Showing 50 of 25456 papers

On the determination of initial pressure and wind fields from temperature distributions and vertical air motions

Unknown
1963 SovietRxiv: ru-196301.89394

This paper addresses the diagnostic determination of initial atmospheric pressure and wind fields when temperature distributions are known, a problem that otherwise remains undetermined up to an arbitrary horizontal function under quasistatic balance. Working within a quasigeostrophic framework, it …

On Some Regularities in the Complexation of Pentavalent Actinide Elements

A. I. MOSKVIN, I. GYÖLGYEANU, A. V. LAPITSKII
1963 SovietRxiv: ru-196301.89306

This paper examines regularities in complex formation by pentavalent actinides, focusing on protactinium, neptunium, and plutonium with anions of organic and inorganic acids. Using ion-exchange data and reported instability constants, the authors compare complex compositions and stabilities, showing…

Kinetics of Stationary Reactions

Unknown
1963 SovietRxiv: ru-196301.89080

This paper develops a general kinetic formulation for stationary and quasi-stationary complex reactions composed of elementary stages, including heterogeneous reactions on homogeneous surfaces. It defines reaction routes through stoichiometric numbers, relates route rates to forward and reverse rate…

On the Polymorphism of Lanthanum Oxide

Unknown
1963 SovietRxiv: ru-196301.88949

This paper examines the polymorphism of lanthanum oxide and the conditions required to obtain its low-temperature cubic form, whose existence had been uncertain in earlier studies. Lanthanum carbonate, oxalate, hydroxide, and nitrate were decomposed under high vacuum, with products characterized by …

A SHOCK WAVE OF FRACTURE IN BRITTLE MEDIA

Unknown
1963 SovietRxiv: ru-196301.88922

The paper develops a continuum-mechanical model for the formation and propagation of a fracture shock wave produced by an explosion in a brittle medium. Assuming spherical symmetry, it treats the intact material ahead of the front as a linear elastic solid, the crushed material behind it as an incom…

Determination of earthquake epicenters on an electronic computer

I. I. Pyatetskii-Shapiro, T. S. Zhelankina, V. I. Keilis-Borok,
1963 SovietRxiv: ru-196301.88846

This paper presents a digital-computer method for determining earthquake epicenters, origin times, and focal depths from P and PKP1 arrival times when no reliable initial approximation is available and some observations may contain large errors. The procedure minimizes residuals iteratively, rejects…

Elementary Reactions of Molecular Fluorine

G. A. Kapralova, L. Yu. Rusin, A. M. Chaikin, A. E. Shilov
1963 SovietRxiv: ru-196301.88525

This paper examines elementary reactions of molecular fluorine that generate atoms and radicals, focusing on additions to olefins and hydrogen abstraction from hydrogen iodide. Using low temperature surface reactions, BET surface measurements, and diffusion flame methods, the authors determine kinet…

Observed and true absorption spectra of liquid $\mathrm{CHCl}_3$ and $\mathrm{CCl}_4$ in the 740–810 cm $^{-1}$ region

N. G. BAKHSHIEV, O. P. GIRIN, V. S. LIBOV
1963 SovietRxiv: ru-196301.88415

This paper examines how observed infrared absorption spectra of liquid chloroform and carbon tetrachloride in the 740 to 810 cm−1 region differ from the corresponding true molecular absorption spectra because of internal-field effects in the condensed medium. Optical constants were determined from r…

Study of the Influence of the Structure of the Electrical Double Layer and Solution $\mathrm{pH}$ on Hydrogen Overpotential on Gallium

Unknown
1963 SovietRxiv: ru-196301.88405

This study examines how the electrical double layer and solution pH influence hydrogen overvoltage on gallium, using liquid, solid, and dropping gallium electrodes in acidic chloride and sulfate solutions. Measurements of overvoltage as a function of electrolyte concentration and pH showed changes o…

On the Nature of Surface Oxides of Platinum Formed during the Anodic Discharge of Hydrogen Peroxide

O_2 + H_2O = O_3 + 2H^+ + 2e.
1963 SovietRxiv: ru-196301.88383

This study examines the nature of higher surface oxides of platinum formed during anodic discharge of hydrogen peroxide in acidic electrolyte. Using oxygen isotope labeling with hydrogen peroxide enriched in oxygen-18 and mass-spectrometric analysis of anodically evolved oxygen, the authors tested w…

Estimates for the Petersson Inner Product with an Application to the Theory of Quaternary Quadratic Forms

O. M. FOMENKO
1963 SovietRxiv: ru-196301.88272

The paper studies theta series associated with positive definite integral quaternary quadratic forms and the decomposition of their Fourier coefficients into Eisenstein and cusp form parts. Using Petersson inner products for modular cusp forms of level q, it proves explicit bounds for the norm of th…

Mössbauer Spectra of Iron Complex Compounds with Diacetyl Thiosemicarbazone Oxime

Corresponding Member of the Academy of Sciences of the USSR V. I. GOLDANSKII, E. F. MAKAROV,
1963 SovietRxiv: ru-196301.88261

Mössbauer absorption spectra were measured for three iron(II) complexes with diacetylthiosemicarbazone oxime derivatives in order to assess how proton removal and changes in ligand bonding affect the electric field at the iron nucleus. Using a cobalt-57 in chromium source, spectra were recorded at r…

Construction of a DCB System of Tetracyclines

M. N. KOLOSOV, S. A. POPRAVKO, M. M. SHEMYAKIN
1963 SovietRxiv: ru-196301.88242

This communication addresses the synthetic construction of the labile DCB ring system of tetracyclines, a key obstacle in routes to natural tetracycline antibiotics. Starting from an acetoxyketodiol derived from juglone, the authors examine protective-group strategies, Grignard addition, hydrolysis,…

THE FIELD EMBEDDING PROBLEM

Let
1963 SovietRxiv: ru-196301.88187

The paper studies the field embedding problem for an exact sequence of groups with abelian kernel of finite period, relative to a finite normal extension containing the required roots of unity. The problem is translated into the construction of a suitable module extension and analyzed through homolo…

Interaction of Radicals of Irradiated Protein and Polymethyl Methacrylate with Oxygen and Alkylphenols

![Figure 1](page-image-figure-1)
1963 SovietRxiv: ru-196301.88085

This study examines the reactions of free radicals formed in irradiated serum albumin, with parallel experiments on irradiated polymethyl methacrylate as a comparison system. Radical decay and light emission during dissolution in selected solvents were followed by electron paramagnetic resonance and…

Fourier Series and Metric Properties of Functions

O. D. TSERETELI
1963 SovietRxiv: ru-196301.87546

This note studies whether properties of Fourier series of summable functions are invariant under metric equivalence, defined by invertible measure-preserving transformations of the interval. Using weak and uniform topologies on the transformation group, it formulates density results for rearrangemen…

Theory of Fluctuation Breakthrough of Wetting Films and Its Application to the Kinetics of Flotation Adhesion

B. V. DERYAGIN, Yu. V. GUTOP
1963 SovietRxiv: ru-196301.87346

This paper develops a theory for the fluctuational rupture of wetting liquid films as a model for the adhesion of mineral particles to gas bubbles in flotation. Treating the film as a two-dimensional layer on a plane substrate, the authors extend earlier rupture theory by incorporating slip friction…

On Some Well-Posed Problems for the Equation $y^mu_{xxx}+y_{xyy}=0$

M. S. SALAKHITDINOV
1963 SovietRxiv: ru-196301.87293

This paper studies boundary value problems for the mixed composite type equation \(y^m u_{xxx}+u_{xyy}=0\), where \(m\) is an odd positive integer, in domains divided by the line of type change and characteristic arcs. Using the representation of regular solutions as a sum of a solution of the relat…

On universal sequences of functions

A sequence of measurable functions
1963 SovietRxiv: ru-196301.87292

The paper studies universal sequences of measurable functions on an interval, meaning sequences whose subsequences can converge almost everywhere to arbitrary measurable target functions, and introduces refined types governed by prescribed lower and upper bounds. It defines classes A, B, and C in te…

Energy splitting of the terms of the hydrogen molecule

L. P. GOR'KOV, L. P. PITAEVSKII
1963 SovietRxiv: ru-196301.87227

This paper examines the asymptotic splitting between the singlet and triplet electronic terms of the hydrogen molecule at large internuclear separation. It argues that the Heitler-London approximation is inadequate in the barrier region because electron interactions there cannot be treated perturbat…

Effect of products on the rate of oxidation of isobutylene over a copper catalyst

L. P. Shapovalova, Ya. B. Gorokhovatskii, M. Ya. Rubanik
1963 SovietRxiv: ru-196301.87176

This study examines how reaction products affect the heterogeneous catalytic oxidation of isobutylene to methacrolein and carbon dioxide on a copper oxide catalyst. Using a flow circulation method with selective removal or addition of products, the authors show that methacrolein chiefly inhibits par…

On Some Extremal Properties of Polynomials

K. DOCHEV
1963 SovietRxiv: ru-196301.86961

This note proves an inequality for trigonometric polynomials of degree n evaluated at conjugate complex arguments, bounding a weighted symmetric combination by the maximum modulus on the real period and a factor involving hyperbolic functions. The proof reduces the problem to an algebraic polynomial…

On Second-Order Linear Differential Equations

A. Yu. Levin
1963 SovietRxiv: ru-196301.86856

This paper presents a collection of results on second order linear differential equations, focusing on comparison principles, oscillation and nonoscillation criteria, eigenvalue estimates, and boundedness or asymptotic behavior of solutions. It proves a comparison theorem for proper fundamental syst…

Phase diagram of the $\mathrm{Tl}_2\mathrm{Te}_3$ – $\mathrm{Bi}_2\mathrm{Te}_3$ system and properties of the resulting alloys

Unknown
1963 SovietRxiv: ru-196301.86689

The study examines phase relations and thermoelectric properties in the Tl2Te3 to Bi2Te3 system, motivated by the poor conductivity and high thermal conductivity of Tl2Te3 despite its large thermoelectric power. Alloys prepared from high purity elements were melted, annealed for extended periods, an…

Descending Thin-Layer Chromatography of Polyoxy Compounds

L. D. BERGELSON, E. V. DYATLOVITSKAYA, V. V. VORONKOVA
1963 SovietRxiv: ru-196301.86637

A descending thin-layer chromatography method on cellulose-coated plates is described for separating polyhydroxy compounds whose close mobility values limit ascending plate chromatography and paper chromatography. The authors specify the plate arrangement, adsorbent-layer geometry, solvent delivery,…

Amorphized State of Natural Graphite Powders

A. S. Fialkov, Ya. G. Davidovich, K. V. Kononova, I. M. Yurkovskii
1963 SovietRxiv: ru-196301.86585

This study examines the amorphization of natural graphite powders under prolonged vibrational grinding and the extent to which heat treatment restores three-dimensional graphite ordering. Taiginsk graphite was ground in a vibratory mill or dispersed by wear in vacuum, then analyzed by X-ray diffract…

Analytical Properties of Contributions of Feynman Diagrams

Unknown
1963 SovietRxiv: ru-196301.86442

This paper studies the analytic properties of perturbative Feynman diagram contributions to scalar meson scattering, with emphasis on identifying which points of a singularity surface are actual singularities. The argument rewrites the integral representation so that relevant coefficients in the Man…

Photolysis of $\alpha$-pyridylferrocene salts

A. N. NESMEYANOV, V. A. SAZONOVA, A. V. GERASIMENKO, N. S. SAZONOVA
1963 SovietRxiv: ru-196301.86395

This paper reports the unusually facile photolytic destruction of the ferrocene system in alpha-pyridylferrocene derivatives at room temperature. Irradiation of alpha-pyridylferrocene methiodide in alkaline solution, under nitrogen, cleaves the iron, cyclopentadienyl ring bonds to give N-methyl-2-cy…

Some transformation reactions of silicon-containing vinylacetylenic glycols

I. M. Gverdtsiteli, T. P. Doksopulo
1963 SovietRxiv: ru-196301.86265

This paper examines transformation reactions of silicon-containing vinylacetylene glycols, focusing on how a triethylsilyl substituent affects addition, hydrogenation, and silylation behavior. Experiments with Speier’s catalyst showed that triethylsilane did not add to the remaining triple bond unde…

On the Expansion in Eigenfunctions of a Non-Self-Adjoint Differential Operator with Spectral Singularities

Unknown
1963 SovietRxiv: ru-196301.86257

The paper studies expansions in eigenfunctions and associated functions for a non-self-adjoint Schrödinger type differential operator on the half-line when spectral singularities occur in the continuous spectrum. Under an exponential summability condition on the complex potential, it defines an appr…

Synthesis of 2,3-Dimercaptopropylamine and Its $\mathrm{N}$-Mono- and $\mathrm{N},\mathrm{N}'$-Dialkyl Derivatives

V. M. Fedoseev, A. G. Tarasenko, L. Mrazek, A. B. Silaev
1963 SovietRxiv: ru-196301.86118

The paper examines the synthesis of 2,3-dimercaptopropylamine and previously undescribed N-monoalkyl, N,N-dialkyl, piperidino, and morpholino derivatives, compounds of interest because vicinal dithiols show biological activity. The authors replace bromine in 2,3-dibromopropylamine hydrobromide and r…

Some Embedding Theorems in Orlicz Classes

Unknown
1963 SovietRxiv: ru-196301.86115

This paper proves embedding theorems for Sobolev spaces and Orlicz classes in the critical case where the order and integrability satisfy pl = n. It establishes that functions in the corresponding Sobolev spaces, including spaces with zero boundary values and general domains satisfying a cone condit…

On Spectral Decompositions of Symmetric Operators

Unknown
1963 SovietRxiv: ru-196301.86044

The paper studies spectral functions of closed symmetric operators in a Hilbert space and interprets the corresponding spectral expansions as expansions in generalized eigenvectors of the adjoint operator. Using Naimark’s dilation theorem and associated self-adjoint extensions, it introduces paramet…