Showing 50 of 25456 papers

General Equation and Electrical Analog of an Electrolytic Cell with a Spherical Stationary Microelectrode

R. Sh. NIGMATULLIN
1963 SovietRxiv: ru-196301.25961

This paper derives a general relation between an arbitrary applied electromotive force and the resulting current in an electrolytic cell with a spherical stationary microelectrode. Using diffusion kinetics, Tafel electrode behavior, double-layer capacitance, and solution resistance, it formulates th…

Investigation of organotin compounds by Mössbauer resonant absorption of $\gamma$-quanta

A. Yu. Aleksandrov, N. N. Delyagin, K. P. Mitrofanov, L. S. Polak,
1963 SovietRxiv: ru-196301.25772

This study examines the electronic environment of tin in 22 organotin compounds using Mössbauer resonance absorption of 23.8 keV gamma quanta by tin-119 nuclei. Isomeric chemical shifts and quadrupole splittings were measured at liquid nitrogen temperature and compared across tetraalkyl, carboxylate…

Integer Points in Multidimensional Ellipsoids

Unknown
1963 SovietRxiv: ru-196301.25672

The paper studies the remainder term in asymptotic formulas for weighted counts of integer points satisfying congruence conditions inside multidimensional ellipsoids defined by positive definite integral quadratic forms, with dimension greater than four. Using methods associated with Landau, Walfisz…

Increasing Property of Direct Values of Generalized Potentials for the Comparison Function and the Principal Fundamental Solution of a General Second-Order Elliptic Equation

Unknown
1963 SovietRxiv: ru-196301.25637

This paper studies regularizing properties of potentials associated with a general uniformly elliptic second-order equation in a bounded domain with sufficiently smooth boundary and coefficients. It proves that the direct value on the boundary of the double-layer potential, and the direct value of t…

Change in the Electrical Resistance of $\mathrm{PbTe}$, $\mathrm{CdTe}$, and $\mathrm{Bi}_2\mathrm{Te}_3$ at Pressures up to 200,000 kg/cm $^2$

A. A. SEMERCHAN, L. F. VERESHCHAGIN, N. N. KUZIN, L. N. DROZDOVA
1963 SovietRxiv: ru-196301.25460

This study reports room temperature measurements of the electrical resistance of PbTe, CdTe, and Bi2Te3 under pressures up to 200,000 kg/cm2. The resistance curves show characteristic anomalies: PbTe exhibits minima near 65,000 kg/cm2 and maxima near 80,000 to 85,000 kg/cm2, CdTe undergoes an abrupt…

Catalytic Waves in Molten Electrolytes

V. F. GRISHCHENKO
1963 SovietRxiv: ru-196301.25377

This paper examines early waves observed on polarization curves of pure molten chlorides of cadmium, tin, and lead at platinum electrodes before the decomposition voltage is reached. Chronopotentiometric measurements of the indicator cathode potential show that the transition time is independent of …

Geodesic Correspondence of Semi-Reducible Riemannian Spaces

G. I. Kruchkovich
1963 SovietRxiv: ru-196301.25312

This paper studies geodesic correspondences of semi-reducible Riemannian spaces with indefinite metric, extending earlier results for positive-definite Levi-Civita spaces and the class of spaces denoted V(K). Using the differential equations characterizing metrics with common geodesics, it analyzes …

Product of bases in arbitrary domains

By the product of two systems
1963 SovietRxiv: ru-196301.25185

This paper studies products of bases of analytic functions in arbitrary simply connected domains, extending earlier results that treated disks or simple unit bases. Using Faber polynomials and associated isomorphisms between disk spaces and spaces of functions analytic on domains bounded by Jordan c…

Acceleration of the Crystallization Process of Polyethylene Terephthalate Under the Influence of Mechanical Actions

A. A. FROLOVA, P. V. KOZLOV
1963 SovietRxiv: ru-196301.25126

This study examines how periodic mechanical forces affect structural changes and mechanical behavior during crystallization of polyethylene terephthalate. Amorphous quenched samples were subjected either to heat treatment or to simultaneous heat and sinusoidal compressive deformation at 80, 95, and …

Vibrational Spectra of Alkali Metal Fluoroberyllates of the Type $\mathrm{M}_2\mathrm{BeF}_4$

Corresponding Member of the USSR Academy of Sciences A. V. NOVOSELOVA
1963 SovietRxiv: ru-196301.25117

The study examines the vibrational spectra of alkali metal fluoroberyllates M2BeF4, whose crystal lattices contain BeF4 2- tetrahedral anions. Infrared absorption spectra of Li, Na, K, Rb, and Cs compounds were recorded from 300 to 1000 cm-1, and the Raman spectrum of solid K2BeF4 was obtained using…

On Some Results of X-ray Spectral Study of Cerium and Lanthanum Hydrides

E. E. Vainshtein, M. N. Bril, I. B. Staryi, M. E. Kost
1963 SovietRxiv: ru-196301.24896

This study examines the valence state and bonding character of cerium and lanthanum in rare-earth hydrides of variable composition, especially within the berthollide region from dihydride to trihydride. Cerium and lanthanum hydrides with different hydrogen contents were prepared by direct hydriding …

On the Application of a Process of Successive Approximations to the Solution of Certain Types of Functional Equations

S. V. SIMEONOV
1963 SovietRxiv: ru-196301.24854

This paper extends a process of successive approximations for solving functional equations from fixed point equations to equations of the form Ax = 0 in semi-ordered spaces. It establishes convergence and uniqueness results for monotone Fréchet differentiable operators whose derivatives are bounded …

Two-quantum photochemistry. Evidence for the participation of molecules at the second triplet level in the reaction

==================
1963 SovietRxiv: ru-196301.24827

This study examines the proposed two-quantum mechanism for radical formation during low-temperature photolysis of diphenylamine and triphenylamine in ethanol, in which alcohol radicals arise from reaction with amine molecules excited to a higher triplet state. A kinetic treatment is developed for in…

Identical transformations in four-valued logic

Unknown
1963 SovietRxiv: ru-196301.24675

This paper addresses the finite axiomatizability of identities in many-valued logics, motivated by Lyndon’s positive result for two-valued logic and negative example for seven-valued logic. It constructs a closed class of functions in four-valued logic generated by a specified binary operation and s…

An Algorithm for Solving the Problem of Convex Chebyshev Approximation

1.** Suppose that an inconsistent system of linear complex equations is given
1963 SovietRxiv: ru-196301.24393

This paper develops and refines an iterative algorithm for the convex Chebyshev approximation problem, presented mainly for inconsistent systems of linear complex equations. At each step the method selects a descent direction from the active or nearly active maximal deviations, reducing its determin…

On Some Methods for Defining Sets in Generation Bases

Unknown
1963 SovietRxiv: ru-196301.24366

This note studies variants of representability of enumerable sets in generating bases, especially when strict representation is modified by partitions of words or by algorithms translating words between alphabets. It introduces notions such as strongly decidable bases, representation relative to pri…

On the mechanism of dialkyldichlorosilane formation reactions

S. A. GOLUBTSOV, Corresponding Member of the Academy of Sciences of the USSR K. A. ANDRIANOV,
1963 SovietRxiv: ru-196301.24143

The paper examines the mechanism by which dialkyldichlorosilanes form during the direct reaction of alkyl chlorides with silicon in the presence of copper. It argues that cuprous chloride, produced by interaction of alkyl chloride with copper, reacts with silicon to generate an intermediate silicon …

ON CONDENSATIONS ONTO EUCLIDEAN SPACES

The main theorem of the present note is as follows:
1963 SovietRxiv: ru-196301.23920

This note proves conditions under which a condensation, understood as a one-to-one continuous mapping, onto Euclidean space must be a homeomorphism. The main theorem states that any condensation from a connected, locally bicompact paracompact space onto Euclidean space is a homeomorphism, with a str…

Sound Scattering by a Cylindrical Shell in a Moving Medium

L. M. LYAMSHEV
1963 SovietRxiv: ru-196301.23756

This paper analyzes scattering of a plane sound wave by a thin finite cylindrical shell mounted in a rigid cylindrical screen and immersed in a moving medium. Using Green’s functions for the convected acoustic equation and the shell vibration equations, the boundary-value problem is reduced to integ…

Phase relations in the scandium oxide–aluminum oxide system

N. A. TOROPOV, V. A. VASIL’EVA
1963 SovietRxiv: ru-196301.23698

The study constructs a phase diagram for the binary scandium oxide, aluminum oxide system, motivated by the limited prior knowledge of scandium aluminates and their relation to rare earth aluminates. Mixtures of high purity oxides were synthesized, annealed, quenched, and examined by metallographic …

On S. L. Sobolev Embedding Theorems for Abstract Functions

Unknown
1963 SovietRxiv: ru-196301.23658

The paper extends Sobolev’s embedding theory for abstract additive set functions with values in a Banach space. It introduces Lipschitz-type classes for such functions on domains and on intersections with smooth manifolds, then derives kernel estimates from an integral representation of sufficiently…

Toward a Nonlinear Theory of Aerodynamic Stability

V. V. Struminskii
1963 SovietRxiv: ru-196301.23475

This paper examines nonlinear aerodynamic stability of laminar viscous incompressible flows, focusing on channel flow and boundary-layer approximations. It applies a small-parameter method in which the first approximation is the usual linear Orr-Sommerfeld problem and higher approximations are obtai…

On Periodic Solutions of Differential-Operator Equations with a Small Parameter Multiplying the Derivative

Yu. G. Borisovich
1963 SovietRxiv: ru-196301.23393

The paper studies the existence of periodic solutions for systems of differential operator equations in Banach spaces, with a small parameter multiplying one derivative and with a known smooth periodic solution of the degenerate system. The method reduces the periodic boundary problem to nonlinear i…

EPR spectra of the products of high-temperature interaction of $\mathrm{CrO}_3$ with $\mathrm{K}_2\mathrm{Cr}_2\mathrm{O}_7$ , $\mathrm{K}_2\mathrm{Cr}\mathrm{O}_4$ , $\mathrm{K}_2\mathrm{CO}_3$ , $\mathrm{KCl}$ and $\mathrm{KOH}$

A. A. Slinkin, E. A. Fedorovskaya
1963 SovietRxiv: ru-196301.23345

This study examines solid state, high temperature reactions of chromium trioxide with potassium dichromate, chromate, carbonate, chloride, and hydroxide, motivated by their relevance to the preparation of multicomponent chromia catalysts. Electron paramagnetic resonance spectra and magnetic suscepti…

Mass Spectrometric Study of Carbohydrates. Methyl Ethers and Acetates of Glycosides

Corresponding Member of the USSR Academy of Sciences N. K. KOCHETKOV, N. S. VUL’FSON,
1963 SovietRxiv: ru-196301.23344

This study examines the use of mass spectrometry for carbohydrate analysis, focusing on methyl ethers and acetates of glycosides as more volatile derivatives. Mass spectra were recorded for methylated methyl glycosides of glucose, galactose, and mannose, as well as selected phenyl glycosides and ace…

MASS, POLARIZATION, AND VERTEX OPERATORS IN A MODIFIED FORMULATION OF THE PROBLEM OF A NONIDEAL BOSE–EINSTEIN SYSTEM

Unknown
1963 SovietRxiv: ru-196301.23255

This note develops the thermodynamic perturbation theory for a nonideal Bose-Einstein system using a previously defined principal dynamical operator as the unperturbed part. It analyzes diagrammatic decompositions with respect to single particle lines and interaction lines, introducing corresponding…

Two-Dimensional Problem of Elastic Collision of Rods

Unknown
1963 SovietRxiv: ru-196301.23162

This paper studies the two-dimensional elastic collision of flat semi-infinite rods, motivated by the reduction of cylindrical rod impact problems to this case. The analysis formulates the motion in terms of volumetric and shear strain functions, applies Sobolev’s method directly to these functions,…

Interaction of Diacetylene with Bifunctional Compounds

Corresponding Member of the USSR Academy of Sciences M. F. Shostakovskii, I. A. Chekulaeva,
1963 SovietRxiv: ru-196301.23159

This study examines the reactions of diacetylene with bifunctional compounds containing primary amino or hydroxyl groups, focusing on alkylenediamines and ethanolamine. Experiments with ethylenediamine and 1,2-propylenediamine showed vigorous exothermic addition followed by cyclization to diazacyclo…

YAN SHI

Unknown
1963 SovietRxiv: ru-196301.23059

This paper applies Bogolyubov’s canonical transformation method to the Overhauser spin density wave state of an interacting electron system in a crystal lattice. Starting from a single band Bloch electron Hamiltonian, it introduces a transformation mixing states with wave vectors k and k plus Q and …

Dual Extremal Problems

Unknown
1963 SovietRxiv: ru-196301.23052

This paper proposes a unified scheme for formulating dual extremal problems arising in linear programming, game theory, moment problems, and approximation theory. It defines primal problems through two ordered families of subsets and constructs a dual problem using real-valued functions that separat…

Boundary Properties of a Class of Mappings in Space

V. ZORICH
1963 SovietRxiv: ru-196301.23005

The paper studies boundary behavior of homeomorphisms from a Euclidean ball onto a domain that belong to a class defined through preservation of zero Mazurkiewicz-type distance between connected sets, a class including quasiconformal and conformal mappings. It introduces attainable boundary points, …

Structure of Polyverbal Operations

O. N. GOLOVIN
1963 SovietRxiv: ru-196301.22917

This paper studies the full lattice of polyverbal subgroups of a countable free product of free groups and the corresponding polyverbal operations on groups, extending earlier work focused mainly on neutral cases. It decomposes each polyverbal subgroup into verbal and neutral components, establishes…

Buckling of a shell of revolution under external pressure uniformly distributed along a parallel

A. V. POGORELOV
1963 SovietRxiv: ru-196301.22886

This paper studies the loss of stability of a shell of revolution subjected to normal pressure uniformly distributed along a parallel. The analysis approximates the buckled shape by an isometric double mirror reflection of portions of the original surface, reduces the deformation energy near the aff…

On the Rectifying Effect in Organic Semiconductors

Unknown
1963 SovietRxiv: ru-196301.22774

This paper examines charge transport and rectification in radiation-thermally modified polyethylene, including the effect of iodine treatment on conductivity type and carrier mobility. Frequency-dependent and temperature-dependent conductivity measurements are used to test a model in which barriers …

Long-wavelength infrared spectra (400–20 cm $^{-1}$) of diphenyliodonium salts

L. M. EPSTEIN, N. G. YAROSLAVSKII
1963 SovietRxiv: ru-196301.22734

This study examines whether diphenyliodonium halides have ionic or nonionic structures by measuring their long-wavelength infrared spectra from 400 to 20 cm^-1 and low-frequency Raman spectra. Spectra were obtained for diphenyliodonium tetrafluoroborate, chloride, and iodide, with attention to bands…

Synthesis of $\mathrm{S}$-Substituted Isothiuronium Derivatives by the Action of Thiourea on Ethers

Corresponding Member of the USSR Academy of Sciences R. Kh. Freidlina, B. V. Kopylova
1963 SovietRxiv: ru-196301.22533

This paper reports a reaction of certain ethers with thiourea in anhydrous formic acid to give S-substituted isothiuronium compounds, isolated as picrates. The authors propose that the process proceeds through dialkylhydroxonium formates and may follow either an SN1 or SN2 pathway depending on ether…

Birefringence of Thin Liquid Layers

Unknown
1963 SovietRxiv: ru-196301.22423

This study investigates whether thin liquid films confined between montmorillonite layers possess optical anisotropy, using polarization microscopy to measure birefringence during swelling in aqueous salt solutions and selected organic solvents. Observed birefringence of sodium montmorillonite swoll…

On the Kinetics of Waves in Plasma

G. I. SURAMISHVILI
1963 SovietRxiv: ru-196301.22421

This paper derives kinetic equations for wave interactions in a weakly turbulent collisionless plasma by expanding the plasma Lagrangian in powers of the oscillation amplitude, rather than starting from hydrodynamic equations. For an isotropic homogeneous plasma, it analyzes three-plasmon and four-p…

Chemiluminescence and the Reaction Mechanism of the Catalyzed Decomposition of Ethylbenzene Hydroperoxide

I. V. Zakharov, V. Ya. Shlyapintokh
1963 SovietRxiv: ru-196301.22254

This paper investigates the mechanism of cobalt acetate catalyzed decomposition of ethylbenzene hydroperoxide using chemiluminescence as a kinetic probe. The authors relate luminescence intensity to hydroperoxide decomposition rate and analyze its dependence on hydroperoxide concentration, catalyst …