Showing 50 of 25456 papers

Viscosity and activation heats of concentrated polymer solutions as functions of concentration, temperature, and solvent nature

Unknown
1962 SovietRxiv: ru-196201.30421

This paper examines how solvent nature affects the viscosity and activation heat of viscous flow in concentrated polymer solutions over a broad concentration range. Viscosities of polyisobutylene and polystyrene solutions in several solvents were measured at low shear rates and at 20, 35, and 50 deg…

Effect of Noise on the Spectral Composition and Angular Distribution of Generation in a Finite Plane-Parallel Layer

Academician of the Academy of Sciences of the Belorussian SSR B. I. STEPANOV and A. M. SAMSON
1962 SovietRxiv: ru-196201.30373

This paper analyzes how noise radiation affects the spectral composition and angular distribution of emission from a finite plane-parallel layer with negative absorption. Using wave-optical expressions derived from Maxwell’s equations together with a nonlinear absorption coefficient, the authors com…

Investigation of the Equilibrium of Alloys Based on the $\gamma$ Solid Solution of the $\mathrm{Fe}$ – $\mathrm{Cr}$ – $\mathrm{Ni}$ – $\mathrm{Mn}$ – $\mathrm{Nb}$ – $\mathrm{V}$ – $\mathrm{Si}$ System

Unknown
1962 SovietRxiv: ru-196201.30248

This study examines phase equilibria in complex iron-based austenitic alloys using a seven-component Fe-Cr-Ni-Mn-Nb-V-Si gamma solid solution as the base composition. Treating this homogeneous base alloy as a single component, the authors investigated additions of titanium, aluminum, and tungsten al…

Study of the free radical

Academician A. E. Arbuzov, F. G. Valitova, A. V. Il’yasov, B. M. Kozyrev,
1962 SovietRxiv: ru-196201.30153

The paper reports the synthesis and electron paramagnetic resonance study of the stable free radical alpha,alpha-diphenyl-beta-pentaphenylcyclopentadienylhydrazyl in solution and in the crystalline state. EPR spectra in several solvents show seven main hyperfine components attributed to coupling wit…

Justification of the Dirichlet Principle for the First Boundary Value Problem of Nonlinear Elasticity Theory

Unknown
1962 SovietRxiv: ru-196201.30097

This paper justifies Dirichlet’s principle for the first boundary-value problem in a class of nonlinear elasticity models where the deviators of strain and stress are related by a hardening law. The argument formulates the displacement problem as minimization of a uniformly convex energy functional …

Redox Properties of Compounds with Two Ferrocenyl Groups

E. G. PEREVALOVA, S. P. GUBIN, S. A. SMIRNOVA, A. N. NESMEYANOV
1962 SovietRxiv: ru-196201.29997

The study examines how one ferrocenyl nucleus affects the oxidation-reduction properties of another when two ferrocenyl groups are connected directly or through linkers such as mercury, methylene, ethylene, ether, and ammonium-containing groups. Formal redox potentials were determined by potentiomet…

Photoconductive single crystals of lead oxide

Unknown
1962 SovietRxiv: ru-196201.29783

This paper reports the preparation and photoelectric characterization of lead oxide single crystals grown by slow cooling from concentrated alkaline solution. Among several crystal habits obtained, appreciable visible photoconductivity was observed only in red crystals, whose dark resistance, temper…

ON THE PROBABILISTIC FORMULATION OF TWO ECONOMIC PROBLEMS

Unknown
1962 SovietRxiv: ru-196201.29671

The paper gives probabilistic formulations and asymptotic estimates for two combinatorial optimization problems with random data: the Euclidean traveling salesman problem and the assignment problem. For independent random points in Euclidean space with density, it constructs lower and upper random e…

Expansion in Eigenfunctions of Non-Self-Adjoint Singular Second-Order Differential Equations

Let us consider the differential equation
1962 SovietRxiv: ru-196201.29351

This paper extends Marchenko’s spectral expansion theory for non-self-adjoint singular second order differential equations from the half-line to the whole real line. For the equation with locally summable complex potential, the author uses transformation operators relating the fundamental solutions …

Accounting for averaging over the ground vibrational state in calculating the second moment of the nuclear magnetic resonance signal

Unknown
1962 SovietRxiv: ru-196201.29166

This paper examines discrepancies between calculated and experimental second moments of proton nuclear magnetic resonance signals in solids, especially ice, where rigid-lattice Van Vleck calculations give values below observation. The authors argue that the zero-point uncertainty of proton positions…

On the Effect of Friction on the Critical Load of a Compressed Rod

In the present paper a solution of the indicated problem is given for the simplest example of a cantilever rod.
1962 SovietRxiv: ru-196201.28989

This paper examines how small velocity-dependent friction affects the critical load and stability boundary of a compressed cantilever rod subjected to end weight and a follower force. Using a two-degree-of-freedom model with end deflection and rotation as generalized coordinates, the authors derive …

Copolymerization of Butadiene with Isoprene under the Influence of Butyllithium Complexes with Triethylamine and Tetrahydrofuran

L. S. BRESLER, B. A. DOLGOPLOSK, M. F. KOLECHKOVA and E. N. KROPACHEVA
1962 SovietRxiv: ru-196201.28650

The study examines the copolymerization of butadiene with isoprene under anionic conditions using complexes of n-butyllithium with triethylamine or tetrahydrofuran. Polymerizations were conducted at low conversion under argon, and copolymer composition was determined using carbon-14 labeled butadien…

On the Magnetic Properties of $\mathrm{U}_2\mathrm{O}_5$

Unknown
1962 SovietRxiv: ru-196201.28641

This paper examines the valence state and magnetic behavior of uranium in U2O5, addressing whether the oxide should be regarded as a pentavalent uranium compound or as a mixed UO2·UO3 compound containing tetravalent and hexavalent uranium. Magnetic susceptibilities of two U2O5 preparations, along wi…

Study of the Addition Reaction of Dichlorosilane to Alkenylsilanes

G. V. ODABASHYAN, T. A. ZHURAVLEVA, and A. D. PETROV
1962 SovietRxiv: ru-196201.28480

The study examines the synthesis of bridged organosilicon monomers by adding dichlorosilane to vinyl- and allylsilanes in the presence of chloroplatinic acid, a route relevant to polymers containing alternating siloxane and carbon-carbon linkages. A series of reactions was carried out in an autoclav…

Reactions of Polyfluorinated Nitrosoalkanes with Unsaturated Compounds

S. P. MAKAROV, V. A. SHPANSKII, V. A. GINSBURG, A. I. SHCHEKOTIKHIN,
1962 SovietRxiv: ru-196201.28064

This paper examines the reactivity of trifluoronitrosomethane and related polyfluorinated unsaturated compounds toward a range of unsaturated substrates beyond polyfluoroolefins. Through autoclave and low-temperature reactions with olefins, acetylenes, ketenes, azodicarboxylic esters, diazo compound…

A Boundedness Criterion for Solutions of Linear Partial Differential Equations with a Leading Term

M. A. RUTMAN
1962 SovietRxiv: ru-196201.27976

The paper establishes a criterion for bounded solvability of a Cauchy, Goursat problem for linear partial differential equations in several variables with Banach-space-valued unknowns and a distinguished highest derivative term. Under compactness and weak variation at infinity assumptions on the ope…

Piezospectroscopic Effect in Ruby Crystals

Unknown
1962 SovietRxiv: ru-196201.27820

This paper investigates the piezospectroscopic effect in synthetic ruby crystals as a means of identifying the nature of chromium-related absorption and luminescence centers. Oriented crystals were subjected at 77 K to uniaxial compression along selected crystallographic directions, and shifts, spli…

Electrical Conductivity and Activation Energy of Chelate Compounds of Dithiocarbamates of Thioamides of Pyridine Derivatives

A. P. Terent'ev, E. G. Rukhadze, V. M. Vozzhennikov, Z. V. Zvonkova, N. S. Oboladze, I. G. Mochalina
1962 SovietRxiv: ru-196201.27771

This study examines how atomic structure affects the semiconductor properties of chelate polymers and related monomeric metal dithiocarbamate complexes containing copper, cobalt, zinc, and comparable metal-free precursors. Electrical conductivity was measured as a function of temperature, and activa…

Cyclomatic and distributive properties of multigraphs

Unknown
1962 SovietRxiv: ru-196201.27500

This paper studies invariants of finite undirected multigraphs with loops and parallel edges through deletion and contraction recurrences for normal edges. It defines polynomial functions satisfying these recurrences, establishes their invariance properties, multiplicative behavior, and special valu…

Shock compressibility of liquid nitrogen and solid carbon dioxide

V. N. ZUBAREV and G. S. TELEGIN
1962 SovietRxiv: ru-196201.27054

This paper reports shock compression measurements for liquid nitrogen and solid carbon dioxide, substances relevant to the products of condensed explosive detonation, at pressures far beyond those accessible by static methods. Plane shock waves were generated using explosive charges and high velocit…

On the mechanism of structure formation in hydrocarbon suspensions of carbon black in connection with the problem of active fillers for rubbers

B. Ya. Yampol’skii, Yu Shu-Shu, and Academician P. A. Rebinder
1962 SovietRxiv: ru-196201.27005

This paper examines the mechanism of structure formation in hydrocarbon suspensions of carbon black as model systems for understanding active rubber fillers. Using electrical conductivity measurements, current-voltage curves, and observations of thixotropic structural-mechanical behavior, the author…

Spectra of the Universal Fluorescence of Polymers

V. F. Gachkovskii
1962 SovietRxiv: ru-196201.27004

This study quantitatively examines the universal fluorescence spectra of several polymers using an ISP-73 spectrosensitometer, extending earlier qualitative observations on the relation between spectral structure and molecular weight. The measurements show that fluorescence depends on chemical struc…

ON THE SORPTION OF WATER VAPOR ON CALCIUM HYDROSILICATES

Unknown
1962 SovietRxiv: ru-196201.27002

This study examines the binding and sorption of water vapor in low temperature calcium hydrosilicates with CaO to SiO2 ratios from 0.1 to 1.0, a point left unclear in earlier work on the CaO, SiO2, H2O system. Samples prepared by reacting silica gel with calcium hydroxide were characterized by water…

On the Stability of a Thick Plastically Deformable Plate

I. D. Legenya
1962 SovietRxiv: ru-196201.26885

The paper analyzes the stability loss of a thick rectangular simply supported plate uniformly compressed in one direction, treating the material as incompressible and plastically deformable. It formulates the problem using elastic-plastic flow theory for an anisotropically hardening material, derive…

On estimates of the number of plane graphs

Unknown
1962 SovietRxiv: ru-196201.26664

The paper studies enumeration problems for planar graphs and planar realizations motivated by the synthesis of logical and contact circuits. It develops combinatorial encodings of plane rooted trees as “rivers” and of certain planar structures as rosettes, using these constructions to bound the numb…

On Diffusion Extraction from Porous Materials during Capillary Impregnation

B. V. DERYAGIN, M. A. AL’TSHULER
1962 SovietRxiv: ru-196201.26611

This paper develops a diffusion model for extraction of substances from porous materials during capillary impregnation, focusing on pores whose walls carry a thin soluble or adsorbed layer and whose remaining volume initially contains gas. By treating transport in a moving coordinate system attached…

On the Influence of a Magnetic Field on the Increase in the Amplitude of Acoustic Waves in a Medium with Decreasing Density

B. A. TVERSKOI
1962 SovietRxiv: ru-196201.26527

The paper examines how a magnetic field affects the growth of acoustic wave amplitudes in a medium whose density decreases, a process that in gas dynamics can lead to cumulative acceleration and shock formation. Using linear magnetohydrodynamics, it analyzes small vertical oscillations in an isother…

Study of the Immobilization of a Dispersion Medium Under the Influence of Structure-Forming Additives

Unknown
1962 SovietRxiv: ru-196201.26444

The study examines immobilized water in hydrophilic disperse systems, especially peat humic colloids, under the influence of structure-forming calcium and sodium additives. Using radioactive indicators, including labeled sulfate and calcium chloride, the authors distinguish nonsolvent water into phy…