Showing 50 of 25456 papers

Precipitation Isotherm

V. V. RACHINSKII, A. A. LUR’E
1963 SovietRxiv: ru-196301.46310

This paper derives a generalized precipitation isotherm needed for the theory of precipitation chromatography and dynamic precipitation sorption. Starting from mass balance, stoichiometric relations, and the solubility product rule with activity coefficients, it obtains a functional relation between…

The generalized self-consistent field method and collective excitations in the theory of superconductivity

E. R. Velibekov
1963 SovietRxiv: ru-196301.46292

This paper studies collective excitations in superconductors using Bogolyubov’s generalized self-consistent field equations, extending the analysis beyond the simplest isotropic interaction. The two-particle interaction is expanded in spherical harmonics, which reduces the integral equations for exc…

Electron microscopic study of the structure of capron and lavsan fibers treated with phosphotungstic acid

Unknown
1963 SovietRxiv: ru-196301.45967

This study examines the internal morphology of capron and lavsan synthetic fibers using electron microscopy with neutral phosphotungstic acid as a negative-contrast agent. Mechanically dispersed fibers were compared in uncontrasted form, after gold-palladium shadowing, and after treatment with neutr…

Radical isomerization of acetophenone diphenyl mercaptol

R. Kh. FREIDLINA, A. B. TERENT’EV, R. G. PETROVA
1963 SovietRxiv: ru-196301.45752

This study examines the radical isomerization of acetophenone diphenylmercaptol under heating in chlorobenzene, chiefly in the presence of tert-butyl peroxide, to clarify how mercaptol structure affects rearrangement. The reaction gave 1,2-bis(phenylthio)ethylbenzene, diphenyl disulfide, and alpha-p…

Investigation of the niobium–beryllium system

P. M. ARZHANYI, R. M. VOLKOVA, D. A. PROKOSHKIN
1963 SovietRxiv: ru-196301.45745

This study investigates the poorly characterized niobium-beryllium system using thermodiffusion alloying, metallography, X-ray diffraction, local X-ray spectral analysis, microhardness measurements, thermal analysis, and heat of formation measurements. Diffusion experiments at 900 to 1300°C and stud…

On Ultraparabolic Equations

T. G. GENCHEV
1963 SovietRxiv: ru-196301.45727

The paper studies a class of ultraparabolic partial differential equations with ellipticity in selected spatial variables and first order dependence on time and additional variables, motivated by problems in probability theory, Brownian motion, and boundary layer theory. Under specified regularity, …

On Linear Diophantine Approximations

Unknown
1963 SovietRxiv: ru-196301.45656

This note studies simultaneous linear Diophantine approximation for triples of real numbers through inequalities involving two linear forms and an error of order \(1/\sqrt{x}\). Building on Minkowski’s lemma and a refinement attributed to Cassels’ method, it establishes infinite solvability with an …

Spectra of EDA complexes of 4-nitrodiphenylalkanes containing a donor group in the other ring. EPR effect

Unknown
1963 SovietRxiv: ru-196301.45644

This study examines the origin of the long wavelength absorption and coloration of 4-nitrodiphenylalkanes bearing amino or dialkylamino donor groups in the second ring. Absorption spectra in nitrobenzene, aniline, dimethylaniline, and diethylaniline are compared at different concentrations with spec…

On the Arithmetic of Rational Surfaces

Unknown
1963 SovietRxiv: ru-196301.45558

This paper studies local to global questions for rational algebraic surfaces, focusing on analogues of the Minkowski-Hasse principles for curves of genus zero. Using forms of minimal rational surfaces and Galois cohomology of their automorphism groups, it proves that both principles hold for relativ…

Synthesis of new $\mathrm{C}$-glycosides

Yu. A. ZHDANOV, G. A. KOROL’CHENKO, G. N. DOROFEENKO, G. V. BOGDANOVA
1963 SovietRxiv: ru-196301.45352

This paper reports the preparation of several new C-glycosides, compounds in which the anomeric carbon of a carbohydrate is joined directly to an aglycone by a carbon to carbon bond. The authors use Grignard reactions of acetohalogeno sugars followed by acetylation or acid-catalyzed deacetylation to…

Local activation of compounds with a conjugation system in reactions involving the inhibition of oxidative processes

Unknown
1963 SovietRxiv: ru-196301.45181

This paper examines how paramagnetic centers formed during activation of anthracene and related conjugated compounds affect their ability to inhibit thermal oxidation of paraffinic hydrocarbons. Activated anthracene was fractionated and characterized by solubility, molecular weight, elemental compos…

Ferrocene Azides

Unknown
1963 SovietRxiv: ru-196301.45142

This paper describes the preparation and reactions of azido derivatives of ferrocene, focusing on ferrocenyl azide and 1,1′-ferrocenylenediazide. The authors show that bromoferrocene and, under more forcing conditions, 1,1′-dibromoferrocene undergo copper-assisted substitution by azide, and they als…

Effect of the Electrolyte Nature on the Electrocapillary Curves of Lead in Molten Salts

E. A. Ukshe, I. V. Tomskikh
1963 SovietRxiv: ru-196301.45064

This study examines how the nature of molten salt electrolytes affects the electrocapillary behavior of liquid lead electrodes at 800 to 820 degrees Celsius. Using a quartz capillary electrometer, the authors measured relative changes in surface tension for lead in sodium and potassium chloride and …

Differential amperometric titration of iridium, palladium, iron, and copper with an 8-mercaptoquinoline solution

Yu. I. USATENKO, V. I. SUPRUNOVICH
1963 SovietRxiv: ru-196301.44858

A differential amperometric titration method is described for the successive determination of iridium, palladium, iron, and copper using 8-mercaptoquinoline as a single reagent. The approach combines oxidation reduction reactions with precipitation of metal thiooxinates, and the authors examine the …

On Complete Systems and Bases in Spaces of Functions Analytic in Hartogs Domains

S. A. EREMIN, A. F. SHADROV
1963 SovietRxiv: ru-196301.44829

The paper develops a multiplicative method for constructing complete systems and bases in spaces of analytic functions, with emphasis on products of domains and complete Hartogs domains. It proves that a product system is complete, or is a basis, in the space of functions analytic on a product domai…

Some Problems on the Oscillation of Solutions of Linear Differential Equations

1.** We shall consider the equation
1963 SovietRxiv: ru-196301.44733

The paper studies oscillation and nonoscillation intervals for linear ordinary differential operators of order n with continuous coefficients, relating these notions to generalized Vallée-Poussin boundary value problems and the sign of the corresponding Green’s function. It introduces conjugate poin…

Interaction of High-Density Plasma Clumps with Magnetic Fields

V. F. DEMICHEV, V. M. STRUNNIKOV
1963 SovietRxiv: ru-196301.44542

This paper reports experiments on the interaction of dense deuterium plasma bunches with strong magnetic fields, motivated by plasma injection into magnetic traps for controlled thermonuclear research. Using a Marshall-type injector, the authors studied plasma jets entering increasing longitudinal f…

Mutarotation and structure formation in gelatin solutions

Unknown
1963 SovietRxiv: ru-196301.44429

This study examines the relationship between mutarotation, optical activity, and structure formation in gelatin solutions. Using purified isoelectric gelatin, the authors measured specific optical rotation during cooling and aging, and compared it with gel-melting temperatures used as an indicator o…

Spectral criteria for the stability of solutions of linear differential equations with periodic coefficients

In our notes (¹–⁴), criteria were obtained for the stability of solutions of differential equations of the form
1963 SovietRxiv: ru-196301.44328

This note establishes spectral criteria for boundedness of solutions on the half-axis for linear differential equations with periodic coefficients, a case not covered by earlier criteria for asymptotically constant coefficients. For first-order equations in a complex Banach space, it proves that bou…

Bis(triethylgermyl)mercury: The First Organogermanium Compound of Mercury

N. S. VYAZANKIN, G. A. RAZUVAEV, E. N. GLADYSHEV
1963 SovietRxiv: ru-196301.44131

This paper reports the synthesis and reactions of bis(triethylgermyl)mercury, presented as the first organogermanium compound of mercury. The compound is obtained by heating triethylgermane with diethylmercury under oxygen-free conditions, giving ethane and a lemon-yellow liquid characterized by mer…

THE OPTIMAL LAW OF REMAGNETIZATION OF FERROMAGNETIC CORES WITH A RECTANGULAR HYSTERESIS LOOP FROM THE STANDPOINT OF MINIMUM LOSSES

The energy dissipated in the core during its switching process can be determined as
1963 SovietRxiv: ru-196301.44089

This paper examines how to minimize energy losses during the remagnetization of ferromagnetic cores with nearly rectangular hysteresis loops over a prescribed switching interval. Using dynamic core characteristics that relate the rate of change of induction to field strength, the authors formulate t…

Conformal transformation groups in gravitational fields

R. F. BILYALOV
1963 SovietRxiv: ru-196301.44043

The paper studies conformal transformation groups in four-dimensional Riemannian spaces of gravitational-field signature, with the analysis restricted to analytic functions. Using Lie group methods, the conformal Killing equations and their integrability conditions are derived and examined for nontr…

Adsorption of Polydimethylsiloxane from Solutions by Aerosils

A. V. KISELEV, V. N. NOVIKOVA, Yu. A. EL’TEKOV
1963 SovietRxiv: ru-196301.43998

This study examines adsorption of high-molecular-weight polydimethylsiloxane from n-hexane solutions on highly dispersed nonporous silica Aerosil samples with different surface treatments, using interferometric concentration measurements to construct adsorption isotherms. Dehydration of the silica s…

On the Optimal Values and Points of a Nonlinear Function

Unknown
1963 SovietRxiv: ru-196301.43997

The paper studies the minimization of a nonlinear sum of products of exponential terms with bases between zero and one, subject to row-sum and nonnegativity constraints on a matrix of variables. It introduces characteristic numbers associated with optimal points, proves their uniqueness, and uses th…

Study of Benzene Adsorption in the Temperature Range from 20 to 450 $^\circ$ on a Chromium-Aluminum-Potassium Catalyst

A. M. Rubinshtein, K. I. Slovetskaya, T. R. Brueva
1963 SovietRxiv: ru-196301.43982

This study examines the adsorption of benzene vapor on a chromium, aluminum, potassium catalyst used for paraffin dehydrogenation and dehydrocyclization, in order to compare benzene behavior with earlier observations for cyclohexane and hydrogen. Adsorption isotherms were measured under vacuum from …

Faraday heterodyning

V. G. Levich, B. I. Khaikin, B. M. Grafov
1963 SovietRxiv: ru-196301.43913

This paper develops a theoretical method of Faradaic heterodyning for studying the kinetics of fast electrochemical reactions using the nonlinear properties of an electrochemical cell. Starting from a general second-order expansion of the electrode potential response to alternating Faradaic current,…

On the Properties of Spectra of Ergodic Dynamical Systems

Below a number of theorems on properties of the spectra of ergodic dynamical systems are formulated.
1963 SovietRxiv: ru-196301.43800

This paper formulates spectral results for ergodic measure-preserving dynamical systems satisfying a density condition, Condition A, expressed through fourth-order spectral set functions and interpreted as a multiple-mixing requirement. It shows that, under this condition, the maximal spectral type …

Tin chalcogenochlorides

Unknown
1963 SovietRxiv: ru-196301.43448

This study examines the formation of mixed tin chalcogenochlorides by direct reaction of tin dichloride with sulfur, selenium, and tellurium, motivated by earlier criteria for oxidation without anion displacement in tin salts. Fusion reactions in sealed ampoules yielded compounds assigned the compos…

Iodine Addition Products of Cobalt(III) Dioximes

Academician of the Academy of Sciences of the Moldavian SSR A. V. ABLOV, G. G. STRATAN
1963 SovietRxiv: ru-196301.43391

This study examines iodine addition products of cobalt(III) dimethylglyoxime complexes in order to clarify whether added iodine is present as lattice iodine or as polyiodide coordinated through an iodide ligand. By reacting iodoaquo, diiodo, iodonitro, and dinitro cobalt dioxime compounds with iodid…

ON THE DEGRADATION OF STELLAR AND COSMIC NEUTRINOS

Unknown
1963 SovietRxiv: ru-196301.43363

This paper examines the possible long term fate and energy degradation of stellar, cosmic ray, and relic neutrinos in a universe where known absorption processes are ineffective. Using cosmological redshift arguments and estimates of matter density, expansion, and neutrino production rates, it deriv…

MAGNETIC SPACE SYMMETRY OF TENSORS

Unknown
1963 SovietRxiv: ru-196301.43323

The paper generalizes a previously developed point group treatment of tensor symmetry to Shubnikov, or magnetic space, groups. It defines tensor functions on the magnetic Euclidean group, gives their transformation law including rotations, inversion, time reversal, and translations, and derives inva…

Lanthanum and neodymium hafnates

L. N. Komissarova, Academician Vikt. I. Spitsyn, Wang Gen-shi
1963 SovietRxiv: ru-196301.43239

This study examines the previously little-studied interaction of hafnium dioxide with trivalent rare-earth oxides, focusing on the synthesis and properties of lanthanum and neodymium hafnates. Mixtures prepared by mechanical grinding of oxides or by coprecipitation of hydroxides were investigated us…

Homolytic Reactions of Tetraethylgermane

N. S. VYAZANKIN, E. N. GLADYSHEV, G. A. RAZUVAEV
1963 SovietRxiv: ru-196301.43179

The paper examines homolytic reactions of tetraethylgermane as both a hydrogen donor and a substrate for radical attack, focusing on reactions with benzoyl peroxide, tert-butyl peroxide, and sulfuryl chloride in the presence of benzoyl peroxide. Product isolation and analysis support a free-radical …