Showing 50 of 25456 papers

On the theory of $I-t$ curves in the reduction of anions at a dropping electrode in the presence of an adsorbing catalyst

Unknown
1961 SovietRxiv: ru-196101.28549

This paper develops a theory of current, time curves for irreversible anion reduction at a dropping mercury electrode in the presence of an adsorbing catalytic species, with explicit allowance for concentration polarization. Starting from convective diffusion near an expanding spherical electrode an…

Ferroelectric Single Crystals with High Nonlinearity

Unknown
1961 SovietRxiv: ru-196101.28424

This paper reports the growth and characterization of barium titanate based ferroelectric single crystals containing small additions of barium hafnate, prepared from a potassium fluoride flux in platinum crucibles. The authors examine dielectric permittivity, field dependent nonlinearity, bias field…

Study of Pathways for the Synthesis of the Peptide Moiety of Ergoalkaloids

G. A. RAVDEL, N. A. KRIT, L. A. SHCHUKINA, and M. M. SHEMYAKIN
1961 SovietRxiv: ru-196101.28369

This study addresses the unresolved structure of the peptide portion of ergoalkaloids by developing synthetic routes to model tripeptides that reproduce the amino acid sequence of ergotamine and related analogues. Using N-benzoyl-alpha-benzyloxy-alpha-amino acids, the authors prepared racemic and op…

On the Construction of the Scattering Matrix in Nonlocal Theories

V. D. KUKIN and A. R. FRENKIN
1961 SovietRxiv: ru-196101.28152

The paper examines how to construct scattering matrices for nonlocal quantum field theories while retaining the graph technique of local perturbation theory. It argues that nonlocality can be introduced by modifying chronological contractions, and hence internal lines of Feynman graphs, without chan…

Inhibition limit in the thermal cracking of alkanes, as dependent on the nature of the inhibitor

A. D. STEPUKHOVICH
1961 SovietRxiv: ru-196101.28111

This paper examines whether the inhibition limit in thermal cracking of alkanes is independent of inhibitor identity, a question bearing on whether the residual reaction is molecular, heterogeneous, or radical-chain in character. Reviewing earlier interpretations and experimental findings, it tests …

Oxidation, Reduction, and Disproportionation Reactions of Polyfluoronitrosoalkanes

A. Ya. Yakubovich, V. A. Ginsburg, S. P. Makarov, V. A. Shpanskii,
1961 SovietRxiv: ru-196101.28089

This paper examines oxidation, reduction, and disproportionation reactions of polyfluorinated aliphatic nitroso compounds, with particular attention to trifluoronitrosomethane. The authors compare behavior in acidic oxidizing media, alkaline aqueous solution, and nonaqueous reactions with nucleophil…

The Structure of Polynomial Ideals and Their Quotient Spaces in Spaces of Infinitely Differentiable Functions

V. P. PALAMODOV
1961 SovietRxiv: ru-196101.28076

The paper studies polynomial ideals in complete spaces of infinitely differentiable functions with prescribed polynomial growth, motivated by solvability and homogeneous solution problems for constant coefficient partial differential equations in spaces of slowly increasing functions or functionals.…

Radicals in group pairs

B. I. PLOTKIN
1961 SovietRxiv: ru-196101.27998

This paper develops a theory of radicals for group pairs, where one group acts by automorphisms on another. It defines abstract properties of group pairs, associated theta-radicals in the acting group and in the domain of action, and studies locally stable and locally theta elements under closure co…

On the Relationship Between Unsaturation and the Rate of Autoxidation of Triglyceride Mixtures of Natural Fats

Unknown
1961 SovietRxiv: ru-196101.27782

This study examines whether the autooxidation rate of natural fat triglyceride mixtures is governed simply by unsaturation as measured by iodine number. Using pork fat samples prepared under nitrogen, the authors determined iodine and thiocyanogen numbers, calculated the average molecular weight per…

System of Copper and Sodium Arsenates and Carbonates

Academician of the Academy of Sciences of the Kirgiz SSR I. G. Druzhinin and A. Akbaev
1961 SovietRxiv: ru-196101.27425

This paper investigates the aqueous system of copper arsenate, sodium carbonate, and water at 50 degrees C, treated as a ternary approximation to a reciprocal quaternary salt system because of the low solubility of the copper salts. Using an isothermal solubility method, chemical analysis of liquid …

An example of a dimensionally deficient compactum

V. KUZ’MINOV
1961 SovietRxiv: ru-196101.27424

For each prime number q, the paper constructs a class of three-dimensional compacta P3(q) as inverse limits of polyhedra obtained by controlled tube identifications generalizing Pontryagin’s compactum P2(q). It analyzes their homological and cohomological dimensions with several coefficient groups, …

On the Thermal Expansion of Water in Microcapillaries

------------------
1961 SovietRxiv: ru-196101.27378

This paper investigates the thermal expansion of water confined in glass microcapillaries with radii comparable to the presumed thickness of boundary liquid layers. A method is described for measuring capillary radius and water-column elongation by optical observation of the meniscus, followed by te…

Polymerization of Styrene, Butadiene, and Isoprene Initiated by Ethyllithium in Various Media

Yu. L. SPIRIN, D. K. POLYAKOV, A. R. GANTMAKHER
1961 SovietRxiv: ru-196101.27342

This study examines the polymerization and copolymerization of styrene, butadiene, and isoprene initiated by lithium ethyl in hydrocarbon and electron-donor media, including toluene, triethylamine, ether, dioxane, and tetrahydrofuran. Kinetic measurements, molecular-weight data, spectrophotometric d…

Divergent series with respect to the Haar system and bases

P. L. ULYANOV
1961 SovietRxiv: ru-196101.27221

This note studies rearrangements of Fourier series with respect to the Haar system, general bases in L2, and orthonormal complete systems, focusing on almost everywhere divergence and nonsummability under arbitrary summability methods. It introduces property D for series whose terms can be rearrange…

Linearly enveloping coupler curves of a four-link ellipsograph

I. I. ARTOBOLEVSKII
1961 SovietRxiv: ru-196101.27202

This paper derives linearly enveloping coupler curves for a general four-link ellipsograph whose sliders move along guides at an arbitrary fixed angle, and for an inverse ellipsograph mechanism. Using instantaneous centers of rotation, perpendicular projections, and parametric equations for the corr…

Catalytic Properties of Cobalt-Manganese Spinels

Unknown
1961 SovietRxiv: ru-196101.27198

This study examines how spinel structure affects the catalytic behavior of normal CoMn2O4 and inverse MnCo2O4 in the deep oxidation of propylene. Reaction rates were measured under static conditions from 200 to 350 °C, with attention to the effects of carbon dioxide removal, reactant pressures, oxyg…

Toward the Theory of Fronts

Unknown
1961 SovietRxiv: ru-196101.26992

This paper develops a simplified hydrodynamic theory of atmospheric fronts separating cold and warm air masses, extending earlier work on frontal surfaces. Under assumptions of hydrostatic balance, small pressure and temperature perturbations, turbulent viscosity, two-dimensional stationary motion i…

ON CONDITIONS FOR THE EXISTENCE OF A SOLUTION OF A QUASILINEAR PARABOLIC EQUATION

Existence theorems for the solution of the first boundary-value problem for the parabolic equation
1961 SovietRxiv: ru-196101.26891

The paper establishes existence and uniqueness results for the first boundary value problem for a one dimensional quasilinear parabolic equation with coefficients depending on time, space, the solution, and its spatial derivative. It weakens earlier growth assumptions on the ratio of the lower order…

Cauchy Directions and Extensions of Regular Spaces

Unknown
1961 SovietRxiv: ru-196101.26838

This paper generalizes the Cantor-Hausdorff completion process beyond metric and uniform spaces by introducing Cauchy directions, defined through primary ideals of an open base in a regular Hausdorff space. It develops basic convergence properties of these directions and proves that suitable equival…

Semigroups with Certain Types of Subsemigroup Structures

Unknown
1961 SovietRxiv: ru-196101.26630

This note studies semigroups through order-theoretic properties of their lattices or posets of subsemigroups, distinguishing between the ordinary subsemigroup structure and the version enlarged by the empty set. It gives structural characterizations for semigroups whose subsemigroups are linearly or…

Adsorption Capacity and Catalytic Activity of Platinized Carbon in the Addition of Certain Silicon Hydrides to Unsaturated Compounds

==================
1961 SovietRxiv: ru-196101.26385

This study examines how adsorption on a 1 percent platinum on carbon catalyst relates to the catalytic addition of selected alkyl and chloroalkyl silicon hydrides to unsaturated fluoroalkyl allyl ethers. Adsorption isotherms at 20 °C were measured in a flow apparatus, saturated vapor pressures were …

On the Mechanism of Transformations of Cyclohexene and Cyclohexa-1,3-diene on Platinum Films

V. M. Gryaznov and V. I. Shimulis
1961 SovietRxiv: ru-196101.26325

This study examines the mechanism of hydrogen redistribution during the transformations of cyclohexene and 1,3-cyclohexadiene on platinum films at 20°C. Using measurements of hydrogen evolution or absorption together with changes in the electrical conductivity of the films, the authors compare condi…

General form of linear differential equations whose order is reduced using the generalized differentiation operator $D^\alpha$

Yu. L. RABINOVICH and S. V. NESTEROV
1961 SovietRxiv: ru-196101.26191

This paper studies linear differential expressions with polynomial coefficients whose order is reduced by the generalized differentiation operator with Euler Cauchy kernel. Under regularity conditions making infinity a regular singular point, the authors derive algebraic conditions on the transforme…

Spaces with centro-projective connection $(\Gamma^i_{jk},\Gamma_{lm})$ as manifolds immersed in the representation space of the prolonged pseudogroup of analytic transformations

Unknown
1961 SovietRxiv: ru-196101.26182

This paper gives an invariant construction of spaces with centro-projective connection from a third-order differential neighborhood using Cartan’s exterior differential equations for the prolonged pseudogroup of analytic transformations. It represents such a space as an n-dimensional submanifold in …

Some Remarks on Flows of Linear Elements and Frames

Unknown
1961 SovietRxiv: ru-196101.26164

This note introduces isotropic flows, a class of tangent dynamical systems on spaces of frames over a Riemannian manifold in which the speed is constant and the curvatures of trajectories depend only on the base point. It proves that such flows preserve the natural measure on the frame space, relate…

Geometry of Two Second-Order Ordinary Differential Equations

Unknown
1961 SovietRxiv: ru-196101.26130

This paper develops a local differential-geometric theory for a pair of second-order ordinary differential equations on the plane under arbitrary analytic point transformations. Using Cartan-type frame canonization for the representation space of the infinite transformation group, it constructs inva…

Thermal Stability and Initiating Activity of Diacyl Peroxides of Paraffinic and Phenylcarboxylic Acids

Unknown
1961 SovietRxiv: ru-196101.25921

This study examines how the structure of diacyl peroxides of paraffinic and phenylcarboxylic acids affects their thermal stability and initiating activity in polymerization. A series of synthesized peroxides was tested by measuring decomposition rates in ethylbenzene, polymerization rates of styrene…

An Interesting Class of Quasilinear Systems

S. K. GODUNOV
1961 SovietRxiv: ru-196101.25840

This paper identifies a class of quasilinear systems written in divergence form through derivatives of generating functions and shows that it includes several equations of mathematical physics, including variational Lagrange equations, crystal optics, and gas dynamics. The author gives explicit redu…

On Some Paley–Wiener Type Theorems

Unknown
1961 SovietRxiv: ru-196101.25706

This note studies Paley-Wiener type questions for the Hilbert space of Fourier transforms of square integrable functions on a bounded domain, focusing on when integration over a measurable subset of frequency space defines a norm equivalent to the usual \(L^2\) norm. It introduces a quantity measuri…

GENERALIZATION OF EXPERIMENTAL DATA ON THE EFFECT OF THE HEATED LENGTH OF A CHANNEL ON CRITICAL HEAT FLUXES

Table 1
1961 SovietRxiv: ru-196101.25675

This paper generalizes experimental data on the influence of heated channel length on critical heat flux during forced flow of steam, water mixtures and related fluids in tubes and annular channels. Using previously proposed dimensionless similarity criteria, the authors process data for short heate…

On the Relationship Between the Spectrum of Radar Signal Fluctuations and the Motion of Scatterers in Meteorological Objects

Unknown
1961 SovietRxiv: ru-196101.25650

This paper develops a method for relating the fluctuation spectrum of a detected radar signal to the motion of scatterers in meteorological objects, including particles with nonuniform sizes and reflectivities. Starting from the field of an ensemble of moving scatterers, the authors derive expressio…

On the Problem of Scalar Diffraction for an Elliptic Cylinder and an Ellipsoid of Revolution

N. D. KAZARINOV
1961 SovietRxiv: ru-196101.25517

The paper develops an asymptotic treatment of scalar diffraction by an elliptic cylinder, with extensions to an ellipsoid of revolution, in the high-frequency regime when the eccentricity may approach unity. For the Dirichlet problem on an elliptic cylinder, the Green function is represented through…

On Inverse Spectra and Dimension

B. PASYNKOV
1961 SovietRxiv: ru-196101.25508

This paper studies inverse spectra and their relations to dimension theory, especially polyhedral, simplicial, and combinatorial spectra and the dimensions of their limit spaces. It gives criteria for an inverse spectrum of compact spaces or finite complexes to have a limit of covering dimension at …

On Compact Topological Spaces

Unknown
1961 SovietRxiv: ru-196101.25468

The paper develops a construction representing compact topological spaces as limits of direct spectra of finite discrete sets, in contrast to the standard inverse spectrum representation. It defines spectra equipped with a proximity relation, constructs threads and pencils, and shows that these dete…

LETTER TO THE EDITOR

Unknown
1961 SovietRxiv: ru-196101.25279

This letter examines a claimed generalization of Voronoi’s normal basis for cubic fields to algebraic fields of arbitrary degree. The authors identify an error in B. Epelbaum’s proof, arguing that the relevant systems of equations do not yield the asserted additional relations because their independ…