Showing 50 of 25456 papers

Existence and Uniqueness Theorem for the Solution of a Boundary Value Problem for a System of Ordinary Differential Equations

Let the following be given:
1958 SovietRxiv: ru-195801.65508

This paper proves an existence and uniqueness theorem for a multipoint boundary-value problem for a nonlinear system of ordinary differential equations. The argument compares the nonlinear problem with an auxiliary linear system, using a nonsingular change of variables, a matricant, and the associat…

Reactions of 1,1'-Dimethylferrocene

Academician A. N. NESMEYANOV, E. G. PEREVALOVA, Z. A. BEINORAVICHUTE
1958 SovietRxiv: ru-195801.65384

This study examines how methyl substituents affect the reactivity of the ferrocene nucleus in 1,1'-dimethylferrocene, focusing on metallation and Friedel-Crafts acylation. Metallation with n-butyllithium was unsuccessful, whereas n-amylsodium gave mainly dimethylferrocenedicarboxylic acid, indicatin…

Telomerization of methacrylic acid with trialkyl phosphites

V. A. KUKHTIN, Gilm Kamai, and L. A. SINCHENKO
1958 SovietRxiv: ru-195801.65136

This paper investigates the telomerization of methacrylic acid with trialkyl phosphites, extending earlier work on Arbuzov rearrangements induced by unsaturated acids. Experiments with triethyl and tribenzyl phosphites examined the effects of catalyst type, benzoyl peroxide concentration, and reagen…

On the Undecidability of Some Problems in Topology

A. MARKOV
1958 SovietRxiv: ru-195801.65069

This note strengthens earlier undecidability results in topology by shifting from homeomorphism of polyhedra to combinatorial questions about complexes. It defines a broad class of binary relations between complexes, lying between combinatorial equivalence and equivalence of fundamental groups for c…

On conformal transformations of rings and on the fundamental basis of the space of functions analytic in an elementary neighborhood of an arbitrary continuum

V. D. EROKHIN
1958 SovietRxiv: ru-195801.65053

This paper studies approximation and basis expansions for functions analytic in neighborhoods of an arbitrary continuum, extending classical results of Bernstein and Faber beyond level-line neighborhoods. It first proves a factorization and uniqueness result for conformal mappings of doubly connecte…

Faraday effect on Mott's excitons

A. G. SAMOILOVICH and L. L. KORENBLIT
1958 SovietRxiv: ru-195801.65032

The paper develops a theoretical treatment of the Faraday effect for Mott excitons of relatively small radius in an isotropic semiconductor. Starting from the exciton Hamiltonian in a constant magnetic field and a monochromatic electromagnetic wave, the authors use perturbation theory in the dipole …

Electrocapillary Movements in Molten Slags

V. V. KHLYNOV and O. A. ESIN
1958 SovietRxiv: ru-195801.64463

This paper investigates whether electrocapillary motion can displace liquid metal and sulfide droplets in molten metallurgical slags, a possible mechanism relevant to losses of suspended metal droplets. Experiments at 1370 to 1500°C used a magnesia cell containing a CaO, Al2O3, and SiO2 slag and mea…

On conformal mappings

Unknown
1958 SovietRxiv: ru-195801.64376

This note studies when weak local metric or angular conditions on a continuous complex mapping force analyticity. It defines preservation of angles, constant stretching, and an orientation condition at isolated image points, then proves several generalizations of results of Menshov and Bohr: angle p…

Asymptotics of solutions of certain boundary value problems for quasilinear equations with a small parameter multiplying the highest derivative

A. B. VASIL’EVA
1958 SovietRxiv: ru-195801.63955

This paper studies boundary-value problems for a quasilinear second-order ordinary differential equation in which a small parameter multiplies the highest derivative. Under smoothness and stability assumptions on the coefficients, it develops asymptotic approximations by combining the degenerate fir…

Radiation of $\mathrm{Tb}^{160}$

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1958 SovietRxiv: ru-195801.63906

The study reports precision measurements of the radiation emitted in the decay of terbium-160, produced by neutron irradiation of high-purity terbium oxide. Using a double-focusing spectrometer, the authors measured the continuous beta spectrum, internal conversion electron spectrum, and photoelectr…

On the Passivating Properties of Sulfate Ions

I. L. ROSENFELD and V. P. MAKSIMCHUK
1958 SovietRxiv: ru-195801.63852

This paper examines the influence of sulfate ions on the chloride-induced breakdown of passivity in stainless steels and related metals. Using anodic polarization curves and potential, time measurements at constant current density, the authors show that sulfate additions shift activation potentials …

Integral Representations of Functions of Two Complex Variables

A. A. TEMLYAKOV
1958 SovietRxiv: ru-195801.63680

This paper studies integral representations for functions of two complex variables in bounded complete bicircular domains. It characterizes the domains defined by parametrized boundary radii satisfying specified differential relations, showing that they coincide with bicircular domains with twice co…

On the uniqueness of a generalized solution of the Cauchy problem for systems of quasilinear equations of hyperbolic type

B. L. ROZHDESTVENSKII
1958 SovietRxiv: ru-195801.63655

The paper addresses uniqueness of generalized solutions to the Cauchy problem for conservative quasilinear hyperbolic systems, a question previously treated mainly for scalar equations or special systems. It proves a uniqueness theorem for piecewise-continuous and piecewise-smooth solutions of two-e…

Stability of Cylindrical Shells from the Standpoint of the Mathematical Theory of Elasticity

K. F. VOITSEKHOVSKAYA
1958 SovietRxiv: ru-195801.63622

The paper analyzes the axial compression stability of a hollow cylindrical shell using the mathematical theory of elasticity, following nonlinear elasticity ideas while neglecting rotation components in the equilibrium equations but retaining the deformation of the boundary surface. For an axisymmet…

Dehydrogenation of unsymmetrical methylisopropylethylene and its mixtures with tetramethylethylene

I. N. Nazarov, L. N. Ivanova, and B. A. Rudenko
1958 SovietRxiv: ru-195801.63549

The study examines the dehydrogenation of unsymmetrical methylisopropylethylene and its mixtures with tetramethylethylene over industrial butylene dehydrogenation catalysts K-12, K-16, and K-18. Products were analyzed by maleic anhydride addition, derivative identification, distillation, and gas-liq…

On the Thermodynamics of Chlorination of Rare-Earth Metal Oxides with Gaseous Chlorine

I. S. MOROZOV and B. G. KORSHUNOV
1958 SovietRxiv: ru-195801.63489

This study examines the thermodynamics of chlorination and oxidation equilibria for rare-earth and related metal oxides and chlorides in systems containing scandium, lanthanum, neodymium, and samarium. Equilibria of the reaction between solid metal chlorides and oxygen to form solid oxides and chlor…

Determination of the composition and stability constants of lead chloride complexes from experiments on the distribution of a radioactive isotope between precipitate and solution

K. B. ZABORENKO, I. V. KOLOSOV, and V. V. FOMIN
1958 SovietRxiv: ru-195801.63434

This paper examines how the distribution of a radioactive microcomponent between a precipitate and solution can be used to determine the composition and stability constants of lead chloride complexes. The authors derive a relation between the distribution coefficient and chloride ion concentration f…

Stereochemistry of $\sigma$ , $\pi$-conjugation. $\alpha$-Chloromercuricamphenilone

A. N. Nesmeyanov, I. I. Kritskaya
1958 SovietRxiv: ru-195801.63125

This paper examines the stereochemical requirements for sigma,pi conjugation in bridgehead bicyclic systems, using alpha-chloromercuricamphenilone as a test case. The authors synthesize this compound through peroxide decomposition in the presence of a mercury salt and compare its reactivity with tha…

On the Stereochemistry of Inner Complex Compounds of Vanadyl

Unknown
1958 SovietRxiv: ru-195801.62748

This paper examines the stereochemistry of vanadyl inner-complex compounds formed with azomethine derivatives of aromatic o-hydroxyaldehydes. Three brominated vanadyl complexes were synthesized, analyzed for composition, and studied by Gouy magnetic susceptibility measurements at room temperature. T…

Intramolecular Acylation in the Ferrocene Series. Cyclization of Ferrocenyl-Substituted Acids and Keto Acids

Unknown
1958 SovietRxiv: ru-195801.62579

This study examines intramolecular acylation and cyclization reactions of monosubstituted ferrocene derivatives, extending earlier work on disubstituted ferrocene acids. The authors prepared beta-carbomethoxypropionylferrocene, beta-carboxypropionylferrocene, omega-carboxypropylferrocene, and ortho-…

The C—H Distance in the Crystal Structure of Paraffins

Unknown
1958 SovietRxiv: ru-195801.62446

This study examines the carbon to hydrogen bond distance in crystalline paraffins, where conventional X-ray methods had limited accuracy for locating hydrogen atoms. Electron diffraction data were collected for three paraffin specimens, including C30H62 and C18H38, and Fourier and difference synthes…

On the Luminosity of Hot Stars

Unknown
1958 SovietRxiv: ru-195801.62414

This paper examines the difficulty of determining luminosities for hot peculiar stars, focusing on Wolf Rayet stars and white dwarfs, whose spectra and atmospheres make ordinary temperature and luminosity estimates unreliable. For Wolf Rayet stars, it argues that extended envelopes transform high fr…

Maximum Correlation Coefficient (Symmetric Case)

O. V. SARMANOV
1958 SovietRxiv: ru-195801.62220

This paper studies the maximal correlation coefficient for symmetrically distributed pairs of random variables, defining it through the first nontrivial eigenvalue of a normalized symmetric kernel associated with the joint density. It gives the corresponding variational characterization, describes a…

On Homogeneous Difference Schemes

A. N. TIKHONOV and A. A. SAMARSKII
1958 SovietRxiv: ru-195801.61904

This paper develops a framework for homogeneous difference schemes for linear differential equations with variable coefficients, emphasizing convergence and accuracy uniformly over specified coefficient classes. It introduces definitions of convergence, approximation order, equivalence, symmetry, an…

ON SOME PROPERTIES OF AXISYMMETRIC SUPERSONIC GAS FLOWS

Unknown
1958 SovietRxiv: ru-195801.61814

This paper studies axisymmetric supersonic gas flow past a body of revolution using the characteristic form of the governing equations. It derives an evolution equation along characteristics for the derivative of the Mach angle function and relates its boundary condition to the radius of curvature o…

CRITERIA FOR BOUNDEDNESS OF SOLUTIONS OF LINEAR DIFFERENTIAL EQUATIONS WITH VARIABLE DELAY OF THE ARGUMENT

Unknown
1958 SovietRxiv: ru-195801.61597

This paper gives necessary and sufficient criteria for boundedness on the half-axis of solutions to linear differential equations with delayed argument, including variable delays and equations with both delayed and nondelayed terms. Working in Banach spaces, it formulates boundary-value problems wit…

ON THE INTERACTION BETWEEN OZONE AND METHYL HYDROPEROXIDE

Unknown
1958 SovietRxiv: ru-195801.61471

The study examines the gas phase interaction of ozone with methyl hydroperoxide, motivated by observed losses of methyl hydroperoxide during methane oxidation experiments in which undecomposed ozone was present. Methyl hydroperoxide was synthesized and reacted with excess ozonized oxygen in a thermo…

A NONLINEAR PROBLEM IN THE THEORY OF A HYDROFOIL

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1958 SovietRxiv: ru-195801.61314

This paper studies the steady flow of an ideal incompressible heavy fluid of finite depth past a submerged hydrofoil, formulated as a nonlinear free boundary problem with a free surface and bottom boundary. Using an inverse method, the physical flow domain is conformally mapped to a strip, the hydro…

On the Interaction of Mutually Distant Atomic Groups through a System of Two Benzene Nuclei Connected by a Bridging Unit

L. M. Litvinenko, R. S. Cheshko, and S. V. Tsukerman
1958 SovietRxiv: ru-195801.61003

This study examines how nitro and amino substituents influence one another when separated by two benzene rings connected through oxygen or sulfur bridges, in comparison with directly linked biphenyl systems. The authors use kinetic measurements of acylation with p-nitrobenzoyl chloride in benzene, d…

Heats of Wetting of Etherified Cellulose by Water

E. F. NEKRYACH and A. V. DUMANSKII
1958 SovietRxiv: ru-195801.60990

This study examines how etherification affects the hydrophilicity of cellulose materials, using heats of wetting by water as a quantitative measure. Methylcellulose, ethylcellulose, and oxyethylcellulose prepared from cotton linters, along with methylcellulose from viscose silk, were measured in an …

On the behavior of solutions to the Cauchy problem for certain quasilinear equations as time increases without bound

A. M. Il’in and O. A. Oleinik
1958 SovietRxiv: ru-195801.60974

This paper studies the large-time behavior of solutions to the Cauchy problem for a scalar quasilinear parabolic conservation law with viscosity and for the corresponding first-order conservation law, under bounded measurable initial data with prescribed limits at spatial infinity. Using comparison …

On the Theory of the Phase Transition in a Nonideal Bose Gas

D. N. ZUBAREV and Yu. A. TSERKOVNIKOV
1958 SovietRxiv: ru-195801.60970

This paper develops an approximate microscopic theory of the phase transition in a weakly interacting nonideal Bose gas using a model Hamiltonian that retains two-index interaction terms and includes Bogolyubov’s superfluidity Hamiltonian as a limiting case. Applying a canonical Bogolyubov transform…

Resonant Scattering of Gamma Quanta by $\mathrm{Mg}^{24}$ Nuclei

N. N. DELYAGIN and V. S. SHPINEL
1958 SovietRxiv: ru-195801.60898

This paper reports an experimental study of resonance scattering of 1.37 MeV gamma quanta from the decay of sodium-24 by magnesium-24 nuclei, aimed at determining the lifetime of the first excited state of magnesium-24. Because recoil losses exceed the natural level width, the experiment uses radioa…

Fluoroorganosilicon Compounds. Simple Fluoroorganosilicon Ethers

Corresponding Member of the Academy of Sciences of the USSR A. D. PETROV, V. A. PONOMARENKO
1958 SovietRxiv: ru-195801.60681

This study extends hydrosilane addition chemistry to allyl ethers of 1,1,2-trifluoro-2-chloroethanol and 1,1,2,2-tetrafluoroethanol in order to prepare previously undescribed fluorosilicon-organic ethers and compare hydrosilane reactivity. Using platinized carbon catalysis in heated autoclave reacti…

On Chebyshev Approximation in a Hilbert Ring

S. I. ZUKHOVITSKII and G. I. ESKIN
1958 SovietRxiv: ru-195801.60504

This paper studies Chebyshev approximation of continuous functions on a compact set with values in a Hilbert ring by functions of the form given by left multiplication by an arbitrary ring element and a fixed function. Using a more general framework of approximation by operator functions in Hilbert …