Showing 50 of 25456 papers

Calculation of depolarization and superpolarization effects in the formation of a galvanic alloy

V. V. SYSOEVA and A. L. ROTINYAN
1962 SovietRxiv: ru-196201.89362

This paper addresses the calculation of depolarization and superpolarization effects during electrolytic formation of binary galvanic alloys, where purely thermodynamic treatments may be inadequate. The authors derive an expression for the deposition potential of a metal entering an alloy using the …

On embedding theorems and maximal subgroups of finite groups

Unknown
1962 SovietRxiv: ru-196201.89304

This note develops embedding and conjugacy theorems for subgroups of finite groups in settings extending the usual theory of Hall subgroups. It introduces quasi-Hall and quasi-Sylow divisors and formulates conditions under which properties such as existence, conjugacy, embedding into larger subgroup…

Interaction of Nitriles with Heavy Water and Deuterium Chloride

E. N. ZILBERMAN, A. Ya. LAZARIS, G. G. PETUKHOV,
1962 SovietRxiv: ru-196201.89256

This study examines the reaction of nitriles with heavy water and deuterium chloride under low-temperature conditions as a route to deuterated amides and amide hydrochlorides. A series of aliphatic, chlorinated, and aromatic nitriles were converted to amides, and the products were analyzed for deute…

Proton magnetic resonance of 2,2-dimethylpropane-1,3-diol sulfite and carbonate

B. A. Arbuzov, Yu. Yu. Samitov, R. M. Mamina
1962 SovietRxiv: ru-196201.89245

This paper examines the proton magnetic resonance spectra and conformational behavior of cyclic carbonate and sulfite esters of 2,2-dimethylpropane-1,3-diol. The authors compare spectra recorded at 24.458 MHz and argue that the carbonate shows averaged methylene and methyl resonances because rapid i…

X-ray diffraction study of the effect of hydrostatic pressure up to 18,000 kg/cm $^2$ on the structure of lead titanate

S. S. KABALKINA and L. F. VERESHCHAGIN
1962 SovietRxiv: ru-196201.89223

This study examines the effect of hydrostatic pressure up to 18,000 kg/cm2 on the room temperature crystal structure of ferroelectric lead titanate. Using high pressure X-ray diffraction on ceramic PbTiO3 specimens, the authors measured changes in lattice parameters and tetragonality as pressure inc…

On the Behavior of Vinyl Butyl Ether on a Platinum Catalyst

Academician of the Academy of Sciences of the Kazakh SSR D. V. Sokol’skii and T. M. Beloslyudova
1962 SovietRxiv: ru-196201.89213

This study examines the hydrogenation and electrohydrogenation behavior of vinyl butyl ether on platinized platinum in acidic aqueous solution and aqueous ethanol, with simultaneous measurement of catalyst potential. Kinetic experiments showed very slow hydrogenation in 0.1 N sulfuric acid and a som…

On the Solution of the Main Boundary Value Problem for Some Linear Partial Differential Equations of Even Order

Unknown
1962 SovietRxiv: ru-196201.89033

The paper extends the notion of weak ellipticity for even order linear partial differential operators in two real variables by using a directional first order operator with arbitrary nonzero constants. It formulates the basic homogeneous boundary value problem for a broad class of weakly elliptic eq…

Faradaic Rectification in a Binary Electrolyte Solution

Corresponding Member of the USSR Academy of Sciences V. G. LEVICH, B. M. GRAFOV
1962 SovietRxiv: ru-196201.88978

The paper develops a theory of Faradaic rectification for an electrochemical cell containing a stationary binary electrolyte without supporting electrolyte, under low-frequency sinusoidal polarization and small current amplitudes. Using slow-discharge kinetics and previously derived first-order impe…

Some Formulas Related to the Reduced Residue System

E. V. NOVOSELOV
1962 SovietRxiv: ru-196201.88794

The paper derives formulas for indices of reduced residue classes using formal logarithmic and exponential series interpreted modulo a natural number. It first treats odd prime powers and powers of two, giving congruences for discrete logarithm type indices and describing suitable choices of primiti…

Several Results on Characteristic Functionals

Unknown
1962 SovietRxiv: ru-196201.88783

The paper studies characteristic functionals of probability measures on spaces in duality, focusing on extensions of Bochner-type characterization theorems beyond the setting considered by Kolmogorov. It shows that the relevant theorem remains valid when the dual space is a separable countably pre-H…

On the Temperature Dependence of the Surface Tension of Cesium

Yu. A. Timofeevicheva, V. B. Lazarev, and A. V. Pershikov
1962 SovietRxiv: ru-196201.88679

This paper reports experimental measurements of the temperature dependence of the surface tension of molten cesium, a quantity previously lacking reliable data because of the metal’s high chemical activity and vapor pressure. The authors used a sealed glass apparatus based on the maximum pressure bu…

High-pressure and high-temperature apparatus with several pairs of electrical feedthroughs

Corresponding Member of the Academy of Sciences of the USSR L. F. VERESHCHAGIN, A. A. SEMERCHAN,
1962 SovietRxiv: ru-196201.88658

The paper describes a high-pressure, high-temperature apparatus designed to overcome the difficulty of introducing electrical leads into conical-punch pressure chambers. The apparatus uses a split high-pressure chamber, insulated between its sections, so that each section can serve as an electrical …

On the Preparation and Reactivity of Some Arylated $\beta$-Iodo Esters

M. A. KHAIMOVA, B. I. KURTEV, and Ts. P. BEZUKHANOVA
1962 SovietRxiv: ru-196201.88542

This study examines the preparation and reactivity of arylated beta-iodo ethers formed from diphenyl-substituted ethylenic hydrocarbons under iodinating conditions in alcohols. Experiments with iodine, mercuric oxide, mercuric iodide, and iodine monochloride showed that beta-iodo ethers from 1,1-dip…

Synthesis and Some Transformations of $\beta$-Substituted Acroleins

V. T. KLIMKO, T. V. PROTOPOPOVA, A. P. SKOLDINOV
1962 SovietRxiv: ru-196201.88492

This communication describes the synthesis, properties, and transformations of beta substituted acroleins as vinylogous derivatives of formic acid compounds and of malondialdehyde enols. The authors develop routes to beta alkoxyacroleins from malondialdehyde salts, acetals, and especially alkyl beta…

Concentration Limits of Flame Propagation in an Acetylene-Air Mixture

S. M. KOGARKO, B. A. IVANOV, and A. E. GRUNIN
1962 SovietRxiv: ru-196201.88404

This paper investigates the concentration limits of flame propagation in acetylene, air mixtures at varying initial pressures, addressing earlier discrepancies attributed to insufficient ignition energy. Experiments in steel vessels measured ignition energy as a function of mixture composition and p…

On the Poincare Problem for a Second-Order Elliptic Equation with Singular Coefficients

In the present note we study the plane boundary-value Poincaré problem (problem A) for an elliptic equation of the form
1962 SovietRxiv: ru-196201.88321

The paper studies the planar Poincare boundary value problem for a second order elliptic equation whose first order coefficients have first order polar singularities and whose zeroth order coefficient has a second order polar singularity. After showing conformal invariance, the problem is reduced in…

Investigation of the Structure of Some Inner Complex Compounds by Electron Paramagnetic Resonance

B. V. Lokshin, A. K. Piskunov, L. A. Kazitsyna, and D. N. Shigorin
1962 SovietRxiv: ru-196201.88264

Electron paramagnetic resonance spectra were measured for a series of inner complex copper compounds derived from imines of salicylaldehyde, o-hydroxyacetophenone, and beta-hydroxynaphthaldehyde, in powders and chloroform solutions. The solution spectra show copper hyperfine splitting, and in one ca…

Semiconductor Properties of Blood Pigments

Unknown
1962 SovietRxiv: ru-196201.87740

This study examines the semiconducting behavior of thin layers of blood pigments, including hematin, hemin, hematoporphyrin, and a heated hematoporphyrin product identified with protoporphyrin. Temperature dependent dark conductivity and photoconductivity were measured under vacuum and in oxygen, us…

Reduction of the Memory Allocation Problem in Program Compilation to the Problem of Coloring Graph Vertices

A. P. ERSHOV
1962 SovietRxiv: ru-196201.87514

This paper extends a previously noted connection between memory allocation in programming and graph coloring from a restricted class of programs to a broad class described as operator schemes. It formalizes quantities, routes, storage zones, admissible transformations, and regions of action, then gi…

ON STABILITY IN THE LARGE OF NONLINEAR PULSE AUTOMATIC SYSTEMS

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1962 SovietRxiv: ru-196201.87352

This paper studies stability in the large for nonlinear pulse automatic systems, including digital systems, with a nonlinear pulse element whose characteristic lies in a sector and a stable reduced continuous part. It adapts Popov’s frequency-domain approach to impulse systems by introducing truncat…

Radiation damage in quartz

E. V. Kolontsova, I. V. Telegina
1962 SovietRxiv: ru-196201.87329

This paper examines radiation-induced structural disturbances in quartz using anomalous X-ray scattering after neutron irradiation. The authors compare diffraction patterns before and after irradiation, noting that at lower fluence diffuse maxima intensify without major structural change, while at a…

ON THE MAGNETIC PROPERTIES AND STRUCTURE OF NICKEL FILMS OBTAINED BY A CHEMICAL METHOD

N. V. KOTELNIKOV, N. A. KORENEV, P. A. MALINEN, T. D. ERMOLINA
1962 SovietRxiv: ru-196201.87310

Chemically deposited nickel films were examined to clarify how deposition conditions, structure, and magnetic behavior are related, particularly in light of earlier reports that freshly prepared deposits are amorphous. Films were produced on copper substrates from sulfate, hypophosphite, and acetate…

On a Class of Locally Convex Spaces

Unknown
1962 SovietRxiv: ru-196201.87226

This note introduces the class of alpha spaces, locally convex spaces whose weak duals have the property that every sequentially closed subspace is closed, and studies related alpha prime spaces defined through sequential completeness of the weak dual in the Mackey topology. It proves permanence pro…

Distribution of Potential and Electric Field Strength in the Dense Part of the Electrical Double Layer

Unknown
1962 SovietRxiv: ru-196201.87187

This paper develops a quantitative calculation of the potential and electric field strength in the dense part of the electric double layer, accounting for the discrete arrangement of specifically adsorbed ions and the dielectric properties of the adjacent phase. Assuming adsorbed ion centers fixed i…

2'-Amino-5,5-dimethylcyclohexanone-1-(2,3 : 4', 5')-thiazole (I)

I. GAILĪTE, E. GUDRINIECE, Academician of the Academy of Sciences of the Latvian SSR G. VANAGS
1962 SovietRxiv: ru-196201.87030

This paper describes the preparation and reactions of 2′-amino-5,5-dimethylcyclohexanone-1-thiazole derivatives as part of a search for physiologically active thiazole compounds. The authors show that 2-halo-5,5-dimethylcyclohexanedione-1,3 reacts with thiourea in ethanol to give the aminothiazole i…

A Note on Commutative Semigroups

Unknown
1962 SovietRxiv: ru-196201.86917

This note studies commutative semigroups with zero that have only finitely many nonregular elements, equivalently those admitting a finite Rees ideal composition series, with particular attention to the case \(A^2=A\). It introduces reduced ideal series whose factors are elementary semigroups, prove…

An Estimate of a Sum with Prime Numbers

G. I. Perel’muter
1962 SovietRxiv: ru-196201.86799

This note derives an estimate for sums over primes of products of a nonprincipal character modulo a prime q evaluated at a rational function and an additive exponential of another rational function. Extending a problem indicated by I. M. Vinogradov, it applies Vinogradov’s method together with stren…

Synthesis of Some Organosilicon Monomers with a Phosphorus-Containing Functional Group

E. F. BUGERENKO, E. A. CHERNYSHEV, and Corresponding Member of the USSR Academy of Sciences A. D. PETROV
1962 SovietRxiv: ru-196201.86693

This study addresses the synthesis of organosilicon monomers bearing phosphorus-containing functional groups, a class of compounds of interest as precursors to phosphorus-containing silicones and other functional materials. The authors propose hydrosilylation of allylphosphinic acid chloride with ch…

Stereospecific polymerization of propylene as influenced by organic compounds with a closed $\pi$-conjugated bond system

Corresponding Member of the Academy of Sciences of the USSR G. A. RAZUVAEV, K. S. MINSKER,
1962 SovietRxiv: ru-196201.86620

This study examines how organic compounds with closed pi-conjugated bond systems affect the stereospecific Ziegler-type polymerization of propylene. Using a titanium trichloride and triethylaluminum catalyst system at 45 degrees, the authors measured propylene uptake in aliphatic solvent containing …

On Coherent Scattering of Plane and Spherical Waves in Deep-Water Layers Containing Discrete Inhomogeneities

V. P. GLOTOV
1962 SovietRxiv: ru-196201.86610

This paper analyzes coherent and incoherent acoustic scattering from a deep-water layer containing randomly distributed discrete inhomogeneities, addressing cases where scatterer spacing is comparable with the wavelength and interference cannot be neglected. Using statistical averaging over scattere…

On Compactifications of Completely Regular Spaces

Unknown
1962 SovietRxiv: ru-196201.86603

The paper studies compactifiability properties of completely regular spaces and spaces obtained by deleting countable sets from products of compacta. It constructs a completely regular, peripherally bicompact space using a product of an interval with an ordinal space, and proves via an auxiliary lem…

On a Certain Boundary Value Problem

V. P. Mikhailov
1962 SovietRxiv: ru-196201.86533

This paper studies existence, uniqueness, and regularity for a boundary value problem in a cylinder for a class of higher order linear differential equations with elliptic spatial part and time derivative of arbitrary order. It establishes a priori estimates in anisotropic Sobolev spaces for both st…

Application of electrochemical persulphate reduction to initiation of polymerization reaction

E. M. Skobets, G. S. Nestyuk
1962 SovietRxiv: ru-196201.86396

This paper proposes electrochemical reduction of persulfate as a controllable method for initiating radical polymerization, based on the presumed stepwise formation of sulfate radical ions at an electrode. The authors test this approach using acrylamide solutions containing potassium persulfate, car…

Extraction Recovery of Perrhenates with Ketones

D. I. RYABCHIKOV, Yu. B. GERLIT, A. V. KARYAKIN, V. A. ZARINSKII, and M. E. ZUBRILINA
1962 SovietRxiv: ru-196201.86384

This study examines the extraction of perrhenates by ketones, focusing on how ketone structure, temperature, and solvation affect distribution coefficients. Measurements of extraction equilibria for several ketones were combined with estimates of extraction heats, conductivity observations, and infr…