Showing 50 of 25456 papers

Effect of Iodine on the Electrical Properties of Products of Radiation-Thermal Modification of Polyethylene

A. V. Vannikov, N. A. Bakh
1963 SovietRxiv: ru-196301.33251

This study examines how iodine alters the electrical properties of radiation-thermally modified polyethylene, whose conductivity, activation energy, and thermoelectric power depend on heat-treatment temperature and spatial polyconjugation. Conductivity and thermoelectric power were measured for samp…

Quinary system $\mathrm{UO}_2(\mathrm{NO}_3)_2$ – $(\mathrm{C}_4\mathrm{H}_9)_2\mathrm{PO}(\mathrm{C}_4\mathrm{H}_9\mathrm{O})$ – $\mathrm{H}_2\mathrm{O}$ – $\mathrm{HNO}_3$ – $\mathrm{CCl}_4$ at a constant ratio of $(\mathrm{C}_4\mathrm{H}_9)_2\mathrm{PO}(\mathrm{C}_4\mathrm{H}_9\mathrm{O})$ to $\mathrm{CCl}_4$ in the phase separation region

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1963 SovietRxiv: ru-196301.33122

The study examines extraction equilibria in the quinary system uranyl nitrate, nitric acid, water, carbon tetrachloride, and a 27.6 wt.% solution of the monobutyl ester of dibutylphosphinic acid in the stratification region at 25 degrees C. Using physicochemical analysis, extraction rays, and determ…

Equivalent Transformations of Automata of Certain Types

N. A. GORBOVITSKAYA
1963 SovietRxiv: ru-196301.32904

The paper studies equivalent transformations of circuits and certain automata built from logical elements, delays, addition modulo 2, constants, and feedback elements realizing periodic summation operators. It first establishes that, for circuits over any complete finite basis of functional elements…

Corrections to the article Necessary and sufficient condition for the Fredholm property of the Dirichlet problem for a certain class of elliptic systems (DAN, Vol. 145, No. 4, 1962)

| | Pages |
1963 SovietRxiv: ru-196301.32826

This text is a contents and corrections page for a scientific issue, listing articles across biophysics, biochemistry, botany, plant physiology, plant ecology, physiology, and embryology. The biophysics entry concerns threshold illumination at the eye pupil from a fixed light source as a function of…

Interaction of Methyl Esters of Ferrocene Mono- and D

A. D. PETROV, E. B. SOKOLOVA, G. P. BAKUNCHIK
1963 SovietRxiv: ru-196301.32802

This study examines the reactions of methyl esters of ferrocene mono- and dicarboxylic acids with Grignard reagents derived from trimethylchloromethylsilane and trimethyl-gamma-chloropropylsilane. The trimethylsilylmethyl reagent, a structural analogue of neopentylmagnesium chloride, reacted anomalo…

Integral intensities of IR absorption bands of some characteristic vibrations of cyclopentadienyl rings in ferrocene derivatives

Unknown
1963 SovietRxiv: ru-196301.32750

This study examines how substituents affect the infrared absorption bands characteristic of cyclopentadienyl rings in ferrocene derivatives, focusing on C,H stretching near 3100 cm-1 and ring stretching near 1100 cm-1. Frequencies and integral intensities were measured in carbon tetrachloride soluti…

Determination of the formation energy of a quasi-aromatic ring with an $\mathrm{H}$-bond from IR spectral data of molecules

D. N. SHIGORIN, A. P. SKOLDINOV, T. S. RYABCHIKOVA
1963 SovietRxiv: ru-196301.32740

This paper proposes a spectroscopic method for estimating the energy of formation of intramolecular hydrogen bonds that generate quasiaromatic six-membered rings in conjugated systems. Using shifts of the O-H stretching vibration in infrared spectra and a calibration constant derived from carboxylic…

Thermal Explosion with Heat Transfer by Convection and Conduction

A. M. GRISHIN, O. M. TODES
1963 SovietRxiv: ru-196301.32541

This paper examines the critical condition for thermal self-ignition of reacting systems when heat is removed simultaneously by internal conduction and surface convection. Starting from the nonstationary heat equation with an Arrhenius reaction rate, the authors linearize the problem in the high act…

Representation Theorem for a Class of Differentiable Functions of Several Variables by Entire Functions of Exponential Type

S. M. NIKOL’SKII
1963 SovietRxiv: ru-196301.32492

The paper studies a class of functions of several real variables with mixed generalized derivatives satisfying Hölder-type difference estimates in Lp. It proves that every function in this class can be expanded as a series of entire functions of exponential type with coordinatewise degree bounds and…

Mass-spectrometric method for determining partial vapor pressures and relative ionization cross sections of molecules from total evaporation isotherms

L. N. SIDOROV, P. A. AKISHIN
1963 SovietRxiv: ru-196301.32467

A mass spectrometric method is proposed for determining partial vapor pressures and relative molecular ionization cross sections in multicomponent systems from isotherms of complete evaporation. The method relates ion-current integrals to the amounts evaporated by the Knudsen effusion equation, prov…

Spectral Distribution of the Photoconductivity of Chlorophyll $\mathrm{a}$ as a Function of Layer Thickness

Unknown
1963 SovietRxiv: ru-196301.32297

This paper examines how the spectral distribution of photoconductivity in chlorophyll a layers depends on layer thickness, with attention to the wavelength dependence of the nonlinearity exponent in the photocurrent response. Thin and thicker chlorophyll a films deposited between platinum electrodes…

Effect of Low-Molecular-Weight Substances Sorbed by Supramolecular Structures on the Mechanical Properties of Rigid-Chain Polymers

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1963 SovietRxiv: ru-196301.32142

This study examines how low molecular weight substances with differing compatibility affect the mechanical behavior and glass transition of rigid chain cellulose esters, focusing on whether plasticization can occur through changes in supramolecular structure rather than only through molecular mixing…

Structure of Ungerine

Kh. A. ABDUAZIMOV, Corresponding Member of the USSR Academy of Sciences S. Yu. YUNUSOV
1963 SovietRxiv: ru-196301.31454

The paper reports the structural elucidation of ungerine, an alkaloid isolated from Ungernia severtzovii, and assigns it to the homolycorine type. Evidence is drawn from elemental composition, infrared and ultraviolet spectra, alkaline opening and acid reclosure of a lactone, reductions to tetrahydr…

Investigation of Ion-Exchange Processes by Physicochemical Analysis

A. V. NIKOLAEV, V. L. BOGATYREV, A. I. VULIKH
1963 SovietRxiv: ru-196301.31221

This paper applies physicochemical analysis to ion-exchange equilibria, treating the ion exchanger as a solid phase of variable composition within a quaternary reciprocal system. The authors experimentally studied the ammonium chloride, hydrochloric acid, UK-2 cation exchanger in hydrogen form, and …

Inequalities for Polynomials and Rational Functions

Unknown
1963 SovietRxiv: ru-196301.31160

This note refines Bernstein-type inequalities for polynomials bounded on an interval by incorporating restrictions on the location of their zeros. Using elementary estimates on products over the zeros, it derives upper and lower bounds relating the maximum modulus of a polynomial on intervals of the…

On the elementary stages of the recombination process of hydrogen atoms on the surface of aluminum. Activation energy of the reaction

V. A. Lavrenko, Academician of the Academy of Sciences of the Ukrainian SSR, and I. N. Frantsevich
1963 SovietRxiv: ru-196301.31090

The paper investigates the heterogeneous recombination of hydrogen atoms on aluminum in order to clarify how nontransition metal surfaces can catalyze atomic gas recombination. Using the Roginskii and Shekhter differential compensation method, the authors measured recombination rates on high-purity …

ON THE CONVERGENCE OF GRADIENT METHODS FOR FINDING A LOCAL CONSTRAINED MINIMUM OF A NONLINEAR FUNCTIONAL UNDER LINEAR CONDITIONS IN HILBERT SPACE

Unknown
1963 SovietRxiv: ru-196301.30880

This paper studies gradient methods for finding a local minimum of a nonlinear functional on a real Hilbert space subject to finitely many linear equality constraints. It formulates the constrained steepest descent as a projected gradient differential equation on the constraint plane and proves conv…

On the Polymerization of Nitroolefins

A. V. TOPCHIEV, V. P. ALANIYA, M. F. VAGIN
1963 SovietRxiv: ru-196301.30785

This study examines the synthesis and polymerization behavior of two nitroolefins, nitroisobutylene and cyclohexylidenenitromethane. Nitroisobutylene was prepared through nitroisobutanol dehydration, and its polymerization was tested with several catalysts, of which only benzoyl chloride and benzoyl…

ON SOME PROPERTIES OF ARITHMETIC OPERATIONS ON DUPLEXES

Unknown
1963 SovietRxiv: ru-196301.30687

This note studies constructive properties of duplexes, represented by rational Cauchy sequences together with regulators of self-convergence, and examines whether minimal regulators can be uniformly obtained. It proves that no algorithm can transform an arbitrary duplex into a minimal regulator for …

Enhancement of the Sensitivity of Luminescent Reactions for Cations with Organic Reagents upon Freezing of Solutions

Unknown
1963 SovietRxiv: ru-196301.30653

This paper examines whether freezing solutions can increase the sensitivity of luminescent analytical reactions for inorganic cations with organic reagents. Using spectrofluorimetric measurements at room temperature and liquid nitrogen temperature, the authors studied complexes of lumogallion IREA w…

Variational Problems of Optimization of Control Processes with Functionals Depending on Intermediate Values of Coordinates

Unknown
1963 SovietRxiv: ru-196301.30610

This paper formulates an optimal control variational problem in which the performance functional and endpoint constraints depend not only on initial and terminal states but also on coordinate values at prescribed intermediate times. Using Lagrange multipliers and comparison curves, it derives first-…

New polyconjugated systems and their electrophysical properties

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1963 SovietRxiv: ru-196301.30571

A series of new polyconjugated polymers, including polyacetylenenitrile, substituted polyacetylenes, and a phenylacetylene-acetylenenitrile copolymer, was synthesized and characterized by infrared and EPR spectroscopy. The materials are insoluble dark powders with high thermal stability, show narrow…

Doubling Mechanism in the Cyclization of Depsipeptides and Peptides

Yu. A. Ovchinnikov, V. T. Ivanov, A. A. Kiryushkin,
1963 SovietRxiv: ru-196301.30500

This paper examines the “doubling” phenomenon in the cyclization of peptides and depsipeptides, in which cyclic products contain twice the number of residues present in the starting linear molecule. Using cyclization experiments on tri- and tetradepsipeptides, including N-methylated compounds and st…

On Chains of Matrix Norms

Unknown
1963 SovietRxiv: ru-196301.30322

This note studies the partially ordered set of matrix norms on the ring of real square matrices of fixed order, ordered by pointwise domination, and asks about the structure of its maximal chains. Using Zorn’s lemma to ensure maximal chains, the argument proves two auxiliary facts: any nonzero pseud…

ON THE METHOD OF TANGENT HYPERBOLAS

For the approximate solution of the equation
1963 SovietRxiv: ru-196301.30300

This paper studies the approximate solution of nonlinear operator equations in Banach spaces by the method of tangent hyperbolas and a related modified iteration that fixes certain derivatives at the initial point. Using the majorant principle, it establishes convergence theorems under assumptions o…

Catalytic Reactions for the Formation of 1,1-Dimethylsilacyclopentane

Corresponding Member of the Academy of Sciences of the USSR N. S. NAMETKIN, V. M. VDOVIN,
1963 SovietRxiv: ru-196301.30175

This paper reports catalytic routes to the formation of the five-membered silicon carbon heterocycle 1,1-dimethylsilacyclopentane, avoiding the usual reliance on organometallic derivatives of tetramethylene dibromide. The authors show that 1-chloromethyldimethylsilyl-3-trimethylsilylpropane undergoe…

Mutual transformations of cis- and trans-1,2-dimethylcyclopentanes in the presence of a platinum catalyst

A. L. LIBERMAN, O. V. BRAGIN, G. K. GUR’YANOVA, B. A. KAZANSKII
1963 SovietRxiv: ru-196301.30035

This study examines the catalytic interconversion of cis and trans 1,2-dimethylcyclopentanes over platinized carbon during attempts to measure hydrogenolysis kinetics of the individual stereoisomers. Using flow experiments in hydrogen, and in selected cases without hydrogen, followed by gas liquid c…

On Ferromagnetism in Organic Structures

L. A. Blumenfeld
1963 SovietRxiv: ru-196301.29960

This paper examines whether anomalous ferromagnetic behavior previously observed in nucleic acids and conjugated synthetic polymers can be attributed to ordinary ferromagnetic contaminants. DNA preparations and several organic polymers were prepared or synthesized, then studied by ferromagnetic reso…

On a class of algorithms over finite sets

Unknown
1963 SovietRxiv: ru-196301.29683

The paper develops a general framework for algorithms that compute information about elements of finite sets, motivated by earlier procedures for simplifying disjunctive normal forms. Elements are equipped with admissible mark vectors representing known predicate values, and algorithms update these …

Preparation and Evaluation of Some Properties of Filamentary and Needle-Like Single Crystals of Solid Solutions in the $\mathrm{Ge}$ – $\mathrm{Si}$ System

Unknown
1963 SovietRxiv: ru-196301.29671

Filamentous and needle-like single crystals of germanium-silicon solid solutions were grown by vapor transport in sealed evacuated quartz ampoules using bromine as a solvent component. The study describes growth conditions, morphology, crystallographic orientation, and composition assessment by X-ra…

Photoreactions of Hexafluoroazomethane with Unsaturated Compounds

V. A. Ginsburg, E. S. Vlasova, M. N. Vasil’eva, N. S. Mirzabekova,
1963 SovietRxiv: ru-196301.29606

Photolysis of hexafluoroazomethane was examined in the presence of compounds containing multiple bonds and in oxygen-containing systems to determine the reactivity of trifluoromethyl and related radical intermediates. Irradiation experiments showed that, among the tested substrates, unsaturated orga…