Showing 50 of 25456 papers

The nature of the $\mathrm{H}$-bond in systems with $\pi$-electrons and its effect on proton magnetic resonance

Unknown
1963 SovietRxiv: ru-196301.22016

This paper examines hydrogen bonding in pi-electron systems and its influence on proton nuclear magnetic resonance, arguing that such bonds may form quasiaromatic six-membered rings in which pi-electron interaction is a decisive energetic contribution. Using NMR and infrared measurements in carbon t…

Behavior of Some Polynitroalkanes at a Dropping Mercury Electrode

Yu. P. Kitaev, I. M. Skrebkova
1963 SovietRxiv: ru-196301.21966

The study examines the polarographic behavior of nitroform, halotrinitromethanes, and tetranitromethane at a dropping mercury electrode in methanol, water buffer solutions over a broad pH range. Measurements of wave form, half-wave potential, limiting current, buffer capacity, salt concentration, su…

ON THE APPROXIMATION OF FUNCTIONS PRESCRIBED OUTSIDE AN INTERVAL BY ENTIRE FUNCTIONS OF FINITE DEGREE

Unknown
1963 SovietRxiv: ru-196301.21942

This note extends Jackson type approximation results of Timan, Dzyadyk, Freud, Brudnyi, and Trigub to bounded functions defined outside an interval or on separated unions of intervals. It proves the existence, for every positive degree parameter, of entire functions of finite exponential degree that…

Emulsion Polymerization with Surface-Activated Initiation

A. I. Yurzhenko, V. A. Vil’shanskii
1963 SovietRxiv: ru-196301.21795

This paper examines emulsion polymerization using surface-activated initiation as a way to combine high polymerization rates with easier isolation of the polymer product. The authors study how N-alkylpyridinium bromides and substituted derivatives activate the decomposition of cumene hydroperoxide i…

DIFFERENTIAL PROPERTIES OF THE TRAJECTORIES OF DIFFUSION PROCESSES DEPENDING ON PARAMETERS, AND THE CAUCHY PROBLEM FOR DEGENERATE PARABOLIC EQUATIONS

Unknown
1963 SovietRxiv: ru-196301.21664

This note studies one-dimensional diffusion processes depending on a numerical parameter and associated with parabolic equations whose diffusion coefficient may vanish. Under Hölder and boundedness assumptions on the coefficients and on the initial random variable, it establishes mean-square and alm…

Some Problems of Cylindrical Bending of Three-Layer Plates Considering Highly Elastic Deformation of the Fiberglass Face Sheet

Unknown
1963 SovietRxiv: ru-196301.21634

This paper develops a theory for cylindrical bending of three-layer plates with light cores and fiberglass skins, accounting for reversible high-elastic deformation in the skins in addition to ordinary elastic strain. Using assumptions for a transversely compliant core and Reissner-type facings, the…

On the Embedding of the Space of $s$-Smooth Functions of $n$ Variables into the Space of Sufficiently Smooth Functions of Fewer Variables

Unknown
1963 SovietRxiv: ru-196301.21596

The paper studies when the Banach space of continuous functions on an n-dimensional cube can be isomorphically embedded into the space of continuous functions on an m-dimensional cube, with n greater than m, so that functions with a prescribed smoothness are sent to functions with higher prescribed …

On Certain Classes of Games and Automata Games

M. L. Tsetlin
1963 SovietRxiv: ru-196301.21523

This note develops game theoretic models for collective behavior of interacting automata, emphasizing games in which each player’s payoff depends only on a small set of neighboring players. It defines and relates several classes of games, including Nash games, K-games with simultaneous maximization …

X-ray Spectroscopic Study of Some Polyferrocenes

E. E. WEINSTEIN, Yu. F. KOPELEV
1963 SovietRxiv: ru-196301.21156

This study investigates how polymerization affects electron-density distribution between iron atoms and ligands in several polyferrocenes. Iron K-edge x-ray absorption spectra were measured for five polyferrocene samples and compared with spectra of ferrocene and ferricinium, using corrected photogr…

Regge Poles and the Bethe–Salpeter Equation

Unknown
1963 SovietRxiv: ru-196301.20951

The paper examines the determination of Regge singularities from equations of Bethe-Salpeter type, motivated by difficulties in extracting Regge poles directly from perturbation theory when pole and cut contributions are mixed. It first analyzes the Schrödinger equation with Yukawa-type interactions…

DIFFERENTIABILITY OF THE NEMYTSKII OPERATOR

Unknown
1963 SovietRxiv: ru-196301.20840

This note studies differentiability at zero, and at general points, of the Nemytskii operator between Orlicz spaces under Carathéodory assumptions. It establishes necessary conditions showing that a differentiable nonlinear operator requires the domain Orlicz function to grow essentially faster than…

Preparation and Investigation of the Properties of Zeolites of Type $\mathrm{X}$ in Ammonium and Hydrogen Ion-Exchange Forms

Unknown
1963 SovietRxiv: ru-196301.20649

This study examines the preparation of ammonium and hydrogen ion-exchange forms of type X zeolite, motivated by the difficulty of obtaining hydrogen zeolites through direct acid exchange. Sodium X zeolite was treated with ammonium salts under varied anion, concentration, temperature, and repeated-ex…

On the Structure of the Ring of Finitely Supported Functions on the Group of Second-Order Unimodular Matrices over a Disconnected Locally Compact Field

I. M. Gel'fand, M. I. Graev
1963 SovietRxiv: ru-196301.20472

This paper studies the convolution ring of finite, locally constant functions on the group of unimodular two by two matrices over a totally disconnected locally compact nondiscrete field of characteristic not equal to two. Using the continuous and discrete series of representations of the group, the…

On the growth of functions harmonic in a cylinder and growing on its boundary together with the normal derivative

Unknown
1963 SovietRxiv: ru-196301.20349

This note addresses Phragmen-Lindelof type growth questions for harmonic functions in a three-dimensional half-cylinder, especially when both the function and its normal derivative may grow on the lateral boundary. Using a modification of an integral representation method, it establishes a represent…

The Use of the Effect of Deflection of Light Rays in the Gravitational Fields of Galaxies in Extragalactic Astronomy

Yu. G. Klimov
1963 SovietRxiv: ru-196301.20234

This paper examines possible applications in extragalactic astronomy of the gravitational deflection of light by galaxies, especially the observation of background “screened” galaxies whose images may appear as rings around foreground galaxies. It derives expressions for the illumination enhancement…

Migration of the methyl group in the toluene molecule under the influence of aluminum bromide and hydrogen bromide

V. A. KOPTYUG, I. S. ISAEV, Corresponding Member of the USSR Academy of Sciences N. N. VOROZHTSOV, Jr.
1963 SovietRxiv: ru-196301.20085

This study examines the mechanism of methyl-group migration in toluene under the action of aluminum bromide and hydrogen bromide, using toluene labeled with carbon-14 at a defined ring position. The authors formed the toluene, aluminum bromide, hydrogen bromide complex, decomposed it after reaction,…

Designing a torsion-free metabelian group

Unknown
1963 SovietRxiv: ru-196301.20043

This note studies projections, or structural isomorphisms, of arbitrary torsion-free metabelian groups, with particular attention to non-locally cyclic groups. Using preliminary lemmas on induced correspondences over abelian subgroups, two-generator torsion-free metabelian subgroups, and the behavio…

On the Remainder Term in Mertens' Formula

Unknown
1963 SovietRxiv: ru-196301.19939

The paper improves the remainder term in Mertens’ formula for the partial Euler product at one. It introduces an averaged Euler product and analyzes its logarithmic derivative by means of a contour integral involving the logarithmic derivative of the Riemann zeta function, followed by standard conto…

The Scattering Problem in the Quasiclassical Approximation

V. MASLOV
1963 SovietRxiv: ru-196301.19664

This paper studies the semiclassical scattering problem for the Schrödinger equation with a rapidly decreasing holomorphic potential, focusing on the asymptotics of the wave function and scattering amplitude as the Planck parameter tends to zero. The method reformulates the quantum problem in terms …

The Action of Oxygen on Oleic Acid

Corresponding Member of the USSR Academy of Sciences I. N. Plaksin, V. I. Solnyshkin,
1963 SovietRxiv: ru-196301.19598

This paper examines how oxygen acts on oleic acid, an oxyhydryl flotation reagent, in order to clarify why aeration can improve mineral recovery and separation. Oleic acid was treated with oxygen and nitrogen for different times, peroxide numbers were measured chemically, and infrared spectra were r…

Study of the hydration kinetics of Portland cement clinker minerals during hydrothermal treatment

M. M. MAYANTS
1963 SovietRxiv: ru-196301.19510

This study examines the hydration kinetics of the principal Portland cement clinker minerals during hydrothermal treatment below 100°C, a temperature range important for accelerated hardening of reinforced concrete products. Synthesized clinker minerals were hydrated at several temperatures, the deg…

On Some Features of Motion in Variable-Structure Automatic Control Systems with a Discontinuous Switching Function

S. V. EMEL’YANOV, N. E. KOSTYLEVA
1963 SovietRxiv: ru-196301.19323

The paper analyzes automatic control systems with variable structure in the case where the operator multiplying the discontinuous control term is not unity, causing the switching function itself to become discontinuous. Using generalized derivatives, the authors reformulate the system through contin…

On inversion formulas generated by a second-order boundary value problem on the half-line in the class of unbounded functions

Unknown
1963 SovietRxiv: ru-196301.19277

This paper studies Fourier-type transforms associated with a second-order boundary-value problem on the half-line for the operator defined by a complex potential satisfying an exponential decay condition and a general complex boundary parameter. Using spaces of test functions and generalized functio…

Investigation of the Reaction of Organic Mercury and Lead Compounds by Isotopic and Mass Spectrometric Methods

Unknown
1963 SovietRxiv: ru-196301.19141

This study examines the photo and thermal decomposition of diphenylmercury, tetraphenyllead, and hexaphenyldilead in benzene using deuterium labeling and low-voltage mass spectrometry. Experiments with organometallic compounds in deuterated benzene, and with deuterated organometallic compounds in or…

On Regularization of Ill-Posed Problems

A. N. TIKHONOV
1963 SovietRxiv: ru-196301.19003

This paper formulates regularization for ill-posed problems, with emphasis on Fredholm integral equations of the first kind and related inverse problems where exact solutions may fail to exist or depend discontinuously on data. It defines regularizing algorithms and constructs them through minimizat…

New Data on the Mechanism of Ethylene Polymerization with a Soluble Catalytic System – $\mathrm{Sn}(\mathrm{C}_6\mathrm{H}_5)_4+\mathrm{AlBr}_3+\mathrm{VCl}_4$

L. L. STOTSKAYA, B. A. KRENTSEL
1963 SovietRxiv: ru-196301.18997

This study examines the mechanism of ethylene polymerization in cyclohexane using the soluble catalytic system tetraphenyltin, aluminum bromide, and vanadium tetrachloride, with particular attention to the role of aluminum bromide. Polymerization experiments varying component ratios show that cataly…

Equilibrium of Complex Formation Between Palladium Chloride and Ethylene in Aqueous Solutions

I. I. MOISEEV, M. N. VARGAFTIK, Ya. K. SYRKIN
1963 SovietRxiv: ru-196301.18865

This study examines reversible complex formation between palladium chloride and ethylene in strongly acidic aqueous chloride solutions, motivated by conditions under which ethylene oxidation by palladium chloride is inhibited. Ethylene solubility was measured at constant pressure in thermostated sol…

On the convergence of the collocation method

È. B. Karpilovskaya
1963 SovietRxiv: ru-196301.18505

This note studies convergence of the collocation method for boundary value problems involving ordinary and partial integro-differential equations. Using Kantorovich’s general theory of approximate methods, it formulates solvability and convergence theorems for polynomial collocation approximations w…

Depassivating effect of halide ions on iron-based alloys

Unknown
1963 SovietRxiv: ru-196301.18451

This study examines how halide ions depassivate passive iron based alloys and promote pitting, using activation potential as the main electrochemical criterion. Anodic polarization and potential time measurements were applied to Fe Cr and Fe Cr Ni alloys in halide solutions while varying halide conc…

Effect of Ether Structure on the Solvation Effect in the Formation of Sodium Diphenyl and Sodium Naphthalene

A. I. Shatenshtein, E. S. Petrov, M. I. Belousova, K. G. Yanova,
1963 SovietRxiv: ru-196301.17979

This study examines how structural features of ether solvents affect solvation in the formation of sodium diphenyl and sodium naphthalene anion radicals. Equilibrium radical concentrations were compared in more than twenty ethers using electronic absorption and EPR measurements, and related to hydro…

Extraction of niobium pyrrolidinedithiocarbamate

I. M. Gibalo, Corresponding Member of the Academy of Sciences of the USSR, I. P. Alimarin,
1963 SovietRxiv: ru-196301.17916

This study examines ammonium pyrrolidinedithiocarbamate as an analytical reagent for niobium, focusing on conditions for quantitative precipitation and solvent extraction of the niobium complex. The reagent was synthesized and tested with niobium solutions prepared in tartaric, citric, and oxalic ac…