Showing 50 of 25456 papers

Issues in the Geometry of Complex Kinematic Chains

Unknown
1958 SovietRxiv: ru-195801.25671

This paper develops structural and geometric relations for closed complex kinematic chains. It defines independent simple closed contours, derives formulas for their number in terms of link multiplicities and numbers of pairs, and formulates transformation equations whose rank is treated as an intri…

On Orthogonal Subgroups of Classical Compact Lie Groups

A. M. VASIL'EV
1958 SovietRxiv: ru-195801.25530

This note studies when subgroups of classical compact Lie groups are orthogonal with respect to the Cartan invariant metric, a question motivated by the geometry of homogeneous spaces and totally geodesic submanifolds. It defines subgroups of a real orthogonal group built as products of orthogonal, …

Adsorption from Three-Component Solutions

Unknown
1958 SovietRxiv: ru-195801.25468

This paper examines adsorption from ternary liquid solutions, a problem less developed than adsorption from binary mixtures, using the system acetic acid, lauric acid, and cetane on an active Volga opoka adsorbent. Adsorption isotherms were measured across a broad concentration range, with a special…

Synthesis of Aromatic Germanium Compounds by Means of Aryldiazonium Borofluorides

A. N. NESMEYANOV, L. I. EMEL'YANOVA, and L. G. MAKAROVA
1958 SovietRxiv: ru-195801.25455

This paper examines the extension of diazonium-based arylation methods, previously used for organotin and organolead compounds, to the synthesis of aromatic germanium compounds. Aryldiazonium borofluorides were decomposed in absolute acetone in the presence of germanium tetrachloride and metal powde…

On the resolution of irreducible representations of the principal of a complex unimodular group of order $n$ into representations of a second order complex unimodular group

Unknown
1958 SovietRxiv: ru-195801.25357

This paper studies the branching problem for continuous irreducible unitary representations of the principal series of the complex unimodular group, focusing on the restriction from the group of order 3 to a subgroup isomorphic to the complex unimodular group of order 2. The representation is realiz…

Some problems of large deviations for the maximum of sums of independent identically distributed random variables

Unknown
1958 SovietRxiv: ru-195801.25210

This paper studies large deviation asymptotics for the maximum of partial sums of independent identically distributed random variables, reformulated as the first passage time of a homogeneous random walk through an absorbing barrier. For bounded lattice jumps, it analyzes the singularities of the ge…

Isometric embedding of polyhedra

V. A. ZALGALLER
1958 SovietRxiv: ru-195801.25023

This paper proves an isometric embedding theorem for polyhedra of dimensions 1 through 4 whose simplices lie in a space of constant curvature, allowing self-intersections and overlaps in the target space of the same dimension. The argument constructs Voronoi-type regions around a finite set of selec…

On the Dynamic Stability of Elastic Systems

V. A. YAKUBOVICH
1958 SovietRxiv: ru-195801.24770

The paper studies mathematical questions in the dynamic stability of elastic systems with periodic perturbations, focusing on second order systems with a positive definite unperturbed matrix and a one-parameter periodic perturbation. It defines resonance and critical frequencies in classes of pertur…

Conjugation of the Lyapunov Norm

Unknown
1958 SovietRxiv: ru-195801.24726

This paper develops an abstract geometric theory of conjugate Lyapunov norms in finite-dimensional Euclidean spaces, motivated by characteristic exponents of conjugate linear differential systems. It defines conjugate norms, defects of conjugate bases, and the irregularity coefficient, then proves t…

Dipole Moments of Some Organosilicon Compounds

G. N. KARTSEV, Corresponding Member of the Academy of Sciences of the USSR Ya. K. SYRKIN, V. F. MIRONOV
1958 SovietRxiv: ru-195801.24717

This study reports dipole moment measurements for a series of organosilicon compounds in benzene at 25°C using the heterodyne method, with extrapolated polarizations calculated by the Hedestrand formula. The authors emphasize that atomic polarization in silicon compounds is significant and introduce…

Determination of the Purity and Crystallization Temperature of Certain Hydrocarbons in Amounts of 1–2 ml

A. G. ANIKIN and G. M. DUGACHEVA
1958 SovietRxiv: ru-195801.24610

This paper addresses the determination of purity and crystallization temperatures of organic compounds when only very small samples are available, a limitation of the standard Rossini crystallization curve method. The authors modify the reaction vessel, thermocouple arrangement, stirring design, and…

Nik. A. NESMEYANOV and O. A. REUTOV

Unknown
1958 SovietRxiv: ru-195801.24435

This paper reports the preparation and characterization of several previously unknown functional derivatives of ferrocene-1,1′-dicarboxylic acid. The authors synthesize the diacid chloride, diamide, carbamido ester, carbamido acid, cyano acid, dinitrile, and a dimeric anhydride, giving reaction cond…

Catalytic alkylation of n-butane with ethylene at high temperatures and pressures

N. M. Nazarova, A. A. Balandin, and L. Kh. Freidlin
1958 SovietRxiv: ru-195801.24267

This study examines the catalytic alkylation of n-butane with ethylene under high-temperature, high-pressure flow conditions using alumina, treated alumina, and aluminosilicate catalysts. Product fractions were distilled, purified from unsaturated compounds by silica gel chromatography, and identifi…

INVESTIGATION OF THE REACTION OF LOW-TEMPERATURE OXIDATION OF METHANE INITIATED BY OXYGEN ATOMS FORMED DURING THE THERMAL DECOMPOSITION OF OZONE

Unknown
1958 SovietRxiv: ru-195801.23880

The study examines low-temperature methane oxidation initiated by oxygen atoms generated through thermal decomposition of ozone, with attention to the formation of methyl hydroperoxide and formaldehyde. Experiments in a jet apparatus at atmospheric pressure measured product yields as functions of co…

X-ray diffraction by regions consisting of long molecules

D. Ya. TSVANKIN
1958 SovietRxiv: ru-195801.23723

This paper develops formulas for X-ray diffraction from polymer regions composed of long, parallel chain molecules forming an axial texture. It treats three idealized degrees of order: complete three-dimensional order, free rotation of chains with regular axial shifts, and one-dimensional diffractio…

Long-period lunisolar tide in the World Ocean

I. V. Maksimov
1958 SovietRxiv: ru-195801.23643

This paper examines long-period luni-solar tides in the World Ocean, focusing on semimonthly, monthly, and semiannual constituents derived from the tide-generating potentials of the Moon and Sun. Using Doodson’s expansion, an elastic Earth correction, and harmonic analyses of long observational sea-…

Effect of the Position and Nature of the Substituent on the Fluorescence Spectra of Anthraquinone Derivatives in Frozen Solutions

D. N. Shigorin, N. A. Shcheglova, R. N. Nurmukhametov, and N. S. Dokunikhin
1958 SovietRxiv: ru-195801.23511

This study examines how the position and chemical nature of substituents affect the fluorescence spectra of anthraquinone derivatives in frozen hydrocarbon solutions at 77 K. Comparing anthraquinone, beta-substituted derivatives, and several alpha-substituted hydroxy, chloro, and amino compounds, th…

On the Question of Ion Hydration in Aqueous Solutions

Unknown
1958 SovietRxiv: ru-195801.23497

The paper examines orientational hydration of ions in aqueous solutions, focusing on why small or multicharged ions reduce the translational mobility of nearby water molecules whereas large ions can increase it. Using an electrostatic model of the internal field in liquid water and the field produce…

Influence of the size of alkyl radicals $\mathrm{R}$ on the stability of the $\mathrm{Si}$ – $\mathrm{R}$ bond toward concentrated sulfuric acid

B. N. Dolgov, D. N. Andreev, and V. P. Lyutyi
1958 SovietRxiv: ru-195801.23473

This study examines how the size of alkyl substituents affects the stability of silicon carbon bonds in gamma organosilicon acids under the action of concentrated sulfuric acid. Three methyldialkylsilylpropionic acids containing n-propyl, n-butyl, or isoamyl groups were synthesized through chloromet…

Pathways of Propylene and Ethylene Formation during Isobutylene Cracking

B. D. MOISEEV, Yu. I. LYADOVA, V. I. VEDENEEV, M. B. NEIMAN
1958 SovietRxiv: ru-195801.23429

This study examines the formation pathways of propylene and ethylene during the thermal cracking of isobutylene, with particular attention to whether these gaseous products arise directly from isobutylene or from intermediate liquid products. Using an isotope kinetic method, the authors added carbon…

Effect of Adsorption of Volatile Inhibitors on the Electrochemical Behavior of Iron

I. L. Rozenfel’d and V. P. Persiantseva
1958 SovietRxiv: ru-195801.22958

This study examines how adsorption of volatile inhibitors affects the electrochemical behavior and passivation of iron under conditions relevant to atmospheric corrosion protection. Using stationary potential measurements in thin electrolyte films, the authors compare benzylamine and morpholine adso…

Alkylation of Phenol with Acetylene under Elevated Pressure

Unknown
1958 SovietRxiv: ru-195801.22927

This study examines the alkylation of phenol with acetylene under elevated pressure to determine how pressure, temperature, and catalyst composition affect formation of 1,1-(4,4′-dihydroxy)-diphenylethane. Experiments were carried out in a rotating stainless-steel autoclave using phenol in aqueous m…

A Note on the Petrovsky Criterion for Uniform Well-Posedness of the Cauchy Problem for Partial Differential Equations

S. L. SOBOLEV
1958 SovietRxiv: ru-195801.22432

This note examines Petrovsky’s criterion for uniform well-posedness of the Cauchy problem for linear partial differential equations with two independent variables and constant coefficients. Using elementary lemmas and Newton polygon analysis of the characteristic equation, it studies the asymptotic …

Radiation of a point charge uniformly moving along the axis of a circular aperture in an infinite perfectly conducting plane

Unknown
1958 SovietRxiv: ru-195801.22411

This paper analyzes the electromagnetic radiation produced by a point charge moving uniformly along the axis of a circular aperture in an infinite ideally conducting plane, in the nonrelativistic limit. The field is represented as the sum of ordinary transition radiation and the radiation associated…

On Accumulation Points of the Set of Markov Numbers

P. G. Kogoniya
1958 SovietRxiv: ru-195801.22265

This paper studies the structure of the sets of Markov numbers obtained from irrational numbers in the unit interval whose continued fraction partial quotients have a fixed limiting upper bound. Using continued fraction estimates for the quantities governing Diophantine approximation constants, it p…

ON A VARIATIONAL PRINCIPLE IN THE STATISTICAL MANY-BODY PROBLEM

Let us consider a system of Fermi particles with Hamiltonian
1958 SovietRxiv: ru-195801.22261

The paper formulates a statistical variational principle for a system of Fermi particles with pair interactions, extending Bogolyubov’s zero-temperature variational method to nonzero temperatures. Using a canonical transformation to quasiparticle amplitudes as variational parameters and Bogolyubov’s…

On limit logics

Unknown
1958 SovietRxiv: ru-195801.22259

This note studies limit logics, defined as countable closed subclasses of infinitely valued logic that contain homomorphic preimages of every finite valued logic. It introduces functions with a box structure and uses their behavior under superposition to associate invariants, encoded by real numbers…

On the Functional Closedness of Completely Regular Spaces

G. I. KAC
1958 SovietRxiv: ru-195801.22177

The paper studies functionally closed completely regular spaces, also called Q-spaces, and their relation to complete topological spaces. It extends a theorem of A. A. Kubenskii by removing the normality assumption, proving that every complete topological space of attainable cardinality is functiona…

ON THE AREA MEASURE UNDER A QUASICONFORMAL MAPPING

Unknown
1958 SovietRxiv: ru-195801.22132

This note studies how planar area measure changes under a quasiconformal mapping whose dilatation is close to one. For a normalized mapping between rectangles, the argument estimates a boundary integral by the Jacobian and derives an inequality involving the square root of the Jacobian, then applies…

\(0^+ \to 0^+\) TRANSITION IN Ce\(^{140}\)

Unknown
1958 SovietRxiv: ru-195801.22085

The paper investigates whether a reported conversion line near 1909 keV in the decay of La140 corresponds to a transition in Ce140 between a 0+ excited state and the 0+ ground state. The authors measured the gamma spectrum near 1900 keV with a ritron-type gamma spectrometer and examined the hard con…

Synthesis of Alkylated Hydroperoxides of the 1,1-Diphenylethane Series Using a Chromatographic Method for Their Isolation

T. I. YURZHENKO, K. S. GRIGOR’EVA, N. V. AREF’EV, and M. R. VILENSKAYA
1958 SovietRxiv: ru-195801.22064

This study examines the synthesis and characterization of alkylated hydroperoxides in the 1,1-diphenylethane series, focusing on how para alkyl substituents in one phenyl ring and an extended alkyl group at the tertiary carbon affect autoxidation and hydroperoxide behavior. The corresponding hydroca…

Coulomb Interaction Energy of a Silica Gel Hydroxyl Group with a Benzene Molecule

A. V. KISELEV and D. P. POSHKUS
1958 SovietRxiv: ru-195801.21841

This paper estimates the Coulomb contribution to the interaction between surface hydroxyl groups on silica gel and adsorbed benzene molecules, a proposed origin of the enhanced adsorption and heat of adsorption observed on hydrated silica gel. Using simplified electrostatic models for the benzene pi…

Radiolysis of heptane and some other alkanes

L. S. Polak, A. V. Topchiev, and N. Ya. Chernyak
1958 SovietRxiv: ru-195801.21637

This study examines the gamma radiolysis of liquid and frozen paraffin hydrocarbons, with emphasis on purified n-heptane irradiated by cobalt-60 sources under deoxygenated conditions. Gas evolution, gas composition, physical properties of the liquid phase, spectra, distillation fractions, sulfonatio…

On the Accumulation of Perturbations in Nonstationary Linear Systems

Unknown
1958 SovietRxiv: ru-195801.21529

This paper studies the accumulation of perturbations in nonstationary linear oscillatory systems described by systems of differential equations with time dependent polynomial operator coefficients. The author reduces the general system to an equivalent first order linear matrix system, introduces ma…

On the Theory of the Temperature Dependence of Coordination Numbers of Ions in Aqueous Solutions

O. Ya. SAMOILOV
1958 SovietRxiv: ru-195801.21431

This paper considers the temperature dependence of ionic coordination numbers in dilute aqueous electrolyte solutions, defining an ion’s coordination number as the average number of water molecules in its immediate environment. It models coordination as a dynamic equilibrium between activated jumps …

On the Relationship Between Stress and Strain-Rate Tensors in the General Case of Large and Small Deformations

G. I. GUREVICH
1958 SovietRxiv: ru-195801.21345

This paper extends a Maxwell-type constitutive law for condensed, practically homogeneous and isotropic bodies from small deformations to cases involving large residual deformation while retaining small elastic strains. It derives tensor relations between stress and strain-rate tensors, allowing the…

On rational approximations to irrational numbers with bounded partial quotients

A. VINOGRADOV, B. DELAUNAY and D. FUKS
1958 SovietRxiv: ru-195801.21310

This note studies the relation between Lagrange classes of irrational numbers with bounded continued fraction partial quotients and Markov extremal classes of indefinite binary quadratic forms, in the setting of rational approximation constants and extremal lattices for the region |uv| < 1. Using af…

Fine structure of X-ray $K$-absorption spectra of titanium in titanates

E. E. VAINSTEIN, M. N. BRIL, and I. B. STARYI
1958 SovietRxiv: ru-195801.21158

This study examines the fine structure of titanium K absorption spectra in a series of titanates, including compounds with perovskite and ilmenite type structures, barium metatitanate and tetratitanate, zinc titanate, and rutile. Using a focusing X ray tube spectrograph and absorbers of varying thic…