SovietRxiv

Study of Commercial Products from Tomsk Oil

K. K. STRAMKOVSKAYA, N. M. SMOLYANINOVA, S. I. SMOLYANINOV
Submitted 1974 | SovietRxiv: ru-197401.10925 | Translated from Russian

Abstract Generated abstract

This study evaluates the potential yield and quality of commercial petroleum products obtainable from crude oil of the Sovetsko-Sosninsko-Medvedevskoye field in Tomsk Oblast. The oil was fractionated by direct distillation using the ARN-2 method, and the resulting gasoline, jet fuel, kerosene, diesel, cracking feedstock, and lubricating oil fractions were characterized against relevant technical standards, with lubricating oil potential assessed by adsorption separation. The results indicate abundant low-sulfur gasoline fractions with low octane numbers, kerosene and diesel fractions meeting applicable specifications, and a favorable lubricating oil feedstock, with total distillate and residual oil yield at a viscosity index of 85 of about 15%.

Full Text

PROCEEDINGS
of the Tomsk Polytechnic Institute, Order of the October Revolution and Order of the Red Banner of Labor,
named after S. M. Kirov

Vol. 198　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　1974

STUDY OF COMMERCIAL PRODUCTS OF TOMSK OIL

K. K. STRAMKOVSKAYA, N. M. SMOLYANINOVA, S. I. SMOLYANINOV,
A. N. BELOUSOV, A. E. SHULIVEISTROV

(Presented by the scientific-methodological seminar of the Faculty of Chemical Technology)

In the present work, the potential content of commercial petroleum products in the oil of the Sovetsko-Sosninsko-Medvedevskoye field of Tomsk Oblast (well 18) was determined. For this purpose the oil was distilled in an ARN-2 apparatus according to the method of the All-Union Scientific Research Institute of the Petroleum Industry [1]. From the fractions obtained, petroleum products were blended and characterized in accordance with the requirements of the technical standards.

Fig. 1. Curves of the dependence of oil quality on the depth of adsorption separation of the 350–450°C fraction

Fig. 1. Curves of the dependence of oil quality on the depth of adsorption separation of the 350–450°C fraction

The results of the analyses are given in Tables 1–5. In the fraction boiling within the range 350–450°C, and in the residue, the potential content of lubricating oils was determined by the adsorption-separation method according to GOST 11244-65.

Characteristics of fractions boiling up to 200°C
Table 1

Fraction selection temperature, °C Density, $\rho^{20}_{4}$ Fractional composition, °C: IBP Fractional composition, °C: 10% Fractional composition, °C: 50% Fractional composition, °C: 90% Fractional composition, °C: FBP Sulfur content, % Acidity, mg KOH per 100 ml Saturated vapor pressure, mm Hg Octane number: neat Octane number: TEL, g per kg 0.82 Oil yield, %
28–85 0.6860 30 38 64 87 85 absent 0.61 564 62.4 78.0 7.5
28–100 0.7005 33 39 70 95 100 absent 0.61 60.0 77.0 10.2
28–110 0.7075 37 41 77 103 110 absent 0.62 58.0 75.0 12.1
28–120 0.7130 40 42 81 110 120 absent 0.63 334 55.6 74.6 13.7
28–130 0.7197 42 44 88 123 130 absent 0.65 54.0 73.0 15.9
28–140 0.7260 44 47 94 132 140 absent 0.69 52.0 72.8 18.0
28–150 0.7310 47 48 99 142 150 traces 0.72 277 50.0 72.4 20.1
28–160 0.7358 48 50 105 149 160 traces 0.78 48.0 70.0 22.2
28–170 0.7404 49 52 111 157 170 traces 0.82 46.0 69.0 24.2
28–180 0.7450 50 54 117 169 180 traces 0.87 44.0 66.0 26.4
28–190 0.7485 51 55 123 175 190 traces 0.97 42.0 65.0 28.2
28–200 0.7530 52 56 127 185 200 traces 1.00 121 40.0 64.0 30.3

Table 2

Characteristics of jet fuels

Fraction selection temperature, °C Density, $d^{20}_{4}$ Fractional composition, °C: I.B.P. Fractional composition, °C: 10% Fractional composition, °C: 50% Fractional composition, °C: 90% Fractional composition, °C: 98% Kinematic viscosity at 20°C, cSt Smoke point, mm Calorific value, kcal/kg Acidity, mg KOH per 100 ml fuel Flash point in closed cup, °C Iodine number, g iodine per 100 g product Aromatics content, % Sulfur content, total, % Sulfur content, mercaptan, % Crystallization onset temperature, °C Yield on crude oil, %
120–240 0.7912 125 131 183 227 237 1.45 25 10260 1.70 64 34 0.56 19.1 0.03 0.02 −54
120–280 0.8043 130 135 199 264 276 1.80 25 10280 1.86 28 36 1.28 16.5 0.06 0.03 −45

Table 3

Characteristics of kerosene fractions

Fraction selection temperature, °C Density, $d^{20}_{4}$ Fractional composition, °C: I.B.P. Fractional composition, °C: 10% Fractional composition, °C: 50% Fractional composition, °C: 90% Fractional composition, °C: 98% Fractional composition, °C: to 270°C Flash point in closed cup, °C Cloud point, °C Sulfur content, % Acidity, mg per 100 ml fraction Nonsmoking-flame height, mm Yield on crude oil, %
150–280 0.8191 155 163 215 266 277 92 53 −40 0.08 2.33 22 26.6
150–320 0.8304 160 167 237 301 317 71 55 −23 0.14 2.33 21 34.4

Characteristics of Diesel Fuels

Table 3

Fraction withdrawal temperature, °C Density, \(p^{20}_{4}\) Fractional composition, °C: 10% Fractional composition, °C: 50% Fractional composition, °C: 90% Fractional composition, °C: 98% Kinematic viscosity, cSt: 20°C Kinematic viscosity, cSt: 50°C Temperature, °C: flash in closed crucible Temperature, °C: pour point Temperature, °C: cloud point Iodine number per 100 g of fuel Cetane number Diesel index Coke content, % Acidity, mg KOH per 100 ml of fuel Sulfur, % Oil yield, %
150–350 0.8370 169 248 327 343 3.40 2.00 73 −33 −20 1.34 54 51.2 2.93 2.93 0.19 39.3
200–350 0.8470 210 269 344 344 4.70 2.50 108 −29 −13 1.32 58 48.5 2.73 2.73 0.32 29.2
240–350 0.8580 250 290 341 346 6.30 3.20 120 −17 −8 1.41 58 49.4 4.73 4.78 0.49 49.4

Characteristics of Catalytic-Cracking Feedstock and Other Secondary Processes

Table 4

Fraction withdrawal temperature, °C Density, \(p^{20}_{4}\) Molecular weight Kinematic viscosity, cSt: 50°C Kinematic viscosity, cSt: 100°C Pour point, °C Sulfur, % Sulfuric-acid resins, % Coke content, % Nitrogen, % Vanadium, % Oil yield, %
from 350 to 450 0.9060 315 14.70 4.30 18 1.21 8.0 0.02 0.38 0.00004 18.5
above 350 0.9467 330 — 16.6 25 1.33 — 6.0 0.36 0.0006 39.2
above 450 0.9867 450 — 93.0 30 1.67 — 10.0 0.70 0.0004 20.7

Curves of the dependence of the quality of distillate and residual oils on the depth of adsorption separation are presented in Figs. 1–2.

The gasoline fractions of this oil, obtained in large quantity, are low-sulfur, but, owing to the predominant content of methane hydrocarbons in them [2], are characterized by a low octane number. They can serve only as base components of commercial gasolines and jet fuels.

Fig. 2. Curves of the dependence of oil quality on the depth of adsorption separation of the residue above 450°C

Fig. 2. Curves of the dependence of the quality of oils on the depth of adsorption separation of the residue above 450°C

Kerosene distillates meet the requirements of the GOST standard for illuminating kerosene.

Diesel-fuel fractions taken in various temperature intervals satisfy the requirements of the technical specifications for summer diesel fuel for high-speed diesels.

The oil studied is a favorable feedstock for obtaining oils. The total yield of distillate and residual oils from it with a viscosity index of 85 is about 15%.

Conclusions

  1. The potential content of commercial petroleum products from the oil of the Sovetsko-Sosninsko-Medvedevskoye field has been determined.

  2. The qualitative characteristics of commercial products that can be obtained by direct distillation of this oil have been shown.

References

  1. Z. V. Driatskaya. Refined program for the study of oil, 1966.

  2. N. M. Smolyaninova, S. I. Smolyaninov et al. Determination of the group hydrocarbon composition of kerosene–gas-oil oil fractions of the oil from the Sovetsko-Sosninsko-Medvedevskoye field. Present collection.

Submission history

[v1] 1974

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Study of Commercial Products from Tomsk Oil