Showing 50 of 25456 papers

Expansion in Eigenfunctions of Ordinary Differential Operators with Irregular Separated Boundary Conditions

Unknown
1963 SovietRxiv: ru-196301.08184

The paper studies expansions in eigenfunctions and associated functions for ordinary differential operators on a finite interval with irregular split boundary conditions. It establishes asymptotic formulas for the eigenvalues, including eventual simplicity, and derives necessary conditions for unifo…

On the Structure of a Toroidal Magnetic Field Having No Magnetic Surfaces

Corresponding Member of the Academy of Sciences of the USSR I. M. GELFAND, M. I. GRAEV, N. M. ZUEVA,
1963 SovietRxiv: ru-196301.08154

This paper investigates the structure of a perturbed toroidal magnetic field in which magnetic surfaces are destroyed, extending earlier numerical studies of a resonantly perturbed three-turn helical field. By computing many field lines for several perturbation amplitudes, the authors analyze radial…

Free-Radical Polymerization of Triazine Rings

A. N. PRAVEDNIKOV, I. E. KARDASH, V. P. BAZOV, N. V. ELISEEVA, V. A. SHARPATYI, S. S. MEDVEDEV
1963 SovietRxiv: ru-196301.07972

The paper examines whether free-radical polymerization can occur in substituted triazine rings whose polymerization enthalpy estimated from bond energies is near zero, if precipitation and strong intermolecular interactions lower the free energy of the polymer. Substituted triazines and trifluoroace…

Optimal quadrature formulas

Unknown
1963 SovietRxiv: ru-196301.07675

This paper studies optimal one-dimensional quadrature formulas on an equidistant partition for Sobolev spaces of functions with square-integrable derivatives, allowing values of derivatives up to a prescribed order at the mesh points. It formulates the quadrature error as a variational problem, iden…

Cruciform Wing of Finite Span in Compressible Flow

Unknown
1963 SovietRxiv: ru-196301.07633

This paper analyzes the linearized problem of a thin cruciform wing of finite span undergoing arbitrary harmonic oscillations in a supersonic compressible flow. Using Hadamard’s method and symmetry with fictitious reflected panels, it derives a basic integral formula for the reduced disturbance pote…

Extremal Algebra of Matrices

Unknown
1963 SovietRxiv: ru-196301.07336

This note develops an algebra of positive matrices in which ordinary addition and multiplication are replaced by elementwise maximization or minimization and by corresponding max-product or min-product matrix multiplication. It records the basic algebraic laws of these operations, including distribu…

Maximum Vacancy Concentrations and Saturated Vapor Pressures of Simple Substances at the Melting Point

B. F. Ormont
1963 SovietRxiv: ru-196301.07234

This paper examines the expected maximum concentration of Schottky vacancies in simple substances near the melting point and its relation to atomization energy and saturated vapor pressure. Using thermodynamic estimates, literature data, and a model in which vacancy formation energy is proportional …

Melting diagram of the $\mathrm{Cl}_2\mathrm{O}_7$ – $\mathrm{SO}_3$ – $\mathrm{H}_2\mathrm{O}$ system in the region of high concentrations of perchloric and sulfuric acids

Anhydrous perchloric acid exists under ordinary conditions only in the form of the equilibrium
1963 SovietRxiv: ru-196301.07100

The study examines the melting diagram of the ternary system Cl2O7, SO3, and H2O in the high-acid region near the composition of perchloric acid, with the aim of assessing whether anhydrous perchloric acid can appear as an individual crystallizing phase in the presence of dehydrating sulfur trioxide…

On the phase diagram of $\mathrm{Ni}$ – $\mathrm{C}$

A. A. VERTMAN, A. M. SAMARIN, E. S. FILIPPOV
1963 SovietRxiv: ru-196301.07012

This paper reexamines the nickel-rich region of the Ni-C phase diagram after viscosity and electrical-conductivity measurements of liquid alloys suggested inconsistencies with the accepted diagram. Alloys prepared from electrolytic nickel and high-purity graphite were studied by contactless electric…

On Infinite Frobenius Groups

Yu. M. GORCHAKOV
1963 SovietRxiv: ru-196301.06998

This note studies when Frobenius’ theorem on complements to isolated subgroups extends from finite groups to infinite groups. It gives sufficient conditions: if an infinite group has a suitably complete locally nilpotent normal subgroup with locally finite quotient, then every isolated subgroup has …

Dependence of Some Physical Properties on the Composition of Polymerization Products in a Ternary System of Vinyl Monomers

Unknown
1963 SovietRxiv: ru-196301.06891

This study examines how composition affects the thermomechanical, mechanical, and optical properties of polymers and copolymers formed from methyl methacrylate, styrene, and benzyl methacrylate for potential use in photoelastic materials. Samples synthesized by induced polymerization were characteri…

Polymerization of Butadiene in the Presence of Alkali Metals and Their Compounds in Various Media

R. V. BASOVA, A. A. AREST-YAKUBOVICH, D. A. SOLOVYKH, N. V. DESYATOVA, A. R. GANTMAKHER, S. S. MEDVEDEV
1963 SovietRxiv: ru-196301.06763

This study examines how alkali metals, organoalkali compounds, solvent polarity, additives, and temperature affect the microstructure of polybutadiene formed by butadiene polymerization. Using vacuum polymerization and infrared analysis of 1,2, 1,4-cis, and 1,4-trans units, the authors compare lithi…

On the embedding of crossed products into division rings

Unknown
1963 SovietRxiv: ru-196301.06716

This note studies when crossed products of groups with a division ring can be embedded in division rings, extending the Mal’cev-Neumann embedding theorem and a result of Ikeda on crossed products of certain groups. It proves auxiliary results on automorphisms of quotient division rings for invariant…

On Rings with Injective Cyclic Modules

L. A. SKORNYAKOV
1963 SovietRxiv: ru-196301.06551

This note proves that if every left cyclic module over an associative ring with identity is injective, then the ring is semisimple in the classical sense. The argument uses homological algebra and the theory of regular and left continuous rings, developing a sequence of lemmas on cyclic submodules, …

Synthesis of an Analog of Demethyltetracycline

I. G. Bolesov, M. N. Kolosov, M. M. Shemyakin
1963 SovietRxiv: ru-196301.06465

This paper reports the synthesis of a hydronaphthacene oxytriketone structurally related to the antibiotic demethyltetracycline, as part of studies on tetracycline synthesis and structure activity relationships. The route proceeds from trans-benzoylacrylic acid and butadiene through cyclohexane and …

Plastic Deformations in a Gravitating Sphere

R. G. ARKHIPOV, L. F. VERESHCHAGIN
1963 SovietRxiv: ru-196301.06426

This paper examines plastic deformation as a possible cause of sharp internal boundaries in a self-gravitating planetary body, in addition to chemical or phase discontinuities. Starting from the classical stress distribution in a stationary elastic sphere of constant density, the authors compare inc…

On the Stability of Shaft Motion

Yu. V. OSETINSKII
1963 SovietRxiv: ru-196301.06422

The paper examines the stability of uniform rotation of a vertical elastic, weightless shaft carrying a centrally mounted thin disk whose transverse principal moments of inertia are slightly unequal. Linearized equations for small translational and angular perturbations are derived using momentum an…

DEPENDENCE OF THE NUCLEAR RELAXATION RATE ON THE SYMMETRY OF THE $\mathrm{Ti}^{3+}$ COMPLEX IN AQUEOUS SOLUTIONS

Unknown
1963 SovietRxiv: ru-196301.06421

The study examines how the symmetry and ligand composition of Ti3+ aquo and fluoro complexes in aqueous solution affect proton nuclear relaxation rates. Using spin echo nuclear magnetic resonance measurements and room temperature electron paramagnetic resonance, the authors measured longitudinal and…

Study of the cationic activity of the components of the “cobalt” system and the nature of the end groups of the polymer chain

E. I. Tinyakova, Corresponding Member of the USSR Academy of Sciences B. A. Dolgoplosk,
1963 SovietRxiv: ru-196301.06404

This study examines the cationic activity of components of the cobalt catalytic system used for stereospecific butadiene polymerization and investigates the end groups of the resulting polybutadiene chains. Using vinyl butyl ether polymerization, the authors show that cobalt chloride, including its …

Kinetic and catalytic currents at a hanging drop electrode

V. G. LEVICH, Z. Ch. GRABOVSKY, V. Yu. FILINOVSKY
1963 SovietRxiv: ru-196301.06389

This paper develops a theoretical treatment of kinetic and catalytic currents at a stationary hanging drop electrode, emphasizing how spherical electrode curvature modifies results known for plane electrodes. The authors formulate diffusion and bulk reaction equations for reversible chemical transfo…

Mechanism of Anodic Activation of Iron

B. N. KABANOV, V. D. KASHCHEEV
1963 SovietRxiv: ru-196301.06199

This paper examines the mechanism of anodic activation and dissolution of passive iron in acidic perchlorate media, with comparison to sulfuric and hydrochloric acid solutions. Using potentiostatic and chronoamperometric observations together with colorimetric determination of dissolved iron valence…

On a finite difference method for solving the one-phase Stefan problem for a quasilinear equation

F. P. VASIL’EV
1963 SovietRxiv: ru-196301.06139

This paper studies a one-phase Stefan problem for a quasilinear heat equation describing heating and melting of a rod with removal of molten material under prescribed boundary heat fluxes. It formulates an implicit finite-difference scheme in which the moving boundary advances by one spatial mesh in…

On Bases in Spaces of Continuous Functions

V. I. GURARII
1963 SovietRxiv: ru-196301.05896

This paper studies bases in Banach spaces of continuous functions using Grinblum’s index, which measures the inclination between initial and subsequent spans of a sequence. It proves that certain differentiable, in particular analytic, systems in the real space of continuous functions on an interval…

Structural and Mechanical Criteria for Assessing the Coagulating Effect of Electrolytes on Aqueous Montmorillonite Dispersions

Unknown
1963 SovietRxiv: ru-196301.05867

This paper examines the coagulating action of electrolytes on aqueous montmorillonite dispersions using structural and mechanical criteria rather than primarily electrokinetic measures. Fifteen percent suspensions of Gorb bentonite, identified mainly as montmorillonite with a kaolinite-like admixtur…

On the system of Prandtl equations in boundary layer theory

In this paper we study the system of boundary-layer equations for an incompressible fluid
1963 SovietRxiv: ru-196301.05849

The paper studies the Prandtl boundary-layer equations for an incompressible fluid in a half-strip with prescribed initial velocity, wall suction or injection, and matching to an outer flow satisfying Bernoulli’s law. Using the von Mises transformation, the system is reduced to a degenerate paraboli…

Study of the $\mathrm{BeF}_2$ – $\mathrm{ZrF}_4$ system

Yu. M. KORENEV, A. V. NOVOSELOVA
1963 SovietRxiv: ru-196301.05821

The paper investigates the previously undescribed binary BeF2, ZrF4 system as part of a broader study of fluoride phase relations. Alloys prepared from ammonium double fluorides were examined by thermal analysis and X-ray phase analysis, with precautions against zirconium fluoride sublimation and wi…

Sulfonation of Phosphorus Ylides. Sulfobetaines

Nik. A. NESMEYANOV, S. T. ZHUZHLIKOVA, Corresponding Member of the Academy of Sciences of the USSR
1963 SovietRxiv: ru-196301.05708

This paper reports electrophilic sulfonation of phosphorus ylides with sulfur trioxide, preferably as the dioxane sulfur trioxide complex in dichloroethane, to form crystalline phosphonium sulfobetaines. Several ylides, including diphenylmethylene, carbomethoxymethylene, benzoylmethylene, and acetyl…

On the Theory of Compensating Fields

Unknown
1963 SovietRxiv: ru-196301.05694

This paper examines tensor quantities, Ricci rotation coefficients, and connection coefficients in orthonormal frames under local Lorentz transformations using the method of compensating fields. It derives the finite and infinitesimal transformation behavior of the Ricci coefficients and shows that …

Long-Wavelength Excitation of Banded Edge Luminescence in $\mathrm{GaP}$ Crystals

Corresponding Member of the USSR Academy of Sciences E. F. GROSS, D. S. NEDZVETSKII
1963 SovietRxiv: ru-196301.05653

This paper examines long-wavelength excitation of banded edge luminescence in GaP crystals at low temperature, extending earlier observations that red light can induce green edge emission. Spectroscopic comparisons of excitation by blue and red light show that red excitation selectively enhances lon…

On the Solvability of the First Boundary Value Problem for Quasilinear Equations with Rapidly Growing Coefficients in Orlicz Classes

Unknown
1963 SovietRxiv: ru-196301.05580

The paper studies the first boundary-value problem for elliptic quasilinear equations and systems of order 2m whose principal coefficients may grow faster than any power in the highest derivatives. It formulates structural, monotonicity, and subordination conditions under which solutions are sought …

Catalytic Activity and EPR Spectra of Molybdenum Oxide Catalysts for Ethylene Polymerization

G. K. BORESKOV, V. A. DZISKO, V. M. EMEL’YANOVA, Yu. I. PECHERSKAYA, V. B. KAZANSKII
1963 SovietRxiv: ru-196301.05414

This study examines the relationship between catalytic activity and electron paramagnetic resonance spectra in molybdenum oxide catalysts for ethylene polymerization. Molybdenum oxide was deposited on or coprecipitated with several supports, reduced in hydrogen, tested for polymerization activity un…

Synthesis of o-fluoro-$\omega$-nitrostyrene and investigation of its ability to polymerize

A. V. Topchiev, V. P. Alaniya, M. F. Vagin
1963 SovietRxiv: ru-196301.05228

This paper reports the synthesis of o-fluoro-omega-nitrostyrene and an investigation of its polymerization as a nitroolefin monomer for high-molecular compounds. The monomer was prepared by condensation of o-fluorobenzaldehyde with nitromethane in the presence of sodium hydroxide, and polymerization…

Effect of Fluoride Ions on the Anodic Dissolution of Indium Amalgam and Some Regularities of Electrode Processes Involving Complexes

V. V. LOSEV, A. I. MOLODOV
1963 SovietRxiv: ru-196301.05081

This paper examines how fluoride ions affect the anodic dissolution and cathodic deposition processes of indium amalgam under conditions of complex formation. Using polarization measurements combined with radiochemical determination of reaction rates, the authors compare fluoride-containing solution…

Stepwise Formation of Compounds with a Stannoxane Bond and Reactive Terminal Groups

N. N. ZEMLYANSKII, E. M. PANOV, N. A. SLOVOKHOTOVA,
1963 SovietRxiv: ru-196301.04974

This paper describes a stepwise method for preparing linear organotin compounds containing stannoxane bonds and reactive acetate terminal groups. Controlled hydrolysis of dibutyltin diacetate and subsequent higher homologs in the presence of diazomethane is used to form discrete members of the serie…

Addition of Trialkyl Phosphites to Acetylenecarboxylic Acids

Unknown
1963 SovietRxiv: ru-196301.04919

The study examines the addition of trialkyl phosphites to acetylenecarboxylic acids containing the conjugated system C≡C, C=O, focusing on propiolic and tetrolic acids. Reactions with several phosphites produced colorless, water-soluble liquids that gave tests for unsaturation, and infrared and anal…