Showing 50 of 25357 papers

Interaction of Oxy Forms of Oleic Acid with the Surface of Certain Minerals

V. I. Solnyshkin, S. A. Parshenkov
1964 SovietRxiv: ru-196401.35714

This study examines how oxidized forms of oleic acid interact with the surfaces of limonite, ferruginized quartz, ferrimolybdite, and molybdenum oxide sol under conditions relevant to flotation. Using infrared spectroscopy of treated mineral layers, the authors compare absorption bands produced by o…

Structure and properties of propylene oxide polymerization catalysts formed during hydrolysis of the $\mathrm{FeCl}_3$–monomer complex

Unknown
1964 SovietRxiv: ru-196401.35688

This study examines the composition, structure, and preliminary catalytic behavior of propylene oxide polymerization catalysts produced by partial hydrolysis of the ferric chloride, propylene oxide complex. Catalysts prepared under controlled anhydrous conditions and hydrolyzed with one or two equiv…

On a Theorem of S. N. Bernstein

Unknown
1964 SovietRxiv: ru-196401.35592

The paper establishes an \(L_p\) inequality for trigonometric polynomials that yields S. N. Bernstein’s theorem as a special case. Using two summation and integral representation lemmas, it derives a basic norm estimate for an operator defined by convolution with an auxiliary trigonometric polynomia…

Acylation of cyclopentadienylrhenium tricarbonyl

Academician A. N. NESMEYANOV, K. N. ANISIMOV, N. E. KOLOBOVA,
1964 SovietRxiv: ru-196401.35481

This paper reports the Friedel-Crafts acylation of cyclopentadienylrhenium tricarbonyl, extending a previously described synthesis of this organorhenium compound. Reactions with acetyl chloride and benzoyl chloride in the presence of aluminum chloride under nitrogen gave acetylcyclopentadienylrheniu…

Best extremal mappings in space

V. V. KRIVOV
1964 SovietRxiv: ru-196401.35444

The paper studies quasiconformal mappings between simply connected domains in n-dimensional space that are closest to conformal mappings in the sense of minimizing the distortion constant relative to conformal capacity. It defines “best extremal” mappings through equality in the capacity distortion …

Polymerization of Pentene-1 in the Presence of Isoprene on a Complex Catalyst

Corresponding Member of the USSR Academy of Sciences A. A. KOROTKOV, I. S. LISHANSKII, A. G. ZAK
1964 SovietRxiv: ru-196401.35374

This study examines the polymerization of isoprene, pentene-1, and their mixtures in hexane using a complex catalyst formed from titanium tetrachloride and triisobutylaluminum. Comparative experiments varied the Al:Ti ratio and measured polymer yield, intrinsic viscosity, and composition by refracti…

On Quasidiffusion Surface Waves in Polarography

S. G. Mairanovskii
1964 SovietRxiv: ru-196401.35345

This paper examines quasi-diffusion surface waves in polarography arising when a rapid chemical reaction preceding electron transfer occurs on the electrode surface with participation of adsorbed species. Using Langmuir adsorption with low surface coverage, it derives relations for the limiting kine…

Investigation of oxygen electroreduction on smooth platinum in acidic solutions by the rotating ring-disk electrode method

L. Müller, L. N. Nekrasov
1964 SovietRxiv: ru-196401.35205

This study examines the electroreduction of oxygen on smooth platinum in acid solutions using polarization measurements and a rotating ring disk electrode. The authors compare several acids to assess anion adsorption effects and analyze oxygen reduction in sulfuric acid as a two stage process involv…

On the Influence of the Structure of Porous Bodies on the Specific Surface Area Determined by the Gas Permeability Method

Unknown
1964 SovietRxiv: ru-196401.35166

The paper examines how the internal structure of porous powder compacts affects specific surface area values obtained by gas permeability methods. It analyzes the molecular and viscous components of gas flow, critiques calculations that neglect structural parameters or assume a constant permeability…

Synthesis and Investigation of the Properties of a New Class of Organoboron Compounds $\mathrm{B}_{10}\mathrm{C}_2\mathrm{H}_{12}$ (Barene) and Its Derivatives

L. I. Zakharkin, V. I. Stanko, V. A. Brattsev, Yu. A. Chapovskii,
1964 SovietRxiv: ru-196401.35160

This paper reports the synthesis and characterization of a new class of organoboron compounds, B10C2H10RR1, termed barenes, formed by reactions of decaborane or its ligand complexes with acetylenic compounds. The authors propose a two-stage mechanism involving formation of B10H12L2 complexes followe…

Study of the Thermodynamic Properties of the Ternary Metallic System Bismuth–Copper–Antimony

A. L. Lomov, A. N. Krestovnikov
1964 SovietRxiv: ru-196401.35106

Thermodynamic properties of liquid bismuth, copper, antimony alloys with a fixed bismuth to antimony atomic ratio of 1:3 were investigated as a function of copper concentration. Electromotive forces of concentration cells with copper electrodes were measured for fifteen melts over 1115 to 1215 K, an…

Decomposition of $\alpha$ -ferrocenylcarbonium ions to fulvenes

Academician A. N. Nesmeyanov, V. A. Sazonova, V. N. Drozd
1964 SovietRxiv: ru-196401.35045

This paper examines the decomposition of α-ferrocenylcarbonium ions formed from ferrocene carbinols under acidic conditions, motivated by earlier observations that positively charged substituents can weaken iron, carbon bonds in ferrocene derivatives. The authors show that carbocations generated fro…

Theoretical Model of Weather Forecasting

Corresponding Member of the Academy of Sciences of the USSR G. I. MARCHUK
1964 SovietRxiv: ru-196401.34714

This paper formulates a theoretical model for numerical weather forecasting based on the full equations of atmospheric motion rather than a quasigeostrophic adiabatic approximation. The model describes a three-dimensional baroclinic atmosphere with momentum, heat, moisture phase transitions, precipi…

On the Mechanism of Formation of Beryllium Silicate $(\mathrm{Be}_2\mathrm{SiO}_4)$

Corresponding Member of the Academy of Sciences of the USSR A. V. Novoselova, Yu. V. Orlova,
1964 SovietRxiv: ru-196401.34667

This study examines the gas phase mechanism by which phenakite, beryllium silicate, forms and is transported during synthesis from beryllium oxide and silica in the presence of sodium fluoroberyllate. Phenakite was synthesized in sealed evacuated quartz ampoules and in a stream of dry nitrogen, whil…

Unsymmetrical aromatic organozinc and organocadmium compounds of the type $\mathrm{ArMeAr}'$

Corresponding Member of the Academy of Sciences of the USSR K. A. KOCHESHKOV
1964 SovietRxiv: ru-196401.34612

This paper reports the preparation of previously unknown unsymmetrical aromatic zinc and cadmium organometallic compounds of the type ArMeAr′, where Me is zinc or cadmium. The compounds were synthesized by reactions of mixed zinc or cadmium organometallic halides with the corresponding Grignard reag…

THE SPACE OF RELATIVE TOPOLOGY\*

Unknown
1964 SovietRxiv: ru-196401.34584

The paper defines and studies the space of relative topology, obtained from a topological space by taking components of elements of a base, as a topological invariant generalizing the Mazurkiewicz and Urysohn space of relative metric. It establishes basic preservation and characterization results, i…

On the Mechanism of Radioactive Decay with Proton Emission

V. I. Gol'danskiĭ
1964 SovietRxiv: ru-196401.34543

The paper examines mechanisms of radioactive decay involving proton emission in neutron-deficient nuclei, distinguishing true proton or two-proton radioactivity from delayed proton emission following beta-plus decay. Using barrier estimates, half-lives, reaction thresholds, decay energies, and compa…

Relation between weighted norms of an entire function of finite degree on lines parallel to the real axis

Unknown
1964 SovietRxiv: ru-196401.34513

This note studies weighted norm estimates for entire functions of finite exponential type on lines parallel to the real axis, under a polynomial growth condition on the weight function. Using an auxiliary factor involving the sine kernel and Boas-type interpolation, the authors derive bounds for sym…

On Codimension $1$ Foliations on Manifolds

S. P. NOVIKOV
1964 SovietRxiv: ru-196401.34400

This paper studies smooth codimension one foliations on compact oriented manifolds, focusing on the structure of connected components defined by transverse accessibility. It classifies possible components, introduces a partially ordered invariant of a foliation, and develops tools based on closed tr…

On the Generation of Ultrafast Plasma Bunches in Railgun-Type Accelerators

L. V. Dubovoi, Yu. E. Nesterikhin
1964 SovietRxiv: ru-196401.34378

This paper reports experiments on producing high velocity plasma clots in a coaxial railgun type electrodynamic accelerator, motivated by the need for plasma injection into magnetic traps at velocities near 10^6 to 10^7 m/s. The authors use a separate plasma source to inject a highly ionized, low ma…

On the Closure of Classes of Spaces under $\omega$-Mappings

Unknown
1964 SovietRxiv: ru-196401.34288

This paper studies closures of classes of Hausdorff topological spaces under omega-mappings, defined by the ability to refine inverse images of an open cover through a continuous map into another space. It introduces the notion of a class omega-generating a space and records general closure properti…

Electron Microscopic Study of the Structure of a Copolymer of Diethyl Vinylphosphonic Acid Ester and Acrylic Acid with Complex-Forming Properties

Unknown
1964 SovietRxiv: ru-196401.34008

This study examines the pH-dependent structure of a complex-forming copolymer of the diethyl ester of vinylphosphinic acid and acrylic acid, motivated by the markedly different rates of copper ion sorption and desorption in cross-linked films of this material. Electron microscopy and electron diffra…

Free energy of mica crystals

M. S. METSIK, R. V. AFANAS’EVA
1964 SovietRxiv: ru-196401.33824

This paper examines the free energy of the (001) cleavage plane of mica crystals, addressing earlier measurement difficulties caused by surface electrification during splitting and capillary condensation in humid air. Using a dipole model of the mica structure, the authors estimate the surface free …

On automorphisms of plane groups

Unknown
1964 SovietRxiv: ru-196401.33699

This paper studies automorphisms of planar groups acting orientation preservingly on cellular decompositions of the plane with bicompact fundamental domain, a class including fundamental groups of orientable closed surfaces. It gives an algebraic description of such groups and proves that every auto…

Proton NMR spectra of ferrocene compounds and the magnetic anisotropy of ferrocene

Yu. Yu. Samitov, R. M. Aminova
1964 SovietRxiv: ru-196401.33502

This paper analyzes high-resolution proton NMR spectra of ferrocene and several ferrocene derivatives, with particular attention to the chemical shifts in ethylferrocene and their relation to ring currents and magnetic anisotropy. Experimental spectra measured in carbon disulfide solution are interp…

Sulfur-containing organic arsenic compounds. Preparation of $\beta$ -diethylaminoethyl $\mathrm{S}$ -esters of some thio acids of trivalent arsenic

Unknown
1964 SovietRxiv: ru-196401.33452

This paper reports the synthesis of previously unknown beta-diethylaminoethyl S-esters of several trivalent arsenic thio acids and their N-hydrochlorides, undertaken as part of a search for physiologically active organoarsenic compounds. The compounds were prepared by reacting beta-diethylaminoethyl…

On the behavior of solutions to boundary value problems for a quasilinear parabolic equation as $t\to\infty$

Unknown
1964 SovietRxiv: ru-196401.33451

The paper studies the large time behavior of solutions to one dimensional boundary value problems for a quasilinear parabolic equation with uniformly positive dependence on the spatial derivative term. Using comparison arguments, auxiliary monotone solutions, compactness, and passage to stationary l…

Description of Extensions of Hermitian Positive Functions

Unknown
1964 SovietRxiv: ru-196401.33283

The paper addresses the problem of describing all Hermitian positive extensions to the whole plane of a continuous Hermitian positive function initially given in a horizontal strip. It constructs spectral measures and associated canonical, or channel, positive-definite functions, proving an integral…