Showing 50 of 25456 papers

Chemiluminescence activated by anthracene derivatives

Unknown
1963 SovietRxiv: ru-196301.38946

This study investigates the activation of weak chemiluminescence during hydrocarbon oxidation by anthracene and 9,10-substituted anthracene derivatives. Oxidation of cyclohexane and ethylbenzene in benzene, initiated by azobisisobutyronitrile decomposition, was examined spectrally and kinetically wi…

On the Form of Impurity Occurrence in Heavily Doped $n$-Type Germanium and Silicon Single Crystals

V. I. FISTUL, M. G. MILVIDSKII, E. M. OMELYANOVSKII, S. P. GRISHINA
1963 SovietRxiv: ru-196301.38876

This paper investigates the form in which Group V donor impurities occur in heavily doped n-type single crystals of silicon and germanium. By comparing Hall-effect carrier concentrations with total impurity concentrations measured by radioactivation analysis, and by using metallographic, mass-spectr…

Method for Calculating Rarefied Gas Flows

B. V. Kuksenko
1963 SovietRxiv: ru-196301.38789

This paper proposes a computational method for rarefied gas aerodynamics that reduces the difficulty of solving integral kinetic equations involving functions of many variables. Using a Hermite polynomial expansion of the distribution function, the author derives nonlinear integral equations for den…

Temperature Dependence of Nuclear Magnetic Relaxation Times of Protons and Deuterons in Aqueous Solutions of $\mathrm{Mn}^{2+}$ Ions

R. K. Mazitov
1963 SovietRxiv: ru-196301.38585

This study examines whether hydrogen nuclei leave the first hydration sphere of aqueous manganese(II) ions through proton chemical exchange or through exchange of whole water molecules. Longitudinal and transverse NMR relaxation times of protons and deuterons were measured by spin echo methods in a …

COUNTABILITY CONDITIONS IN LOCALLY CONVEX SPACES

B. S. BRUDOVSKII
1963 SovietRxiv: ru-196301.38520

This paper addresses two questions posed by Dieudonné concerning locally convex spaces with a fundamental sequence of compact sets, namely whether a barrelled or bornological space with this property must coincide with the strong dual of a Fréchet-Montel space, and whether the result extends to infr…

On the Role of Kinetic Factors in the Process of Adsorption-Induced Reduction in the Strength of Metals

Yu. V. GORYUNOV, B. D. SUMM, E. D. SHCHUKIN, P. A. REHBINDER
1963 SovietRxiv: ru-196301.38503

This paper analyzes kinetic limitations on the adsorptional lowering of metal strength in the presence of adsorption active liquid metals. The authors argue that embrittlement requires not only a thermodynamic reduction of surface energy, but also sufficiently rapid delivery of liquid metal atoms to…

Photosensitized Reduction of Thiazine Dyes in Sols and Solutions

Kh. L. Arvan, A. N. Terenin
1963 SovietRxiv: ru-196301.38476

This study examines photosensitized photoreduction of thiazine dyes, chiefly methylene blue and thionine, in oxygen-free sols and solutions where the medium or an added reagent acts as the reducing agent. Using spectrophotometric measurements after filtered irradiation, the authors compare dye bleac…

Changes in the Infrared Spectrum of $\mathrm{X}$ Zeolites upon Thermal Treatment in Vacuum

S. P. ZHDANOV, A. V. KISELEV, V. I. LYGIN, T. I. TITOVA
1963 SovietRxiv: ru-196301.38387

This study examines changes in the infrared spectra of sodium and ammonium forms of zeolite X during thermal treatment in vacuum, with additional observations on deuterated samples. Pressed zeolite tablets were evacuated at increasing temperatures and analyzed by infrared spectroscopy to distinguish…

On transfer theorems

Unknown
1963 SovietRxiv: ru-196301.38363

The paper develops transference theorems in Diophantine approximation in which bounds are imposed on products of variables and fractional parts of linear forms, termed hyperbolic transference theorems, rather than on maxima as in the classical cubic case. Using a method based on estimates of trigono…

Mode of Addition of Silicon Hydrides to Propargyl Chloride

Unknown
1963 SovietRxiv: ru-196301.38243

This paper examines the hydrosilylation of propargyl chloride by trichlorosilane, methyldichlorosilane, and ethyldichlorosilane in the presence of chloroplatinic acid, with attention to the regiochemical order of addition. The experiments show that, unlike most monosubstituted acetylenes, propargyl …

On a problem of P. S. Urysohn

O. V. Lokutsievskii
1963 SovietRxiv: ru-196301.38227

The paper addresses a problem of P. S. Urysohn asking whether there exists a continuum whose space of relative distances is zero-dimensional. It constructs such a continuum as an inverse limit of compacta in the Hilbert parallelepiped, using auxiliary plane continua and monotone nearly contractive p…

Vibrational Spectra of Cyclopentadiene and Monodeuterocyclopentadienes

E. V. SOBOLEV, V. T. ALEKSANYAN, V. A. MIRONOV
1963 SovietRxiv: ru-196301.38180

This study examines the vibrational spectra of cyclopentadiene and isomeric monodeuterocyclopentadienes in order to clarify structural features connected with double-bond migration and electronic conjugation in the ring. Infrared spectra in liquid and gas phases and Raman spectra, including polariza…

On the influence of friction on ocean currents

Unknown
1963 SovietRxiv: ru-196301.38091

This paper examines stationary wind-driven ocean currents in a nonlinear barotropic model that includes both vorticity advection and horizontal turbulent friction. Using an asymptotic boundary-layer construction for small parameters with the scaling gamma equals a epsilon to the three halves, the au…

MIROSLAV FIEDLER, VLASTIMIL PTÁK

(MIROSLAV FIEDLER, VLASTIMIL PTÁK)
1963 SovietRxiv: ru-196301.38065

The paper studies the localization and computation of an eigenvalue of a complex block matrix whose off diagonal blocks are sufficiently small, so that an eigenvalue is expected near the scalar block entry. Using a determinant factorization via the Schur complement and bounds derived from a prescrib…

Separation of silicon isotopes in monosilane by thermal diffusion

G. G. DEVYATYKH, G. K. BORISOV
1963 SovietRxiv: ru-196301.37744

This paper investigates the separation of stable silicon isotopes by thermodiffusion using monosilane as the working gas, motivated by the high cost of calutron separation and the weak isotope effect in monosilane rectification. Experiments were performed in a coaxial-cylinder metal thermodiffusion …

On the Theory of Capillary Equilibrium in a Porous Body

A. A. Chernenko, Yu. A. Chizmadzhev
1963 SovietRxiv: ru-196301.37696

This paper develops a probabilistic model of capillary equilibrium in a porous body, motivated by gas penetration in liquid-filled porous electrodes and the location of three-phase reaction boundaries. The porous medium is idealized as parallel pores composed of successive cylindrical cavities with …

Correlation of frequencies and intensities of IR absorption bands $\nu$ for diazonium salts $\mathrm{X}$ – $\mathrm{C}_6\mathrm{H}_4 \mathrm{N}_2\mathrm{Cl}$ with substituent constants

L. A. KAZITSYNA, B. S. KIKOT’, L. D. ASHKINADZE, O. A. REUTOV
1963 SovietRxiv: ru-196301.37688

This study examines how substituents in substituted aryldiazonium chlorides affect the infrared stretching frequency and absorption intensity of the diazonium group. Frequencies of the N≡N absorption band were measured in several solvents and correlated with Hammett substituent constants, giving cle…

Description of Point Symmetry Groups Using Tensors

L. I. SEDOV, V. V. LOKHIN
1963 SovietRxiv: ru-196301.37687

The paper addresses how point symmetry groups of orthogonal transformations, relevant to textures, crystals, and physical tensor equations, can be characterized through invariant tensor quantities. It argues that the geometric symmetry of such systems can be specified uniquely and completely by a sm…

On the Theory of Growth of Whisker Crystals on the Cathode

S. I. Krichmar
1963 SovietRxiv: ru-196301.37632

This paper develops a theoretical treatment of the cathodic growth of filamentary silver crystals in electrolytes containing surface-active impurities. Starting from impurity effects on two-dimensional nucleation, diffusion of metal ions and impurity molecules, adsorption, and overvoltage relations,…

Syn-anti isomerism of 3-arylhydrazones of 6-methylpiperidine-2,3-dione

M. N. Preobrazhenskaya, N. V. Uvarova, Yu. N. Sheinker,
1963 SovietRxiv: ru-196301.37480

This paper examines the syn and anti isomerism of 3-arylhydrazones of 6-methylpiperidinedione-2,3, compounds encountered in work on biologically active tryptamine derivatives. The authors prepared a series of arylhydrazones by the Japp-Klingemann reaction and compared paired yellow benzene-soluble a…

Crystalline Phases of the Barium Oxide–Germanium Dioxide System

R. G. GREBENSHCHIKOV, N. A. TOROPOV, V. I. SHITOVA
1963 SovietRxiv: ru-196301.37244

This study investigates crystalline phases in the barium oxide, germanium dioxide system as analogues relevant to silicate chemistry and cement materials. Using solid state synthesis of multiple BaO to GeO2 compositions, combined with chemical analysis, X-ray diffraction at ordinary and elevated tem…

On the Solution of a One-Dimensional Initial-Boundary Value Problem for Second-Order Quasilinear Hyperbolic Equations by the Fourier Method

A. I. GUSEINOV, K. I. KHUDAVERDIEV
1963 SovietRxiv: ru-196301.37103

This paper studies a one-dimensional mixed initial boundary value problem for a second order quasilinear hyperbolic equation with homogeneous boundary conditions. Using the Fourier method, it formulates sufficient conditions on the initial data, nonlinear term, parameter, and time interval for exist…

Vertical Motions in Thunderstorm Clouds

Unknown
1963 SovietRxiv: ru-196301.36823

This paper examines vertical air motions and turbulence structure in powerful cumulus and cumulonimbus thunderstorm clouds using flight measurements collected in 1959 to 1962 by an instrumented TU-104 aircraft at the Central Aerological Observatory. From recorded overloads, airspeed, pitch angle cha…

On a Class of Special Automorphisms and Special Flows

B. M. GUREVICH
1963 SovietRxiv: ru-196301.36786

This note gives sufficient conditions under which special automorphisms and special flows built over a Kolmogorov system are again K-systems. It proves that a special automorphism with an integer-valued roof function is a K-automorphism when the roof values are relatively prime and a specified decre…

Ionization of bases and proton transfer in nucleic acids and their components

B. I. SUKHORUKOV, V. I. POLTEV, L. A. BLUMENFELD
1963 SovietRxiv: ru-196301.36781

Using ultraviolet spectrophotometry over pH 1.8 to 12.5 and 20 to 80 degrees C, this study determines dissociation constants and thermodynamic ionization parameters for nucleic acid bases and nucleosides in ground and excited states. The authors compare acid and alkaline dissociation processes, note…

On the three-dimensional problem of diffraction by a prism

Unknown
1963 SovietRxiv: ru-196301.36766

The paper studies the three-dimensional diffraction of waves by an infinite prism with a convex polygonal base, focusing on the Green function for the wave equation with zero boundary conditions and on the singularities that determine high-frequency behavior for the corresponding Helmholtz problem. …

On the Relationship Between the Structure of the Surface Layer of a Pure Liquid and Its Surface and Bulk Properties

Unknown
1963 SovietRxiv: ru-196301.36753

This paper develops a thermodynamic model relating the structure of the surface layer of a pure liquid to surface tension, its temperature coefficient, molecular orientation, association, and layer thickness. Starting from the force balance for a stretched liquid film and using Frenkel’s expression …

Asymptotics of Some Rotational Motions

Unknown
1963 SovietRxiv: ru-196301.36642

The paper studies rotational regimes in one degree of freedom systems that are small perturbations of Hamiltonian motion with slowly varying parameters and periodic potential forces. Using first approximation averaging methods, it derives equivalent evolution equations for the slowly varying energy,…

Some types of quotient mappings and relations between classes of topological spaces

All spaces are assumed to be Hausdorff, all maps continuous and single-valued.
1963 SovietRxiv: ru-196301.36497

This paper studies quotient mappings of Hausdorff spaces, focusing on the failure of quotient maps to be hereditary and introducing pseudo-open maps as the hereditary quotient maps. It proves that pseudo-open images of metric spaces are exactly Fréchet spaces, gives related characterizations for loc…

On the Entropic Expression of the Uncertainty Principle

D. A. BOCHVAR, I. V. STANKEVICH, A. L. CHISTYAKOV
1963 SovietRxiv: ru-196301.36397

This paper examines entropic formulations of the quantum uncertainty principle for canonically conjugate position and momentum, comparing them with the standard variance-based Weyl inequality. Using Fourier transform inequalities, including results of Babenko and the Riesz theorem, the authors argue…

Infrared Spectra of Polyynes

O. I. EGOROVA, Corresponding Member of the USSR Academy of Sciences V. V. KORSHAK
1963 SovietRxiv: ru-196301.36392

Infrared absorption spectra were measured for carbyne and a series of polyynes obtained by oxidative polycondensation of acetylene derivatives, including phenylacetylene, para-diethynylbenzene, and para-nitrophenylacetylene. The spectra are interpreted in terms of terminal and disubstituted acetylen…

SPECTROPHOTOMETRIC STUDY OF ETHANOL SOLUTIONS OF CoCl₂ AND CoBr₂ AT HIGH CONCENTRATIONS OF Cl⁻ AND Br⁻ ANIONS

Unknown
1963 SovietRxiv: ru-196301.36289

This study examines the composition and structure of cobalt(II) halide complexes formed in anhydrous ethanol at very high chloride and bromide ion concentrations. Absorption spectra of CoCl2 and CoBr2 solutions containing varying amounts of LiCl or LiBr were measured with an SF-10 spectrophotometer …