Showing 50 of 25357 papers

Recombination Radiation in Lead Selenide Layers

Unknown
1965 SovietRxiv: ru-196501.46418

This paper reports measurements of recombination radiation in lead selenide layers and compares their photoluminescence and photoconductivity spectra with those of lead sulfide layers. Using infrared spectral measurements with corrected detector response, the study finds weak room-temperature lumine…

A Steroid Hydroxylation Reaction New to Actinomycetes

Leonid M. KOGAN, N. E. VOISHVILLO, G. K. SKRYABIN, I. V. TORGOV
1965 SovietRxiv: ru-196501.46385

This study reports a steroid transformation by actinomycetes, focusing on the microbiological introduction of a 17alpha hydroxyl group into pregnane steroids. Using Actinomyces spheroides LNGI-56 fermentations with progesterone and related substrates, the authors isolated or chromatographically iden…

REACTIONS OF *o*-CARBOXYBENZOYLFERROCENE

A. N. Nesmeyanov, V. D. Vil'chevskaya, N. S. Kochetkova
1965 SovietRxiv: ru-196501.46356

This study examines reactions of o-carboxybenzoylferrocene with nucleophilic and phosphorus-containing reagents, extending earlier work on its acid-promoted transformations. Treatment with phosphorus trichloride gave a chloroanhydride-like product, characterized by elemental analysis, molecular weig…

Electrode reversible to the ferricinium cation

A. A. PENDIN, M. S. ZAKHAR’EVSKII
1965 SovietRxiv: ru-196501.46299

The study addresses the difficulty of obtaining stable potentials for platinum electrodes in aqueous ferrocene suspensions, caused by the low solubility of ferrocene and interference from other redox systems. An electrode reversible to the ferricinium cation was prepared by mechanically applying a m…

FEATURES OF THE CATALYSIS OF ETHYLENE POLYMERIZATION ON THE SYSTEM $(\mathrm{C}_5\mathrm{H}_5)_2\mathrm{TiCl}_2$—$\mathrm{Et}_2\mathrm{AlCl}$ AND $(\mathrm{C}_5\mathrm{H}_5)_2\mathrm{TiCl}_2$—$\mathrm{Et}_3\mathrm{Al}$ IN AN ALKYL CHLORIDE MEDIUM

È. A. Fushman, V. I. Tsvetkova, N. M. Chirkov
1965 SovietRxiv: ru-196501.46182

The study examines ethylene polymerization catalyzed by cyclopentadienyltitanium dichloride with diethylaluminum chloride or triethylaluminum in solvents containing labile chlorine atoms. Kinetic measurements in several solvents, together with EPR, visible and infrared spectroscopy, and redox titrat…

Role of Alkali Metal Hydroxides and Carbonates in the Oxidative Dissolution of Diamond

A. P. Rudenko, I. I. Kulakova, Academician A. A. Balandin
1965 SovietRxiv: ru-196501.46151

This study examines the oxidative dissolution of Yakut diamond crystals in alkali-metal hydroxide and carbonate melts under controlled gas atmospheres near 870 to 880°C. Using a quartz microapparatus with a platinum reactor, the authors measured weight loss and surface etching after exposure to air,…

On Some Optical Properties of 4-Chloro-2-sulfobenzalacetophenone

B. M. KRASOVITSKII, D. G. PEREYASLOVA, B. A. ZADOROZHNYI,
1965 SovietRxiv: ru-196501.45828

This paper examines the moisture-dependent coloration and optical properties of 4-chloro-2-sulfobenzalacetophenone, whose free sulfonic acid becomes intensely yellow on drying while its moist form, aqueous solution, and sodium salt remain nearly colorless. The authors compare ultraviolet absorption …

Constructive Locally Convex Linear Topological Spaces

Unknown
1965 SovietRxiv: ru-196501.45804

This note formulates a constructive version of locally convex linear topological spaces, giving axioms for the underlying linear structure, neighborhoods of zero, continuity of addition and scalar multiplication, and comparison of topologies. It examines constructive analogues of closedness and sepa…

Effect of Filler on the Aging of Polydimethylsiloxane Rubber

Unknown
1965 SovietRxiv: ru-196501.45658

This study examines how fillers affect the aging of polydimethylsiloxane rubber, focusing chiefly on silica filler under oxidative heating and vacuum heating conditions. Using filled and unfilled rubber samples, the authors compare methyl group cleavage, evolution of low molecular organosilicon comp…

On the Action of Quaternary Salts of $\beta$-Chlorovinyl Derivatives of Heterocyclic Bases on Some Carbo- and Dimethine Merocyanine Dyes

Unknown
1965 SovietRxiv: ru-196501.45619

This paper investigates the reactivity of carbo- and dimethinemerocyanine dyes toward quaternary salts of beta-chlorovinyl derivatives of heterocyclic bases, proposed as highly active electrophilic reagents. The authors show that these salts react at room temperature in anhydrous chloroform, without…

On the application of the method of variation of a parameter to the construction of iterative formulae of higher accuracy for matrix inversion

D. F. DAVIDENKO
1965 SovietRxiv: ru-196501.45548

The paper develops iterative formulas for refining approximate inverse matrices by applying the method of variation of a parameter to a matrix equation involving an auxiliary parameter matrix. Starting from an approximate inverse, the approach interprets refinement as numerical integration of differ…

Degenerate pinch in $\mathrm{InSb}$

Unknown
1965 SovietRxiv: ru-196501.45502

This paper examines the pinch effect in an electron, hole plasma of indium antimonide under conditions where experimental densities and temperatures imply strong degeneracy. Using a simplified free electron, hole gas model, the analysis replaces classical plasma pressure with the pressure of a degen…

Variation regularities of certain physical and chemical properties when semiconductors of different structural groups are fused

Unknown
1965 SovietRxiv: ru-196501.45464

This paper examines changes in electrical conductivity and magnetic susceptibility during melting for semiconductor compounds with ZnS, NaCl, and anti-CaF2 type structures. Comparing series with cationic substitution, anionic substitution, and isoelectronic composition, the authors show that some co…

BLAGOVEST SENDOV

Unknown
1965 SovietRxiv: ru-196501.45430

This note studies approximation of bounded periodic functions in a Hausdorff-type metric defined through supplementary graphs, allowing treatment of functions with jumps under a modulus of nonmonotonicity. It establishes a general estimate for convolution approximants with nonnegative even kernels, …

Study of the Kinetics of Mutarotation in Aqueous Solutions of Monosaccharides

Academician of the Academy of Sciences of the Kirghiz SSR V. I. Ivanov, N. M. Chetverikov, K. D. Dzhundubaev
1965 SovietRxiv: ru-196501.45403

This paper examines the unresolved kinetics of mutarotation in aqueous monosaccharide solutions, focusing on whether two-component and three-component reaction schemes adequately describe observed polarimetric behavior. Experimental data for d-xylose, d-galactose, and l-arabinose are compared with e…

On ill-posed problems of optimal planning and stable methods for their solution

Corresponding Member of the Academy of Sciences of the USSR A. N. TIKHONOV
1965 SovietRxiv: ru-196501.45331

The paper studies ill-posedness in optimal planning problems formulated as linear programming with possibly dependent constraint equations and data known only approximately. It shows by example that arbitrarily small perturbations of coefficients and right-hand sides can produce arbitrarily large ch…

Study of Alkaloids in the Aerial Part of Vinca erecta

Sh. Z. KASYMOV, P. Kh. YULDASHEV, Corresponding Member of the Academy of Sciences of the USSR S. Yu. YUNUSOV
1965 SovietRxiv: ru-196501.45285

The paper examines the alkaloid composition of the aerial parts of Vinca erecta collected in the Tashkent region and compares changes in total alkaloid content across stages of plant development. Using ether extraction, fractionation into phenolic and nonphenolic bases, buffer separation, chromatogr…

Velocities of ultrasonic longitudinal waves in oil and gas reservoirs of Azerbaijan at high pressures

M. P. Volarovich, E. I. Bayuk, T. M. Salekhli
1965 SovietRxiv: ru-196501.45067

This study examines how high hydrostatic pressure affects ultrasonic longitudinal wave velocities in oil and gas reservoir rocks from the Caspian Lowland and Baku Archipelago of Azerbaijan, with relevance to ultrasonic logging and seismic prospecting at great depths. Using an ultrasonic pulse method…

ON THE SPECTRAL WIDTH OF THE RADIATION OF A QUANTUM GENERATOR

Yu. A. Tarasov
1965 SovietRxiv: ru-196501.45045

This paper examines the spectral width of radiation from a quantum generator, with particular application to a ruby laser. Starting from the Hamiltonian for a two-level atomic system interacting with a quantized radiation field in a resonator, the author derives equations for photon populations, pop…

QUANTUM DEPOLARIZATION OF ELECTRONS

V. N. Baier, Yu. F. Orlov
1965 SovietRxiv: ru-196501.44971

This paper analyzes quantum depolarization of high energy electrons in storage rings, complementing the known radiative polarization mechanism in a magnetic field. Using the classical spin precession equations with perturbing radial and azimuthal magnetic fields, while treating synchrotron radiation…

Synthetic Chabazites and Their Absorption Properties

S. P. Zhdanov, N. N. Buntar’-Samulevich, M. E. Ovsepyan
1965 SovietRxiv: ru-196501.44970

This study examines synthetic sodium, potassium, and sodium, potassium chabazites prepared from alkaline silica alumogels and compares their structures and adsorption behavior with natural chabazite. X-ray diffraction, chemical analysis, thermal stability observations, and adsorption isotherms for n…

On the Theory of the First Variation

Unknown
1965 SovietRxiv: ru-196501.44931

This note develops a theory of the first variation for broad variational problems, including optimal control problems, formulated through quasiconvex families of measurable vector fields. It defines quasiconvexity, gives common examples involving essentially bounded and \(L^p\) controls, and uses an…

On the Rate of Convergence to the Normal Distribution

Unknown
1965 SovietRxiv: ru-196501.44899

This note studies rates of convergence in the central limit theorem for sums of independent identically distributed random variables whose distribution lies in the domain of attraction of the normal law. It gives necessary and sufficient conditions for the uniform error in approximation by the norma…

Reduction of the Surface Tension of Solid Metals upon Adsorption of Atoms of Surface-Active Metallic Melts on Their Surface

V. I. LIKHTMAN, L. S. BRYUKHANOVA, I. A. ANDREEVA,
1965 SovietRxiv: ru-196501.44881

This study investigates the proposed adsorption mechanism by which thin films of surface-active metallic melts reduce the strength and plasticity of more refractory metals, focusing on direct measurement of surface tension changes in solid zinc. Using the zero creep method near the melting temperatu…

ON THE THEORY OF GENERALIZED ALMOST-PERIODIC SEQUENCES

I. S. Frolov
1965 SovietRxiv: ru-196501.44717

This note studies sequences that are almost periodic with respect to generalized shift operators generated by ultraspherical orthogonal polynomials. Building on earlier work of Levitan, it defines the relevant scalar product and Fourier coefficients, then proves that Parseval’s equality holds for th…

Synthesis of organosilicon polyhydric ether alcohols

Academician K. A. ANDRIANOV, L. I. MAKAROVA
1965 SovietRxiv: ru-196501.44601

This paper reports the synthesis of new organosilicon tri- and tetrahydric ether alcohols containing β-hydroxyethoxymethyl groups. The compounds were prepared by acid-catalyzed cohydrolysis of 1,1-dimethylsila-2,5-dioxacyclohexane with methyl-, ethyl-, and phenyltriethoxysilanes or tetraethoxysilane…

The Role of Cation Vacancies in Redox Processes in Ionic Crystals

I. I. Vishnevsky, B. Ya. Sukharevsky
1965 SovietRxiv: ru-196501.44500

This paper develops a thermodynamic treatment of oxidation and reduction equilibria in ionic crystals containing multivalent substituent cations and cation vacancies. By minimizing the free energy, including vacancy formation, oxidizer chemical potential, oxidation work, elastic energy, and configur…

Mechanism of Formation of Secondary Products During High-Temperature Cracking of Ethane

Corresponding Member of the USSR Academy of Sciences K. P. LAVROVSKII
1965 SovietRxiv: ru-196501.44436

High-temperature cracking of ethane was studied to clarify how secondary products, especially methane, coke, divinyl, allene, and methylacetylene, are formed. Flow experiments at 800 to 920°C and low pressure used small additions of radiocarbon-labeled acetylene, with corundum or quartz as heat carr…

Equation of Radiation Accumulation of Electron Centers in Alkali Halide Crystals

D. I. Vaisburd, I. Ya. Melik-Gaikazyan
1965 SovietRxiv: ru-196501.44378

This paper develops kinetic equations for the radiation-induced accumulation and coagulation of electron centers in alkali-halide crystals, with emphasis on F and M centers in LiF irradiated by protons. Starting from coagulation volumes for reactions between F centers and complex centers, the author…

Direct Fluorovinylation Reaction

A. Ya. Yakubovich, A. P. Sergeev, I. N. Belyaeva
1965 SovietRxiv: ru-196501.44267

This paper examines direct fluorovinylation as a preparative route to fluorovinyl derivatives, focusing on reactions of fluorinated olefins with metallic derivatives of nitrogen and silicon compounds. Lithium and potassium amides derived from secondary aliphatic and aromatic amines, as well as carba…

ON THE DECOMPOSABILITY OF ALGEBRAS OF A CERTAIN CLASS INTO A DIRECT PRODUCT OF SIMPLE ALGEBRAS

In the paper (¹) the following theorems are proved:
1965 SovietRxiv: ru-196501.44252

The paper extends decomposition criteria known for groups to a broader class of algebras, including loops, equipped with a distinguished element and operations satisfying specified compatibility conditions. It develops a notion of normal divisor as a homomorphism kernel, proves characterizations via…