Showing 50 of 25456 papers

Elastic-strength properties of plastic dispersed systems in relation to the phenomenon of thixotropy

V. P. PAVLOV and G. V. VINOGRADOV
1958 SovietRxiv: ru-195801.93391

This study examines the elastic strength properties of plastic disperse systems and their relation to thixotropy, focusing on shear modulus and yield stress in lubricating greases. Using a concentric cylinder elastoviscosimeter with rigid and soft dynamometers, the authors measured stress deformatio…

THE INFLUENCE OF THE RADIUS OF CATIONS ON THE PROPERTIES OF BOUNDARY LAYERS OF ELECTROLYTE SOLUTIONS IN PLANE GAPS BETWEEN QUARTZ SURFACES

Unknown
1958 SovietRxiv: ru-195801.93289

This study examines how cation radius, valence, concentration, temperature, and load affect boundary layers of alkali and alkaline earth chloride solutions confined between negatively charged quartz surfaces. Using measurements of disk approach and separation, the authors determine boundary-layer th…

Dependence of the Surface Structure of Electrolytic Alloy Deposits on Their Phase Composition

------------------
1958 SovietRxiv: ru-195801.93115

This study examines how phase composition affects the surface structure of electrodeposited alloy coatings, focusing on systems in which supersaturated solid solutions may form during electrocrystallization. Copper-bismuth, copper-tin, and tin-lead deposits were prepared from simple acidic electroly…

On a Boundary Value Problem for Linear Elliptic Systems of First-Order Differential Equations in the Plane

Let us consider the system of differential equations
1958 SovietRxiv: ru-195801.93092

This paper studies a boundary value problem for uniformly elliptic first order linear systems in a simply connected planar domain, with Hölder continuous oblique real boundary condition. The system is reduced by complex notation and conformal mapping to a generalized Beltrami type equation in the di…

Synthesis of High-Molecular-Weight Hydrocarbons of Mixed Structure

S. R. SERGIENKO, L. N. KVITKOVSKII, A. L. TSEDILINA and Al. A. PETROV
1958 SovietRxiv: ru-195801.92797

This paper reports the synthesis of high molecular weight hydrocarbons intended as model compounds for studying the structural group composition of heavy petroleum fractions. The authors prepared a series of previously undescribed C24 to C32 hydrocarbons with mixed aliphatic, cycloaliphatic, aromati…

On Fluctuations in Quartz Oscillators

M. E. ZHABOTINSKII and P. E. ZILBERMAN
1958 SovietRxiv: ru-195801.92631

This paper analyzes the fluctuation limit of frequency stability in practical quartz oscillators, emphasizing the distinct time constants of the regenerated circuit and the quartz resonator. Using symbolic differential equations and the method of a small parameter, the authors derive fluctuation equ…

Thermal ionization of hydrogen and hydrocarbons in the presence of metal catalysts

P. G. IVANOV and A. A. BALANDIN
1958 SovietRxiv: ru-195801.92194

This paper investigates the appearance of charged particles in hydrogen and hydrocarbon vapors in contact with heated metallic surfaces possessing catalytic properties. Using a sealed electrode apparatus with palladium, aluminum, copper, and carbon surfaces, the authors measured gas ionization indir…

Infrared Spectra of Organolithium Compounds. Intermolecular Lithium Bond

A. N. RODIONOV, D. N. SHIGORIN, T. V. TALALAEVA
1958 SovietRxiv: ru-195801.92099

This study examines the infrared absorption spectra of several alkyl and aryl lithium compounds in vapor, crystalline, and solution states to clarify the nature of the carbon-lithium bond and molecular association. The authors assign a band near 1050 cm-1 to the stretching vibration of the free carb…

Electron diffraction study of the structure of the chloroprene molecule

P. A. AKISHIN, L. V. VILKOV and V. M. TATEVSKII
1958 SovietRxiv: ru-195801.92009

This study examines the spatial configuration and geometrical parameters of the chloroprene molecule, with particular attention to the arrangement of its conjugated double bonds and possible rotation about the central carbon-carbon single bond. Fast electron diffraction patterns of chloroprene vapor…

Polymerization of isobutylene in the presence of boron fluoride on activated carbon

A. V. TOPCHIEV and L. A. ADLYAVLINA
1958 SovietRxiv: ru-195801.91989

This study examines gas phase polymerization of isobutylene at atmospheric pressure using boron fluoride supported on activated carbon, with attention to temperature, space velocity, support effects, and catalyst lifetime. Experiments showed that increasing temperature or space velocity reduced the …

A “Lunar” Radio Interferometer

G. A. Gurzadyan
1958 SovietRxiv: ru-195801.91971

This paper proposes a “lunar” radio interferometer in which radio waves from a compact cosmic source reach Earth both directly and after refraction in the Moon’s rarefied ionosphere, allowing the Moon to act as an effective second antenna. The author derives expressions for the received intensity as…

Maximum correlation coefficient (asymmetric case)

O. V. SARMANOV
1958 SovietRxiv: ru-195801.91874

This paper extends the notion of a maximal correlation coefficient to the nonsymmetric case of two random variables with a joint density on a rectangular, possibly infinite, domain. Using Hilbert-Schmidt theory, it associates the nonsymmetric density with two symmetric kernels having the same eigenv…

Oxygen isotope exchange between the free hydroxyl radical and water

I. A. Kazarnovskii, N. P. Lipikhin and M. V. Tikhomirov
1958 SovietRxiv: ru-195801.91544

This study examines oxygen isotopic exchange between free hydroxyl radicals and water, a problem relevant to radiation chemistry and oxidative reaction mechanisms. Potassium ozonide decomposition in water enriched with oxygen-18 was used as a source of hydroxyl radicals, and the isotopic composition…

On the Mechanism of Electrolytic Polishing of Metals and the Structure of the Electropolished Surface

G. S. Vozdvizhenskii, G. A. Gorbachuk, and G. P. Dezider’ev
1958 SovietRxiv: ru-195801.91540

This paper examines the mechanism of electrolytic polishing of metals, focusing on whether polishing proceeds through two distinct stages in which structural etching is first produced and then suppressed. Polycrystalline copper specimens were electropolished in phosphoric acid for different duration…

Study of Films on a Mercury Electrode

A. Ya. Gokhshtein and Ya. P. Gokhshtein
1958 SovietRxiv: ru-195801.91503

A polarographic method is described for studying anodic and cathodic films on a dropping mercury electrode through discrete current pulses observed at constant potential. Experiments with several 0.1 N electrolytes show reproducible pulse patterns whose potential ranges, amplitudes, durations, and f…

On the Theory of Superconductivity of Metals

Corresponding Member of the USSR Academy of Sciences S. V. Vonsovskii and M. S. Svirskii
1958 SovietRxiv: ru-195801.91335

This paper develops a many-electron model of metallic superconductivity that incorporates crystal structure into the treatment of interacting outer electrons. Starting from a second-quantized Hamiltonian, the authors derive an electron spectrum with transfer integrals, introduce electron-phonon coup…

Nonlinear Nonstationary Problem of Determining Planetary-Scale Pressure Fields at the Middle Level of the Atmosphere

E. N. BLINOVA and S. L. BELOUSOV
1958 SovietRxiv: ru-195801.91321

This paper presents a hydrodynamic method for nonlinear, nonstationary long range forecasting of planetary scale pressure fields at the middle atmospheric level. The authors formulate the problem through the spherical vorticity transport equation for the stream function, introduce an auxiliary funct…

Structural Characterization of Some Classes of Algebras

Unknown
1958 SovietRxiv: ru-195801.91203

This note studies when a category of structures can be represented, in the stronger sense of structural equivalence, by a subclass of algebras of a fixed type. It develops conditions involving free structures, homomorphic closure, additivity, boundedness, regularity, divisible homomorphisms, and fin…

A New Method for the Synthesis of Indoles Substituted in the Benzene Ring

A. P. TERENT’EV and M. N. PREOBRAZHENSKAYA
1958 SovietRxiv: ru-195801.91126

This paper proposes a method for preparing indoles substituted in the benzene ring, motivated by the difficulty of existing Reissert, Fischer, and Bischler syntheses for such compounds. The approach reduces indole or its homologs to indolines, introduces substituents into the benzene nucleus by ordi…

Molecular Homogeneity and Properties of Cellulose

B. A. ZAKHAROV, V. I. IVANOV, G. A. KRYLOVA, and N. G. VYUNOVA
1958 SovietRxiv: ru-195801.90928

This paper examines how molecular weight distribution, rather than average molecular weight alone, affects the physical properties of cellulose and cellulose-based fibers. The authors argue that cellulose homogeneity should be characterized by the concentration of material near the maximum of the ma…

Synthesis of 5-Mercaptoindole and 5-Mercapto-1-methylindole Derivatives

Corresponding Member of the Academy of Sciences of the USSR A. P. Terent’ev and M. N. Preobrazhenskaya
1958 SovietRxiv: ru-195801.90760

This paper addresses the synthesis of indole derivatives containing divalent sulfur in the benzene ring, a class of compounds previously difficult to obtain by standard indole syntheses and of interest because of the physiological activity of related indole compounds. The authors apply a route based…

Diffusion in the Critical Region of Ternary Solutions

I. R. Krichevskii, N. E. Khazanova, and L. R. Linshits
1958 SovietRxiv: ru-195801.90756

This study examines molecular diffusion near the critical region of ternary solutions, where theory suggests that a minor third component should continue to diffuse while diffusion of the two principal components is strongly reduced. Using the capillary method, the authors measured diffusion in the …

Internal Homology

V. A. ROKHLIN
1958 SovietRxiv: ru-195801.90749

This note studies the image of the natural homomorphism from the group of internal homologies to the group of internal homologies modulo 2, using the known Thom and Dold description of the unoriented cobordism algebra by generators. Rokhlin proves that several conditions on a manifold are equivalent…

On Weak and Strong Convergence

M. I. KADEC
1958 SovietRxiv: ru-195801.90722

The paper studies the relation between weak and strong convergence in Banach spaces and proves that every separable Banach space admits an equivalent norm for which weak convergence together with convergence of norms implies norm convergence. The proof is first carried out for the space of continuou…

Heat of Adsorption of Benzene and Hexane Vapors on Quartz

==================
1958 SovietRxiv: ru-195801.90554

This study examines adsorption of benzene and n-hexane vapors on quartz, motivated by the relation between quartz surface chemistry and silica adsorbents and by the need to separate polymolecular adsorption from capillary condensation effects. Using adsorption calorimetry, the authors measured adsor…

27-day variations of cosmic ray intensity in the stratosphere

S. N. VERNOV, V. F. TULINOV, and A. N. CHARAKHCHYAN
1958 SovietRxiv: ru-195801.90427

This paper examines recurrent variations in cosmic ray intensity in the stratosphere associated with solar rotation, using balloon borne RK-1 radiosonde measurements conducted during 1957 and early 1958 at geomagnetic latitudes near Moscow and in the Murmansk region. The authors describe the instrum…

Interaction of Diacetylene with Ethyl Mercaptan and Some Properties of the Compounds Obtained

A. V. Bogdanova, M. F. Shostakovskii, and G. I. Plotnikova
1958 SovietRxiv: ru-195801.90376

The study examines the addition of ethyl mercaptan to diacetylene and the properties of the sulfur-containing products formed. Experiments under alkaline, acidic, thermal, and radical-initiated conditions showed that ethyl mercaptan first gives ethynylvinyl thioethyl ether, followed by addition of a…

On the Differential Properties of Generalized Solutions of Some Multidimensional Variational Problems

Unknown
1958 SovietRxiv: ru-195801.90303

This paper studies generalized minimizers of multidimensional variational integrals whose integrands depend on the first derivatives and satisfy growth, ellipticity, and differentiability assumptions of order p at least 2. Using difference quotient arguments and weak variational identities, it estab…

EXPANSION IN EIGENFUNCTIONS OF NON-SELF-ADJOINT SINGULAR DIFFERENTIAL OPERATORS

The expansion formulas for the boundary-value problem on the half-axis
1958 SovietRxiv: ru-195801.90257

This note develops expansion formulas for non-self-adjoint singular differential operators on the half-axis, generalizing Weyl’s spectral representation for self-adjoint boundary-value problems. It introduces spectral functions as generalized functions on a space of even entire functions of exponent…

Irregular surfaces of bounded extrinsic curvature

I. Ya. BAKELMAN
1958 SovietRxiv: ru-195801.89952

This paper addresses Aleksandrov’s problem of defining a class of irregular surfaces in three-dimensional Euclidean space whose intrinsic metrics have bounded curvature while also including smooth surfaces of bounded extrinsic curvature, general convex surfaces, and DC surfaces. The author replaces …

ACTION OF $\gamma$-RADIATION FROM $\mathrm{Co}^{60}$ ON $\mathrm{Ca}(\mathrm{NO}_3)_2 \cdot 4\mathrm{H}_2\mathrm{O}$

Unknown
1958 SovietRxiv: ru-195801.89928

This study examines the radiolysis of calcium nitrate tetrahydrate under gamma irradiation from cobalt-60, comparing its behavior with anhydrous calcium nitrate, melts of the hydrate, and concentrated aqueous solutions. Samples irradiated in vacuum at 25 degrees C were analyzed for nitrite and oxyge…

Study of Extensive Air Showers of Cosmic Radiation

O. DOVZHENKO, V. ZATSEPIN, E. MURZINA, S. NIKOLSKY,
1958 SovietRxiv: ru-195801.89773

This paper reports high-altitude measurements of extensive atmospheric showers of cosmic radiation conducted in 1955 using hodoscopic counters, underground penetrating-particle detectors, a Wilson chamber, and ionization chambers with variable filters. The study determined shower axes and particle n…

On the Structure, Properties, and Ability of Some Hydrazine Derivatives to Dissociate into Free Radicals. On the Relationship Between Chemical Structure and the Ability to Form Nitrogen Free Radicals

L. B. RADINA, Z. V. PUSHKAREVA, and Z. Yu. KOKOSHKO
1958 SovietRxiv: ru-195801.89764

This study examines why substituents appear to affect dissociation into free nitrogen radicals differently in tetraarylhydrazines than in related hexaarylethanes and diaryl nitrogen oxides. The authors synthesized selected di- and tetrasubstituted hydrazines and investigated them by polarographic re…

Solving a System of Finite Difference Equations Corresponding to the Dirichlet Problem Using a Normal Sequence of Signs

Unknown
1958 SovietRxiv: ru-195801.89513

The paper proposes a method for solving finite difference equations arising from the planar Dirichlet problem by using a normal sequence of signs. It first proves a theorem on the asymptotic frequency with which variable length combinations from a prescribed set occur in a normal sequence, under con…