Balance of Associated Gas Components During Stepwise Degassing of Oil from the Sovetskoye Field

A. V. Kravtsova, N. M. Smolyaninova
Submitted 1975 | SovietRxiv: ru-197501.12150 | Translated from Russian

Abstract Generated abstract

This study evaluates the component balance of associated petroleum gas during staged degassing of reservoir oil from the Sovetskoye field, with attention to light hydrocarbons important for petrochemical use. Using data on gas released during separation and measurements of gases remaining dissolved after atmospheric degassing, including tracer determination with ethyl bromide, the authors calculate free and dissolved gas components for oils from wells 17, 501, and 27 at 16, 6, and 0 atm. The results indicate broadly similar total associated gas contents among the samples, about 10 to 12 wt. percent of reservoir oil, and show that methane, ethane, and nonhydrocarbon gases are mainly released by separation to 6 atm. Most recoverable C3 to C5 hydrocarbons are obtained during further separation to atmospheric pressure and stabilization, reaching about 75 kg/t for bed A-1 and 80 kg/t for bed B-VIII.

Full Text

Component Balance of Associated Gas During Staged Degassing of Oil from the Sovetskoye Field

A. V. Kravtsova, N. M. Smolyaninova

(Presented by the scientific-methodological seminar of the CTF)

Schemes for the gathering and transportation, and variants of processing, of associated petroleum gas are determined to a considerable extent by the amount of light hydrocarbons it contains, mainly \(C_3—C_5\), a valuable feedstock for petrochemical production.

The total resources of associated gas and of its individual components consist of the gas dissolved in the oil and released from it under the given conditions of staged degassing, i.e., at the pressure and temperature under study. Data on the yields and component composition of petroleum gas during staged degassing of reservoir samples of Sovetskoye oil have been given previously.1

In the present work, a complete balance of the components of associated gas is presented for various conditions of separation of reservoir oil from the Sovetskoye field (wells 17, 501, and 27). The yield and composition of the gases dissolved in the oil after its degassing to atmospheric pressure were determined by the method of the All-Union Scientific Research Institute for Oil Refining, using ethyl bromide as a tracer.

A qualitative test for hydrogen sulfide showed its absence in all samples. The results of the analysis are given in Table 1.

Table 1

Content of soluble gases in degassed oil, by components and in total
(% by weight of oil)

Component Well No. 501 Well No. 17 Well No. 27
ethane 0.03 0.03 0.04
propane 1.05 0.77 1.06
iso-butane 0.58 0.53 0.60
n-butane 1.52 1.81 1.69
iso-pentane 1.20 1.26 1.29
n-pentane 1.82 1.87 1.85
total to \(C_4\) 3.18 3.14 3.39
total to \(C_5\) 6.20 6.27 6.53

The calculation of the amount of free gas and gas dissolved in oil at various pressures in the stages was carried out on the basis of the data in Table 1 and the results of the preceding work.

The results presented in Table 2 show that the total amount—

Table 2

Balance of associated gas, in kg per 1 t of reservoir oil from the Sovetskoye field during staged degassing

Well No. Components Stages, atm Stages, atm Stages, atm
16.0 6.0 0.0
17 Free gas (up to C$_5$) 29.0 37.8 48.8
17 Gas in solution (up to C$_5$) 79.5 70.7 59.7
501 Free gas (up to C$_5$) 33.5 42.0 54.2
501 Gas in solution (up to C$_5$) 79.3 70.8 58.6
27 Free gas (up to C$_5$) 36.0 45.0 58.4
27 Gas in solution (up to C$_5$) 83.9 74.9 61.5

amount of associated gas is approximately the same for all the oils investigated and lies within the range of 10—12 wt. % per reservoir sample.

Table 3 presents the balance of gas components during staged degassing of reservoir oil from the investigated wells, calculated—

Table 3

Balance of gas components during staged degassing of reservoir oil from the Sovetskoye field, kg/t of reservoir oil

Component Well No. 16.0: in gas phase 16.0: dissolved in oil 16.0: total 6.0: in gas phase 6.0: dissolved in oil 6.0: total 0.0: in gas phase 0.0: dissolved in oil 0.0: total
Methane 17 20.80 8.31 29.11 26.08 3.03 29.11 29.11 0.00 29.11
Methane 501 24.07 7.93 32.00 28.50 3.50 32.00 32.00 0.00 32.00
Methane 27 25.70 7.70 33.40 30.30 3.10 33.40 33.40 0.00 33.40
Ethane 17 1.51 1.94 3.45 2.22 1.34 3.45 3.13 0.32 3.45
Ethane 501 1.98 2.02 4.00 2.58 1.42 4.00 3.73 0.27 4.00
Ethane 27 1.76 2.17 3.93 2.32 1.62 3.93 3.57 0.36 3.93
Propane 17 2.70 10.67 13.37 3.96 9.41 13.37 5.82 7.55 13.37
Propane 501 2.63 13.87 16.50 3.87 12.63 16.50 6.50 10.00 16.50
Propane 27 2.76 15.24 18.00 4.60 13.40 18.00 8.00 10.00 18.00
Isobutane 17 0.70 6.73 7.43 1.11 6.32 7.43 2.16 5.27 7.43
Isobutane 501 1.15 7.31 8.46 1.74 6.72 8.46 3.03 5.43 8.46
Isobutane 27 1.54 8.43 9.97 2.25 7.72 9.97 4.33 5.64 9.97
n-Butane 17 1.39 20.14 21.53 2.04 19.49 21.53 4.21 17.32 21.53
n-Butane 501 1.65 17.68 19.33 2.65 16.68 19.33 4.93 14.40 19.33
n-Butane 27 2.22 20.51 22.73 3.46 19.27 22.73 6.73 16.00 22.73

Continuation of Table 3

1 2 3 4 5 6 7 8 9 10 11
iso-Pentane 17 0,44 12,80 13,24 0,67 12,57 13,24 1,52 11,72 13,24
iso-Pentane 501 0,67 12,14 12,81 0,92 11,89 13,81 1,41 11,40 12,81
iso-Pentane 27 0,37 12,09 12,46 0,42 12,04 12,46 0,36 12,10 12,46
i-Pentane 17 0,44 18,60 19,04 0,67 18,37 19,04 1,52 17,52 19,04
i-Pentane 501 0,59 18,24 18,83 0,97 17,86 18,83 1,73 17,10 18,83
i-Pentane 27 0,27 17,57 19,94 0,44 17,50 17,94 0,54 17,40 17,94
Nonhydrocarbon gases 17 1,02 0,31 1,33 1,16 0,17 1,33 1,33 0,00 1,33
Nonhydrocarbon gases 501 0,76 0,11 0,87 0,77 0,10 0,87 0,87 0,00 0,87
Nonhydrocarbon gases 27 1,28 0,19 1,47 1,22 0,25 1,49 1,47 0,00 1,47

… according to the data of Tables 1–2. It is evident that, during separation down to 6 atm, the main quantities of methane, ethane, and nonhydrocarbon gases are released from the reservoir oil.

The overwhelming portion of the hydrocarbons \(C_3—C_5\) can be recovered and used during separation of the oil from 6 to 0 atm and during its subsequent stabilization. The recoverable quantities of hydrocarbons \(C_3—C_5\) from 1 ton of reservoir oil from well 17 (bed A-1) and wells Nos. 27 and 501 (bed B-VIII) are, respectively, \(74{,}61\ \text{kg/t}\), \(81{,}10\ \text{kg/t}\), and \(75{,}93\ \text{kg/t}\).

Taking into account that at the Sovetskoye field by 1975 approximately 10 million tons of oil and more than \(0{,}5\) billion \(\text{m}^3\) of associated gas will be produced, the total resources of hydrocarbons will amount to approximately 1 million tons.

Conclusions

  1. The yield and composition of gases dissolved in the oil of the Sovetskoye field after its degassing to atmospheric pressure have been determined.

  2. A complete balance of the components of associated gas during staged degassing of oil from the Sovetskoye field has been compiled, calculated per reservoir oil.

  3. It has been shown that the recoverable quantities of hydrocarbons \(C_3—C_5\) from 1 ton of reservoir oil for beds A-1 and B-VIII reach, respectively, \(75\ \text{kg/t}\) and \(80\ \text{kg/t}\).

  1. N. M. Smolyaninova, A. V. Kravtsov, V. A. Kuznetsova. Study of the component composition of associated gas from the Sovetskoye field. Present collection. ↩

Submission history

Balance of Associated Gas Components During Stepwise Degassing of Oil from the Sovetskoye Field