Showing 50 of 25357 papers

DIFFUSION MECHANISM OF THE DIURNAL VARIATION OF COSMIC RAYS

Unknown
1965 SovietRxiv: ru-196501.50309

This paper proposes a diffusion mechanism for the diurnal variation of cosmic rays based on anisotropic propagation in the interplanetary magnetic field carried by the solar wind. Treating solar wind streams as Archimedean spiral magnetic structures, the author derives the transverse cosmic ray flux…

THEORY OF DIFFUSIOPHORESIS OF LARGE NONVOLATILE AEROSOL PARTICLES

Yu. I. Yalamov, Corresponding Member of the Academy of Sciences of the USSR B. V. Deryagin
1965 SovietRxiv: ru-196501.50086

A theory is developed for diffusiophoresis of large nonvolatile aerosol particles in a binary gas mixture in the limit of small Knudsen number. Using irreversible thermodynamics, Onsager reciprocity, diffusion with barodiffusion, and hydrodynamic flow around widely separated spheres with slip bounda…

On the Theory of Radical Polymerization

Unknown
1965 SovietRxiv: ru-196501.49850

This paper examines deviations from Arrhenius behavior observed in low-temperature radical photopolymerization of vinyl monomers, particularly styrene and methyl methacrylate. It argues that, while collective interaction theories are not excluded, the curvature of polymerization-rate plots can be ex…

On the Fluorescence Lifetime of Complex Molecules

Academician of the Academy of Sciences of the BSSR A. N. Sevchenko, L. G. Pikulik, M. Ya. Kostko
1965 SovietRxiv: ru-196501.49736

This paper investigates how the fluorescence lifetime of complex organic molecules in solution depends on the frequency of exciting light, with particular attention to the anti-Stokes excitation region where direct measurements had been scarce. Using a phase fluorometer, the authors measured lifetim…

On the topological structure of stability regions of a self-adjoint system of differential equations with periodic coefficients

V. B. LIDSKII, P. A. FROLOV
1965 SovietRxiv: ru-196501.49708

This paper studies the topological structure of strong stability regions for real self-adjoint first-order systems of differential equations with periodic coefficients, generalizing Hamiltonian systems. Using a characterization of admissible matriciants by symplectic endpoint conditions, the authors…

Stability of Difference Schemes for the Cauchy Problem for Systems of Partial Differential Equations

Unknown
1965 SovietRxiv: ru-196501.49595

The paper studies stability of finite difference schemes for the Cauchy problem for linear systems of partial differential equations with constant coefficients that are correct in the sense of Petrovskii. Using Fourier analysis in Sobolev norms for periodic initial data, it proves stability of an ex…

Solubility polytherm in the ternary system $\mathrm{HNO}_3$ – $\mathrm{H}_2\mathrm{O}$ – $(\mathrm{C}_4\mathrm{H}_9\mathrm{O})\mathrm{PO} (\mathrm{C}_4\mathrm{H}_9)_2$

Corresponding Member of the Academy of Sciences of the USSR A. V. Nikolaev, Yu. A. Dyadin,
1965 SovietRxiv: ru-196501.49519

This paper examines phase equilibria and mutual solubility in the ternary system nitric acid, water, and the butyl ester of dibutylphosphinic acid at different temperatures, motivated by the need to characterize extraction systems and possible component interactions. Using experimental phase separat…

EPR Detection of the Two-Photon Nature of the Sensitized Photodecomposition of Methyl Iodide

V. V. Ryl'kov, V. E. Kholmogorov, A. N. Terenin
1965 SovietRxiv: ru-196501.49410

The study investigates the sensitized photodecomposition of methyl iodide at 77 K using electron paramagnetic resonance detection of methyl radicals. Methyl iodide in inert frozen matrices was irradiated in the presence of phosphorescent sensitizers including aromatic amines, hydrocarbons, benzophen…

Thermal Degradation of Vinylphosphinic Acid Ester Polymers

Academician K. A. Andrianov, G. S. Kolesnikov, E. F. Rodionova,
1965 SovietRxiv: ru-196501.49399

This study examines the thermal degradation of polymers of vinylphosphinic acid esters, motivated by the differing self-extinguishing behavior of their styrene copolymers as a function of ester group structure. The authors propose that decomposition proceeds through cleavage of alkyl ester groups wi…

ON A PROPERTY OF “INSTABILITY” OF HARMONIC CAPACITY

A. A. Gonchar
1965 SovietRxiv: ru-196501.49195

This note studies an instability property of Newtonian harmonic capacity for open subsets of three-dimensional Euclidean space and its consequences for uniform approximation by harmonic functions. It shows that if the local capacity of an open set is sufficiently large in a limsup sense at almost ev…

The Cauchy Problem and a Boundary Value Problem for Some Nonlinear Second-Order Ordinary Differential Equations

Unknown
1965 SovietRxiv: ru-196501.48961

This note studies Cauchy and boundary-value problems for several singular nonlinear second-order ordinary differential equations on the half-line, including equations related by a radial substitution and arising in spherically symmetric scalar-field models. It analyzes when solutions can change sign…

$\mathrm{Co}(\mathrm{III})$ dioximes containing a water molecule and a molecule of ammonia or an organic amine in the inner sphere

Unknown
1965 SovietRxiv: ru-196501.48919

This communication reports the synthesis of cobalt(III) dimethylglyoxime complexes containing one coordinated water molecule and one molecule of ammonia or an organic amine, with the general cationic form [Co(DH)2(H2O)A]+. The compounds were prepared by adding calculated amounts of amines, including…

RADIATION OF ELECTROMAGNETIC WAVES IN THE NONLINEAR INTERACTION OF SURFACE OSCILLATIONS IN A PLANE PLASMA LAYER

D. D. Ryutov
1965 SovietRxiv: ru-196501.48896

This paper analyzes electromagnetic radiation produced by nonlinear interactions of surface electrostatic oscillations in a bounded plasma, motivated by observations of intense oscillations and radiation in turbulent plasma heating experiments. For a plane plasma layer with thickness small compared …

ON BOUNDARY-VALUE PROBLEMS FOR DIFFERENTIAL AND INTEGRO-DIFFERENTIAL EQUATIONS IN THE SPACES \(W_{p_1\ldots p_k}^{m_1\ldots m_k}\), \(W_{p_1\ldots p_k,b_1\ldots b_n}^{m_1\ldots m_k}\)

Unknown
1965 SovietRxiv: ru-196501.48870

The paper studies boundary value problems for differential and integro-differential equations associated with mixed Sobolev-type spaces and their weighted analogues, including cases that lead to degenerate equations. It establishes trace and compact embedding properties for these spaces on boundary …

Locally bicompact rings without zero divisors

Unknown
1965 SovietRxiv: ru-196501.48849

This paper studies locally bicompact rings with identity and without zero divisors, focusing on the totally disconnected case beyond the known classification of locally bicompact division rings. It proves that locally bicompact normed rings of this type are either division rings or bicompact local r…

$\alpha$-Ferrocenylcarbonium Salts

---------
1965 SovietRxiv: ru-196501.48800

This paper reports the preparation and characterization of several alpha-ferrocenylcarbonium salts, with emphasis on diphenylferrocenylcarbonium ferrichloride and perchlorate and ferrocenylphenylcarbonium perchlorate and tetraphenylborate. The salts were obtained from the corresponding ferrocenylcar…

SYNTHESIS OF NEW AROMATIC POLYIMIDES BASED ON 3,3′:4,4′-DIPHENYLTETRACARBOXYLIC DIANHYDRIDE

N. A. Adrova, M. M. Koton, E. M. Moskvina
1965 SovietRxiv: ru-196501.48713

This paper reports the synthesis of new aromatic polyimides from 3,3′,4,4′-diphenyltetracarboxylic dianhydride and several aromatic diamines, motivated by the search for heat-resistant polymers with improved chain flexibility. The polymers were prepared through soluble polyamidic acid intermediates …

SYNTHESIS OF PHOSPHORUS-CONTAINING POLYESTERS BY THE REACTION OF HOMOPOLYTRANSESTERIFICATION

A. N. Pudovik, G. I. Evstaf'ev
1965 SovietRxiv: ru-196501.48651

This study examines the synthesis of phosphorus-containing polyesters through homopolytransesterification of oxymethylphosphinic acid esters, a reaction type reported as previously undescribed. Ethyl ethyl-(oxymethyl)-phosphinate, ethyl phenyl-(oxymethyl)-phosphinate, and related esters were prepare…

Processes at Cold Cathodes of an Arc Discharge

G. I. LESKOV, Corresponding Member of the Academy of Sciences of the USSR, K. K. KHRENOV
1965 SovietRxiv: ru-196501.48385

The paper addresses the unresolved mechanism sustaining arc discharge currents at “cold” cathodes, where cathode temperatures and surface electric fields appear insufficient for standard thermionic or electrostatic emission explanations. It proposes applying Einstein’s theory of induced radiation to…

Two-quantum photochemical reaction of alcohol dehydrogenation by aromatic amines at $77^\circ$ K

Kh. S. Bagdasar’yan, Z. A. Sinitsyna
1965 SovietRxiv: ru-196501.48353

This study examines low-temperature photochemical dehydrogenation of alcohols sensitized by aromatic amines at 77 K, focusing on hydrogen formation as a final reaction product. Using gas chromatographic analysis, actinometry, intermittent illumination, EPR comparison, and phosphorescence lifetime me…

Determination of the rate constants for reactions of $\mathrm{H}$ and $\mathrm{O}$ atoms with the $\mathrm{NH}_3$ molecule

K. T. OGANESYAN, Academician of the Academy of Sciences of the Armenian SSR A. B. NALBANDYAN
1965 SovietRxiv: ru-196501.48177

This study determines rate constants for elementary reactions of hydrogen and oxygen atoms with ammonia, addressing contradictory earlier data and the lack of high-temperature measurements. Using first ignition limits for hydrogen, oxygen, ammonia and carbon monoxide, oxygen, ammonia mixtures in a q…

On the Shift of Adsorption Equilibrium on a Semiconductor Surface under Illumination

F. F. Vol'kenshtein, I. V. Karpenko
1965 SovietRxiv: ru-196501.48176

This note develops a theoretical expression for the magnitude of the photoadsorption effect on semiconductor surfaces within the electronic theory of chemisorption, considering established adsorption equilibrium and photoexcitation of electrons from the valence to the conduction band. The authors de…

On the dimension of remainders in compact extensions

A. Lelek
1965 SovietRxiv: ru-196501.47902

This paper studies dimension-theoretic properties of remainders in compact extensions of metrizable spaces with countable bases. It proves that if X is compact and Y is not locally compact, then every compact extension of X × Y has a remainder of dimension at least dim X, yielding consequences for p…

On the crystal structure of $\mathrm{Bi}$-molybdate $\mathrm{Bi}_2[\mathrm{Mo

K. M. Mekhtiev, R. S. Gamidov, Kh. S. Mamedov, Academician N. V. Belov
1965 SovietRxiv: ru-196501.47754

Single crystals of Bi2[MoO4]3 obtained from oxide melts were examined by X-ray rotation photographs, goniometric sweeps, Patterson projections, and preliminary electron-density synthesis to clarify the compound’s crystal structure. The study refines the monoclinic unit-cell parameters, assigns the s…

Thionylamide of Diethylphosphoric Acid in the Diels–Alder Reaction

E. G. KATAEV, V. V. PLEMENKOV, V. V. MARKIN
1965 SovietRxiv: ru-196501.47737

This paper reports the synthesis and characterization of the thionylamide of diethylphosphoric acid by reaction of diethylphosphoric acid amide with thionyl chloride under anhydrous conditions. The authors substantiate the product assignment through elemental analysis, hydrolysis to the parent amide…

Periods of $\mathfrak{A}$-closed forms

Unknown
1965 SovietRxiv: ru-196501.47703

This paper introduces periods for forms closed with respect to a generalized differential operator on a compact real analytic Riemannian manifold. Using bilinear differential forms associated with solutions of adjoint equations, it defines period pairings with cycles and proves an isomorphism betwee…

The behaviour of styrene and phenylacetylene in a platinum catalyst

T. M. BELOSUDOVA, Academician of the Academy of Sciences of the Kazakh SSR D. V. SOKOLSKII
1965 SovietRxiv: ru-196501.47619

This study examines the liquid phase catalytic hydrogenation of styrene and phenylacetylene on platinized platinum in 0.1 N sulfuric acid, using charging curve measurements, potentiometry, electroreduction data, gas phase analysis, and kinetic observations. The experiments compare adsorption on dega…

EXPERIMENTAL TEST OF THE HYPOTHESIS

I. A. Akimov, A. N. Terenin
1965 SovietRxiv: ru-196501.47601

This study experimentally tests the proposed p-n junction mechanism of spectral sensitization in dye and semiconductor systems. The authors compare sensitization of n-type ZnO and p-type TlJ by dyes whose photoconductivity type is varied through amorphous or crystalline states, and by related brilli…

On the Nature of Radicals in the Initiation of Polymerization by Organic Peroxydicarbonates

L. M. TERMAN, D. M. YANOVSKII
1965 SovietRxiv: ru-196501.47568

This study examines which radical species initiate vinyl monomer polymerization during thermal decomposition of dialkyl peroxydicarbonates. Using measurements of carbon dioxide evolution during decomposition of dicyclohexyl peroxydicarbonate in the presence of styrene or methyl methacrylate, togethe…

CONDITIONS FOR DISCRETENESS AND CONTINUITY OF THE SPECTRUM IN THE CASE OF A SELF-ADJOINT SYSTEM OF FIRST-ORDER DIFFERENTIAL EQUATIONS

V. V. Martynov
1965 SovietRxiv: ru-196501.47254

This paper studies the spectral type of self-adjoint first-order differential systems on the real line with constant real diagonal principal matrix and continuous Hermitian potential. It derives sufficient criteria for discreteness of the spectrum using quadratic estimates and a splitting principle,…

On the Calculation of the “Stabilization” Energy of Iron-Group Ions in Oxides with the Spinel Structure

D. Z. Brainina, A. N. Men, V. S. Chudakov,
1965 SovietRxiv: ru-196501.47240

This paper examines the calculation of stabilization energies for iron group ions occupying tetrahedral and octahedral sites in spinel oxides, a quantity relevant to cation distribution in ferrites. Using a point charge crystal field treatment, the authors derive general expressions for ions with di…

FORMATION OF MOLECULAR HYDROGEN FROM A PROTON AND THE HYDRIDE-MOBILE HYDROGEN OF A C–H BOND

Z. N. Parnes, M. I. Kalinkin, D. N. Kursanov
1965 SovietRxiv: ru-196501.47180

This study examines whether molecular hydrogen can be formed from a proton and hydridically mobile hydrogen bound to carbon, using cycloheptatriene as a hydride donor. Experiments showed that trifluoroacetic acid converts cycloheptatriene to tropylium salt and polymeric products without hydrogen evo…

On the Stability of Solutions of the Cauchy Problem for Linear Differential Equations of Hyperbolic Type

Unknown
1965 SovietRxiv: ru-196501.46923

This paper studies stability of solutions to the Cauchy problem for linear hyperbolic differential equations with values in a complex Banach space and constant bounded operator coefficients. The argument reformulates the boundary-value problem as an operator equation using integral operators, repres…

ON THE CONTINUAL PRODUCT OF LEBESGUE SPACES

Unknown
1965 SovietRxiv: ru-196501.46693

This note studies when a probability measure space is isomorphic to the product of continuum many unit intervals with Lebesgue measure. It formulates conditions involving completeness with respect to null subsets, homogeneity, equality of metric and exact weights with the continuum cardinal, and a c…