Showing 50 of 25456 papers

Behavior of a platinum electrode bathed in a mixture of oxygen and carbon dioxide in molten carbonates

Unknown
1962 SovietRxiv: ru-196201.95814

This study examines the behavior and reversibility of platinum electrodes exposed to oxygen and carbon dioxide mixtures in molten alkali carbonates. Gas concentration cells with a potassium, sodium, and lithium carbonate melt were measured at about 720 °C while varying the partial pressures of oxyge…

On the Reaction of Sodium Hexanitrocobaltate with Pyridine

A. V. BABAEVA, I. B. BARANOVSKII, and G. G. AFANAS’EVA
1962 SovietRxiv: ru-196201.95803

The study examines the reaction of sodium hexanitrocobaltate with pyridine under anhydrous and aqueous conditions in order to obtain and characterize nitropyridine complexes of cobalt. Heating the solid hexanitrocobaltate hydrate with excess anhydrous pyridine gave crystalline inner-sphere trinitrot…

Lyapunov Stability and Equations with Concave Operators

Yu. S. KOLESOV and M. A. KRASNOSEL’SKII
1962 SovietRxiv: ru-196201.95780

This paper studies periodic solutions and Lyapunov stability for systems of ordinary differential equations with periodic right-hand sides that preserve the nonnegative cone. Using the Poincare-Andronov operator and the theory of nonlinear positive and concave operators, it formulates growth and dec…

Study of the Thermal Stability of Zirconium and Hafnium Tetrahalide Molecules upon Impact with a Hot Surface in Vacuum

V. I. TSIREL’NIKOV, L. N. KOMISSAROVA, and Academician Vikt. I. SPITSYN
1962 SovietRxiv: ru-196201.95773

This study examines the thermal stability of zirconium and hafnium tetrachlorides, tetrabromides, and tetraiodides during single impacts with a heated molybdenum surface in high vacuum, a problem relevant to separation processes for these elements. Purified tetrahalides were effused from a capillary…

On the Impact of a Viscoplastic Rod Against a Rigid Barrier

Unknown
1962 SovietRxiv: ru-196201.95568

The paper formulates the nonstationary problem of axial impact of a finite viscoplastic rod against a rigid barrier, treating the motion as quasi-one-dimensional and separating the rod into viscoplastic and rigid regions divided by a moving boundary. By nondimensionalizing the governing relations, t…

On approximate $\gamma_5$-invariance in the theory of strong interactions

A. A. LOGUNOV, V. A. MESHCHERYAKOV, and A. N. TAVKHELIDZE
1962 SovietRxiv: ru-196201.95514

This note examines the hypothesis that, at high energies and large momentum transfers, matrix elements of strong-interaction processes become approximately invariant under gamma5 transformations of spinor particles. Using Lorentz-invariant forms of electromagnetic vertices and scattering amplitudes,…

Amorphin glycoside

E. S. KONDRATENKO, N. K. ABUBAKIROV
1962 SovietRxiv: ru-196201.95484

This paper investigates the composition and structure of amorphin, a glycoside from fruits of Amorpha species, and its aglycone amorphigenin. Through acid hydrolysis, methylation analysis, spectroscopy, oxidation, hydrogenation, and comparison with known rotenoid derivatives, the authors identify th…

Estimation of the Vertical Dispersion Coefficient of a Settling Impurity in the Atmosphere from Its Distribution on the Earth's Surface

Unknown
1962 SovietRxiv: ru-196201.95317

This paper addresses the estimation of the vertical turbulent diffusion coefficient for a monodisperse atmospheric admixture that settles under gravity after release from an instantaneous point source. Solving the turbulent diffusion equation with constant wind, settling velocity, and diffusion coef…

Interaction of Unsymmetrical Fluoroolefins with Hydrogen Sulfide

A. V. Fokin, A. A. Skladnev, Yu. N. Studnev, and I. L. Knunyants
1962 SovietRxiv: ru-196201.95280

The paper examines the photochemical radical addition of hydrogen sulfide to unsymmetrical fluoroolefins, principally perfluoropropylene, under moderated conditions in a perfluorinated solvent. Irradiation of perfluoropropylene with hydrogen sulfide gave two isomeric monohydroperfluoropropyl mercapt…

ON THE DIRICHLET PROBLEM FOR A CERTAIN CLASS OF ELLIPTIC SYSTEMS

A u_{xx} + 2B u_{xy} + C u_{yy} = 0
1962 SovietRxiv: ru-196201.95258

The paper studies the Dirichlet problem in the unit disk for a finite system of elliptic equations of the form \(A u_{xx} + 2B u_{xy} + C u_{yy} = 0\), extending an earlier two-equation case to arbitrary finite order under the same characteristic-root assumptions. It derives an explicit representati…

CRYSTAL STRUCTURE OF CADMIUM BROMIDE DIPYRIDINATE

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1962 SovietRxiv: ru-196201.95097

The crystal structure of cadmium bromide dipyridinate, CdBr2·2(C5H5N), was investigated to clarify whether substitution of ammonia by an aromatic amine changes the coordination of cadmium in cadmium halide addition compounds. X-ray diffraction data from needle-shaped orthorhombic crystals were analy…

On the Algorithmic Complexity of Discrete Functions

Unknown
1962 SovietRxiv: ru-196201.94866

This paper studies the algorithmic complexity of discrete functions computed by binary and fixed finite-state automata, measuring complexity by the tradeoff between the number of cells and operating time. It defines a complexity set for automata realizing a given function and discusses cascades and …

Relative Rates of Peptide Synthesis

Table 1
1962 SovietRxiv: ru-196201.94679

This study examines how the composition of peptide-forming components affects the relative rates of peptide bond synthesis in model glycine systems. The authors measured pseudo-first-order aminolysis rates of p-nitrophenyl esters of acetic acid and N-carbobenzoxy glycine peptides with ethyl esters o…

On Polymethine Dyes Derived from Substituted Thiazolines

T. G. Gnevysheva, I. I. Levkoev
1962 SovietRxiv: ru-196201.94615

This paper examines how substituents in thiazoline heteroresidues influence the color and basicity of polymethine dyes when the substituents are not conjugated with the main chromophore. The authors synthesized a series of symmetric thiazolinocyanines and dimethinemerocyanines containing methyl or p…

Influence of Radioactive Radiation from the Solid Phase on the Kinetics of Potassium Sulfate Recrystallization

Academician Vikt. I. SPITSYN, V. V. GROMOV
1962 SovietRxiv: ru-196201.94577

This study examines how the specific radioactivity of solid potassium sulfate affects its recrystallization from saturated nitric acid solutions and the distribution of a cerium microimpurity. Potassium sulfate precipitates containing different activities of sulfur 35 and tracer cerium 141 were prep…

Interaction of Trialkylarsine Oxides with Alkyl Halides

Gilm KAMAI, B. D. CHERNOKALSKII, and L. A. VOROB’EVA
1962 SovietRxiv: ru-196201.94548

This paper examines the reaction of trialkylarsine oxides with electrophilic reagents, focusing on the interaction of triethylarsine oxide with alkyl iodides in benzene solution. Heating triethylarsine oxide with isopropyl iodide or isobutyl iodide gave the same crystalline product, identified by el…

Study of the Mechanism of the Effect of Pre-Irradiation on the Thermal Decomposition of Silver Oxalate Containing a Cadmium Impurity

Unknown
1962 SovietRxiv: ru-196201.94246

The study examines how cadmium impurities modify the effect of preliminary irradiation on the subsequent thermal decomposition of silver oxalate. Samples containing varying amounts of cadmium oxalate were prepared by coprecipitation, characterized by X-ray analysis, and studied by measurements of ph…

On the uniqueness of extremal functions in estimates of Taylor coefficients of bounded functions of two complex variables

Unknown
1962 SovietRxiv: ru-196201.94189

This note studies the uniqueness of extremal functions in sharp estimates for Taylor coefficients of bounded holomorphic functions of two complex variables. Using diagonal series representations, boundary values in Hardy class H1, and integral formulas for coefficients, it derives coefficient estima…

On the Transformation of Cloud Droplets into Ice Crystals

Unknown
1962 SovietRxiv: ru-196201.93960

This paper investigates whether supercooled water droplets of cloud size can transform directly into well-faceted individual ice crystals, a question relevant to theories of secondary ice formation in the atmosphere. Laboratory experiments used distilled water droplets tens of microns in diameter co…

Study of IR Spectra of Uranyl Inner-Complex Compounds with Schiff Bases and Determination of the $\mathrm{U}=\mathrm{O}$ Bond Length

V. V. ZELENTSOV
1962 SovietRxiv: ru-196201.93936

The study examines infrared spectra of solid inner-complex uranyl compounds with several Schiff bases in the 700 to 1000 cm⁻¹ region, focusing on the symmetric and asymmetric stretching vibrations of the uranyl group. From the observed bands, the U, O force constants were calculated and used with Ba…

Study of the conditions for isolating the metallic compound $\mathrm{Ni}_3\mathrm{Al}$ formed in multicomponent nickel alloys

R. B. Golubtsova and L. A. Nudz
1962 SovietRxiv: ru-196201.93897

This study examines conditions for electrolytically isolating the intermetallic compound Ni3Al formed in multicomponent nickel-base alloys containing chromium, tungsten, molybdenum, aluminum, niobium, and titanium. Several electrolytes previously used for extracting the gamma prime phase were compar…

Interaction of Polyester and Polyamide in the Melt

Corresponding Member of the Academy of Sciences of the USSR V. V. KORSHAK, S. V. VINOGRADOVA,
1962 SovietRxiv: ru-196201.93875

This study examines whether a polyester and a polyamide can undergo exchange reactions in the melt to form a polyamido ester, using polyethylene sebacinate and polyhexamethylene sebacamide as the principal system. Model experiments with acetanilide and benzyl benzoate indicated that amide and ester …

On the Effect of the Relaxation Boundary Layer

V. N. Zhigulev
1962 SovietRxiv: ru-196201.93830

This paper analyzes supersonic flow of a weakly relaxing gas past a wedge, with particular attention to vibrational relaxation behind an oblique shock. By linearizing the gas-dynamic equations with a relaxation term and solving the resulting boundary-value problem, it derives exact series expression…

Calculation of the Normal Flame Propagation Velocity in Hydrogen–Chlorine Mixtures

A. G. ISTRATOV and V. B. LIBROVICH
1962 SovietRxiv: ru-196201.93766

This paper applies an approximate theory of normal flame propagation for chain reactions to hydrogen chlorine mixtures, using integrated heat conduction and diffusion profiles rather than a prescribed Michelson profile. The authors derive expressions for flame velocity and chlorine atom concentratio…

Study of High-Purity Metallic Scandium

Unknown
1962 SovietRxiv: ru-196201.93713

This study examines the preparation and chemical behavior of metallic scandium, with emphasis on obtaining higher purity material from calcium-reduced scandium chloride products. High-vacuum sublimation in a tantalum apparatus produced compact scandium of about 99.5 wt.% purity with reduced oxygen c…

On the Interaction of Some Substituted Triarylchloro- and Triarylbromomethanes with Salts of Dialkylphosphorous Acids

Unknown
1962 SovietRxiv: ru-196201.93515

This study examines the reactions of substituted triarylchloro- and triarylbromomethanes with sodium and potassium salts of dialkylphosphorous acids, focusing on methoxy-, ethoxy-, chloro-, and bromo-substituted derivatives. The authors synthesize several triarylbromomethanes and compare reaction ou…

On the Formation of Free Radicals in Autooxidation Reactions Photosensitized by Chlorophyll and Pheophytin

V. E. KARPITSKAYA, I. A. DOLIDZE, M. S. ASHKINAZI
1962 SovietRxiv: ru-196201.93507

This study investigates the formation of free radicals during autoxidation reactions of diphenylamine and paraphenylenediamine photosensitized by chlorophyll a and pheophytin a. Using spectrophotometry and electron paramagnetic resonance, the authors irradiated purified amine solutions with red ligh…

On the Dynamics of a Stratified Fluid

Corresponding Member of the USSR Academy of Sciences A. M. OBUKHOV
1962 SovietRxiv: ru-196201.93417

This note derives an expression for the evolution of potential vorticity in a stratified fluid subject to weak external influences, including heat influx and frictional forces. Starting from the hydrodynamic equations, continuity equation, equation of state, and a prescribed entropy change, it shows…

Experimental Determination of the Earth's Outgoing Radiation

A. V. LIVENTSOV, M. N. MARKOV, Ya. I. MERSON, M. R. SHAMILIEV
1962 SovietRxiv: ru-196201.93348

This paper reports direct experimental measurements of the Earth’s outgoing thermal radiation, a key component of the planetary energy balance previously estimated mainly by calculation. The authors describe infrared radiometric apparatus flown on stabilized high-altitude geophysical rockets, using …

THE INFLUENCE OF THE STRUCTURE OF THE DOUBLE LAYER ON IRREVERSIBLE POLAROGRAPHIC WAVES OF REDUCTION OF ORGANIC SUBSTANCES WITH CONSUMPTION OF PROTONS IN THE POTENTIAL-DETERMINING STAGE

Unknown
1962 SovietRxiv: ru-196201.93336

The paper analyzes how the structure of the electrical double layer affects irreversible polarographic reduction waves of organic compounds when proton consumption occurs in the potential-determining stage. Building on Frumkin’s theory, it argues that such reductions are generally preceded by proton…

Energy Transfer during Radiolysis of Toluene with Additives

A. T. Koritskii, V. N. Shamshev, and N. Ya. Buben
1962 SovietRxiv: ru-196201.93072

This study examines energy transfer during the radiolysis of frozen toluene containing small additions of carbon tetrachloride, benzoyl peroxide, or carbon disulfide. Using electron paramagnetic resonance during irradiation by 1.6 MeV electrons at low temperature, the authors measured radical accumu…

Investigation of the copper electroreduction process using a ring-disk electrode

L. N. NEKRASOV and N. P. BEREZINA
1962 SovietRxiv: ru-196201.92875

This study examines the mechanism of electroreduction of divalent copper in sulfate solutions, focusing on whether monovalent copper is formed as an unstable intermediate despite the appearance of a single polarographic wave. Using a rotating disk electrode with a concentric ring, the authors measur…

Emulsion Polymerization of $\alpha$-Methacrolein in the Presence of Various Redox Systems

Corresponding Member of the Academy of Sciences of the USSR M. M. Koton, I. V. Andreeva
1962 SovietRxiv: ru-196201.92494

The study examines emulsion polymerization of alpha-methacrolein using several oxidation reduction initiating systems and an aqueous sulfurous acid polyacrolein emulsifier intended to promote polymerization in micelles. Polymerizations with potassium persulfate alone or combined with silver nitrate,…

Structure of the Solution Set of Parabolic-Type Equations

M. A. Krasnosel’skii, P. E. Sobolevskii
1962 SovietRxiv: ru-196201.92415

This paper studies the structure of solution sets for nonlinear parabolic evolution equations and mixed boundary value problems, extending the Kneser Hukuhara connectedness principle from ordinary differential equations to parabolic settings. Using a topological connectedness theorem for fixed point…