Showing 50 of 25456 papers

Selective Sorption on Porous Glasses

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1961 SovietRxiv: ru-196101.48673

This paper examines selective sorption in porous glasses produced by acid leaching of alkali silicate glasses, comparing their behavior with molecular sieve zeolites. Sorption isotherms for water, alcohols, nitrogen, and hydrocarbons show that some porous glasses strongly absorb small molecules such…

Convex Homogeneous Domains

Unknown
1961 SovietRxiv: ru-196101.48587

This paper studies convex domains homogeneous under affine transformations, with projectively homogeneous bounded convex domains reformulated through associated homogeneous cones. It establishes structural results for the automorphism group, including maximal compact stabilizers, embedding in an alg…

Entropy of the Horocycle Flow

B. M. GUREVICH
1961 SovietRxiv: ru-196101.48374

This note proves that the horocycle flow on a compact surface of constant negative curvature has zero entropy, in contrast with the known positive entropy of the corresponding geodesic flow. The argument constructs a finite measurable partition of the space of line elements such that, for sufficient…

On Symmetric Spaces of Affine Connection of the First Class

Unknown
1961 SovietRxiv: ru-196101.48327

The paper studies the immersion of torsion-free symmetric spaces of affine connection of the first class into an affine space of minimal dimension, under the assumptions that the Ricci tensor is nondegenerate and, for dimension greater than two, that the curvature matrix has rank greater than two. U…

ON THE TYPE OF GLUING OF A STRIP

Unknown
1961 SovietRxiv: ru-196101.48100

The paper studies when a Riemann surface obtained by conformally gluing the two boundary lines of an infinite strip by a continuously differentiable increasing function has parabolic type. It constructs piecewise linear approximations to the gluing function, decomposes the strip into quadrilaterals,…

ON THE STABILITY OF COMBUSTION OF POROUS EXPLOSIVES

Unknown
1961 SovietRxiv: ru-196101.48082

This paper analyzes the breakdown of normal combustion in powdered and porous explosives, relating the instability to the penetration of hot combustion gases into pores and surface irregularities. It formulates a critical condition in which the characteristic pore or roughness size becomes comparabl…

On the Reducibility of Continuous Functions of a Real Variable and the Structure of Fixed Points of the Corresponding Iterative Process

A. N. SHARKOVSKII
1961 SovietRxiv: ru-196101.47992

This paper studies continuous self-maps of the real line through reducible invariant sets and the structure of fixed points of their iteration processes. It establishes relations among periodic points of different orders, including restrictions when periods that are powers of two are absent and the …

SPECIFIC ADSORPTION OF IODINE IONS ON SILVER

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1961 SovietRxiv: ru-196101.47845

This study examines the specific adsorption of iodide ions on silver in 1.0 N sulfuric acid and its effect on hydrogen overvoltage. Using iodine 131 radiochemical measurements combined with polarization and differential capacitance measurements, the authors determine adsorption as a function of elec…

Current buildup in dielectrics under gamma irradiation

Unknown
1961 SovietRxiv: ru-196101.47728

This paper examines the time dependence of radiation-induced electrical current in dielectrics exposed to gamma irradiation, with attention to the role of electron traps and recombination centers. Using a simplified kinetic model for free-electron generation, recombination, and trap capture, it expl…

On Isotopic Analysis of Nitrogen by Electron Paramagnetic Resonance

and Corresponding Member of the Academy of Sciences of the USSR G. A. RAZUVAEV
1961 SovietRxiv: ru-196101.47682

This paper examines the use of electron paramagnetic resonance for quantitative isotopic analysis of nitrogen-14 and nitrogen-15 in nitrogen-containing compounds. The method converts sample nitrogen to ammonia and then to a stable nitroxide radical, 2,2,6,6-tetramethyl-N-dehydropiperidone-4-oxide-1,…

On the Structure of “Anomalous” Aminonitrile Complex Compounds of Platinum(II)

Yu. Ya. Kharitonov, Ni Tsze-Tsang, and A. V. Babaeva
1961 SovietRxiv: ru-196101.47668

This paper examines the disputed structure of “anomalous” aminonitrile complexes of divalent platinum, whose formulas appeared to imply coordination numbers higher than four. The authors use infrared absorption spectra of solid nitrile platinum complexes, related non-anomalous complexes, and anomalo…

A paper chromatography method for diaryl organotin compounds and its application to the study of the reaction products of unsymmetrical diaryliodonium salts with tin(II) chloride

O. A. REUTOV, O. A. PTITSYNA, and M. F. TURCHINSKII
1961 SovietRxiv: ru-196101.47240

This paper develops a paper chromatographic method for separating and identifying symmetrical and unsymmetrical diaryltin dichlorides, using oil-impregnated chromatographic paper, methanol in hydrochloric acid as the mobile phase, and diphenylcarbazone detection. The method is applied to reaction mi…

On the condensation (sticking) coefficient of gas molecules during their chemisorption on a metal surface

Unknown
1961 SovietRxiv: ru-196101.47235

This paper examines the apparent decrease of the condensation, or sticking, coefficient observed during chemisorption of gases on metal surfaces as adsorbate concentration increases. It argues that the true chemisorption coefficient may be independent of surface concentration, while the measured dec…

Some Theorems on Diffusion Processes with a Small Diffusion Coefficient and Their Applications to Second-Order Parabolic Equations with a Small Parameter

Yu. N. BLAGOVESHCHENSKII
1961 SovietRxiv: ru-196101.47227

This paper studies diffusion processes with a small diffusion coefficient and derives local asymptotic results for their transition densities as the small parameter tends to zero. Starting from an asymptotic expansion of the stochastic process around the deterministic solution, it gives conditions u…

Faye gravitational anomalies and isostasy

B. A. ANDREEV
1961 SovietRxiv: ru-196101.47123

This paper examines whether mean Faye gravity anomalies can be used to infer isostatic compensation where direct calculation of isostatic anomalies is difficult. Using published data for 2210 continental stations and 596 oceanic stations, it analyzes the correlation between the difference of Faye an…

Radiolysis of n-Hexane

V. G. BEREZKIN, A. E. MYSAK, and L. S. POLYAK
1961 SovietRxiv: ru-196101.47086

This study examines the gamma radiolysis of purified, degassed n-hexane at room temperature in a low integral dose range, 3 x 10^18 to 1 x 10^20 eV/ml, where earlier work had provided limited kinetic information. Gaseous C1 to C4 hydrocarbon products were measured by gas chromatography using a highl…

KINETICS OF THE REACTION OF REDUCTION OF TRIPHENYLCARBINOL BY ISOPROPYL ALCOHOL IN AQUEOUS SULFURIC ACID MEDIUM BY HYDRIDE TRANSFER

Unknown
1961 SovietRxiv: ru-196101.47034

The study examines the kinetics of triphenylcarbinol reduction to triphenylmethane by isopropyl alcohol in aqueous sulfuric acid, treating the process as hydride transfer from nonionized alcohol to the triphenylmethyl cation. Reaction rates were measured spectrophotometrically over varied acid, alco…

Mechanism of Iodine Transfer under Intraparticle Diffusion Kinetics of Its Adsorption on Carbons from Different Solvents

A. N. KHARIN and N. A. KATAEVA
1961 SovietRxiv: ru-196101.47022

This study investigates the mechanism of molecular iodine transfer during intradiffusional adsorption on BAU, KAD, and AG charcoals from water, ethanol, benzene, and carbon tetrachloride. Equilibrium adsorption isotherms, heats of wetting, adsorption kinetics, half-saturation times, and effective in…

On a Criterion for the Completeness of the System of Eigenvectors and Associated Vectors of a Polynomial Operator Pencil

Yu. A. PALANT
1961 SovietRxiv: ru-196101.46748

The note proves a completeness criterion for the eigen and associated vectors of a polynomial operator pencil in a Hilbert space. It extends Keldysh’s result for linear pencils by reducing the polynomial pencil to a linear pencil on the orthogonal sum of n copies of the space, then applying estimate…

Luminescence Spectra of Diamonds from the Mir Pipe

Unknown
1961 SovietRxiv: ru-196101.46688

This study examines the luminescence spectra of more than 100 diamonds from the Mir pipe, focusing on variations in the yellow-green spectral component under ultraviolet excitation and low-temperature observation. Spectra were photographed with prism and grating spectrographs, and selected specimens…

ON A SYSTEM OF EQUATIONS IN THE PROBLEM OF BENDING OF A CIRCULAR PRISMATIC BAR WITH AN ECCENTRIC ELLIPTICAL HOLE

Unknown
1961 SovietRxiv: ru-196101.46630

This paper examines the infinite system of linear algebraic equations previously obtained for the transverse bending of a circular prismatic bar with an eccentric elliptical hole. Using the conformal mapping formulation and contour integral representations of the associated analytic functions, it de…

On the limiting pressure of spontaneous propagation of the reaction zone in acetylene

S. M. Kogarko and B. A. Ivanov
1961 SovietRxiv: ru-196101.46561

This paper reexamines the limiting pressure for spontaneous propagation of an acetylene decomposition reaction zone, a value commonly reported as 1.35 to 1.40 ata. Using steel tubes with optical recording and several ignition methods, including heated nichrome, capacitor sparks, and explosive mixtur…

Quantum-Mechanical Theory of Absorption and Luminescence Spectra of Complex Molecules

Academician of the Academy of Sciences of the Belorussian SSR B. I. STEPANOV
1961 SovietRxiv: ru-196101.46504

This paper develops a quantum mechanical account of the continuous absorption and luminescence bands of complex molecules, focusing on band contours and the origin of Stokes losses. It models electronic excitation as coupled directly to one or a few vibrational degrees of freedom, while the remainin…

Molecular Ions in the Upper Atmosphere

A. D. DANILOV
1961 SovietRxiv: ru-196101.46235

This paper examines mechanisms governing molecular ions in the upper atmosphere using rocket and satellite measurements of ion, electron, and neutral particle concentrations. It argues that charge transfer from atomic ions explains nitrogen molecular ions and lower altitude oxygen molecular ions, bu…

Asymptotics of the Equations of Large Deflection of a Circular Symmetrically Loaded Plate

1.** Consider the system of nonlinear differential equations:
1961 SovietRxiv: ru-196101.46162

The paper studies the singular perturbation problem arising in the nonlinear equations for large axisymmetric deflections of a circular plate under symmetric loading, with several standard edge-fixing boundary conditions. It constructs asymptotic expansions as the plate-thinness parameter tends to z…

PROOF OF THE MINIMALITY OF A CONTACT REALIZATION OF ONE CLASS OF BOOLEAN FUNCTIONS OF \(n\) VARIABLES

Unknown
1961 SovietRxiv: ru-196101.45875

This note proves the minimality of contact circuit realizations for a class of Boolean functions in an arbitrary number of variables, extending known minimality results beyond previously studied cases. The function considered is the chain function, whose perfect disjunctive normal form is analyzed t…

On the Photoconductivity of Polycrystalline Cadmium Sulfide Layers

K. V. SHALIMOVA, T. S. TRAVINA, and R. R. REZVYI
1961 SovietRxiv: ru-196101.45791

This paper investigates the photoconductivity of polycrystalline cadmium sulfide films over wavelengths from 225 to 700 nm as a function of preparation conditions. More than 600 films were deposited on insulating substrates in vacuum, argon, or hydrogen sulfide, with varied substrate temperature and…

Kinetics of Cathodic Processes on Semiconductor Electrodes Involving Valence Band Electrons

R. M. LAZORENKO-MANEVICH and S. O. IZIDINOV
1961 SovietRxiv: ru-196101.45785

This paper develops kinetic expressions for cathodic processes on semiconductor electrodes when valence-band electrons, rather than only conduction-band electrons, participate in the reaction. Starting from established semiconductor electrode theory and assuming no surface states, the authors derive…

Organoboron compounds. Complex compounds of borane and phenylborane with diethylamine and some of their transformations

Unknown
1961 SovietRxiv: ru-196101.45403

This study examines complex compounds formed by borane and phenylborane with diethylamine and describes several thermal and substitution reactions of the resulting organoboron compounds. Diethylamine-borane was prepared in high yield from diborane and diethylamine and found to be a liquid rather tha…

Geometric Description of All Possible Representations of a Riemannian Metric in Levi-Civita Form

1°.** As is known, the problem of the geodesic mapping of Riemannian spaces leads to metrics of the form (see (¹))
1961 SovietRxiv: ru-196101.45381

This paper addresses the non-uniqueness of Levi-Civita representations of Riemannian metrics arising in the theory of geodesic mappings, focusing on exceptional metrics whose associated spaces have constant negative curvature. It reduces the description of all such representations to two tasks: clas…

Measurements of the Potential Decay of a Platinum Anode after Interruption of the Polarizing Current

Unknown
1961 SovietRxiv: ru-196101.45334

This study examines the anodic polarization of platinum in perchloric acid by measuring potential decay after interruption of the polarizing current, with particular attention to the potential jump observed during oxygen evolution. Decay curves recorded by oscilloscope were used to estimate electrod…

Scattering Problem for a Difference Equation

V. G. TARNOPOLSKII
1961 SovietRxiv: ru-196101.45314

This note formulates direct and inverse scattering problems for one-dimensional difference equations, first with scalar coefficients and then with operator coefficients in a Hilbert space. Using radiation conditions, weighted Banach spaces, compactness of associated resolvent-type operators, and Fre…