Showing 50 of 25456 papers

Quantitative Determination of Salts and Their Mixtures with Acids and Bases by Potentiometric Titration in a Methyl Ethyl Ketone Medium

A. P. Kreshkov, A. N. Yarovenko, and I. Ya. Zelmanova
1962 SovietRxiv: ru-196201.20110

A potentiometric method is described for the quantitative acid base analysis of salts and multicomponent mixtures of salts with acids or bases in methyl ethyl ketone, addressing limitations of aqueous titration caused by non-titratable salts and leveling effects. The procedure treats the sample with…

AN EXAMPLE OF THE APPLICATION OF S. L. SOBOLEV’S EMBEDDING THEOREM IN COMPUTATIONAL MATHEMATICS

Suppose it is required to solve approximately the boundary-value problem
1962 SovietRxiv: ru-196201.20030

This paper justifies a fictitious-domain method for the numerical solution of a Dirichlet problem for the Poisson equation in a plane domain bounded by coordinate-parallel line segments. The method embeds the domain in a rectangle, solves an auxiliary transmission problem with a large parameter on t…

On a Generalized Concept of a Spectral Operator

V. E. LYANTSE
1962 SovietRxiv: ru-196201.19990

This paper proposes a generalized framework for spectral theory of non-self-adjoint operators when invariant subspaces are complete but need not yield unconditionally convergent eigenvector expansions. It introduces generalized resolutions of the identity on rings of Borel sets, constructs associate…

On the Reduction of a Game with Perfect Recall to a Matrix Game

I. V. ROMANOVSKII
1962 SovietRxiv: ru-196201.19984

This paper addresses finite two-person zero-sum positional games with perfect recall and develops a reduction of the search for optimal behavior strategies to a constrained matrix game. The method constructs an information tree for each player, preserving the partial ordering of that player’s inform…

On the Theory of Terrestrial Atmospherics

P. E. Krasnushkin
1962 SovietRxiv: ru-196201.19876

This paper develops a theoretical description of terrestrial atmospherics produced by the return stroke of lightning and propagated in the spherical Earth, ionosphere waveguide. Representing the discharge as a vertical Hertz dipole with a prescribed current moment, the author expresses the received …

Study of the Catalytically Active Centers of Lysozyme

N. A. KRAVCHENKO, G. V. KLEOPINA, and E. D. KAVERZNEVA
1962 SovietRxiv: ru-196201.19872

This study examines whether the single histidine residue in lysozyme is essential to its catalytic activity. Lysozyme from hen egg white was selectively modified with iodoacetic acid at pH 5.5, the reaction products were separated chromatographically, and the modified protein was compared with nativ…

Synthesis and Study of Rhenium(IV) Aminohalides. Preparation and Properties of Rhenium Dipyridinetetrabromide

Unknown
1962 SovietRxiv: ru-196201.19784

This study addresses the limited knowledge of aminohalide complexes of tetravalent rhenium, especially bromide analogues, by synthesizing pyridinium hexabromorhenate and using it as a precursor to rhenium dipyridinetetrabromide. Thermal analysis, decomposition experiments, elemental analysis, conduc…

On One Model of Quantum Field Theory

V. D. KUKIN, A. R. FRENKIN
1962 SovietRxiv: ru-196201.19700

This paper examines an exactly solvable model of quantum field theory with interacting particles of three types, designed to clarify the appearance of ghost states under violations of crossing symmetry. Using Green’s functions in sectors with fixed conserved quantum numbers, the authors derive the o…

Some problems in the theory of optimal control

Yu. V. EGOROV
1962 SovietRxiv: ru-196201.19583

This paper studies optimal control problems for processes governed by the one-dimensional heat equation with boundary or initial controls bounded in magnitude. It proves existence of controls minimizing terminal deviation functionals, analyzes conditions under which such controls are nonunique, and …

On Paracompact Spaces and Their Continuous Mappings

V. PONOMAREV
1962 SovietRxiv: ru-196201.19429

This note characterizes paracompact spaces through projection spectra and perfect irreducible mappings. It defines regular and uniform spectra of simplicial complexes, proves that the spaces of regular uniform spectra are paracompact, and conversely constructs a complete regular uniform spectrum for…

On a General Approximate Method for Solving Linear Problems

Unknown
1962 SovietRxiv: ru-196201.19077

This paper studies a general approximate method for linear problems in normed spaces, seeking finite linear combinations from an operator complete system that minimize the residual norm and converge to the best attainable approximation. The proposed method reduces the finite dimensional convex minim…

Effect of Curvature on the Propagation Velocity of a Laminar Flame in a Lean Propane-Air Mixture

V. S. BABKIN, I. L. KUZNETSOV, L. S. KOZACHENKO
1962 SovietRxiv: ru-196201.19051

This paper investigates how spherical curvature affects the normal propagation velocity of laminar flames in lean propane air mixtures, a question relevant to flame stability, combustion near ignition limits, and flame propagation in confined or low pressure conditions. Detached nearly spherical bur…

On Spaces with a Point-Countable Base

Unknown
1962 SovietRxiv: ru-196201.18994

This note studies topological spaces with point-countable bases, especially the extent to which such bases imply metrizability or compactness properties. It proves that any bicompact T1 space whose base has bounded point multiplicity has base cardinality bounded by the same cardinal, yielding in par…

Embedding of zero-dimensional compacta in $E^n$

Lyudmila **KELDYSH
1962 SovietRxiv: ru-196201.18972

This paper studies embeddings of zero-dimensional compacta in Euclidean space, with emphasis on distinguishing tame embeddings from wild ones in dimensions at least three. It introduces the notion of a cellularly separated compactum and proves that any cellularly separated zero-dimensional compactum…

The thermodynamics of tungsten oxides of variable composition

R. F. KSENOFONTOVA, I. A. VASIL'EVA
1962 SovietRxiv: ru-196201.18671

This paper examines the thermodynamics of nonstoichiometric tungsten oxides in the composition range WO2.702 to WO2.976, where available data for variable-composition oxides were limited. The authors used an electromotive-force method with a calcia-stabilized zirconia solid electrolyte and an iron, …

Radial distribution of positive column plasma in a magnetic field

L. L. ARTSIMOVICH and A. V. NEDOSPASOV
1962 SovietRxiv: ru-196201.18417

This paper investigates the radial plasma density distribution in the positive column of a helium gas discharge subjected to a longitudinal magnetic field above the instability threshold. Using movable spherical probe measurements in a long glass discharge tube, together with measurements of the lon…

On the Lee Model

F. A. BEREZIN
1962 SovietRxiv: ru-196201.18249

This paper examines whether the Lee model can be formulated in Hamiltonian terms by replacing the formal divergent Hamiltonian with a self-adjoint extension of its restriction to vectors annihilated by the interaction. The analysis shows that in the three-dimensional model, within the ordinary Hilbe…

On Domains Star-Shaped with Respect to a Ball

The following assertion proves the validity of this conjecture.
1962 SovietRxiv: ru-196201.18169

This note addresses a conjecture arising in the use of Sobolev embedding theorems, namely that every bounded domain satisfying the cone condition can be expressed as a finite union of domains star-shaped with respect to balls. The proof establishes a compactness-type lemma: if a bounded domain is co…

Diffusion of Water Molecules in Natrolite

Unknown
1962 SovietRxiv: ru-196201.17894

Proton nuclear magnetic resonance was used to study the mobility and diffusion of water molecules in a natural single crystal of natrolite, a zeolite whose channels contain alternating sodium atoms and water molecules. Temperature-dependent spectra show a direct transition near 135 to 180 °C from a …

Electrode Potentials of Radioactive Samples of Armco Iron and Steel-2 in Distilled Water and Aqueous Inhibitor Solutions

K. N. Yandushkin, S. A. Balezin, Academician Vikt. I. Spitsyn
1962 SovietRxiv: ru-196201.17764

This study examines how induced radioactivity affects the electrode potentials and corrosion behavior of Armco iron and steel-2 in distilled water and in aqueous sodium nitrite and sodium benzoate inhibitor solutions. Neutron-irradiated samples containing Fe-59 were compared with inactive controls b…

Methylcyclopentadiene as an Equilibrium Mixture of Isomers

Unknown
1962 SovietRxiv: ru-196201.17718

This study examines the interconversion of 1-, 2-, and 5-methylcyclopentadienes, focusing on the hindered thermodynamic equilibrium among isomers differing in the positions of intracyclic double bonds. 5-Methylcyclopentadiene was obtained by low-temperature alkylation of cyclopentadienylmagnesium br…

Paramagnetic Relaxation in Vanadyl Sulfate and Its Solutions

Unknown
1962 SovietRxiv: ru-196201.17674

Paramagnetic absorption was measured by the Q-meter method in solid vanadyl sulfate hydrate and in aqueous vanadyl sulfate solutions over several concentrations and radiofrequencies. Spin-lattice relaxation times and internal-field constants were determined from two-frequency susceptibility measurem…

Organosilicon Compounds of the Furan Series. Organosilicon Derivatives of Furylcarbinols and 5-Substituted Furfuryl Alcohols

E. Ya. LUKEVITS, Yu. P. ROMADAN, Academician of the Academy of Sciences of the Latvian SSR S. A. GILLER
1962 SovietRxiv: ru-196201.17493

This study examines the synthesis of organosilicon derivatives of furylcarbinols and substituted furfuryl alcohols, extending earlier work on furfuryloxysilanes. Trialkylchlorosilanes were reacted with furylalkyl and furylaryl carbinols in the presence of pyridine, and hydrosilanes were reacted with…

Categories of group representations and the problem of classifying irreducible representations

I. M. GELFAND, M. I. GRAEV
1962 SovietRxiv: ru-196201.17150

This note studies the category of representations of the group of second order unimodular matrices over a finite field of odd characteristic, associated with its unipotent subgroup. Using induced representations from additive characters, it describes the corresponding intertwining rings and spaces, …

Multiple production of nucleon pairs by thermal photons in an open cosmological model

D. A. FRANK-KAMENETSKII
1962 SovietRxiv: ru-196201.17146

This paper examines the possible multiple production of nucleon and antinucleon pairs by thermal photons in an open cosmological model filled with equilibrium radiation. Using detailed balance for the inverse of two-photon annihilation, it estimates the probability of single and multiple pair creati…

On the Preparation of Alkylmagnesium Halides from Primary Alkyl Halides and Magnesium in a Hydrocarbon Medium

Unknown
1962 SovietRxiv: ru-196201.16899

This paper examines the preparation of alkylmagnesium and arylmagnesium halides directly from halides and magnesium in hydrocarbon media without ether or other Grignard catalysts, addressing earlier conflicting reports that such reactions were slow or of little preparative value. The authors systema…

Diophantine Equation with a Matrix Exponential Function

Unknown
1962 SovietRxiv: ru-196201.16879

This note extends work of Mineev on Diophantine equations with exponential terms to equations involving powers of a nonsingular integral matrix. It obtains an asymptotic formula, with a remainder term, for the number of solutions in a finite interval to a matrix Diophantine equation containing vecto…

Polymerization of Ethylene with a Soluble Organometallic Complex Catalyst $\mathrm{Sn}(\mathrm{C}_6\mathrm{H}_5)_4+\mathrm{AlCl}_3+\mathrm{VCl}_4$

L. L. Stotskaya, A. V. Topchiev, B. A. Krentsel
1962 SovietRxiv: ru-196201.16858

Ethylene polymerization was studied using the soluble organometallic catalytic system tetraphenyltin, aluminum chloride, and vanadium tetrachloride in cyclohexane at 65 °C under near atmospheric pressure. The work examines the behavior of this homogeneous catalyst, including the influence of compone…

Electroreduction of Anions and Adsorption Phenomena on a Dropping Thallium Amalgam Electrode

A. N. FRUMKIN, O. A. PETRII, N. V. NIKOLAEVA-FEDOROVICH
1962 SovietRxiv: ru-196201.16846

This study examines how the shift of the point of zero charge and adsorption phenomena affect the electroreduction of anions on dropping thallium amalgam electrodes. Polarographic and differential capacitance measurements were made for peroxydisulfate, ferricyanide, and tetrachloroplatinate anions o…