Showing 50 of 25456 papers

New phenyl derivatives of titanium

Corresponding Member of the Academy of Sciences of the USSR G. A. Razuvaev, V. N. Latyaeva,
1963 SovietRxiv: ru-196301.92702

This paper investigates the formation and decomposition of covalent phenyl derivatives of titanium, motivated by earlier unsuccessful attempts and by evidence for transient organotitanium species in catalytic systems. Reactions of titanium tetrachloride with diphenylmercury and phenyllithium were ex…

Activity of Alkali Metal and Ammonium Chlorides in an Aqueous Sodium Chloride Solution

A. N. KIRGINTSEV, A. V. LUK’YANOV
1963 SovietRxiv: ru-196301.92584

This paper examines the activities of lithium, potassium, rubidium, cesium, and ammonium chlorides in aqueous sodium chloride solutions under isopiestic conditions at 25 degrees Celsius. Using the McKay and Perring differential equation, the authors relate salt activities to the dependence of total …

Synthesis and Dehydration of Some Diene Germanium-Containing Carbinols

I. M. Gverdtsiteli, T. P. Guntsadze,
1963 SovietRxiv: ru-196301.92567

This study examines the addition of triethylgermane to several tertiary vinyl ethynyl carbinols in the presence of Speier’s catalyst and the subsequent dehydration of the resulting diene germanium-containing carbinols. Dimethyl, methylethyl, tetramethylene, and pentamethylene substrates were convert…

On Quasiprojective Classes of Models

Unknown
1963 SovietRxiv: ru-196301.92534

The paper studies quasiprojective classes of models, defined as abstract classes closed under ultraproducts, and develops general closure and compactness properties for such classes. It proves that membership on an ultrafilter-large set is preserved in ultraproducts, derives a finite-intersection co…

The functional space $K^m_\Lambda(\Omega)$. Some applications to the theory of boundary value problems

D. F. KALINICHENKO
1963 SovietRxiv: ru-196301.92373

The paper introduces the Hilbert space K^m_Lambda(Omega), a subspace of weighted Sobolev spaces adapted to boundary constraints expressed through boundary functionals. It proves a key inequality controlling lower order norms by weighted highest derivatives and boundary integrals, establishes complet…

Effect of electrolyte acidity on the properties of electrolytic cobalt deposits

N. A. BALASHOVA, St. RASHKOV
1963 SovietRxiv: ru-196301.92175

This study examines how the acidity of cobalt sulfate electrolytes affects the microstructure, adsorption behavior, and self-dissolution of electrolytic cobalt deposits. Cobalt was deposited at pH 1.5 to 5.1 under controlled conditions, then characterized by microphotography, dissolution in sulfuric…

On the Determination of Intermolecular Interaction Forces from the Results of a Study of Vibrational Relaxation in Oxygen

Unknown
1963 SovietRxiv: ru-196301.92174

This paper examines whether measurements of vibrational relaxation can be used to determine intermolecular repulsive forces in oxygen at energies higher than those directly accessible in many scattering experiments. Using shock tube measurements of highly purified oxygen over 1200 to 6600 K, the aut…

Magnetic Susceptibility of Group IV Semiconductor Elements According to X-ray Diffraction Analysis

Academician of the Academy of Sciences of the BSSR N. N. SIROTA, A. U. SHELEG
1963 SovietRxiv: ru-196301.92165

This paper determines the diamagnetic and paramagnetic components of the magnetic susceptibility of diamond, silicon, germanium, and gray tin from X-ray diffraction data on electron-density distributions in their sp3-bonded lattices. The authors calculate Langevin diamagnetic terms, polarizabilities…

Normal flame speed of decomposition of pure acetylene

B. A. IVANOV, S. M. KOGARKO
1963 SovietRxiv: ru-196301.92046

This study investigates the normal flame velocity of pure acetylene decomposition as a function of initial pressure at 18 to 20°C over 2.5 to 5.0 atm. Using a large receiver to minimize pressure rise, photographic recording to measure visible flame speed, and ionization probes to reconstruct the fla…

On the Relationship Between the Mechanical Properties of Sulfonated Cation-Exchanger Grains and the Establishment of Pseudo-Equilibrium States During the Sorption of Organic Ions on Them

Unknown
1963 SovietRxiv: ru-196301.91944

This study examines how the mechanical properties of KU-2 sulfonated cation-exchange resin grains influence the sorption of methylene blue ions and the formation of pseudoequilibrium states. The authors measured reversible deformation under load for resins containing 2% and 6% divinylbenzene at diff…

Activation Energy of the Chain Formation and Consumption of Alcohols in the Oxidation of n-Decane

I. P. SKIBIDA, Z. K. MAIZUS, N. M. EMANUEL
1963 SovietRxiv: ru-196301.91905

The paper examines the chain formation and chain consumption of alcohols during liquid-phase oxidation of n-decane, focusing on the activation energies of the elementary reactions involving peroxy radicals, hydroperoxides, and alcohols. Using an open-flow oxidation system, the authors compare steady…

Interaction of Two Inhibitors in the Hydrocarbon Oxidation Reaction

G. V. KARPUKHINA, Z. K. MAIZUS, Corresponding Member of the USSR Academy of Sciences N. M. EMANUEL’
1963 SovietRxiv: ru-196301.91725

This study examines the nonadditive action of amine and phenolic inhibitors during the initiated oxidation of ethylbenzene at 70°C, a model unbranched chain oxidation system. By following inhibitor concentrations spectrophotometrically and measuring rate constants for reaction with peroxy radicals b…

Corrections to the article On the Gas-Chromatographic Determination of the Solubility of Gases and Vapors in Liquids (DAN, vol. 145, no. 5, 1962)

Unknown
1963 SovietRxiv: ru-196301.91703

This biophysics paper concerns the threshold illumination on the eye pupil produced by a fixed light source and its dependence on background brightness at different retinal points. From the available translated text, the work is identifiable as an experimental or theoretical study of visual sensitiv…

Radiol from sulfuric acid

L. T. Bugaenko, Huang Guan-lin, N. A. Bakh
1963 SovietRxiv: ru-196301.91680

This study examines the radiolysis of aqueous sulfuric acid over a concentration range of 0.4 to 18 M, separating direct radiation effects on sulfuric acid from indirect effects mediated by water radiolysis products. Solutions containing ferrous ions were irradiated with x-rays and cobalt-60 gamma r…

On a Diophantine equation of the third degree

V. P. MYAKISHEV
1963 SovietRxiv: ru-196301.91428

The paper studies primitive integral solutions of a cubic Diophantine equation defined by a determinant in four variables. It gives an explicit parametrization of all such solutions by three coprime integer parameters through four cubic forms, with a common divisor factor, and relates the constructi…

Finite $p$-adic automata

================================
1963 SovietRxiv: ru-196301.91365

This note proposes a formulation of finite automata using analysis over the space of p-adic numbers, interpreting input, output, and state sequences as p-adic quantities and automaton behavior as p-adic functions. It defines p-adic logical and automaton functions, represents Mealy and Moore automata…

On the Basic Equations of the Theory of Elastic Shells

Unknown
1963 SovietRxiv: ru-196301.91246

This paper develops a method for deriving self-adjoint equilibrium equations for thin elastic shells of arbitrary configuration, addressing difficulties in extending earlier Love, Timoshenko, and Vlasov formulations to general shells with body forces. The approach starts from the three-dimensional e…

ON THE METHOD OF GROUP INTEGRALS IN SCATTERING PROBLEMS

Unknown
1963 SovietRxiv: ru-196301.91168

This paper develops a group integral approach to electromagnetic wave scattering by statistical ensembles in which both ordinary pair interactions and electrodynamic multiple scattering must be accounted for. Starting from the canonical ensemble expression for the scattered light density matrix, the…

On a Universal Bicompactum of Weight $\aleph$

Unknown
1963 SovietRxiv: ru-196301.91068

Assuming the continuum hypothesis, the paper studies the Čech remainder of the natural numbers, identified with the Boolean algebra of subsets of the integers modulo finite sets, as a universal bicompact space of weight \(\aleph\). It gives a topological characterization of this remainder as the uni…

Study of the Reduction of the $\mathrm{MnO}_4^-$ Anion at a Dropping Mercury Electrode

B. N. RYBAKOV, N. V. NIKOLAEVA-FEDOROVICH
1963 SovietRxiv: ru-196301.91041

This study examines the cathodic reduction of the singly charged permanganate anion at a dropping mercury electrode, focusing on the origin of the current minimum observed at negative surface charges. Polarization curves, drop-growth current measurements, and differential capacitance measurements we…

Study of the Reaction of Polybenzimidazole Formation

Corresponding Member of the Academy of Sciences of the USSR V. V. Korshak, T. M. Frunze, V. V. Kurashev, A. A. Izynéev
1963 SovietRxiv: ru-196301.90701

This study examines the formation of polybenzimidazoles through the polycondensation of 3,3′-diaminobenzidine with diphenyl sebacinate, with attention to reaction temperature, time, pressure, reagent imbalance, and monofunctional additives. The authors characterize the resulting polymers by solution…

On ion-acoustic oscillations excited by an electron current

Unknown
1963 SovietRxiv: ru-196301.90687

The paper analyzes the saturation of ion sound oscillations excited in a plasma by an electron current when the electron drift velocity exceeds the ion sound speed. Using nonlinear kinetic equations for the spectral function of the electric potential, it argues that a one-dimensional treatment is in…

On the Thermal Stability of Sodium Alumohydride

T. N. DYMOVA, N. G. ELISEEVA, M. S. SELIVOKHINA
1963 SovietRxiv: ru-196301.90636

This study examines the thermal stability and decomposition behavior of high purity sodium aluminum hydride, information needed for preparing alkali metal aluminum hydrides and for interpreting reactions involving them. Sodium aluminum hydride prepared by a modified Klassen method was analyzed by di…

A Certain Generalization of K. Friedrichs Space

V. M. SHALOV
1963 SovietRxiv: ru-196301.90609

This note generalizes the Friedrichs space used in variational treatments of operator equations in Hilbert space. It considers pairs of distributive operators A and B, introduces the notions of B-symmetry and B-positivity, and defines corresponding extensions in the senses of Friedrichs and Sobolev.…

On the Consistency of Available Experimental Data on the Spectrum and Asymmetry of Locally Isotropic Turbulence

Unknown
1963 SovietRxiv: ru-196301.90512

This note examines whether experimental measurements of the energy spectrum, structure constant, and skewness in locally isotropic turbulence can be reconciled across different flows and Reynolds numbers. Using Kolmogorov’s relations among the inertial-range spectral constant, second-order structure…

SOLUTION OF THE PROBLEM OF THE MOTION OF CHARGED PARTICLES OF DIFFERENT SIGNS AND MASSES IN THE FIELD OF “MAGNETIC BOTTLES” ON ELECTRONIC COMPUTING MACHINES

Unknown
1963 SovietRxiv: ru-196301.90511

This paper presents numerical calculations of the motion and diffusion of enlarged charged particles of different signs and masses in magnetic bottle fields, extending an earlier model for particles of one sign. The equations of motion include external magnetic fields and Coulomb interaction terms, …

ON THE STUDY OF THE ATMOSPHERE OF VENUS BY OPTICAL METHODS

Unknown
1963 SovietRxiv: ru-196301.90459

The paper examines how multiple scattering in the optically thick, turbid atmosphere and cloud layer of Venus affects optical observations and the interpretation of spectroscopic and photometric data. Using approximate radiative transfer relations for different absorption regimes, it argues that abs…

Measurement of the Electrostatic Field Strength Near the Surface of Geophysical Rockets

I. M. Imyanitov, G. L. Gdalevich, Ya. M. Shvarts
1963 SovietRxiv: ru-196301.90307

This paper examines measurements of electrostatic field strength at the surface of a stabilized geophysical rocket launched by the USSR Academy of Sciences on 15 November 1961. Using a modified electrostatic fluxmeter with diametrically opposed sensors, mesh generator plates, interference suppressio…

Invariant charge and Regge asymptotics

Corresponding Member of the USSR Academy of Sciences D. V. SHIRKOV
1963 SovietRxiv: ru-196301.90281

This paper examines whether Regge asymptotic behavior of elastic scattering amplitudes can be derived consistently by the renormalization group in quantum field theory. It argues that renormalization group equations should be applied to the real spectral densities in analytic representations, such a…

ON THE QUESTION OF INEQUALITIES BETWEEN NORMS OF PARTIAL DERIVATIVES OF FUNCTIONS OF SEVERAL VARIABLES

Unknown
1963 SovietRxiv: ru-196301.90012

This note studies inequalities bounding the \(L_q\) norm of a mixed partial derivative of a smooth function of several variables by a finite sum of \(L_p\) norms of other mixed derivatives on a rectangular parallelepiped. Using a geometric formulation in terms of integer multi-indices as points in E…

SOME QUESTIONS IN THE THEORY OF NAVIGATION

Unknown
1963 SovietRxiv: ru-196301.89951

This paper proposes a general methodological framework for navigation based on the theory of space, time, and gravitation. It defines navigational information as information about the relative coordinates of bodies in a four-dimensional space-time manifold, and argues that navigation signals, spaces…

Interpretation of the Spectral Composition of Light Scattered by Anisotropy Fluctuations in a Liquid

Unknown
1963 SovietRxiv: ru-196301.89815

The paper analyzes the spectral composition of depolarized Rayleigh scattering in liquids, focusing on anisotropy fluctuations not fully accounted for by earlier relaxation theories based on strain fluctuations. It derives intensity distributions for rotational Brownian diffusion of linear molecules…

Wiener–Hopf-Type Equation for Multidimensional Random Processes with Rational Spectral Density

V. F. Pisarenko
1963 SovietRxiv: ru-196301.89422

This paper studies a finite-interval Wiener-Hopf type equation arising in statistical problems for multidimensional stationary random processes whose spectral density matrix is rational and nondegenerate almost everywhere. It extends earlier one-dimensional results by reducing general rational spect…

Structure of Blood Group Substances. Hydroxylaminolysis of Blood Group Substance $\mathrm{A}$ and the General Structure of the Biopolymer

N. K. KOCHETKOV, S. G. KARA-MURZA, V. A. DEREVITSKAYA
1963 SovietRxiv: ru-196301.89407

This study examines the general structure of blood-group substance A by applying hydroxylaminolysis as a method for selective fragmentation of the biopolymer. The authors treated purified substance A with hydroxylamine, separated dialyzable and nondialyzable products by electrophoresis, chromatograp…

On the uniqueness conditions for a continuous solution of the Riemann problem for a system of three equations

Consider the hyperbolic system of three quasilinear equations
1963 SovietRxiv: ru-196301.89402

The paper studies uniqueness of continuous self-similar solutions of the Riemann problem for strictly hyperbolic systems of three quasilinear conservation laws. It reformulates the characteristic structure using Riemann invariants of the second family and constructs an explicit local example in whic…

Mechanism of Radiolytic Oxidation of Ferrous Iron in Aqueous Sulfuric Acid Solutions Containing Oxygen at High Absorbed Dose Rates

A. K. Pikaev, P. Ya. Glazunov, Academician Vikt. I. Spitsyn
1963 SovietRxiv: ru-196301.89395

The study examines why the radiolytic oxidation yield of divalent iron in oxygen-containing sulfuric acid solutions decreases at high absorbed-dose rates. Ferrous sulfate solutions of varying iron, oxygen, acid, and sodium chloride concentrations were irradiated with short high-intensity electron pu…