Showing 50 of 25357 papers

Experimental Verification of the Applicability of Pascal's Law in Nonuniformly Heated Gases

Corresponding Member of the Academy of Sciences of the USSR B. V. DERYAGIN, Ya. I. RABINOVICH
1965 SovietRxiv: ru-196501.40158

This paper reports a direct experimental test of whether Pascal’s law remains applicable in a gas with a strong temperature gradient. The authors compare two kinetic-theory predictions for air between closely spaced horizontal plates, one based on Maxwell’s thermal-stress tensor, which implies press…

Ring Opening and Reverse Cyclization of Perhalogenated Amines under the Influence of Aluminum and Antimony Halides

S. V. SOKOLOV, S. A. MAZALOV
1965 SovietRxiv: ru-196501.40076

This paper examines the reactions of tertiary perfluorinated amines, including heterocyclic derivatives, with anhydrous aluminum chloride and selected antimony halides. The authors argue that complex formation with aluminum chloride activates fluorine atoms at alpha carbon atoms, enabling chlorine s…

On the Periodic Problem in the Calculus of Variations

Unknown
1965 SovietRxiv: ru-196501.40074

This note studies the periodic problem in the calculus of variations for positive regular reversible functionals on closed differentiable manifolds, with particular attention to nondegenerate closed extremals and their iterates. Using Morse theory, Bott’s index formula, homological arguments for spa…

RADIOLYSIS OF HEXACHLOROCYCLOPENTADIENE

N. S. RABOVSKAYA, L. M. KOGAN
1965 SovietRxiv: ru-196501.39854

This study examines the gamma radiolysis of hexachlorocyclopentadiene and compares its radiation chemical behavior with previously studied unsaturated chlorocarbons. Purified hexachlorocyclopentadiene was irradiated with cobalt-60 gamma radiation over a range of doses, and the products were separate…

Study of the Kinetics of Benzene Hydrogenation at Atmospheric and Elevated Pressures

Yu. S. SNAGOVSKII, G. D. LYUBARSKII, G. M. OSTROVSKII
1965 SovietRxiv: ru-196501.39853

This paper examines the kinetics of benzene hydrogenation over nickel based catalysts under atmospheric and elevated pressures, addressing inconsistencies in earlier reported reaction orders and activation parameters. Using flow circulation methods under isothermal conditions, the authors measured r…

Method for Determining the Degree of Gas Atomization in a Flow and the Catalytic Efficiency of Metal Surfaces in Atom Recombination Processes

A. V. ROKHLENKO, V. A. LAVRENKO
1965 SovietRxiv: ru-196501.39836

This paper develops a method for determining both the degree of atomization of a gas flow and the heterogeneous recombination coefficient of atoms on metallic surfaces. The authors formulate a diffusion and convection model for atoms in a cylindrical tube containing two absorbing probe cross section…

On the instability of a liquid surface under the sliding of detonation and shock waves over it

A. A. BORISOV, S. M. KOGARKO, A. V. LYUBIMOV
1965 SovietRxiv: ru-196501.39553

This paper examines the instability of a liquid free surface after a detonation or shock wave slides over it, a problem relevant to the safety of transporting explosive gas mixtures. Using Landau’s stability criterion for a gas flowing over a liquid surface and shadowgraph high-speed photography in …

Nonlocal Problems of the Theory of Oscillations

V. I. Smirnov
1965 SovietRxiv: ru-196501.39448

This review summarizes V. A. Pliss’s monograph on nonlocal problems in the qualitative theory of ordinary differential equations and nonlinear oscillations, with emphasis on systems with periodic time dependence and related autonomous systems. It outlines the book’s treatment of dissipative and conv…

On the Theory of Incomplete Macdonald Functions

O. S. BERLYAND, L. V. KIRICHENKO, R. M. KOGAN
1965 SovietRxiv: ru-196501.39443

The paper introduces incomplete Macdonald functions defined by splitting the standard integral representation at a finite limit, and notes their occurrence in parabolic partial differential equations for turbulent diffusion and in calculations of scintillation detector response to gamma radiation. I…

Mass-spectrometric study of photosorption processes in the oxygen–zinc oxide system

A. A. LISACHENKO, F. I. VILESSOV, Academician A. N. TERENIN
1965 SovietRxiv: ru-196501.39358

This study examines light induced oxygen adsorption and desorption on zinc oxide, a system relevant to photocatalytic oxidation and semiconductor surface processes. A quartz photosorption cell coupled to a mass spectrometer was used with oxygen enriched in O18, allowing changes in isotopic compositi…

On the Complexation of Vinyl Ethers with Phosphorus(V) Chlorides

V. S. Tsivunin, Gilm Kamai, R. Sh. Khisamutdinova
1965 SovietRxiv: ru-196501.39322

The study examines complex formation between simple vinyl ethers and chlorides of pentavalent phosphorus, comparing phosphorus pentachloride with alkyl and aryl substituted chlorophosphoranes. Through reactions in hydrocarbon solvents, hydrolytic and alcoholytic decomposition, thermal cleavage, prod…

Theory of Thermal Potential

Unknown
1965 SovietRxiv: ru-196501.38933

This paper studies smoothness properties of heat single-layer, double-layer, and volume potentials in domains bounded by time lines and moving curves. It formulates anisotropic Hölder-type classes adapted to the heat equation and gives regularity tables and norm estimates relating the smoothness of …

STUDY OF THE SYSTEMS $\mathrm{Gd_2O_3}$—$\mathrm{Al_2O_3}$ AND $\mathrm{Sm_2O_3}$—$\mathrm{Al_2O_3}$

P. P. Budnikov, V. I. Kushakovskii, V. S. Belevantsev
1965 SovietRxiv: ru-196501.38829

The study examines phase relations and compound formation in the Gd2O3-Al2O3 and Sm2O3-Al2O3 systems, motivated by evidence that rare-earth oxides can form more than the previously reported perovskite phases with alumina. Coprecipitated mixtures and oxide melts were thermally treated and analyzed by…

Quasi-geostrophic Instability of Ocean Currents

Unknown
1965 SovietRxiv: ru-196501.38695

This paper examines the quasi-geostrophic instability of oceanic geostrophic currents with partial inclusion of horizontal and vertical turbulent friction. Starting from linearized perturbation equations for a stratified current, the analysis filters internal gravity waves, assumes wave-like disturb…

A NOTE ON ORDERS WITH CYCLIC INDEX

Z. I. Borevich, D. K. Faddeev
1965 SovietRxiv: ru-196501.38595

This note studies orders in a finite separable field extension over a Dedekind ring and the module-theoretic condition under which finitely generated torsion-free modules split as direct sums of ideals. Building on a previously proved sufficiency result and on a theorem of Bass, it proves that such …

Features of the Mechanism of Liquid-Phase Oxidation of Butene in the Presence of Alkaline Additives

R. V. KUCHER, B. I. CHERNYAK
1965 SovietRxiv: ru-196501.38578

The paper examines how alkaline additives affect the liquid phase oxidation mechanism of alpha butene at 120 degrees and 60 atm, focusing on product distributions and the formation of alpha butene oxide. Using kinetic measurements and analyses of peroxides, acids, and chromatographically determined …

Some remarks on the types of $n$ -dimensional parallelehedra and on the density of latticed coverings of the space $E^n$ by equal spheres

S. S. RYSHKOV
1965 SovietRxiv: ru-196501.38534

This paper studies affine types of Voronoi decompositions associated with higher dimensional lattices and their relation to lattice coverings of Euclidean space by equal spheres. Using Selling frames and Voronoi reduction, it gives explicit parameter inequalities and simplex-chain descriptions for l…

A New Method for the Automatic Microdetermination of Carbon and Hydrogen in Organic Compounds

N. E. Gel'man, P. I. Bresler, B. N. Ruzin, N. V. Grek,
1965 SovietRxiv: ru-196501.38350

The paper describes an automated method for microdetermination of carbon and hydrogen in organic compounds, addressing limitations of instrumental approaches that require additional chemical transformations or separate determinations. Small samples are combusted in a large oxygen volume within a qua…

Statistical-Thermodynamic Consideration of Spinel-Type Solid Solutions

M. G. ZHURAVLEVA, A. N. MEN, Corresponding Member of the Academy of Sciences of the USSR G. I. CHUFAROV
1965 SovietRxiv: ru-196501.38223

This paper develops a statistical thermodynamic treatment for spinel type solid solutions in equilibrium with a phase of variable composition, extending an earlier method used for MeO solid solutions. Expressions are derived for configurational entropy, internal energy, and component activities, wit…

ON THE MATHEMATICAL THEORY OF ATOMIC SPECTRA

The classification of atomic spectra is based on the symmetry properties of the solutions of the equation
1965 SovietRxiv: ru-196501.37990

The paper studies the spectral theory of an n-particle atomic Hamiltonian with Coulomb attraction and repulsion, decomposed according to irreducible symmetry types of the permutation, rotation, and inversion groups. Using projection operators onto these symmetry subspaces, it formulates variational …

On the role of population inversion diffusion in the generation of stimulated emission

B. L. LIVSHITS, V. N. TSIKYUNOV
1965 SovietRxiv: ru-196501.37638

This paper examines how diffusion of inverse population affects induced radiation generation in a multimode plane resonator, addressing limits in earlier treatments that either assumed infinitely rapid diffusion or neglected it entirely. The authors formulate rate equations for inverse population an…

Generalized solution of the Tricomi problem

Unknown
1965 SovietRxiv: ru-196501.37583

The paper studies the Tricomi boundary value problem for a second order mixed type equation with lower order terms, after reducing the equation to a form without a first derivative in the degeneracy variable. Under specified regularity, sign, and boundary assumptions on the coefficients, the domain,…

STATIONARY STATES IN THE RADIOLYSIS OF NEUTRAL AQUEOUS SOLUTIONS OF OXYGEN

S. A. Kabakchi, V. N. Shubin, P. I. Dolin
1965 SovietRxiv: ru-196501.37454

This study examines stationary states formed during prolonged gamma radiolysis of neutral aqueous oxygen solutions, focusing on the dose-rate and oxygen-concentration dependence of hydrogen, hydrogen peroxide, and oxygen. Using cobalt-60 irradiation, gas-pressure measurements, spectrophotometric det…

Reaction of ethyldichlorophosphine with $\alpha$ , $\beta$ -unsaturated acids

{: style="text-align: right;"}
1965 SovietRxiv: ru-196501.37381

The study examines reactions of ethyl and phenyl dichlorophosphines with acrylic and methacrylic acids as a route to phosphorus-containing carboxylic acid chlorides. It proposes that addition begins with attack of the phosphorus lone pair at the beta carbon of the unsaturated acid, forming a bipolar…

BEHAVIOR OF ALKALI-METAL IMPURITIES DURING THE CRYSTALLIZATION OF CESIUM SALTS FROM THE MELT

A. N. Kirgintsev, E. G. Avvakumov, A. I. Vulikh
1965 SovietRxiv: ru-196501.37185

This study examines the behavior of alkali metal impurities, chiefly rubidium, potassium, and sodium, during directional crystallization from melts of several cesium salts. Distribution coefficients were determined from impurity concentration profiles along crystallized ingots for cesium chloride, i…

On the Theory of Interpolation

D. L. Berman
1965 SovietRxiv: ru-196501.37086

This note examines whether interpolation results known for Chebyshev nodes extend to more general quasi-uniformly distributed nodes on the interval [-1,1]. Using a node system formed by adjoining the endpoints to Chebyshev nodes, it proves that Lagrange interpolation of the function |x| diverges at …

Synthesis of optical isomers of $\beta$-aminobutyric acid

T. F. Dedenko
1965 SovietRxiv: ru-196501.37064

This paper presents a method for synthesizing both optical antipodes of beta-aminobutyric acid from crotonic acid using optically active alpha-phenylethylamine. Addition of either enantiomer of alpha-phenylethylamine gives separable diastereomeric N-phenylethyl beta-aminobutyric acids, which are iso…

Second Variations in Extremum Problems with Constraints

A. Ya. DUBOVITSKII, A. A. MILYUTIN
1965 SovietRxiv: ru-196501.36968

The paper extends a general method for constrained extremum problems from linear approximation to higher order variations in Banach spaces. It formulates admissible and forbidden cones for first and second variations, derives corresponding Euler equations through separation conditions in the adjoint…

On a New Type of Polymer Dispersions

V. I. ELISEEVA, K. M. ZURABYAN, A. L. ZAIDES
1965 SovietRxiv: ru-196501.36882

This paper examines emulsifier-free heterophase polymerization as a route to stable aqueous polymer dispersions, using methyl acrylate initiated by a persulfate based redox system. The authors argue that sulfate end groups formed during initiation can stabilize particles when the polymer degree of p…

CHEMICAL FIXATION OF MOLECULAR NITROGEN BY AQUEOUS SOLUTIONS OF TRANSITION-METAL COMPOUNDS

K. B. Yatsimirskii, V. K. Pavlova
1965 SovietRxiv: ru-196501.36797

This study examines the chemical fixation of molecular nitrogen in acidic aqueous solutions containing transition metal compounds under room temperature and atmospheric pressure. Solutions of selected group IV to VII metal compounds in hydrochloric or sulfuric acid were treated with zinc or zinc ama…

On the Trace of a Differential Operator

R. F. Shevchenko
1965 SovietRxiv: ru-196501.36678

The paper studies the regularized trace of the differential operator d n/dx n plus a smooth potential q(x) on the interval [0,1], under regular boundary conditions identical to those for the unperturbed operator and with zero mean potential. Extending earlier trace formulas known mainly for second o…

Polyhedrally closed systems of linear inequalities

S. N. CHERNIKOV
1965 SovietRxiv: ru-196501.36523

The paper studies infinite systems of linear inequalities over real linear spaces and formulates a notion of polyhedral closure for their dual cones, extending Minkowski’s finite theorem on consequences of linear inequalities. It proves that a consistent system is finitely determined, in the sense t…

Uranyl perchlorate complexes with neutral ligands

Corresponding Member of the Academy of Sciences of the USSR V. M. VDOVENKO, L. G. MASHIROV,
1965 SovietRxiv: ru-196501.36479

This paper examines coordination compounds of uranyl perchlorate with neutral ligands of differing donor strength, including pyridine, antipyrine, nitromethane, camphor, tributyl phosphate, dibutyl ether, methanol, acetonitrile, and water. Using chemical analysis and infrared vibrational spectra, th…

ON THE THEORY OF DIFFERENCE SCHEMES

A. A. Samarskii
1965 SovietRxiv: ru-196501.36407

The paper develops a general framework for difference schemes approximating abstract Cauchy problems with possibly unbounded, time-dependent operators in Banach and Hilbert spaces. Instead of placing the discrete solution in the original space, it introduces a sequence of approximating spaces with p…

ASYMPTOTICS OF SOLUTIONS OF ORDINARY LINEAR DIFFERENTIAL EQUATIONS OF THE \(n\)-TH ORDER

1. Consider the equation
1965 SovietRxiv: ru-196501.36283

The paper studies asymptotic solutions on the half-line for ordinary linear differential equations of order n with a small parameter, and for a related class of even order quasi-differential equations. Under hypotheses on coefficient limits, separation of characteristic roots, and summability of der…

Radiation Polymerization of Polyester Acrylates

E. V. EGOROV, G. V. KOROLEV, V. B. RAPOPORT
1965 SovietRxiv: ru-196501.36269

This paper examines the kinetics of radiation polymerization of polyester acrylates and compares them with known features of thermally initiated three-dimensional polymerization. Using differential thermography during irradiation with cobalt-60 gamma rays and accelerated electrons, the authors measu…

ON PERIODIC SOLUTIONS OF NONAUTONOMOUS SYSTEMS

P. G. Aizengendler, M. M. Vainberg
1965 SovietRxiv: ru-196501.36235

This paper studies Poincare’s problem on periodic solutions of nonautonomous differential systems with analytic right hand sides in the resonant case, focusing on solutions branching from a periodic solution of the generating equation. The authors reduce the existence and enumeration problem to a fi…

Effect of the Crystal Structure of the Target on the Energy Spectra of Scattered Ions

E. S. MASHKOVA, V. A. MOLCHANOV, V. S. SOSHKA
1965 SovietRxiv: ru-196501.36197

This paper examines how the crystallographic orientation of a copper target affects the energy spectra of ions scattered from its surface under irradiation by 30 keV singly charged argon ions. Using energy analysis at varied glancing and scattering angles, the authors compare spectra from a copper c…

On the Calculation of Cylindrical Shells Loaded Along Lines

Corresponding Member of the USSR Academy of Sciences É. I. Grigolyuk, V. M. Tolkachev
1965 SovietRxiv: ru-196501.36118

The paper studies an infinitely long thin elastic circular cylindrical shell subjected to loads distributed along a finite segment of a generator, with load components directed longitudinally and circumferentially. Using Green’s functions for concentrated forces and asymptotic properties of Cauchy-t…