Showing 50 of 25456 papers

On a conjecture of V. A. Steklov

Ya. L. Geronimus
1962 SovietRxiv: ru-196201.62961

This note studies V. A. Steklov’s conjecture that positivity of the weight is necessary and sufficient for boundedness of an orthonormal polynomial system on an interval. Working first with polynomials orthonormal on the unit circle, the paper gives sufficient conditions, involving pointwise bounded…

On the Luminescence of Long-Period Variable Stars

V. G. GORBATSkii
1962 SovietRxiv: ru-196201.62947

This paper examines whether the brightness variations of long-period variable stars can be explained by mechanisms other than ordinary stellar pulsation. Using reported rapid optical and near-infrared brightness changes, together with estimates of photon escape time from subphotospheric layers, it a…

ON EXPANSION IN EIGENFUNCTIONS OF A NON-SELF-ADJOINT DIFFERENTIAL OPERATOR OF EVEN ORDER IN THE SPACE OF VECTOR FUNCTIONS

Unknown
1962 SovietRxiv: ru-196201.62909

This paper studies expansions in eigenfunctions for a non-self-adjoint system of differential equations of arbitrary even order on the half-axis in the space of vector functions. Under exponential decay assumptions on the matrix coefficients and regularity conditions on the boundary forms, it constr…

On a Generalization of T. Regge’s Theorem

Unknown
1962 SovietRxiv: ru-196201.62893

This note revisits Regge’s theorem on the analytic continuation of functions expanded in Legendre polynomials, where the coefficients are values of an analytic interpolating function in a half-plane. It argues that the theorem follows from the classical Le Roy-Lindelöf theorem on power series togeth…

Adsorption of methylcyclohexene from solutions at elevated temperature

I. V. SMIRNOVA, K. V. TOPCHIEVA, A. A. KUBASOV, L. V. SAVCHENKO
1962 SovietRxiv: ru-196201.62799

This paper investigates adsorption of 1-methylcyclohexene-1 from n-heptane solutions on alumina at elevated temperature, with attention to conditions relevant to chromatographic separation and heterogeneous catalysis. The authors develop an ampoule method that separates the equilibrium solution from…

ON ONE METHOD FOR SOLVING THE POISSON EQUATION

To find the solution of the equation
1962 SovietRxiv: ru-196201.62769

An iterative finite difference method is proposed for the first boundary value problem for the Poisson equation, using the standard five point approximation on rectangular grids. The method alternates one dimensional implicit steps in the coordinate directions and is analyzed through the eigenfuncti…

On the Asymptotics of Third-Order Integer Matrices

Yu. V. LINNIK, B. F. SKUBENKO
1962 SovietRxiv: ru-196201.62704

The paper studies the asymptotic enumeration of primitive integer matrices of order three with prescribed determinant N, restricted after scaling to a fixed bounded domain in the group of unimodular matrices. It proves that, as N tends to infinity, the count is asymptotic to the Haar measure of the …

Correlation of the Rate Constants of Alkaline Hydrolysis of Aromatic Sulfonic Acid Esters Depending on Their Structure

Unknown
1962 SovietRxiv: ru-196201.62699

This paper analyzes quantitative relationships between structure and reactivity for the alkaline hydrolysis of several series of aromatic sulfonic acid esters, using literature rate constants for substituted phenyl, benzenesulfonyl, diaryl, and ethyl benzenesulfonate derivatives. The authors apply m…

Congruences of Parabolas in Equiaffine Geometry

Unknown
1962 SovietRxiv: ru-196201.62627

This paper studies nondegenerate congruences of parabolas in equiaffine geometry under assumptions on a distinguished focal surface. A canonical moving frame is constructed, yielding structure equations, invariants, the equation of the parabola, and the determination that the general congruence depe…

Chemical interaction between nickel and manganese at different temperatures in copper-based ternary solid solutions

Unknown
1962 SovietRxiv: ru-196201.62466

This study examines preferential chemical interaction between nickel and manganese in ternary copper-based solid solutions, using the Cu-Ni-Mn system where the NiMn compound has limited thermal stability. Alloys along sections intersecting the quasibinary Cu-NiMn section at 90 and 95 atomic percent …

Physicochemical Study of Complexes Between Alkyl(aryl)chlorosilanes and Tetrasubstituted Ammonium Halides

N. M. Alpatova, A. I. Gorbanev, Yu. M. Kessler, and L. G. Lozhkina
1962 SovietRxiv: ru-196201.62420

This study examines complex formation between several chlorosilanes, including methyltrichlorosilane, trimethylchlorosilane, phenyltrichlorosilane, and silicon tetrachloride, and a range of alkali, ammonium, and tetrasubstituted ammonium halides. Interactions were assessed by chemical analysis, visu…

On Splitting in the Künneth Formula

M. BOKSHTEIN
1962 SovietRxiv: ru-196201.62302

The paper studies when the exact Künneth sequence for tensor products of complexes splits, especially in the case where only one factor is torsion free. It gives an explicit two term example, with one complex over the integers and one over the cyclic group of order 8, in which the degree one Künneth…

Preparation and properties of nitrate complex compounds of tetravalent uranium

A. D. GEL'MAN, N. N. KROT, and N. P. ERMOLAEV
1962 SovietRxiv: ru-196201.62293

This study examines complex formation between tetravalent uranium and nitrate ions in hydrochloric, nitric, and mixed acid media, using spectrophotometry, ion exchange, and preparative isolation. It finds stepwise formation of lower cationic and neutral nitrate complexes at nitric acid concentration…

STUDY OF THE STATE OF WATER SORBED ON CALCIUM HYDROSILICATE BY THE METHOD OF NUCLEAR MAGNETIC RESONANCE

Unknown
1962 SovietRxiv: ru-196201.62174

This study examines the state and bonding of water sorbed on low-temperature calcium hydrosilicate, focusing on the interpretation of a characteristic dehydration isotherm section near relative vapor pressure 0.35. Proton nuclear magnetic resonance spectra were measured at room temperature for sampl…

Classification of Polynomial Operations

D. L. Berman
1962 SovietRxiv: ru-196201.62148

The paper studies linear operators on the space of continuous periodic functions that take values in trigonometric polynomials of bounded order, classifying such operators by an averaging procedure invariant under translations. It establishes a one-to-one correspondence, with natural algebraic inter…

On the Determination of the Constant $\alpha$ from the Dependence of Electroreduction Kinetics on Potential and Supporting Electrolyte Concentration

O. A. PETRII, A. N. FRUMKIN
1962 SovietRxiv: ru-196201.62107

This paper examines how the transfer coefficient alpha may be estimated from the dependence of electroreduction kinetics on electrode potential and supporting electrolyte concentration, emphasizing the role of double layer corrections. Using corrected Tafel representations based on the Frumkin, Flor…

Structure Formation in Plasticized Crystalline Polystyrene

V. A. KARGIN, T. I. SOGOLOVA, and G. Sh. TALIPOV
1962 SovietRxiv: ru-196201.62018

This study examines how plasticizers affect supramolecular structure formation and mechanical properties in crystalline isotactic polystyrene. Using optical observations of crystallization at several temperatures together with mechanical measurements and comparison of X-ray diffraction patterns, the…

Potentiometric Study of Catalytic Hydrogenation in Dielectric Media

A. B. Fasman, Academician of the Academy of Sciences of the Kazakh SSR, D. V. Sokol’skii, A. V. Bykov,
1962 SovietRxiv: ru-196201.61931

This study examines potentiometric measurement of powdered catalyst potentials during catalytic hydrogenation in dielectric organic media, where high resistance and static charge complicate conventional methods. The authors designed and tested two variants of a measuring electrode with a conducting …

$\delta$ -Lactones and $\delta$ -lactams. Chloromethylation of 2-pyrones

N. P. SHUSHERINA, N. D. DMITRIEVA, R. Ya. LEVINA
1962 SovietRxiv: ru-196201.61850

This study examines chloromethylation as an electrophilic substitution reaction of 5,6-disubstituted 2-pyrones, extending earlier work on the reactivity of the 2-pyrone ring. Using mixtures of chloromethyl and bis-chloromethyl ethers, or formalin saturated with hydrogen chloride, the authors prepare…

On the Analytic Arithmetic of Quadratic Forms in an Odd Number of Variables in Connection with the Theory of Modular Forms

Notation.
1962 SovietRxiv: ru-196201.61601

The note studies representation numbers of positive definite integral quadratic forms in an odd number of variables through generating series connected with modular forms. For a squarefree parameter l, it defines weighted sums of the representation numbers r_f(lt²) and proves that their generating f…

Synthesis of Vinyl Chloride by Chlorination of Ethylene in a Fluidized Catalyst Bed

Corresponding Member of the Academy of Sciences of the USSR Yu. G. Mamedaliev, Mageram Mamedov,
1962 SovietRxiv: ru-196201.61573

This paper examines the synthesis of vinyl chloride by high-temperature chlorination of ethylene in a fluidized bed, motivated by the difficulty of promoting substitution chlorination while limiting destructive chlorination and by-product formation. The authors carried out experiments at 450°C using…

On Rearrangements of Hexamethyl- and Octamethylcyclosilazanes

K. A. Andrianov and G. Ya. Rumba
1962 SovietRxiv: ru-196201.61551

This paper reports experimental observations on rearrangements of dimethylcyclosilazanes involving changes in the silicon-nitrogen ring framework. Hexamethylcyclotrisilazane was treated under several conditions, including trimethylchlorosilane with ammonia, ammonium chloride, triethylmethylammonium …

On the computation of the electrical conductivity tensor

Unknown
1962 SovietRxiv: ru-196201.61317

This paper develops a method for calculating the electrical conductivity tensor using retarded and advanced two-time temperature Green functions. For electrons scattered by phonons or impurity centers, the current Green function is related to a two-particle Green function whose equation has the form…

On a Model of the Combustion Front in Condensed Mixtures

Unknown
1962 SovietRxiv: ru-196201.61193

This paper addresses the experimentally observed S-shaped dependence of combustion velocity on component particle size in condensed mixtures whose components gasify before mixing, a behavior not adequately described by one-dimensional theories. The authors propose a simplified nonuniform combustion-…

On the Motion of Droplets in Liquids under the Action of Surfactants

Corresponding Member of the USSR Academy of Sciences V. G. Levich, A. M. Kuznetsov
1962 SovietRxiv: ru-196201.60999

This paper analyzes the motion of a liquid drop suspended in another liquid when a maintained concentration gradient of an insoluble surface-active substance produces a nonuniform surface concentration on the drop. Using a slow-motion approximation, the authors couple convective diffusion near the i…

Extremal Properties of Solutions to Elliptic Equations

Unknown
1962 SovietRxiv: ru-196201.60893

This paper studies extremal properties of regular solutions to linear elliptic equations under general assumptions on the zeroth order coefficient and the right hand side, without requiring fixed signs for these functions. Using Chaplygin’s theorem on subcritical domains, it proves a criterion exclu…

On Mappings of Metric Spaces

Unknown
1962 SovietRxiv: ru-196201.60547

This paper studies when topological spaces arise as images of metrizable spaces under continuous mappings with openness, closedness, compact fibers, or related conditions. It proves that a T1 space has a uniform base exactly when it is an open continuous compact image of a metrizable space, with a z…

Rhenium thiourea complex compounds

D. I. RYABCHIKOV and L. V. BORISOVA
1962 SovietRxiv: ru-196201.60465

This paper examines complex compounds formed by rhenium with thiourea in hydrochloric acid media, extending earlier work on the yellow-green analytical complex. By varying acid concentration and the molar ratio of perrhenic acid to stannous chloride, the authors identify at least four colored comple…

Magnetic Susceptibility and Stereochemistry of $\mathrm{Mo}$ (III) Complex Compounds with Urea, Thiourea, and Their Derivatives

V. B. EVDOKIMOV, V. V. ZELENTSOV, I. D. KOLLI, TAM VZEN-SYA
1962 SovietRxiv: ru-196201.60353

This paper examines the magnetic susceptibility and stereochemistry of trivalent molybdenum complexes with urea, thiourea, and related derivatives. Measurements on nine compounds distinguish mononuclear complexes, which show magnetic moments close to those expected for three unpaired electrons, from…

Electrical and Paramagnetic Properties of Products of Radiation-Thermal Treatment of Polyethylene

N. A. Bakh, V. D. Bityukov, A. V. Vannikov, and A. D. Grishina
1962 SovietRxiv: ru-196201.60202

This study examines the transformation of polyethylene from a dielectric into a material with semiconductor-like properties under combined radiation and thermal treatment. Pre-irradiated high-pressure polyethylene was pyrolyzed in vacuum at increasing temperatures, and the resulting products were ch…

Elastic Scattering of 6.9 MeV Protons by Chromium and Zinc Isotopes

B. F. Orlenko, Academician of the Academy of Sciences of the Ukrainian SSR M. V. Pasechnik, V. S. Prokopenko,
1962 SovietRxiv: ru-196201.60199

Elastic scattering of 6.9 MeV protons by separated chromium and zinc isotopes was investigated to examine isotope-dependent differences in angular distributions and their implications for nuclear potential descriptions. Measurements were made for chromium-50, -52, -53, -54 and zinc-64, -68, -70 usin…

On the Construction of High-Quality Automatic Control Systems for Plants with Varying Parameters

S. V. EMEL’YANOV and M. A. BERMANT
1962 SovietRxiv: ru-196201.60147

This paper addresses the design of automatic control systems for plants whose parameters vary over wide ranges, using variable-structure, piecewise-linear control laws. The authors analyze conditions under which a sliding mode arises on a switching hyperplane and show that, once the system trajector…

On Riesz Bases in $\mathscr{L}_2(0,1)$

Unknown
1962 SovietRxiv: ru-196201.60136

This note studies when the root functions of an ordinary linear differential operator on a finite interval form a Riesz basis in the space of square integrable functions. For operators of arbitrary order with sufficiently smooth summable coefficients and strongly regular boundary conditions, the pap…

Stationary Electrochemical Process in an Irradiated $\mathrm{Pt}$ | Sulfuric Acid Solution | $\mathrm{Au}$ System

Unknown
1962 SovietRxiv: ru-196201.60059

This paper examines the conditions for maintaining a stationary directed electrochemical process in irradiated sulfuric acid solutions containing water radiolysis products. The authors argue and experimentally show that a single platinum electrode, even when selective toward radiolysis products, can…

Reactions of Diene Hydrocarbons with Nitroso Compounds. Addition of Isoprene and 2-Methoxy-1,3-butadiene to Nitrosobenzene

Yu. A. ARBUZOV and L. K. LYSANCHUK
1962 SovietRxiv: ru-196201.60058

This study examines the addition of nitrosobenzene to 2-substituted conjugated dienes, specifically isoprene and 2-methoxybutadiene-1,3, in the context of diene synthesis leading to substituted 3,6-dihydro-1,2-oxazines. The structure of the isoprene adduct was established by reductive cleavage to an…

Vacancy Chromatography

A. A. ZHUKHOVITSKII and N. M. TURKEL’TAUB
1962 SovietRxiv: ru-196201.60057

This paper proposes vacantochromatography, a variant of chromatography in which a pulse of carrier gas creates a moving vacancy in a sorbed layer rather than introducing a sorbed sample band. The authors argue from chromatographic dynamics that, in the linear sorption region, vacancy motion and spre…

DETERMINATION OF THE DIFFUSION COEFFICIENTS OF ELEMENTS IN LIQUID CAST IRON BY OSCILLOGRAPHY AT CONSTANT CURRENT

Unknown
1962 SovietRxiv: ru-196201.60027

This paper investigates diffusion coefficients of silicon, titanium, vanadium, and niobium in carbon-saturated liquid cast iron, addressing discrepancies and possible convection errors in earlier capillary-based measurements. The authors apply constant-current oscillography, using the time required …

On a boundary estimate for the solution of an elliptic-type equation of arbitrary order with constant coefficients

Unknown
1962 SovietRxiv: ru-196201.60020

The paper derives boundary growth estimates in the L2 metric for generalized solutions of elliptic-type Euler equations of arbitrary order associated with a positive definite Dirichlet integral, primarily in two dimensions with extension to higher dimensions indicated by analogy. Using normal coordi…