Showing 50 of 25456 papers

Effect of Cations on Oxygen Overvoltage

Academician A. N. FRUMKIN, R. I. KAGANOVICH, E. V. YAKOVLEVA
1961 SovietRxiv: ru-196101.34954

This study examines how added cations affect oxygen overvoltage on platinum during anodic oxygen evolution in perchloric and sulfuric acid solutions. Polarization curves, continuously recorded current, potential curves, and potential decay measurements were used to compare the effects of cesium, pot…

Winter Heat Transfer from the Ocean and Effective Radiation with a Complex Structure of the Continental Surface

Unknown
1961 SovietRxiv: ru-196101.34567

This paper extends an earlier scheme for describing winter atmospheric heat transfer from oceans into continents, treating the active atmospheric layer as a heat conducting and radiating film. Using Australian winter temperature anomalies as a simple case, it argues that a linear decrease of tempera…

Singular Operators of Arbitrary Order on a Manifold

A. S. Dynin
1961 SovietRxiv: ru-196101.34524

The paper introduces singular operators of arbitrary nonnegative order on compact smooth manifolds, unifying differential operators and singular integral operators within a common symbolic framework. It defines their principal symbols intrinsically on the nonzero tangent bundle, proves basic symboli…

ON THE FORM OF EXTREMAL FUNCTIONS OF ONE CLASS, LEAST DEVIATING FROM ZERO AND SATISFYING SEVERAL RELATIONS LINEAR WITH RESPECT TO THE COEFFICIENTS

Unknown
1961 SovietRxiv: ru-196101.34467

The paper studies extremal problems for functions represented by integrals of nonnegative polynomials subject to several linear conditions on their coefficients, with attention to nonsymmetric intervals and cases including monotone behavior on a half-axis. It establishes structural restrictions on e…

On the Differential Properties of the Green's Function for a Multipoint Boundary Value Problem

A. Yu. LEVIN
1961 SovietRxiv: ru-196101.34463

This paper studies the Green’s function for an nth order linear ordinary differential equation with multipoint boundary conditions given by linear functionals of derivatives at prescribed points. Assuming the corresponding homogeneous problem has only the trivial solution, the author derives an expl…

Study of the Optical Properties of Transparent Substances at Ultrahigh Pressures

Ya. B. Zel’dovich, S. B. Kormer, M. V. Sinitsyn, and K. B. Yushko
1961 SovietRxiv: ru-196101.34362

This paper investigates optical methods for determining the refractive index and transparency of transparent substances subjected to ultrahigh pressures in shock waves. Using high-speed photochronography, the authors measured light reflected from shock-wave fronts and analyzed water in detail by bot…

Study of the Thermodynamic Properties of Platinum–Lead Alloys

P. P. Otopkov, Corresponding Member of the Academy of Sciences of the USSR Ya. I. Gerasimov
1961 SovietRxiv: ru-196101.34349

This study determines thermodynamic properties of platinum-lead alloys in the 700 to 875 °C range, with emphasis on the solid intermetallic compounds PtPb and Pt3Pb. Lead activities were measured by the Knudsen effusion vapor pressure method, then used to calculate partial enthalpies and entropies, …

On the Structure of Subspaces of a Hilbert Space

V. V. PASHENKOV
1961 SovietRxiv: ru-196101.34298

This note addresses whether the completion by intersections or cuts of a Dedekind lattice with complements must itself be Dedekind. Using the lattice of subspaces of a Hilbert space, it studies the ordered set consisting of all finite-dimensional subspaces and their orthogonal complements, showing t…

Complex uranyl dicarbonate

Unknown
1961 SovietRxiv: ru-196101.34105

This paper examines the formation of uranyl carbonate complexes in reactions of uranyl nitrate with sodium bicarbonate, contrasting the product with the more commonly reported uranyl tricarbonate species. The authors prepare an isolable crystalline sodium uranyl dicarbonate by adding sodium bicarbon…

Kinetics of the Oxidation of Cyclohexene by Palladium Salts in Aqueous Solutions

M. N. VARGAFTIK, I. I. MOISEEV, and Ya. K. SYRKIN
1961 SovietRxiv: ru-196101.34100

The paper investigates the kinetics of cyclohexene oxidation to cyclohexanone by palladium salts in aqueous perchloric acid solutions, using p-benzoquinone to reoxidize palladium and prevent complications from metallic palladium precipitation. Reaction progress was followed potentiometrically throug…

On Metastable Solutions of Calcium Silicates

==================
1961 SovietRxiv: ru-196101.34071

This study examines the formation of metastable supersaturated solutions during the hydration of beta-dicalcium silicate and tricalcium silicate in the CaO, SiO2, H2O system. Using dilute suspensions protected from atmospheric carbon dioxide, the authors measured calcium and silicate ion concentrati…

Asymptotic Representations and Some Estimates for Integral Error Functions of Arbitrary Order

O. S. BERLYAND and A. Ya. PRESSMAN
1961 SovietRxiv: ru-196101.34066

This paper studies integral error functions of arbitrary real order, defined as solutions of a second order differential equation and represented by an integral for suitable indices. It derives series and asymptotic representations for positive and negative real arguments, treating separately positi…

New Cotidal Charts of Semidiurnal Tidal Waves ( $M_2$ and $S_2$ ) in the Australo-Asian Seas

K. T. BOGDANOV and V. P. NEFED’EV
1961 SovietRxiv: ru-196101.34023

This paper presents new cotidal charts for the principal semidiurnal tidal constituents M2 and S2 in the Australo-Asian seas, a region where large and spatially variable tides had been insufficiently generalized in earlier studies. Using harmonic constants from 650 coastal and island stations, reduc…

Addition of Hydrogen Chloride and Acetic Acid to Isomeric Cyclododeca-1,5,9-trienes

L. I. ZAKHARKIN, V. V. KORNEVA, and A. V. IOGANSEN
1961 SovietRxiv: ru-196101.34014

This study examines the addition of acetic acid and hydrogen chloride to trans,trans,trans- and cis,trans,trans-cyclododecatriene-1,5,9. Using boron trifluoride etherate for acetic acid addition and ferric chloride in methylene chloride for hydrogen chloride addition, the authors compare product com…

Free-radical addition of carboxylic acids to vinyl and allyl acetates

G. N. NIKISHIN, Yu. N. OGIBIN, and A. D. PETROV
1961 SovietRxiv: ru-196101.33926

This paper investigates a route to alkyl-substituted gamma and delta lactones, compounds of interest for odor studies, through free-radical addition of carboxylic acids and their methyl esters to vinyl and allyl esters. Using tert-butyl peroxide at about 155 to 164 degrees, the authors prepared 1:1 …

On Magnetohydrodynamic Effects in the Ocean

Unknown
1961 SovietRxiv: ru-196101.33458

This paper examines weak magnetohydrodynamic effects in the electrically conducting ocean under the Earth’s magnetic field. It derives an exact solution for wind-driven Ekman currents in a conducting half-space with Coriolis forces, estimating the associated electric currents and induced horizontal …

On the Law of Deformation of Highly Elastic Polymer Bodies

Unknown
1961 SovietRxiv: ru-196101.33453

This paper addresses the deformation law of highly elastic polymeric bodies, arguing that high elasticity should be treated as an independent reversible deformation rather than as a combination of elasticity and internal friction. Using molecular considerations of flexible chain segments, it propose…

ON SOME PROPERTIES OF CODE SYSTEMS

Unknown
1961 SovietRxiv: ru-196101.33422

This paper studies effective criteria for recognizing unique decipherability, bounded decoding delay, and synchronization in code systems defined by paired dictionaries of messages and code words. It introduces right and left classes generated from a code dictionary and uses them to give finite test…

On the Order of Best Approximation of Functions Defined on a Continuum by Linear Aggregates of Elements of an Extendable Basis

Unknown
1961 SovietRxiv: ru-196101.33236

This note studies best approximation of functions on a bounded nonseparating continuum by finite linear combinations of elements of a basis of analytic functions. Building on Erokhin’s extension of Bernstein’s theorem and using the principal basis of the space of functions analytic in a surrounding …

Study of the Kinetics of Catalytic Oxidation of Propylene to Acrolein by the Flow-Circulation Method

V. M. BELOUSOV, Ya. B. GOROKHOVATSKII, M. Ya. RUBANIK, and A. V. GERSHINGORINA
1961 SovietRxiv: ru-196101.33215

The study examines the kinetics of catalytic oxidation of propylene to acrolein over a cuprous oxide, copper contact using a flow circulation method designed to minimize distortions from external and internal diffusion. Measurements over varied gas velocities, oxygen and propylene concentrations, te…

Sylow-type theorems

Unknown
1961 SovietRxiv: ru-196101.33180

This note establishes several Sylow type embedding theorems for finite groups, formulated in terms of sets of primes, Pi-subgroups, and Pi-Hall subgroups. It introduces a strong Pi-Sylow condition requiring conjugate embedding of subgroups of appropriate order into a given Pi-subgroup, and proves th…

On the Theory of Anodic Dissolution of Silicon

Unknown
1961 SovietRxiv: ru-196101.33148

The paper develops a theory for the anodic dissolution of electronic silicon, emphasizing that unlike germanium, silicon requires explicit consideration of carrier generation in the near-contact Debye layer. Using transport and recombination equations for the quasineutral and depleted regions, the a…

Homogeneous Functions and Some Problems of Integral Geometry in Spaces of Constant Curvature

V. I. SEMYANISTYI
1961 SovietRxiv: ru-196101.32947

This paper studies integral transformations of homogeneous generalized functions in Euclidean space and the corresponding operators on functions defined on spaces of constant curvature. Using convolution operators, Fourier transforms, analytic continuation, and related transformations on elliptic an…

Effect of terminal substituents in 5-nitrofurylpolyene derivatives on their electronic spectra

Ya. A. EIDUS, K. K. VENTER, and Academician of the Academy of Sciences of the Latvian SSR S. A. GILLER
1961 SovietRxiv: ru-196101.32832

This study examines how terminal substituents influence the electronic absorption spectra of asymmetric 5-nitrofurylpolyene derivatives in which the substituent is separated from the nitrofuran chromophore by zero to four conjugated vinylene groups. Spectral measurements for a series of derivatives …

On exact Weyl multipliers for unconditional convergence

Unknown
1961 SovietRxiv: ru-196101.32764

This note studies Weyl multipliers for unconditional almost everywhere convergence of series in the Haar orthonormal system. Building on earlier results that powers of logarithms with exponent greater than one are sufficient and those with exponent less than one are not, it proves a sharp criterion …

Detection of Spontaneously Arising Effects

Unknown
1961 SovietRxiv: ru-196101.32633

This paper formulates a discrete time problem of detecting a spontaneously arising change in the distribution of independent observations, where the unknown change time has a geometric prior distribution. It relates the expected number of false signals before the change to the probability of a prema…

ON ISOMORPHIC REPRESENTATIONS OF RINGS AND GROUPS

Unknown
1961 SovietRxiv: ru-196101.32507

This paper introduces two notions for the representation theory of complete completely regular rings, and by extension locally compact groups: isomorphism of representations, defined by equality of kernels or equivalently by equality of operator norms on all ring elements, and simple representations…

On a Class of Completely Continuous Operators

V. I. Matsaev
1961 SovietRxiv: ru-196101.32370

This note studies compact operators in the class defined by summability of singular numbers with weights \((2n-1)^{-1}\), and their role in triangular integral representations of Volterra operators in a separable Hilbert space. It proves that for every self-adjoint component in this class and every …

Polanyi's Rule for Proton Transitions and the Hydrogen Bond

E. A. PSHENICHNOV and N. D. SOKOLOV
1961 SovietRxiv: ru-196101.32271

This paper examines Polanyi’s rule for reactions in which proton transfer through a hydrogen bond is the determining step, questioning the usual classical interpretation based on changes in barrier height. The authors model the proton quantum mechanically in an asymmetric double potential well and s…

APPROXIMATE SOLUTION OF A BOUNDARY-VALUE PROBLEM FOR A NONLINEAR ORDINARY DIFFERENTIAL EQUATION OF SECOND ORDER WITH A SMALL PARAMETER AT THE HIGHEST DERIVATIVE ON THE BASIS OF NEWTON’S METHOD

Unknown
1961 SovietRxiv: ru-196101.32114

This paper studies a nonlinear second order boundary value problem with a small parameter multiplying the highest derivative, motivated by the temperature field of a cooled gas turbine blade. The differential equation is formulated as an operator equation in a normed space, and Newton’s method is an…

On a Basis in a Space of Abstract Functions

L. A. GUREVICH
1961 SovietRxiv: ru-196101.32044

The paper studies bases in spaces of abstract functions with values in a Banach space X, constructed from a Banach function space B and a basis in X. It defines the space B^X through approximation by step functions, establishes its basic integration and completeness properties, and formulates condit…

Isometric immersion in the large of a two-dimensional Riemannian manifold into a three-dimensional one

A. V. POGORELOV
1961 SovietRxiv: ru-196101.32019

This note addresses the global isometric immersion of a two-dimensional Riemannian manifold homeomorphic to a sphere into a complete three-dimensional Riemannian space of nonpositive curvature. It improves an earlier curvature condition by proving that, when the ambient sectional curvatures do not e…

Study of the kinetics of the direct substitution of the nitro group by chlorine in nitrobenzene and m-chloronitrobenzene under the action of carbon tetrachloride

Unknown
1961 SovietRxiv: ru-196101.32016

This paper examines the kinetics and probable mechanism of direct substitution of the nitro group by chlorine in nitrobenzene and m-chloronitrobenzene using carbon tetrachloride as the chlorinating agent. Reactions were followed in sealed tubes with a thermophotometer by monitoring visible light abs…