Showing 50 of 25456 papers

Invariant Hyperbolic Systems and the Goursat Problem

Unknown
1960 SovietRxiv: ru-196001.78437

This paper studies a class of invariant first order systems that become hyperbolic for a Lorentz signature metric, focusing on their structure after separating a distinguished time coordinate. The system is rewritten in terms of spatial exterior differentiation and its adjoint, and it is shown that …

Inverse Scattering Problem for Equations with a Singularity

V. F. KOROP
1960 SovietRxiv: ru-196001.78292

This paper addresses the inverse scattering problem on the half-line for second-order differential equations whose coefficients include an inverse-square singularity, under weighted integrability assumptions on the real potential. Using a method related to the Agranovich and Marchenko approach, it g…

Study of the Temperature Dependence of the Fine Structure of the Main Edge of Titanium X-ray Absorption Spectra in Barium Titanates near the Curie Point for $\mathrm{BaTiO}_3$

Unknown
1960 SovietRxiv: ru-196001.78268

This study examines how temperature affects the fine structure of the titanium K absorption edge in barium monotitanate and tetratitanate, with emphasis on the region near the ferroelectric Curie point of BaTiO3. X-ray absorption spectra were recorded photographically using a focusing tube spectrogr…

On the stability of plasma in the field of a magnetic dipole

Unknown
1960 SovietRxiv: ru-196001.78207

This paper examines the stability of a plasma confined in a magnetic dipole field, motivated by mirror trapping in the Earth’s magnetic field and the observed radiation belts. Using the hydrodynamic approximation and the energy principle for small perturbations, the authors derive a stability condit…

Reaction of sodium cyclopentadienide with alkoxytitanium chlorides

A. N. NESMEYANOV, O. V. NOGINA, and A. M. BERLIN
1960 SovietRxiv: ru-196001.78192

The study examines reactions of sodium cyclopentadienide with alkoxytitanium chlorides as a route to cyclopentadienyl alkoxy derivatives of titanium. Mono-cyclopentadienyl triethoxy and tri-n-propoxy titanates, a bis-cyclopentadienyl ethoxy chloride, and mixed chloro-alkoxy cyclopentadienyl titanium…

Centers of Noncompact Simple Lie Groups

A. I. SIROTA
1960 SovietRxiv: ru-196001.78143

This paper computes the centers of all connected simply connected noncompact simple real Lie groups, extending a method used by Dynkin and Onishchik for compact and complex simple groups. The argument realizes each real form through an involutive automorphism of a compact simple Lie algebra, proves …

The Motion of Comet Encke–Backlund During the Years 1898–1911 and a New Determination of the Mass of Mercury

S. G. MAKOVER and N. A. BOKHAN
1960 SovietRxiv: ru-196001.78080

This paper reexamines the motion of Encke Backlund’s comet during the 1898 to 1911 apparitions in order to derive a new estimate of Mercury’s mass from the comet’s close 1905 approach to the planet. The authors recompute planetary perturbations, including repeated recalculation after orbital improve…

Organomagnesium Compounds of the Isoxazole Series

Unknown
1960 SovietRxiv: ru-196001.77884

This paper reports the first preparation of organomagnesium compounds in the isoxazole series, using 3,5-dimethyl-4-bromo- and 3,5-dimethyl-4-iodoisoxazole under entrainment conditions with ethyl bromide. Reaction conditions were compared by carbonation to 3,5-dimethylisoxazole-4-carboxylic acid, sh…

On the Principles of Designing Geophysical Equipment for Electrical Prospecting by the Method of Measuring Frequency Characteristics

Unknown
1960 SovietRxiv: ru-196001.77838

The paper addresses the design of electrical prospecting apparatus capable of combining the productivity of transient-field methods with the noise immunity of multifrequency measurements. It analyzes the limitations of sequential fixed-frequency measurements and broadband transient recording, then p…

On the Nature of the Alkylation of Aromatic Hydrocarbons with Olefins in the Presence of $\mathrm{BF}_3\cdot\mathrm{H}_3\mathrm{PO}_4$

Unknown
1960 SovietRxiv: ru-196001.77750

This study examines the relative reactivity of benzene and alkylbenzenes in olefin alkylation catalyzed by boron trifluoride phosphoric acid, addressing whether benzene homologs are generally more reactive than benzene. The authors compare alkylation by propylene, butylenes, isobutylene, and cyclohe…

On the Dehydrogenation of Butane-Butylene Mixtures over an Alumina-Chromium Catalyst

A. P. SHCHEGLOVA, O. K. BOGDANOVA, and A. A. BALANDIN
1960 SovietRxiv: ru-196001.77747

The study examines the kinetics and reaction pathways of butane and butane, butylene mixtures over an alumina, chromia catalyst at 600 to 635 °C and atmospheric pressure. Flow experiments with binary mixtures of butane with butylene, butadiene, or hydrogen, and with butylene or butadiene diluted by …

Asymptotic Formulas for the Solution of a Boundary Value Problem for a Second-Order Equation with a Small Parameter at the Highest Derivative

A. B. VASIL’EVA and V. A. TUPCHIEV
1960 SovietRxiv: ru-196001.77602

This note studies a singularly perturbed boundary value problem for the second order equation with a small parameter multiplying the highest derivative, in the case where the right hand side depends only on the unknown function and the independent variable. Under smoothness assumptions near the limi…

On the Basic Equations of Filtration of Homogeneous Fluids in Fractured Rocks

G. I. BARENBLATT and Yu. P. ZHELTOV
1960 SovietRxiv: ru-196001.77497

The paper formulates continuum equations for unsteady filtration of a homogeneous fluid in rocks with strongly developed fracturing, where explicit modeling of individual fractures is impractical. It represents the rock as two interacting porous media, a highly permeable fracture system and a lower …

On the Action of Diborane on Esters of Diarylborinic and Arylboronic Acids

B. M. MIKHAILOV and V. A. DOROKHOV
1960 SovietRxiv: ru-196001.77403

This study examines reactions of diborane with butyl esters of diarylboronic and arylboronic acids in diethyl ether at room temperature. The authors show that diarylboronic acid esters react readily to give 1,2-diaryldiboranes, including diphenyl, di-p-chlorophenyl, and di-alpha-naphthyl derivatives…

On the Influence of the Nature of the Cation on Kolbe Electrosynthesis

M. Ya. Fioshin, Yu. B. Vasil'ev, and E. T. Gaginkina
1960 SovietRxiv: ru-196001.77364

This study examines how the cation in acetate salts influences anodic processes and product yields in Kolbe electrosynthesis on platinum electrodes. Polarization measurements with alkali, alkaline earth, ammonium, tetramethylammonium, and several variable-valence metal cations were combined with gas…

Fine structure of Rayleigh light scattering in solutions and dispersion of hypersonic oscillations

L. V. LANSHINA and M. I. SHAKHPARONOV
1960 SovietRxiv: ru-196001.77283

This paper investigates the fine structure of Rayleigh light scattering in acetone-water and methyl alcohol-water solutions in order to separate scattering contributions from different fluctuations and to determine hyperacoustic propagation velocities. Using a high-resolution Fabry-Perot interferome…

On the Catalytic Activity of Tungsten Pentoxide

A. A. BALANDIN, A. A. TOLSTOPYATOVA, and V. STIZHEVSKII
1960 SovietRxiv: ru-196001.77251

The study examines the catalytic activity of tungsten pentoxide in alcohol dehydration and in the dehydrogenation of methyl alcohol and tetralin under flow, low-conversion, approximately isothermal conditions. Using diluted catalyst and alcohol mixtures with reaction products, the authors determined…

Cis-isomer of the intracomplex salt of divalent platinum with $\alpha$ -alanine

L. M. VOL’SHTEIN and I. O. VOLODINA
1960 SovietRxiv: ru-196001.77032

This paper addresses the previously unknown cis isomer of the inner-complex divalent platinum salt with alpha-alanine, in the context of analogous glycine and alpha-aminobutyric acid complexes. The authors prepare potassium tetrakisalaninoplatinate, acidify the solution, and heat it to induce format…

Triangles in Riemannian Spaces with a Pole

Unknown
1960 SovietRxiv: ru-196001.76901

This note studies metrically complete, sufficiently smooth Riemannian spaces possessing a pole, under the assumption of positive curvature, or more specifically positivity in two-dimensional directions tangent to geodesic rays from the pole. Using Fermi coordinates, associated two-dimensional surfac…

Destruction and formation of structures of natural proteins during their transfer through nonporous membranes

V. A. KARGIN, P. V. KOZLOV, S. Ya. MIRLINA, and Z. A. KAPRALOVA
1960 SovietRxiv: ru-196001.76613

This study examines the destruction and reformation of natural protein structures during high-voltage electrodialysis through nonporous cellophane membranes. Using gelatin, myosin, denatured egg albumin, and edestin, the authors combine transfer experiments under varied temperature, concentration, v…

EPR spectra and kinetics of radical accumulation during radiolysis of certain aromatic compounds

I. I. Chkheidze, Yu. N. Molin, N. Ya. Buben
1960 SovietRxiv: ru-196001.76531

This study examines the radicals formed during radiolysis of benzene, diphenyl, terphenyls, and ditolyls, and relates radical yields to molecular structure. Electron paramagnetic resonance spectra and accumulation kinetics were measured during irradiation by 1.6 MeV electrons at low and room tempera…

Densely embedded ideals of semigroups

Unknown
1960 SovietRxiv: ru-196001.76493

This note studies densely embedded ideals in abstract semigroups, extending earlier characterizations related to transformation semigroups. Using right and left shifts and their linked pairs, it constructs for a semigroup without equiacting elements a canonical semigroup in which the original semigr…

Catalytic Conversion of 2-Alkyl-5-Acylfurans to Alkylphenols

N. I. SHUIKIN, I. F. BELSKII, and G. K. VASILEVSKAYA
1960 SovietRxiv: ru-196001.76331

This study examines the vapor-phase catalytic hydrogenation of 2-alkyl-5-acylfurans over platinum on carbon at atmospheric pressure and 300 to 310°C, focusing on how carbonyl-containing substituents direct furan-ring hydrogenolysis. The authors show that cleavage occurs primarily at the C-O bond adj…

Alkylation of 2-chloroanisole with propylene, but-2-ene, and cyclohexene in the presence of $\mathrm{BF}_3\cdot\mathrm{H}_3\mathrm{PO}_4$

A. V. TOPCHIEV, V. G. KRYUCHKOVA, and S. V. ZAVGORODNII
1960 SovietRxiv: ru-196001.76152

The study examines the alkylation of 2-chloroanisole with propylene, butene-2, and cyclohexene using a boron fluoride, phosphoric acid catalyst, extending earlier work on haloanisole alkylation. Under conditions previously found favorable for 4-chloroanisole, propylene and butene-2 gave only the cor…

ON THE ROLE OF PHYSICOCHEMICAL PROCESSES IN THE SURFACE LAYERS OF STEEL DURING CYCLIC DEFORMATION IN MELTS OF LOW-MELTING METALS

Unknown
1960 SovietRxiv: ru-196001.76133

This paper examines why low-melting metal melts can either reduce or increase the fatigue strength of steel under cyclic deformation, focusing on surface-active effects and secondary physicochemical processes in surface layers. Fatigue tests on steel specimens with stress concentrators compare behav…

Study of the Surface State of Anodically Polarized Germanium in Alkaline Solutions

E. A. EFIMOV and I. G. ERUSALIMCHIK
1960 SovietRxiv: ru-196001.75990

The study examines the surface state of anodically polarized germanium during electrochemical etching in alkaline media, a problem relevant to semiconductor processing but previously investigated mainly in acidic solutions. Using cathodic charging curves for polycrystalline degenerate germanium in 0…

Kinetic Features of Hydration Hardening of Sulfates

O. I. Luk'yanova, P. A. Rebinder, G. M. Belousova
1960 SovietRxiv: ru-196001.75813

This paper examines the hydration hardening of sulfate binders with different cations, focusing on how crystallization kinetics govern the formation and strength of dispersed structures. Using heat evolution measurements, dissolution studies, suspension hardening tests, and microscopy, the authors c…

On the stability of the Ritz method

Unknown
1960 SovietRxiv: ru-196001.75502

This note studies the numerical stability of the Ritz method for solving equations with positive definite operators in Hilbert spaces, focusing on how the choice of coordinate system affects the behavior of the coefficients as the number of terms increases. It reviews reliable coordinate systems, re…

On the index of boundary value problems for a system of harmonic functions with three independent variables

A. I. VOLPERT
1960 SovietRxiv: ru-196001.75411

This paper studies the index of boundary value problems for systems of harmonic functions in a three dimensional convex domain with elliptic first order boundary operators. It associates the problem with elliptic first order systems on the boundary surface, defines a characteristic through a bundle …

Finite-Difference Scheme for Solving the Complete System of Equations for Short-Term Weather Forecasting and Quasi-Geostrophic Relations

Corresponding Member of the USSR Academy of Sciences I. A. KIBEL
1960 SovietRxiv: ru-196001.75388

This paper develops a finite-difference formulation for short-range weather prediction using the complete hydrodynamic equations in pressure coordinates, with unknown geopotential, horizontal wind components, and vertical motion variable. The system is reduced by eliminating vertical velocity, discr…

Absorption spectra of derivatives of 4- $\mathrm{NO}_2$ -diphenylamine. On the influence of electron-donating groups in the m-position and alkylation of the $\mathrm{NH}$ group

V. A. IZMAIL’SKII and K. A. NURIDZHANYAN
1960 SovietRxiv: ru-196001.75249

This study examines how electron donor substituents in the meta position and alkylation of the NH group affect the absorption spectra of 4-nitrodiphenylamine derivatives. Using a chromophoric decomposition approach, the authors compare spectral maxima for substituted and N-alkylated compounds in eth…

Alkylation of $4$-fluorophenol with propylene and cyclohexene in the presence of $\mathrm{BF}_3\cdot\mathrm{H}_3\mathrm{PO}_4$ and $\mathrm{BF}_3\cdot\mathrm{O}(\mathrm{C}_2\mathrm{H}_5)_2$ catalysts

A. V. TOPCHIEV, V. G. KRYUCHKOVA, and S. V. ZAVGORODNII
1960 SovietRxiv: ru-196001.75234

This study examines the alkylation of 4-fluorophenol with propylene and cyclohexene using boron fluoride based catalysts, BF3, H3PO4 and BF3, O(C2H5)2, a reaction not previously described for fluorophenols. Experiments varied catalyst type and amount, temperature, and reactant ratios, and products w…

Standard enthalpies of formation of perchloric acid and some perchlorates

A. F. VOROB'EV, N. M. PRIVALOVA, A. S. MONAENKOVA, and S. M. SKURATOV
1960 SovietRxiv: ru-196001.75125

This paper reports a thermochemical determination of standard enthalpies of formation for perchloric acid and several perchlorates, motivated by limited existing data. The authors measure decomposition, dissolution, and neutralization enthalpies calorimetrically, then apply Hess’s law with selected …

Investigation of Metallic Compounds in Multicomponent Nickel Alloys Containing Niobium

R. B. GOLUBTSOVA and L. A. NUDE
1960 SovietRxiv: ru-196001.75026

This study examines excess metallic phases in heat-treated multicomponent nickel alloys of the Ni, Cr, W, Mo, Nb, Ti, Al system, with emphasis on compounds formed at different niobium contents. Using intermetallic analysis, anodic dissolution in methanol-based electrolytes, microchemical analysis, e…