Showing 50 of 25456 papers

On Radiation-Thermal Cracking of Liquid Hydrocarbons

A. M. BRODSKII, K. P. LAVROVSKII, and V. B. TITOV
1961 SovietRxiv: ru-196101.70037

This paper examines radiation-thermal cracking in liquid hydrocarbon mixtures, using gas-oil fractions irradiated at elevated temperatures in evacuated quartz ampoules. The authors distinguish three regimes of decomposition and show that above a critical temperature near 600 K the radiation-chemical…

New conditions for synthesis involving $\mathrm{PtCl_4^{2-}}$ ions

Kh. I. Gildengershel and E. P. Panteleeva
1961 SovietRxiv: ru-196101.69884

This paper addresses difficulties in preparing cis-diamine platinum compounds from potassium chloroplatinite, where reactions with free amines often give Magnus salt analogues or hydrolysis products instead of the desired complexes. The authors propose replacing potassium with sodium to form concent…

On the Solvability of the Dirichlet and Neumann Problems for a Linear Elliptic Operator with Discontinuous Coefficients

Unknown
1961 SovietRxiv: ru-196101.69799

The paper studies classical solvability of Dirichlet and Neumann boundary value problems for general second order linear elliptic operators whose coefficients may be discontinuous across an interior Lyapunov surface. It formulates transmission conditions for the jump of the solution and its conormal…

On extensions of the indexial of a finite group

Unknown
1961 SovietRxiv: ru-196101.69645

This note continues the author’s development of the method of indexials for locating subgroups of finite groups, focusing on the additional multiplier that appears in earlier existence criteria for subgroups. It introduces primary specially arithmetically closed extensions, chains of such extensions…

Interaction of Weak Pressure Waves with a Flame Front

S. S. Novikov and Yu. S. Ryazantsev
1961 SovietRxiv: ru-196101.69598

This paper develops a gas dynamic treatment of the nonrelaxation interaction between weak pressure waves and a flame front, accounting for changes in flame propagation velocity caused by variations of the thermodynamic parameters of the combustible mixture. By linearizing the conservation laws at th…

Some Estimates of Solutions to Second-Order Elliptic Equations

V. G. MAZ'YA
1961 SovietRxiv: ru-196101.69553

This paper derives a priori estimates for solutions of second order elliptic equations in finite domains, with coefficients subject to ellipticity and integrability conditions and constants independent of coefficient moduli of continuity. It extends Stampacchia’s estimates by proving endpoint and re…

Stability of wing panels under heating

L. M. KURSHIN
1961 SovietRxiv: ru-196101.69435

This paper analyzes thermal buckling of multi-spar wing skin panels subjected to nonstationary aerodynamic heating, where the skin heats more rapidly than the spar webs and develops temperature stresses. The author formulates coupled heat-conduction and stability equations, represents temperatures a…

Application of the complete system of thermohydrodynamic equations to short-term weather forecasting in a two-level model

Dzen Tsin-tsun
1961 SovietRxiv: ru-196101.69364

This paper develops a simplified two-level numerical scheme for applying the complete thermo-hydrodynamic equations to short-range weather forecasting. Starting from equations of motion, continuity, and heat inflow at standard pressure levels, the author derives prognostic equations for mean and she…

Transient Gas Flow in Trunk Pipelines

G. Pascal
1961 SovietRxiv: ru-196101.69363

This paper examines transient gas flow in long main pipelines after an instantaneous closure at the terminal valve, focusing on the subsequent pressure recovery and its practical use in pipeline characterization. By neglecting small inertial effects and linearizing the governing unsteady flow equati…

A Method for the Degradation of Toluene- $\mathrm{C}^{14}$ to Determine the Position of the Label in the Ring

V. A. Koptyug, I. S. Isaev, and N. N. Vorozhtsov
1961 SovietRxiv: ru-196101.69327

This paper addresses the need for a degradation method that can determine the position of carbon-14 labeling in the benzene ring of toluene, in order to study migration mechanisms in monosubstituted aromatic compounds without the perturbing influence of a second substituent. The authors propose redu…

Photoreduction and Demethylation of Thiazine Dyes on Silica Sol

Kh. L. Arvan, G. A. Korsunovskii, and S. Yu. Lebedev
1961 SovietRxiv: ru-196101.69276

This study examines the photoreduction of methylene blue, azure I, and thionine adsorbed on weakly scattering aqueous silica sols, using visible and ultraviolet absorption spectroscopy under vacuum illumination and subsequent oxidation by air or ferric ions. The experiments show that methylene blue …

Electron Microscopic Study of the Effect of Radioactive Radiation from Solids on Their Surface Structure

Academician VIKT. I. SPITSYN, L. I. ZEMLYANOVA, I. E. MIKHAILENKO,
1961 SovietRxiv: ru-196101.69094

This study examines how radioactive radiation emitted by solids affects the surface structure of potassium, magnesium, and barium sulfates and molybdenum anhydride, motivated by earlier observations of altered sorption, solubility, isotope exchange, and catalytic behavior. Using electron microscopy …

On the State of Water in the Chlorophyll Molecule

A. V. KARYAKIN, V. M. KUTORIN, and A. K. CHIBISOV
1961 SovietRxiv: ru-196101.68606

This study examines whether water is present in chlorophyll as a stoichiometrically bound component and how it interacts with chlorophyll a and b. Purified chlorophyll preparations were analyzed by infrared absorption spectroscopy in solid films and potassium bromide tablets, with spectra recorded b…

SEMIGROUPS OF ONE-TO-ONE TRANSFORMATIONS

E. G. SHUTOV
1961 SovietRxiv: ru-196101.68508

This paper studies semigroups of one-to-one transformations of an infinite set, especially the full semigroup of injective self-maps and the subsemigroup consisting of maps whose defect has the cardinality of the set. It classifies stable equivalences, normal complexes, ideals, and normal subsemigro…

On a Regularity in the Interatomic Distances of Halide Molecules of Different Groups of the Periodic Table of Elements

V. M. TATEVSKII, V. P. SPIRIDONOV, and P. A. AKISHIN
1961 SovietRxiv: ru-196101.68502

This paper examines regularities in interatomic distances for halide molecules of the form AXn, where the central atom belongs to a given group or subgroup of the periodic system and the ligand atoms are halogens. Using available gas phase structural data, the authors arrange related halides into se…

Lamb’s Problem for an Internal Source

Unknown
1961 SovietRxiv: ru-196101.68482

This paper examines Lamb’s problem for an internal source in a homogeneous isotropic elastic half-space, motivated by wave motion in soils produced by underground explosions. It represents the surface displacement field as a convolution of an arbitrary source velocity history with the response to a …

Silane Derivatives with Hydrocarbon Bridges Between Silicon Atoms. On the Polymerization of 1,1-Dimethylsilacyclopentane

V. M. VDOVIN, K. S. PUSHCHEVAYA, N. A. BELIKOVA, R. SULTANOV,
1961 SovietRxiv: ru-196101.68161

The study examines the reaction of 1,1-dimethylsilicacyclopentane with aluminum halides as an extension of previously observed organosilicon polycondensations involving hydrocarbon bridges between silicon atoms. The authors show that aluminum bromide or chloride induces vigorous polymerization throu…

Solubility of Nitrogen in Liquid Manganese

I. B. Baratashvili, V. P. Fedotov,
1961 SovietRxiv: ru-196101.68104

The study examines the solubility of nitrogen in liquid manganese, addressing discrepancies among earlier reported values and the experimental difficulties caused by manganese vaporization in hot-volume methods. The authors used a dynamic equilibrium method with nitrogen or nitrogen-hydrogen gas mix…

On the Spreading of Mercury over the Free Surface of Zinc in Connection with the Study of Adsorption-Induced Reduction in Strength

B. D. Summ, Yu. V. Goryunov, N. V. Pertsov, E. D. Shchukin
1961 SovietRxiv: ru-196101.68091

This study examines the spreading of mercury over the free surface of zinc in the absence of mechanical stress, motivated by adsorption-induced strength reduction in metals. Experiments on zinc plates and wire, with oxide formation suppressed by aqueous media, compared vertical and horizontal geomet…

Qualitative Analysis of Electrical Circuits with Finite Conductances Using the Theory of Cumulative Networks

Unknown
1961 SovietRxiv: ru-196101.67993

This paper addresses qualitative analysis of electrical circuits containing both contacts and elements of finite conductance, where the task is to determine whether conductance between nodes is zero, finite, or infinite. It models these values using the three-element algebra of Łukasiewicz with max …

Study of the Mechanism of Anodic Ozone Formation from Sulfuric Acid Solutions

V. A. LUNENOK-BURMAKINA, A. P. POTEMSKAYA, and A. I. BRODSKII
1961 SovietRxiv: ru-196101.67900

This study examines the mechanism of anodic ozone formation from sulfuric acid and bisulfate solutions, using oxygen 18 labeling to trace the sources of oxygen in ozone, anodic oxygen, water, sulfate, and added peroxy compounds. Electrolysis experiments with labeled water, labeled sulfate, concentra…

Rearrangements in the Process of Homolytic Addition of Hydrogen Bromide to Polyhaloalkenes

Corresponding Member of the Academy of Sciences of the USSR R. Kh. Freidlina, V. N. Kost, M. Ya. Khorlina
1961 SovietRxiv: ru-196101.67529

This study examines rearrangements of radicals formed during benzoyl peroxide initiated homolytic addition of hydrogen bromide to polyhaloalkenes containing dichloromethyl or dichloromethylene groups adjacent to the radical center. Addition reactions of several dichloroalkenes were carried out, prod…

Boundary Value Problem for Linear and Quasilinear Parabolic Equations

O. A. LADYZHENSKAYA and N. N. URAL’TSEVA
1961 SovietRxiv: ru-196101.67519

This paper studies boundary value problems for linear and quasilinear parabolic equations in a cylinder, focusing on generalized solutions under weak coefficient assumptions and natural growth conditions. Using integral inequalities for level sets and De Giorgi type iteration arguments, the authors …

Hydrogenation of Unsaturated Compounds under Equilibrium Conditions over Platinum-Group Catalysts

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1961 SovietRxiv: ru-196101.67425

The paper examines hydrogenation of unsaturated compounds under near equilibrium conditions achieved by slow, uniform feeding of substrate into the reaction vessel. Using sodium maleate, sodium o-nitrophenolate, and dimethylethynylcarbinol in alkaline and alcoholic media, the authors compare reactio…

CALCULATION OF THE STRUCTURE OF LAYERS IN CRYSTALS OF NICKEL DIMETHYLGLYOXIMATE ON THE BASIS OF THE THEORY OF CLOSE PACKING OF MOLECULES

Unknown
1961 SovietRxiv: ru-196101.67399

A graphical method for determining densest lattice packings of plane figures is applied to the molecular layers of nickel dimethylglyoximate, using a planar molecular model derived from standard bond lengths, angles, and intermolecular radii. The calculation considers layer cells containing one or t…

Study of the Lead Selenite–Lead Oxide System

B. A. Popovkin and A. V. Novoselova
1961 SovietRxiv: ru-196101.67384

The study examines the lead selenite, lead oxide system in order to clarify the composition and stability ranges of lead oxyselenites previously observed during oxidation and decomposition reactions. Mixtures prepared from purified lead selenite and lead oxide were equilibrated by annealing and inve…

Nuclear Magnetic Resonance Spectra of Irradiated Perfluorooctadiene and Perfluorododecadiene

N. M. POMERANTSEV, V. A. KHRAMCHENKOV, L. V. SUMIN, and A. V. ZIMIN
1961 SovietRxiv: ru-196101.67108

This study applies fluorine-19 nuclear magnetic resonance to characterize structural changes in perfluorooctadiene and perfluorododecadiene after cobalt-60 irradiation, comparing spectra with those of unirradiated samples. Chemical shifts, measured relative to trifluoroacetic acid, are used to assig…

A CONDITION FOR THE EXPANDABILITY OF FUNCTIONS IN A QUASI-POWER SERIES OUTSIDE THE FUNDAMENTAL INTERVAL

Unknown
1961 SovietRxiv: ru-196101.66991

This paper studies expansion of functions in quasi-power series on the nonfundamental interval t greater than u, contrasting this problem with earlier results for the interval (0,u]. It introduces a smoothness class defined through iterated differential operators associated with a nondecreasing sequ…

Thin-Layer Chromatography of Cerebrosides

Corresponding Member of the USSR Academy of Sciences N. K. Kochetkov, I. G. Zhukova
1961 SovietRxiv: ru-196101.66909

This study addresses the difficulty of separating and monitoring cerebroside fractions, for which paper chromatography and earlier column methods gave insufficient resolution. The authors develop thin-layer chromatography on silica gel using anhydrous chloroform and methanol systems, then apply it t…

On the determination of transition frequencies between different states of the activator molecule in organoluminophores

Unknown
1961 SovietRxiv: ru-196101.66903

This paper addresses the determination of nonradiative transition frequencies between fluorescent, phosphorescent, and normal states of activator molecules in organoluminophores, especially when quenching or temperature changes may alter these rates. Starting from a kinetic scheme with radiative and…

Logarithmic Criterion for Superconductivity

Unknown
1961 SovietRxiv: ru-196101.66850

This paper reexamines the criterion for superconductivity in the presence of both phonon-mediated attraction and Coulomb repulsion, with particular attention to the damping of one-electron excitations far from the Fermi surface. Using Bogolyubov’s formulation of the Feynman diagram technique and ass…

Structure of Surface Compounds of Carbon Monoxide on Palladium from Adsorption Measurements and Infrared Spectra

N. N. Kavtaradze, V. I. Lygin
1961 SovietRxiv: ru-196101.66551

Carbon monoxide adsorption on palladium films and palladium supported on Aerosil was studied over a wide temperature and pressure range using adsorption measurements and infrared spectroscopy. The adsorption data show rapid uptake with two coexisting components: strong irreversible adsorption, which…

On Estimating the Spectrum of a Stationary Gaussian Process

Unknown
1961 SovietRxiv: ru-196101.66496

This note studies estimation of the spectral distribution function of a real stationary Gaussian process from a finite discrete-time sample, focusing on the integrated periodogram estimator and its convergence properties. It shows that although the Lévy distance between the estimator and the true sp…

Sufficient Conditions for Optimality

V. G. Boltyanskii
1961 SovietRxiv: ru-196101.66472

This note studies time-optimal control for differential systems and addresses gaps in the justification of dynamic programming for such systems, especially when the value function is not continuously differentiable. It formulates sufficient conditions for optimality using a refined dynamic programmi…

Effect of the Concentration and Nature of Alkali on Oxygen Overvoltage at a Nickel Anode

Ya. I. Turyan and A. I. Tsinman
1961 SovietRxiv: ru-196101.66363

This study examines how hydroxide concentration and alkali cation identity affect oxygen overvoltage at a smooth nickel anode in purified KOH, NaOH, and LiOH at 25 degrees C, over current densities up to 1 A/cm². Polarization curves corrected for ohmic drop show wave-like behavior with distinct kine…

Oxidation of Diisopropylmercury

Corresponding Member of the Academy of Sciences of the USSR G. A. RAZUVAEV, G. G. PETUKHOV,
1961 SovietRxiv: ru-196101.66270

This study examines the oxidation of diisopropylmercury, a secondary organomercury compound, by atmospheric oxygen in isopropyl alcohol, carbon tetrachloride, and chloroform. Using carbon-14 labeled diisopropylmercury and labeled isopropyl alcohol, the authors show that oxidation in isopropyl alcoho…

5-Hydroxy-5-(1,3-indandion-2-yl)barbituric acid

Academician of the Academy of Sciences of the Latvian SSR G. Ya. VANAG and Yu. E. PELCHER
1961 SovietRxiv: ru-196101.66259

This paper describes the preparation and characterization of a compound combining the indandione-1,3 and barbituric acid structural motifs, motivated by the known physiological activity of indandione derivatives and their resemblance in some effects to barbiturates. After unsuccessful attempts to cy…

On Periodically Correlated Random Sequences

E. G. GLADYSHEV
1961 SovietRxiv: ru-196101.66175

The paper studies discrete random sequences whose means and covariance functions are periodic in time, and characterizes when a proposed periodic covariance representation can arise from such a sequence. By reducing the problem to the correlation matrix of a finite-dimensional stationary sequence, i…

On the Structure of Liquid Water

Unknown
1961 SovietRxiv: ru-196101.65886

This paper proposes a structural model for liquid water based on the predominance of mirror-symmetric, or cis, hydrogen bonds rather than on a disordered variant of the ice lattice. Using stereochemical constraints on bond linearity, bond length, tetrahedral angles, and maximization of cis-bonds, it…