SovietRxiv: ru-196301.77971

This paper investigates the ionization rate of hydrogen on partially immersed smooth nickel and platinum electrodes in concentrated potassium hydroxide solutions under conditions where activation polarization is negligible. Using conical electrodes to vary separately the immersed surface area and th…

On the Theory of Linear Polynomial Operations

Unknown
1963 SovietRxiv: ru-196301.77968

The paper studies convergence criteria for sequences of linear operators that map continuous functions on [-1,1] to algebraic polynomials of bounded degree, focusing on alternatives to the usual uniform boundedness of operator norms. Using the correspondence with even periodic functions and a Faber,…

Symmetric magnetohydrodynamic flow

A. I. MOROZOV, L. S. SOLOV’EV
1963 SovietRxiv: ru-196301.77843

The paper derives a symmetric formulation for stationary flows of an ideally conducting compressible fluid in a magnetic field under helical symmetry. Starting from the nondissipative magnetohydrodynamic equations, it introduces stream, magnetic, vorticity, and current functions, obtains integrals o…

Addition of triphenyl radicals to 1,3-enyne organotin compounds

V. S. Zavgorodnii, A. A. Petrov
1963 SovietRxiv: ru-196301.77797

The study examines free radical addition to 1,3-enyne organotin hydrocarbons as part of an effort to assess how tin affects the reactivity of conjugated enyne systems. Triphenylmethyl radicals, generated mainly from hexaphenylethane in benzene, were added to triethyltin vinylacetylene and triethylti…

On the Structure of 2-Aminothiazoline

Yu. N. Sheinker, E. M. Peresleni, A. I. Kol’tsov, N. M. Bazhenov,
1963 SovietRxiv: ru-196301.77753

This study examines the tautomeric structure of 2-aminothiazoline, a nonaromatic heterocyclic amine for which amino and imino forms had been considered possible. Infrared spectra, including deuteration experiments and dilution studies, were compared with nuclear magnetic resonance spectra in chlorof…

On the Oxidation of Aluminum Alkyls

Corresponding Member of the Academy of Sciences of the USSR G. A. RAZUVAEV, A. I. GRAEVSKII,
1963 SovietRxiv: ru-196301.77699

This paper investigates the oxidation of triethylaluminum and related organoaluminum compounds in heptane solution, a process important both as an impurity-forming reaction in aluminum alkyl synthesis and as a route to alcohol precursors. Using oxygen absorption measurements, conductivity monitoring…

Paramagnetic Component of the Magnetic Susceptibility of Semiconductor Crystals Based on Experimental Electron Density Distribution Data

N. N. Sirota
1963 SovietRxiv: ru-196301.77603

This paper proposes a way to estimate the paramagnetic component of the magnetic susceptibility of semiconductor and covalent crystals from experimentally determined electron-density distributions. Building on the Van Vleck expression for susceptibility, it argues that nonspherical ion clouds and bo…

On the isomerization of $\Delta^3$-carene oxide in the reaction with alcohols in the presence of acids

Unknown
1963 SovietRxiv: ru-196301.77575

This study reexamines the acid-catalyzed reactions of delta-3-carene oxide with alcohols, addressing discrepancies in earlier reports on whether isomerization gives aldehydic or ketonic products. Using sulfuric acid in methyl, isopropyl, and tert-butyl alcohols, the authors isolate and characterize …

Oligosides – a New Type of Plant Glycosides

Table 1
1963 SovietRxiv: ru-196301.77514

This paper proposes “oligosides” as a class of plant glycosides containing more than four or five monosaccharide residues, based chiefly on systematic studies of triterpene saponins from several plant species. It summarizes methods for isolating and characterizing these compounds, including mild ext…

$\Omega$-semigroups, $\Omega$-rings and representations

Unknown
1963 SovietRxiv: ru-196301.77313

This note develops a general framework connecting representations of automorphism groups of universal algebras with Ω-semigroups, Ω-rings, and their representations. It defines Ω-semigroups via left distributivity over a system of operations, studies distributive and strictly distributive elements, …

Plasma studies on a traveling-wave setup

N. A. BORZUNOV, N. Ya. KUZMINA, I. Kh. NEVYAZHSKII, S. M. OSOVETS,
1963 SovietRxiv: ru-196301.77298

This paper reports experimental studies of hydrogen plasma in a toroidal apparatus driven by a high-frequency three-phase traveling electromagnetic wave at 2.5 MHz, intended to examine plasma confinement and wave-plasma interaction. Measurements of azimuthal drift current, electron density and tempe…

The Effect of Microscopic Structures on the Mechanical Behavior of Crystalline Polypropylene

![Fig. 1. Dependence of elongation on load for polypropylene films of different structure](image)
1963 SovietRxiv: ru-196301.77181

This paper examines how crystalline morphology affects the mechanical behavior of isotactic polypropylene films. Films with different spherulitic and elongated intergrowth structures were produced by controlled cooling from the melt, then tested in tension and examined optically after deformation. S…

On the Stability of Emulsions

Unknown
1963 SovietRxiv: ru-196301.77168

This paper examines the stability of emulsions with particular attention to the distinction between reversible droplet coagulation and irreversible coalescence, arguing that emulsion destruction depends on the latter rather than on aggregation alone. The authors measured streaming potentials in high…

Study of the Properties of Fast-Moving Plasma Clumps

V. F. Demichev, V. D. Matyukhin
1963 SovietRxiv: ru-196301.77167

Experiments are reported on fast plasma clots produced by a coaxial electrodynamic injector using hydrogen, deuterium, and helium, with injector voltage, gas amount, and discharge timing varied. Magnetic probes, displaced-flux measurements, calorimetry, thermal probes, ballistic momentum measurement…

On the Theory of the Double Compton Effect on an Electron

Unknown
1963 SovietRxiv: ru-196301.76836

This paper derives a general expression for the differential cross section of the double Compton effect on an electron in the first nonvanishing order of perturbation theory. Using Feynman notation, the calculation includes the six photon-line permutations contributing to the matrix element, followe…

Application of the Phenomenon of Surface Ionization to the Study of Catalytic Reactions on Surfaces

N. I. IONOV, M. A. MITTSEV
1963 SovietRxiv: ru-196301.76829

This paper examines the use of surface ionization as a method for studying catalytic reactions occurring in adsorbed layers on metallic surfaces. Experiments with a heated tungsten filament and magnetic-sector mass spectrometer measured ion emission during joint adsorption of barium atoms with lithi…

Some Equivalent Transformations of Algorithm Schemes

Unknown
1963 SovietRxiv: ru-196301.76824

This paper defines a formal notion of an algorithm scheme in which operators, logical conditions, arrows, brackets, and parameters may vary over ordered sets during execution. It introduces order and alphabetic products, parameterized systems, ranks of expressions, execution semantics, and equivalen…

Anisotropy of the Ion-Electron Emission Coefficient of Single Crystals

E. S. MASHKOVA, V. A. MOLCHANOV, D. D. ODINTSOV
1963 SovietRxiv: ru-196301.76759

This paper investigates the angular anisotropy of ion induced electron emission from the (100) face of copper single crystals irradiated by singly charged argon ions at 20 and 30 keV. The authors measure the emission coefficient as a function of ion incidence angle and compare the results with polyc…

Study of Rubber Cyclization by Nuclear Magnetic Resonance

I. A. Tutorskii, I. Ya. Slonim, Ya. G. Urman, E. P. Kudryavtseva,
1963 SovietRxiv: ru-196301.76696

Natural rubber cyclization in phenol media, catalyzed by phosphorus pentoxide, was investigated by nuclear magnetic resonance over 77 to 400 K, with residual unsaturation measured chemically and phase state checked by X-ray diffraction. The NMR line width changes little at early cyclization stages, …

Kinetics of Ammonia Synthesis during Catalyst Poisoning by Water Vapor

I. A. Smirnov, N. M. Morozov, M. I. Temkin
1963 SovietRxiv: ru-196301.76657

This paper examines the kinetics of ammonia synthesis on promoted iron catalysts in the presence of water vapor, addressing limitations of earlier poisoning equations that fail to reduce to the standard synthesis rate law when water is absent. A kinetic expression is derived by treating adsorbed nit…

Electron Microscopic Study of Grafted Polymers

Unknown
1963 SovietRxiv: ru-196301.76335

This paper investigates how grafted polyacrylic acid is distributed within synthetic polymer fibers and addresses the low electron-microscopic contrast between grafted and ungrafted polymer regions. Polyethylene, isotactic polypropylene, and capron fibers prepared by radiation gas-phase graft polyme…

Interpretation of Logical Formulas by Means of Finite Problems and Its Connection with Realizability Theory

Unknown
1963 SovietRxiv: ru-196301.76318

This paper studies the interpretation of formulas of Heyting propositional calculus as finite Kolmogorov-type problems and compares the resulting notion of general validity with Kleene and Rosser realizability. It proves that, for formulas omitting disjunction or implication, general validity implie…

Decomposition into irreducible representations of the restriction of principal series representations of the proper Lorentz group to the real Lorentz group

B. D. ROMM
1963 SovietRxiv: ru-196301.76295

This paper studies the restriction to the real Lorentz group of unitary irreducible representations in the principal series of the proper Lorentz group, formulated via the locally isomorphic group of complex unimodular two by two matrices. Using the Plancherel formula for the real subgroup, it const…

Preparation, Structure, and Some Properties of Single-Crystal Lead Selenide Films

S. A. Semiletov, I. P. Voronina
1963 SovietRxiv: ru-196301.76063

This paper investigates the preparation of single-crystal lead selenide films by vacuum sublimation and epitaxial growth, with attention to how substrate material and temperature affect structure and electrical properties. PbSe was evaporated onto NaCl, LiF, and glass substrates, and the resulting f…

On the Synthesis of Tetrahydrofuran Ketones and Their Isomerization into $\gamma$-Diketones

R. A. KARAKHANOV
1963 SovietRxiv: ru-196301.76040

This paper reports a selective route to tetrahydrofuran ketones from furfurylideneacetone and their conversion into gamma diketones. Hydrogenation in the liquid phase over a skeletal palladium aluminum catalyst is shown to reduce first the side chain double bond and then the furan ring while largely…

On the Index of Systems of Multidimensional Singular Integral Equations

A system of singular integral equations is considered:
1963 SovietRxiv: ru-196301.75923

This paper studies the index of systems of multidimensional singular integral equations on a smooth manifold bounding a ball, under the standard ellipticity condition that the determinant of the associated symbol is nonzero on the tangent unit bundle. It defines a topological integer associated with…

Radiation-Initiated Polymerization of Fluoroolefins

V. A. Khramchenkov
1963 SovietRxiv: ru-196301.75766

This paper examines the radiation-initiated bulk polymerization of several fluoroolefins under cobalt-60 gamma irradiation at room temperature, with attention to how fluorine and hydrogen substitution affects chain growth. Polymerization rates, radiation-chemical yields, molecular weights, conversio…

Imines of hexafluoroacetone

Yu. V. ZEIFMAN, N. P. GAMBARYAN, I. L. KNUNYANTS
1963 SovietRxiv: ru-196301.75369

This paper reports methods for preparing imines of hexafluoroacetone, compounds previously difficult to obtain by conventional dehydration or ketal routes. The authors describe a catalytic synthesis of the anil from phenyl isocyanate and hexafluoroacetone in the presence of triphenylphosphine oxide,…

On the Vietoris–Begle Theorem

Unknown
1963 SovietRxiv: ru-196301.75237

This paper generalizes the Vietoris-Begle theorem for closed mappings of paracompact Hausdorff spaces by allowing non-acyclic point preimages, provided the exceptional sets have sufficiently small relative dimension. Using sheaf cohomology and Leray spectral sequences, it gives conditions under whic…