Showing 50 of 25357 papers

AN OPTICAL CdS OSCILLATOR UNDER TWO-PHOTON EXCITATION BY A RUBY LASER

V. K. Konyukhov, L. A. Kulevskii, A. M. Prokhorov
1965 SovietRxiv: ru-196501.35978

This paper reports experimental characteristics of an optical oscillator based on CdS single crystals excited by two-photon absorption from a ruby laser. The authors examine reflection and luminescence spectra at low temperature, measure the two-photon absorption coefficient at 694 nm, and study cha…

ON THE NATURE OF THE INTERACTION OF ARYLSULFONYL CHLORIDES WITH PRIMARY ALKYLAMINES IN BENZENE SOLUTION

Unknown
1965 SovietRxiv: ru-196501.35900

The study examines the kinetics of arylsulfonyl chloride reactions with primary alkylamines in benzene, focusing on n-butylamine and 2,4-dinitrobenzenesulfonyl chloride. Rate measurements at varying concentrations and temperatures show that, unlike analogous reactions with secondary amines, the proc…

UNSTEADY WAVES OVER AN UNDERWATER RIDGE

Unknown
1965 SovietRxiv: ru-196501.35873

This paper studies, in linear approximation, how an underwater ridge affects surface waves generated by an initial disturbance in an ideal incompressible fluid. The problem is formulated through a self-adjoint positive operator for the free-surface potential, then decomposed by Fourier transformatio…

Initiation of Vinyl Chloride Polymerization by Reactions of Lower Unsaturated Chlorocarbons with Triethylaluminum

Corresponding Member of the USSR Academy of Sciences G. A. Razuvaev, Yu. A. Sangalov, K. S. Minsker,
1965 SovietRxiv: ru-196501.35852

This study examines the initiation of vinyl chloride polymerization by mixtures of triethylaluminum with lower unsaturated perchlorocarbons, in comparison with the previously observed activity of carbon tetrachloride. Polymerizations were conducted in sealed ampoules at 20°C using purified vinyl chl…

Gas Chromatographic Standardless Method for the Identification of n-Aliphatic Amines

R. V. GOLOVNYA, G. A. MIRONOV, I. P. ZHURAVLEVA
1965 SovietRxiv: ru-196501.35689

This paper proposes a gas chromatographic method for identifying primary, secondary, and tertiary normal aliphatic amines without using authentic standards. The approach uses Kovats retention indices measured on columns with nonpolar and polar liquid phases, exploiting differences in hydrogen bondin…

Promotion of a Skeletal Nickel Catalyst with Oxygen-Containing Anions of Transition Metals

A. B. Fasman, T. Kabiev,
1965 SovietRxiv: ru-196501.35501

This study examines how oxygen-containing anions of transition metals modify the activity of skeletal nickel catalysts in liquid phase hydrogenation of unsaturated compounds. Vanadate, tungstate, and molybdate salts were introduced either during alkaline leaching of a nickel aluminum alloy or direct…

On the Equilibrium Distribution of an Amino Acid in the Water–Ion Exchanger System

E. M. SAVITSKAYA, L. S. NYS, B. P. BRUNS
1965 SovietRxiv: ru-196501.35500

This paper examines the equilibrium distribution of amino acids between aqueous solution and a swollen ion exchanger, emphasizing that amino acid ionization in both phases must be included in the thermodynamic description. Using glycine, and additionally alpha-alanine and asparagine, the authors mea…

Determination of the oscillator strength of the $R_1$ line of ruby at $78^\circ$ K by the Rozhdestvenskii hook method

Unknown
1965 SovietRxiv: ru-196501.35488

This paper investigates the temperature dependence of the oscillator strength of the ruby R1 absorption line by measuring it at liquid nitrogen temperature. The authors adapt Rozhdestvenskii’s hook method to narrow polarized crystal lines using a polarization interferometer and apply it to ruby samp…

Polarity and Strength of Intermolecular Bonds in Complexes of Tin Tetrachloride with Organic Sulfides

I. P. Goldshtein, E. N. Gur’yanova,
1965 SovietRxiv: ru-196501.35456

This study examines the relationship between bond polarity and bond strength in donor acceptor complexes of tin tetrachloride with organic sulfides. Using dielectric and calorimetric titration, the authors measured dipole moments and heats of formation for complexes with aliphatic sulfides and with …

An Investigation into the Activation of Certain Analogues of Amino Acids in the Presence of the Total Fraction of pH 5 Enzymes of E. coli B

M. B. REZNIKOVA, M. A. NOVIKOVA, G. L. ZHDANOV
1965 SovietRxiv: ru-196501.35416

This study examines the enzymatic activation of fifteen amino acid analogues in the presence of the total pH 5 enzyme fraction from Escherichia coli B, using the hydroxamate assay to detect formation of aminoacyl adenylate intermediates. Four analogues, ethionine, norleucine, 3-fluorotyrosine, and b…

X-ray Study of Zirconium and Hafnium Dioxides at Temperatures up to $2750^\circ$

A. G. BOGANOV, V. S. RUDENKO, L. P. MAKAROV
1965 SovietRxiv: ru-196501.35376

This study examines the high-temperature polymorphism of pure zirconium dioxide and hafnium dioxide, focusing on whether stable cubic phases exist near their melting points. Using a specially designed high-temperature X-ray diffraction chamber with radiative and electron-beam heating in high vacuum,…

Frequency capture range of a laser oscillator

I. L. BERSHTEIN
1965 SovietRxiv: ru-196501.35140

This paper analyzes frequency locking in a continuously operating laser generator subjected to a weak external optical signal. Using a simplified phenomenological model of a traveling wave resonator with an active element described by an amplitude transfer function, it derives boundary conditions fo…

Approximation Theorem and Structural Isomorphisms

Unknown
1965 SovietRxiv: ru-196501.35137

The paper studies when a structural isomorphism, or projection, between groups is induced by an actual group isomorphism, a property that does not hold in general. It proves an approximation theorem: if a group is approximable, via a strict filter of normal subgroups, by a class of groups whose proj…

Mutual Limited Solubility of Gases in the Water–Nitrogen System

D. S. Tsiklis, V. Ya. Maslennikova
1965 SovietRxiv: ru-196501.35132

This paper reports experimental measurements of phase equilibria in the water, nitrogen system at 330 and 365°C and pressures up to 4000 atm, aimed at determining whether limited mutual solubility of gases occurs in this binary mixture. Using high-pressure sampling and compositional analysis, the au…

Semigroups of transformations of rank at most two

B. V. POPOV
1965 SovietRxiv: ru-196501.35065

The paper studies semigroups of full transformations whose elements have rank at most two and whose images collectively cover the underlying set, with at least one rank one transformation. It gives intrinsic algebraic criteria for a semigroup to be isomorphic to one in this class, using relations de…

On the influence of inertia on aerosol particle deposition from a flow at subcritical Stokes numbers

L. M. Levin, Yu. S. Sedunov
1965 SovietRxiv: ru-196501.35060

This paper examines how particle inertia modifies diffusional deposition of aerosols from a flow when the Stokes number is below the critical value for direct inertial capture. Using coupled equations for particle motion and diffusion, the authors derive analytic results for a hyperbolic flow near a…

On Nonnormal Regular Partitions of Euclidean Space

Unknown
1965 SovietRxiv: ru-196501.34944

This note addresses the role of normality in regular convex partitions of Euclidean space, particularly in relation to Delone’s finiteness theorem for stereohedra. It constructs four infinite series of regular but nonnormal partitions of three-dimensional space into congruent brick-like parallelepip…

Nature of Hydration of Exchangeable Cations in Clay Minerals

Unknown
1965 SovietRxiv: ru-196501.34921

This study examines whether exchange cations in clay minerals influence adsorbed water primarily through their own hydration or through broader changes in clay surface properties and microstructure. Monomineral clays saturated with Mg2+, Ca2+, Na+, and K+ were investigated using isothermal dehydrati…

Low-Temperature Radiation Polymerization of Acrolein

E. I. FINKEL’SHTEIN, A. D. ABKIN
1965 SovietRxiv: ru-196501.34891

This study examines the gamma radiation polymerization of acrolein at low temperatures, with attention to how the monomer state affects polymer structure. Acrolein was irradiated in bulk and in solvents at minus 78 degrees Celsius and as a solid at minus 196 degrees Celsius, and the resulting polyme…

On the Study of Conjugation in Systems with a Tetrahedral Phosphorus Atom. Phosphaazacyanines

Academician M. I. Kabachnik, V. A. Gilyarov, M. M. Yusupov
1965 SovietRxiv: ru-196501.34803

This paper examines conjugation in organophosphorus systems containing a tetrahedral phosphorus atom, focusing on positively charged phosphorus analogs of azacyanines as models for assessing whether phosphorus interrupts or transmits conjugation. The authors synthesize two nominal isomeric phosphaaz…

On the Complexity of Gate Circuits Implementing Boolean Matrices with Indeterminate Elements

E. I. NECHIPORUK
1965 SovietRxiv: ru-196501.34791

This paper studies the synthesis complexity of depth two gate circuits for Boolean matrices containing undetermined entries, motivated by control systems whose outputs need not be specified on forbidden input combinations. It formalizes completions of such matrices, proves a covering lemma for verti…

Tin arsenide – a new intermetallic semiconductor

Ya. A. Ugai, Yu. P. Zavalskii, V. A. Ugai,
1965 SovietRxiv: ru-196501.34749

This paper investigates whether tin arsenide, Sn3As2, is a semiconductor and how its electrical behavior depends on the method of preparation. The authors synthesized the compound both by direct fusion of tin and arsenic in evacuated ampoules and by chemical precipitation from alcoholic stannous chl…

Kinetics of hydrogen Oxidation on Clean Platinum Surfaces

Yu. A. BalovneV, Corresponding Member of the Academy of Sciences of the USSR S. Z. Roginskii,
1965 SovietRxiv: ru-196501.34666

The paper examines the kinetics of hydrogen oxidation on clean platinum surfaces, with comparison to palladium and silver, under conditions designed to minimize contamination and vary the excess of either hydrogen or oxygen. From pressure-time measurements and graphical differentiation, the authors …

Formal Dynamic Model of Unitary Symmetry

N. N. ACHASOV, Yu. B. RUMER, V. L. CHERNYAK,
1965 SovietRxiv: ru-196501.34535

The paper constructs a formal quantum mechanical model whose bound-state degeneracies correspond one-to-one to all irreducible representations of the unitary symmetry group SU(3). Starting from the accidental degeneracy of the Coulomb problem, the authors consider a five-dimensional Coulomb Hamilton…

Optimal Quadrature Formulas for Certain Classes of Functions

Unknown
1965 SovietRxiv: ru-196501.34346

This paper constructs optimal quadrature formulas for classes of functions on the unit interval whose even order derivative is bounded in the uniform, \(L_1\), or \(L_2\) norm. The formulas use function derivatives up to order \(r-2\), are exact for all polynomials of degree \(r-1\), and are obtaine…

Singular Operator in a Scale of Banach Spaces

Corresponding Member of the Academy of Sciences of the USSR L. V. OVSYANNIKOV
1965 SovietRxiv: ru-196501.34342

The paper introduces singular linear operators on scales of Banach spaces, defined by bounded action between smaller spaces with a norm growing at most like the inverse loss of scale parameter. Using successive approximations, it proves a local existence and uniqueness theorem for the abstract Cauch…

A Numerical Method for Solving a Convex Programming Problem in a Hilbert Space

S. I. Zukhovitskii, R. A. Polyak, M. E. Primak
1965 SovietRxiv: ru-196501.34335

The paper develops a numerical method for minimizing a convex Fréchet differentiable functional over a bounded convex feasible set in a Hilbert space defined by convex inequality constraints. The proposed feasible direction algorithm chooses each descent direction by solving a finite-dimensional qua…

Analytical Study of Relationships Between Wind and Current in the Equatorial Zone of the Ocean

N. B. Shapiro
1965 SovietRxiv: ru-196501.34330

This paper develops an analytical model for steady wind-driven currents in the equatorial ocean, assuming a homogeneous fluid, constant vertical exchange, negligible nonlinear and horizontal exchange terms, and a zonal wind stress varying with latitude. By linearizing the governing coefficients near…

Plasma Conductivities in Strong Electric and Magnetic Fields

V. P. Silin
1965 SovietRxiv: ru-196501.34307

This paper analyzes plasma conductivity in a strong homogeneous magnetic field when a strong circularly polarized high frequency electric wave propagates along the field. Using the kinetic equation for charged particles in strong fields, it derives a generalized Ohm law and evaluates the collision c…

ON DOUBLE OPERATOR STIELTJES INTEGRALS

M. Sh. Birman, M. Z. Solomyak
1965 SovietRxiv: ru-196501.34278

The paper develops a systematic theory of double operator Stieltjes integrals of the form involving two spectral resolutions, a bounded operator, and a scalar kernel, viewed as transformations on ideals of compact operators in a Hilbert space. It defines these integrals first in the Hilbert Schmidt …

Optical and Photoelectric Properties of $\mathrm{ZnSiP}_2$ Single Crystals

M. L. Belle, Yu. A. Valov, A. N. Goryunova, L. B. Zlatkin,
1965 SovietRxiv: ru-196501.34202

The paper reports optical absorption and photoconductivity measurements on n-type single crystals of ZnSiP2 grown from the gas phase by transport reactions. Using polarized light and measurements at 300 K, 77 K, and 4.2 K, the authors characterize the absorption edge, spectral photoconductivity, and…

On Some Cases of Preservation of Quasiperiodic Motions under a Small Change in the Hamiltonian Function

Unknown
1965 SovietRxiv: ru-196501.34058

This note proves a generalization of Kolmogorov’s theorem on the persistence of conditionally periodic motions under small analytic perturbations of a Hamiltonian. For Hamiltonians depending on transverse variables and action-angle variables, under specified nondegeneracy and nonresonance conditions…

Locally Equilibrium Gibbs Ensemble and Its Relation to the Theory of Fluctuations and Transport Phenomena

Unknown
1965 SovietRxiv: ru-196501.33885

This paper formulates a locally equilibrium Gibbs ensemble for nonequilibrium systems with spatially varying temperature, chemical potentials, and velocity fields. It constructs the statistical operator by maximizing informational entropy under constraints on local densities of energy, particle numb…

On the Hölder Continuity of Solutions of Singular Integral Equations of Normal Type

I. N. Vekua stated the following hypothesis.
1965 SovietRxiv: ru-196501.33814

This note proves a regularity assertion for singular integral equations of normal type in Euclidean space, addressing a hypothesis of I. N. Vekua on when solutions inherit the smoothness class of the right hand side. For singular operators of class \(C_\alpha^\infty\) acting on \(L_p(E_n)\), the pap…

On the Equations of Aerodynamics in the Presence of Binary Molecular Processes

B. V. EGOROV, V. N. ZHIGULEV, V. M. KUZNETSOV
1965 SovietRxiv: ru-196501.33748

This paper develops aerodynamic equations for gases with excited internal degrees of freedom in the presence of binary molecular processes, emphasizing cases of two-temperature relaxation far from thermodynamic equilibrium. Starting from kinetic theory, the authors separate fast and slow collision p…