Showing 50 of 25456 papers

ON ONE VARIANT OF THE STEFAN PROBLEM\*

Unknown
1962 SovietRxiv: ru-196201.92343

This paper studies a one-phase generalized Stefan problem for a parabolic equation with nonlinear dependence on the unknown function, its spatial derivative, and the moving boundary and velocity. The problem is reformulated as a system of integral equations using Green’s functions for the heat equat…

Crystal Structure of Beryllonite $\mathrm{NaBePO}_4$

Unknown
1962 SovietRxiv: ru-196201.92100

The paper determines the crystal structure of beryllonite, NaBePO4, using X-ray diffraction data from Weissenberg photographs and analysis of interatomic-vector and electron-density projections. The study confirms the monoclinic space group P21/n and refines atomic positions through successive Fouri…

Catalytic Properties of Chelate (Intracomplex) Polymers

Corresponding Member of the Academy of Sciences of the USSR G. K. BORESKOV, N. P. KEIER, L. F. RUBTSOVA
1962 SovietRxiv: ru-196201.91869

This study examines organometallic chelate polymers as solid catalysts with properties potentially intermediate between inorganic catalysts and enzymes. Using hydrazine decomposition as the principal test reaction, and also considering dehydrogenation of isopropyl alcohol and formic acid, the author…

Crystal Lattice Energy and Reactivity of Solids

Academician of the Academy of Sciences of the BSSR M. M. PAVLYUCHENKO
1962 SovietRxiv: ru-196201.91859

This paper examines how lattice energy and dispersion affect the reactivity of solids in decomposition and formation reactions involving complex anions, especially carbonates and sulfates. It develops thermochemical expressions linking activation energy and reaction heat to the lattice energies of i…

Association of Organolithium Compounds and Its Role in Polymerization Processes

Yu. L. Spirin, A. R. Gantmakher, S. S. Medvedev
1962 SovietRxiv: ru-196201.91849

This paper examines how association of organolithium active centers affects the kinetics of lithium-initiated polymerization of styrene, isoprene, and butadiene in hydrocarbon media. Using optical density measurements to separate initiation from chain growth, and dilatometric rate measurements over …

On the Reducibility of a System of Ordinary Differential Equations in a Neighborhood of a Quasi-Periodic Motion

E. G. BELAGA
1962 SovietRxiv: ru-196201.91544

This paper studies the analytic reducibility of ordinary differential equations in a neighborhood of an invariant torus filled with quasi-periodic trajectories. Assuming that the linear variational system with conditionally periodic coefficients has already been reduced to constant coefficients, the…

Neutral-type equation with a small delay

A. B. VASIL’EVA
1962 SovietRxiv: ru-196201.91417

This note studies a neutral differential equation with a constant small delay, in which the right hand side depends on the delayed derivative, and examines the behavior of its solution as the delay tends to zero. Under smoothness assumptions and a stability condition bounding the derivative of the r…

Homolytic Reactions of Organotin Compounds with Alkyl Halides Initiated by Peroxides

G. A. RAZUVAEV, Yu. I. DERGUNOV, and N. S. VYAZANKIN
1962 SovietRxiv: ru-196201.91253

The study examines whether peroxide compounds can initiate homolytic reactions between organotin compounds and alkyl halides, which are otherwise relatively inert under comparable conditions. Benzoyl peroxide was heated under nitrogen with mixtures of tetraethyltin, dimethyldiethyltin, hexaethyldist…

Polymerization of allylcyclohexane in the presence of the catalytic system $\mathrm{TiCl}_4+\mathrm{Al}$ (iso - $\mathrm{C}_4\mathrm{H}_9)_3$

Table 1
1962 SovietRxiv: ru-196201.91231

The study examines the polymerization of allylcyclohexane in n-heptane at 70°C under nitrogen using the catalytic system titanium tetrachloride with triisobutylaluminum. Allylcyclohexane was synthesized and purified, then polymerized in sealed ampoules and in an open system while varying catalyst ra…

On singular Cauchy problems for the Chaplygin equation

Unknown
1962 SovietRxiv: ru-196201.91183

The paper studies singular Cauchy problems for the Chaplygin equation in a half-plane near the degeneracy line, focusing on the construction of singular kernels and Riemann type functions. It introduces Duhamel and Doetsch resolvents with discontinuous boundary data, reduces their computation to mix…

Reaction of the $n$-nitrophenyl ester of carbobenzoxy-$D$-phenylalanine with chym

M. M. BOTVINNIK and I. P. KURANOVA
1962 SovietRxiv: ru-196201.91180

This study examines whether chymotrypsin forms a detectable acyl-enzyme intermediate during hydrolysis of the p-nitrophenyl ester of carbobenzoxy-D-phenylalanine, a D-amino acid ester expected to react more slowly than corresponding L-substrates. Kinetic measurements showed an initial burst of p-nit…

Radiation from a charged particle passing near a metallic screen

A. P. Kazantsev, G. I. Surdutovich
1962 SovietRxiv: ru-196201.91140

This paper analyzes radiation produced when the electromagnetic field of a point charge is diffracted by an ideally conducting half-plane, for a particle trajectory perpendicular to the screen edge and arbitrary particle velocity. Using Fourier components of the electromagnetic potentials and Wiener…

On the Theory of Weak Solutions of Boundary Value Problems

Unknown
1962 SovietRxiv: ru-196201.91082

The paper studies weak solutions of the first boundary-value problem for uniformly strongly elliptic systems of order 2m in a bounded domain, using Sobolev space formulations and Gårding-type coercive inequalities. It reduces the weak problem to an operator equation in a Hilbert space involving a bo…

Evaluation of the Flexibility of Polybutylene Chains from Sorption Data

G. M. PAVLYUCHENKO, T. V. GATOVSKAYA, V. A. KARGIN
1962 SovietRxiv: ru-196201.91026

This study examines the sorption of n-octane vapor by crystalline polybutylene over 50 to 115°C in order to estimate the flexibility of its polymer chains. Sorption isotherms obtained with spring balances show increasing uptake with temperature, with anomalies in the premelting region that are inter…

Some Concepts of the Crack Zone and Crack Front

Unknown
1962 SovietRxiv: ru-196201.91017

The paper develops a simplified model for spherically symmetric fracture in a solid whose tensile strength is much lower than its compressive strength, focusing on the formation of a densely cracked radial zone behind an outgoing elastic wave. It assumes that radial cracks instantaneously relieve az…

On a General Formulation of the Problem of Best Approximation

E. G. GOL’SHTEIN
1962 SovietRxiv: ru-196201.91013

This note formulates a general best approximation problem in Banach spaces with additional linear equality constraints and cone-defined inequality constraints. Under a regularity condition, it proves an analogue of Chebyshev’s theorem, giving necessary and sufficient optimality conditions in terms o…

On the conditions of mineral formation in pegmatites based on the study of primary inclusions in topaz

G. G. Lemmlein, M. O. Kliya, and I. A. Ostrovskii
1962 SovietRxiv: ru-196201.90948

Primary inclusions in topaz crystals from Volhynian pegmatites were examined to infer the conditions of pegmatite mineral formation. The inclusions, identified as negative crystals containing abundant quartz and muscovite with cryolite, minor fluorides and chlorides, aqueous solution, and gas, were …

On the Mechanism of Homogeneous Radical Stereospecific Polymerization of Vinyl Chloride in Aldehydes

Corresponding Member of the Academy of Sciences of the USSR G. A. RAZUVAEV, K. S. MINSKER,
1962 SovietRxiv: ru-196201.90889

The paper examines the mechanism of homogeneous free radical stereospecific polymerization of vinyl chloride in aldehyde media, a process known to yield highly crystalline syndiotactic polyvinyl chloride. On the basis of inhibition tests, ultraviolet and gamma irradiation experiments, infrared cryst…

On Oscillations of the Tunneling Current in a Magnetic Field

Unknown
1962 SovietRxiv: ru-196201.90775

This paper examines oscillations of tunnel current in a magnetic field as a possible probe of the conduction electron energy spectrum in metals. The authors consider tunneling between two identically oriented single crystals separated by a thin dielectric layer, with a magnetic field perpendicular t…

Three-Dimensional Problem of Forecasting Smoothed Values of Meteorological Elements

Corresponding Member of the USSR Academy of Sciences E. N. BLINOVA
1962 SovietRxiv: ru-196201.90690

This paper generalizes a previous treatment of forecasting smoothed meteorological fields to a fully three-dimensional atmospheric model in which the stream function depends on horizontal coordinates, height, and time. Starting from a quasi-solenoidal dynamical equation with boundary conditions at t…

Diene synthesis with glyoxylic acid esters

Unknown
1962 SovietRxiv: ru-196201.90488

The study examines diene syntheses of glyoxylic acid esters and their hemiacetals with 1,3-dienes as a route to 5,6-dihydro-1,2-pyran derivatives, a class of reactions previously little explored for carbonyl compounds. Butadiene, 2,3-dimethylbutadiene, and 1,3-cyclohexadiene were condensed with ethy…

Chemical Shift and Dienophile Activity in the Diene Synthesis Reaction

B. A. ARBUZOV, A. I. KONOVALOV, and Yu. Yu. SAMITOV
1962 SovietRxiv: ru-196201.90426

This study examines whether the activity of substituted ethylenic dienophiles in diene synthesis correlates with the NMR chemical shift of the terminal hydrogen atoms at the double bond. Chemical shifts were measured or taken from literature, averaged where the two terminal hydrogens were nonequival…

Spectral Representations of the Mass and Polarization Operators at Arbitrary Temperature

V. L. Bonch-Bruevich
1962 SovietRxiv: ru-196201.90256

The paper generalizes spectral representations of mass and polarization operators from zero temperature to arbitrary temperature using retarded and advanced Green functions rather than causal functions. For a homogeneous fermion system, it derives analytic properties of the mass operator, locates po…

Successive Laplace Transformations with Stratified Congruences of Axes

G. B. KHASIN
1962 SovietRxiv: ru-196201.90192

This paper studies conjugate nets in three-dimensional projective space whose successive Laplace transforms have fibering congruences of first and second axes. Using a moving projective frame and Cartan’s exterior differential forms, the author derives the differential systems expressing the require…

Study of the interaction of lead selenide with oxygen

V. P. ZLOMANOV and A. V. NOVOSELOVA
1962 SovietRxiv: ru-196201.90187

The study examines the oxidation of lead selenide by oxygen between 122 and 496°C, focusing on kinetics, oxidation products, surface area, and electrical resistivity. Powdered PbSe samples were oxidized at controlled oxygen pressure, analyzed gravimetrically with torsion microbalances, characterized…

On Some Differential Equations Arising in the Study of Oscillations with Small Random Perturbations

R. Z. KHAS’MINSKII
1962 SovietRxiv: ru-196201.90159

The paper studies elliptic and parabolic second order differential equations with a small parameter multiplying the highest derivatives, motivated by oscillatory systems subject to small random perturbations and fast motion along closed trajectories. It proves averaging results for solutions in an a…

ON THE SET SWEPT OUT BY A LINE SEGMENT

Unknown
1962 SovietRxiv: ru-196201.90144

The paper studies the planar set swept out by segments joining the line y = 0 to the line y = 1 when the segment through each base point has a prescribed inclination, asking what can occur when the inclination function is discontinuous. It develops a construction using finite systems of parallelogra…

Constructive Characterization of One Class of Functions

V. F. VLASOV
1962 SovietRxiv: ru-196201.90106

This paper gives a constructive characterization of continuous periodic functions whose trigonometric conjugates, together with the original functions, satisfy the Lipschitz condition of order one. The criterion is formulated in terms of approximation by Jackson interpolation polynomials at equally …

On the Normability of a Boolean Algebra

D. A. Vladimirov
1962 SovietRxiv: ru-196201.90083

This note studies when a complete Boolean algebra is normable, meaning that it admits a strictly positive countably additive probability measure, by examining groups of automorphisms of the algebra. It introduces complete homogeneity, defined by a transitivity condition and a uniform continuity cond…

On the Instability of Alfvén Waves

A. A. GALEEV, V. N. ORAEVSKII
1962 SovietRxiv: ru-196201.90007

This paper examines the stability of finite-amplitude Alfvén waves in magnetohydrodynamics, despite their status as exact nonlinear solutions. Using perturbation theory in a frame moving with the wave, the authors derive resonance conditions coupling perturbations whose wave vectors and frequencies …

Oxazole Derivatives in Diene Synthesis

Unknown
1962 SovietRxiv: ru-196201.89982

This study examines diene synthesis reactions of oxazole derivatives bearing electron-acceptor, methyl, and phenyl substituents with maleimide and, in selected cases, maleic anhydride. By comparing yields of substituted pyridinedicarboximides and partially hydrolyzed semiamides, the authors show tha…

The localization principle and systems $\{\varphi(nx)\}$

Unknown
1962 SovietRxiv: ru-196201.89872

This note studies whether Riemann’s localization principle extends from trigonometric Fourier series to systems of the form \(\{\varphi(nx)\}\) whose generating function satisfies specified absolute convergence and Dirichlet series nonvanishing conditions. Although such \(T\)-systems share several g…

Photosorption of Hydrogen on Titanium Dioxide

V. L. RAPOPORT and Yu. P. SOLONITSYN
1962 SovietRxiv: ru-196201.89761

This study investigates the light-induced sorption of hydrogen on powdered titanium dioxide using pressure measurements under controlled vacuum, illumination, and sample pretreatment conditions. Hydrogen photosorption was observed only after calcination of titanium dioxide in oxygen, proceeded irrev…

THEORY OF ELECTRON PARAMAGNETIC RESONANCE IN SOLUTIONS

Unknown
1962 SovietRxiv: ru-196201.89691

This paper develops a theoretical treatment of electron paramagnetic resonance line narrowing and relaxation in paramagnetic solutions, where thermal motion and exchange interactions act simultaneously. Using the Kubo and Tomita formalism, it derives approximate correlation functions for fast and sl…

Spectra of 2,4-dinitroaniline derivatives. Presence of quasi-autonomous cochromophoric systems

E. E. Milliarsi, V. A. Izmailskii
1962 SovietRxiv: ru-196201.89520

The paper examines the ultraviolet spectra of 2,4-dinitroaniline, 2,4-dinitrodiphenylamine, and related derivatives in order to clarify how multiple nitro, amino, and aryl substituent systems contribute to observed absorption bands. Using decomposition of molecular structures into polar chromophoric…

On the Distribution of Elastic Constants in Quasi-Isotropic Polycrystals

S. D. VOLKOV, N. A. KLINSKIKH
1962 SovietRxiv: ru-196201.89500

This paper addresses the statistical distribution of elastic constants in quasi-isotropic, single-phase polycrystals, where crystallographic orientations are random at the microscopic scale. The authors formulate the elastic-constant transformation in terms of Euler angles and derive the joint densi…

On Averaging over an Unbounded Interval

Unknown
1962 SovietRxiv: ru-196201.89466

This note extends an earlier asymptotic averaging method for singularly perturbed systems of differential equations to intervals that may be unbounded in time. It formulates additional hypotheses involving Lyapunov stability of a solution of the degenerate fast system, uniform existence of time aver…

Dipole Moments of Merocyanines Derived from Imidazolidine-2,4-dione and Its Thio- and Dithio-Substituted Analogs

E. A. Shott-Lvova, Corresponding Member of the Academy of Sciences of the USSR Ya. K. Syrkin,
1962 SovietRxiv: ru-196201.89366

Dipole moments were measured in benzene at 25 degrees Celsius for eight imidazolidinedione, thiohydantoin, and merocyanine derivatives containing oxygen and sulfur substitutions, and the visible absorption maxima of the dyes were also determined. The data are interpreted in terms of conjugation, cha…

ASYMPTOTICS OF THE EIGENVALUES OF A LINEAR INTEGRAL EQUATION WITH A DISCONTINUOUS KERNEL

Consider the integral equations
1962 SovietRxiv: ru-196201.89364

This paper studies the asymptotic distribution of eigenvalues for linear Fredholm integral equations with bounded kernels having a finite jump discontinuity on the diagonal. Under smoothness, nondegeneracy, and boundary-type conditions expressed through auxiliary resolvent kernels, the equation is r…