Showing 50 of 25456 papers

Siloxane Polymers with Phenylene Units in the Main Chain

S. B. DOLGOPLOSK, A. L. KLEBANSKII, L. P. FOMINA,
1963 SovietRxiv: ru-196301.86036

This study examines siloxane polymers containing phenylene units in the main chain, motivated by the potential of aromatic units to modify heat resistance, radiation resistance, crystallinity, and elastomeric properties. High molecular weight phenylene-containing siloxane polymers were synthesized, …

Free-Radical Addition of $N$-Alkylacetamides to Methyl Acrylate

G. I. Nikishin, R. I. Mustafaev,
1963 SovietRxiv: ru-196301.85865

This study examines the tert-butyl peroxide initiated free-radical addition of several N-alkylacetamides to methyl acrylate as a route to methyl esters of gamma-N-acetylamino acids and related lactams. Experiments with N-methylacetamide, N-acetylethylamine, N-acetylbutylamine, and N-acetylpiperidine…

A Generalization of Einstein's Equations of Gravitation

Unknown
1963 SovietRxiv: ru-196301.85750

This paper proposes a generalization of Einstein’s gravitational field equations motivated by the author’s view that the standard equations do not adequately express conservation of the combined energy and momentum of matter and the gravitational field. Using a variational formulation, it replaces t…

Temperature Dependence of Deactivation of the Metastable State of Chlorophyll

A. K. CHIBISOV, A. V. KARYAKIN
1963 SovietRxiv: ru-196301.85748

This study examines the temperature dependence of radiationless deactivation of the metastable, probably triplet, state of chlorophyll in solution. Using flash photolysis on chlorophyll a and b mixtures in toluene from 20 to minus 50 degrees Celsius, and in a solid ether, isopentane, alcohol glass a…

Preparation of Graft Copolymers. Copolymers of Polytetrafluoroethylene with Methyl Methacrylate

K. K. Mozgova, T. M. Babchinitsér
1963 SovietRxiv: ru-196301.85645

This paper addresses the low adhesion of polytetrafluoroethylene by proposing a comparatively mild surface activation method for grafting vinyl monomers. Polytetrafluoroethylene films were treated in air or air with oxygen by a silent electric discharge at 50 Hz and 22 to 30 kV, then contacted with …

Ion-exchange and electrochemical properties of sulfocation exchangers in solutions of some 1-1 charged electrolytes

O. K. Stefanova, E. A. Materova, B. P. Nikol'skii
1963 SovietRxiv: ru-196301.85615

This study examines the ion-exchange and electrochemical behavior of heterogeneous sulfocationite membranes based on KU-2 and SBS-1 resins in chloride electrolyte systems containing hydrogen, sodium, potassium, and ammonium ions. Using independently measured exchange constants, ion mobility ratios, …

Diffusion from an Instantaneous Source in a Gravitational Field

Unknown
1963 SovietRxiv: ru-196301.85548

This paper analyzes diffusion from an instantaneous point source in a gas subject to a gravitational field, assuming a barometric background distribution and an exponentially height-dependent diffusion coefficient. It derives an integral solution using Bessel-function eigenfunctions and evaluates as…

Fixation of Porosity in Condensation Structures of Synthetic Polymers

G. M. Sinitsyna, I. N. Vlyudavets, P. A. Rebinder
1963 SovietRxiv: ru-196301.85462

This paper examines the fixation of porous condensation structures formed from polyvinyl alcohol during acid-catalyzed acetalization with formaldehyde, with attention to preserving vapor permeability and porosity after drying. The authors compare the behavior of freshly formed structures with sample…

Postcritical deformations of boundedly elastic shells

A. V. POGORELOV
1963 SovietRxiv: ru-196301.85336

This paper examines postcritical deformation in geometrically nonbendable elastic shells when the material has a finite elastic limit. It argues that loss of stability produces sharp edge-like singularities, and that if bending near such an edge causes plastic deformation, the local surface form bec…

On the Unique Determination of a Piecewise Regular Surface of Positive Curvature with a Boundary Condition

G. S. BARKHIN, V. T. FOMENKO
1963 SovietRxiv: ru-196301.85270

This paper studies the unique determination of a piecewise regular ovaloid of positive Gaussian curvature with boundary, allowing discontinuities of second derivatives along an internal gluing curve. The authors formulate boundary conditions on the increments of normal curvature and geodesic torsion…

Ship Waves in a Viscous Fluid

L. V. CHERKESOV
1963 SovietRxiv: ru-196301.85260

This note analyzes the three-dimensional wave pattern generated on the free surface of a viscous incompressible fluid by a system of normal stresses moving uniformly along the surface. Using the linearized hydrodynamic equations, free-surface boundary conditions, and Fourier transforms, it derives a…

On the Solution of Ill-Posed Problems and the Method of Regularization

Corresponding Member of the USSR Academy of Sciences A. N. TIKHONOV
1963 SovietRxiv: ru-196301.85113

This paper addresses ill-posed inverse problems arising in mathematical physics, focusing on Fredholm equations of the first kind and the instability of recovering an unknown function from approximate data. It formulates a regularization principle using a smoothing functional composed of a residual …

Pitting Corrosion of Iron by Perchlorate Ions

Unknown
1963 SovietRxiv: ru-196301.85091

This study examines the activation and pitting corrosion of passive iron by perchlorate ions in neutral, alkaline, and acidic solutions, addressing conflicting interpretations of perchlorate as either inhibiting or promoting metal dissolution. Armco iron electrodes were tested mainly by quasi-potent…

On reduced free multioperator groups

Unknown
1963 SovietRxiv: ru-196301.85033

The paper studies orderability for reduced free distributive multioperator groups and related algebraic structures. It gives an orderability criterion for distributive operator groups in terms of signs on finite sets of nonzero elements and semigroups generated by values of absolutely free operator …

A New Synthesis of 3-Hydroxyflavone, Flavonol

Unknown
1963 SovietRxiv: ru-196301.84683

A new route to 3-hydroxyflavone, flavonol, is described from o-benzyloxyphenyl-omega-nitrostyryl ketone via its epoxide. Treatment of the nitrostyryl ketone with alkaline hydrogen peroxide gave the corresponding nitroketone epoxide in good yield, characterized by elemental analysis and ultraviolet a…

Mechanism of moisture transfer in capillary-porous bodies

Unknown
1963 SovietRxiv: ru-196301.84498

This paper analyzes moisture transfer during evaporation in capillary porous bodies, considering both vapor diffusion and motion of liquid films along capillary walls. Using the Derjaguin and Nerpin formulation for film flow together with Stefan diffusion, the author derives expressions for the rela…

An Algorithm for Solving a Convex Programming Problem

S. I. ZUKHOVITSKII, R. A. POLYAK, M. E. PRIMAK
1963 SovietRxiv: ru-196301.84495

The paper treats a convex programming problem with a linear objective and smooth convex inequality constraints, motivated by the reduction of constrained convex Chebyshev approximation to this form. It presents two feasible direction algorithms in which each iteration determines a descent direction …

Reaction of 2,3-diaryl- and 2-aryl

=========
1963 SovietRxiv: ru-196301.84281

This study examines the reaction of 2,3-diaryl and 2-aryl-3-alkyl indones with nitrogen dioxide and compares the formation of mononitro and dinitro hydroxyhydrindone products under different solvents, temperatures, and nitration conditions. Experiments with diphenylindone, phenyl-p-tolylindone, and …

Heats of Combustion of Wheat Gliadin during Its Thermal Denaturation

V. V. Ponomarev, N. I. Sosedov, T. A. Alekseeva, Z. B. Drozdova
1963 SovietRxiv: ru-196301.84218

This study examines how thermal treatment affects the heat of combustion and solubility of wheat gliadin, comparing protein heated in isolated preparations with gliadin extracted from grain heated for one hour at specified temperatures. Calorimetric measurements showed that isolated gliadin changed …

ON SOME PROPERTIES OF ABSOLUTES

Unknown
1963 SovietRxiv: ru-196301.84116

This paper studies absolutes of Hausdorff spaces and related extremally disconnected spaces mapping irreducibly onto a given space. It gives a new construction of the absolute using auxiliary extensions and introduces a companion space that maps continuously, irreducibly, bicompactly, and canonicall…

On Order-Extendable Groups

A group is called **order-extendable** if every partial order on it can be extended to a linear one.
1963 SovietRxiv: ru-196301.84020

The paper studies groups in which every partial order extends to a linear order, focusing on order-independent subgroup conditions that preserve this property under quotients. It proves that for an order-extendable group, a quotient by a subgroup is order-extendable exactly when the subgroup is inva…

Semigroup of varieties of groups

Unknown
1963 SovietRxiv: ru-196301.83897

This paper addresses H. Neumann’s question whether the semigroup of nontrivial proper varieties of groups, with multiplication defined by extensions, is free. Using discrete and complete wreath products, the author proves embedding and identity transfer lemmas for group extensions, establishes left …

Energetics of the Complex Crystal Lattice of Silicates

R. G. Grebenshchikov, and N. A. Toropov
1963 SovietRxiv: ru-196301.83879

The paper analyzes the energetics of complex crystal lattices in alkaline-earth metal silicates, treating them as salts containing silicon-oxygen anionic radicals of different structural types. Using revised thermochemical data, Born-Haber cycles, and Kapustinskii-type lattice-energy equations with …

Effect of the Molecular Weight of Polyisobutylene on the Viscosity and Activation Heats of Its Concentrated Solutions

A. A. TAGER, V. E. DREVAL, N. G. TRAYANOVA
1963 SovietRxiv: ru-196301.83878

This study examines how molecular weight, concentration, and temperature affect the Newtonian viscosity and activation heat of viscous flow in concentrated polyisobutylene solutions in iso-octane. Measurements on seven polyisobutylene samples spanning molecular weights from about 10^3 to 2.8 million…

SOLUTION OF THE PROBLEM OF THE MOTION OF INTERACTING CHARGED PARTICLES OF ONE SIGN IN A “MAGNETIC BOTTLE” ON ELECTRONIC COMPUTERS

Unknown
1963 SovietRxiv: ru-196301.83597

The paper presents a computational formulation for studying the motion of many interacting charged particles of one sign in a magnetic bottle, using enlarged particles or azimuthally symmetric charged rings rather than a Boltzmann kinetic description. Equations of motion in cylindrical coordinates a…

On the Vlasov equation for a crystal

Unknown
1963 SovietRxiv: ru-196301.83431

This note examines the applicability of the linearized Vlasov kinetic equation with a self-consistent field to a crystal at zero temperature. Starting from an equilibrium phase density concentrated at lattice sites, the author represents small variations by particle displacements and momenta, showin…

Organic Derivatives of Kaolin

E. V. Kukharskaya, Yu. I. Skorik, N. G. Boiko
1963 SovietRxiv: ru-196301.83275

This study investigates the preparation of organic derivatives of kaolin, a layered aluminosilicate for which such derivatives had not been experimentally established. Chinese kaolin was ultrasonically disintegrated in media of diphenyl, diphenylmethane, or ethylpolysiloxane, followed by washing and…

Spirodiphosphites

E. T. MUKMENEV, GIL’M KAMAI
1963 SovietRxiv: ru-196301.83231

This paper examines bicyclic diphosphites derived from pentaerythritol and shows that transesterification of trialkyl phosphites can give different isomeric products depending on reaction conditions. Simultaneous reaction of two moles of trialkyl phosphite with pentaerythritol, or reaction of alkyl …

Study of the Oxidation of Benzene and Phenol by Pernitrous Acid and Salicylaldehyde by Fenton's Reagent

Unknown
1963 SovietRxiv: ru-196301.83101

This study examines the source of oxygen incorporated during oxidation of benzene and phenol by pernitrous acid and salicylaldehyde by Fenton’s reagent, using oxygen-18 labeled water and isotopic analysis of the products. Experiments showed that o-nitrophenol from benzene oxidation reflected incorpo…

Electrophysical Properties of Lanthanum and Cerium Sesquisulfides

G. V. SAMSONOV, V. I. MARCHENKO
1963 SovietRxiv: ru-196301.82723

This paper investigates the electrophysical properties of lanthanum and cerium sesquisulfides, compounds whose bonding and defective crystal structure suggest semiconductor behavior. Polycrystalline stoichiometric samples were prepared by sintering in hydrogen sulfide, and their electrical resistivi…

Features of the Formation of $\mathrm{Li}_3^8$ in the Interaction of 660 MeV Protons with $\mathrm{C}_6^{12}$ Nuclei

O. V. LOZHKIN, N. A. PERFILOV, Yu. P. YAKOVLEV
1963 SovietRxiv: ru-196301.82686

The paper examines the formation of fast lithium 8 fragments in the disintegration of carbon 12 nuclei by 660 MeV protons, with attention to angular distributions and energy spectra relevant to direct reaction and fragmentation mechanisms. Thin carbon containing films were irradiated in a vacuum cha…

Uniform Distribution of Points on the Sphere and Some Ergodic Properties of Solutions of Linear Ordinary Differential Equations in the Complex Domain

Unknown
1963 SovietRxiv: ru-196301.82603

This note studies ergodic phenomena in which “time” is represented by a noncommutative discrete group, motivated by solutions of linear ordinary differential equations in the complex domain. It proves that, for two rotations of the sphere, density of the semigroup orbit implies uniform distribution,…

Quasiclassical Asymptotics of the Dirac Equation

V. A. DUBROVSKII
1963 SovietRxiv: ru-196301.82598

The paper constructs quasiclassical asymptotics for the Dirac equation by relating it to a five-variable first-order wave equation whose characteristic manifolds reproduce the relativistic Hamilton-Jacobi equation. A periodicity condition in the action coordinate is introduced, leading by separation…

Kinetic Equation for an Adsorption Monolayer

Unknown
1963 SovietRxiv: ru-196301.82580

This paper derives a kinetic equation for an adsorption monolayer on a body surface interacting with a rarefied gas flow, accounting for thermal desorption, impact-induced desorption, and adsorption probabilities dependent on energy exchange with clean and covered surface regions. Using a statistica…

Structural changes in some glasses during sitallization

E. S. Sorkin, N. M. Vaysfel'd
1963 SovietRxiv: ru-196301.82573

This study examines structural changes during glass-ceramic formation in lithium aluminosilicate glasses containing titanium oxide or zirconium oxide crystallization additives. Using electron microscopy of replicas after isothermal heat treatment, the authors compare microstructural evolution with p…