Showing 50 of 25456 papers

Quantum Green’s Function Method in the Theory of Optical Bands in Crystals

S. V. TYABLIKOV and V. A. MOSKALENKO
1961 SovietRxiv: ru-196101.73755

This paper applies the method of quantum Green’s functions to optical multiphonon transitions in polarons and F-centers under adiabatic electron, phonon coupling. It formulates the absorption characteristic function using phonon Hamiltonians for the initial and final electronic states, including bot…

Investigation of the thermodynamic properties of cobalt antimonides by the electromotive force method

Unknown
1961 SovietRxiv: ru-196101.73676

The study determines thermodynamic properties of cobalt antimonides in the Co-Sb system, focusing on CoSb3, CoSb2, and CoSb despite known or possible deviations from stoichiometry in some phases. Electromotive-force measurements were made with cells containing cobalt, molten CoCl2-KCl-LiCl electroly…

Synthesis and Structural Study of Double Diazonium Salts of Aluminum Halides

L. A. Kazitsyna, S. V. Pasynkevich,
1961 SovietRxiv: ru-196101.73651

This paper reports the first preparation and infrared study of double aryldiazonium salts of aluminum chloride and bromide. Because conventional aqueous or alcoholic methods caused hydrolysis, the authors developed a synthesis using aluminum halide etherates, obtaining substituted aryldiazonium alum…

ON THE CONVERGENCE OF CERTAIN DIFFERENCE SCHEMES

Unknown
1961 SovietRxiv: ru-196101.73568

This note develops a direct method for proving convergence of certain difference and differential-difference schemes without invoking existence or uniqueness theorems for the limiting differential problem. The argument uses one-sided a priori estimates and comparison of solutions on successively ref…

One-dimensional adiabatic flows of an ultrarelativistic gas

Unknown
1961 SovietRxiv: ru-196101.73525

This paper develops exact treatments of one-dimensional adiabatic flows of an ultrarelativistic gas from the equations of relativistic hydrodynamics. After deriving the governing equations and characteristic relations for plane, cylindrical, and spherical symmetry, it focuses on the plane case and s…

Study of Infrared Absorption Spectra during the Curing of Resole Phenol-Formaldehyde Resin

L. A. Igonin, M. M. Mirakhmedov, K. I. Turchaninova, and A. N. Shabadash
1961 SovietRxiv: ru-196101.73522

This study investigates changes in the infrared absorption spectra of a resol phenol formaldehyde resin during curing from 20 to 200°C, using pressed KBr windows to improve reproducibility of sample thickness and spectral comparison. Spectra of uncured and cured samples show decreasing hydroxyl and …

Concentration Dependence of the Magnetic Shielding of $\mathrm{F}^{19}$ Nuclei in the $\mathrm{KHF}_2$ – $\mathrm{H}_2\mathrm{O}$ and $\mathrm{KHF}_2$ – $\mathrm{KF}$ – $\mathrm{H}_2\mathrm{O}$ Systems

Unknown
1961 SovietRxiv: ru-196101.73412

This paper examines the concentration dependence of the fluorine-19 nuclear magnetic resonance chemical shift in aqueous potassium bifluoride and potassium bifluoride, potassium fluoride systems, motivated by conflicting interpretations of shielding in hydrofluoric acid solutions. Using measured shi…

On the Motion of a Gyroscope in a Gimbal Suspension in the Presence of a Moment About the Axis of Spin

S. A. KHARLAMOV
1961 SovietRxiv: ru-196101.73280

This paper analyzes the motion of an astatic gyroscope in a gimbal suspension when resistance to proper rotation is balanced by a driving moment, so that deviations of rotor speed influence the nutational motion. Using d’Alembert’s principle, the equations of motion are derived for the outer ring, i…

A generalization of the multidimensional Bochner theorem

Unknown
1961 SovietRxiv: ru-196101.73228

This paper generalizes the multidimensional Bochner theorem for positive definite functions to positive definite generalized kernels associated with systems of differential, and more general, operators. Using Hilbert space scales, generalized eigenvector expansions, and spectral measures for self-ad…

On the Steady Flow of a Conducting Fluid Through a Rectangular Pipe in an External Magnetic Field with Two Conducting and Two Nonconducting Walls

Unknown
1961 SovietRxiv: ru-196101.73080

This note examines steady magnetohydrodynamic flow of a conducting viscous incompressible liquid through a rectangular pipe in a uniform transverse magnetic field, for the boundary configuration in which the walls parallel to the field are ideally conducting and the perpendicular walls are nonconduc…

Study of the Magnetic Susceptibility of Polyalkanopolyferrocenes and Polyferrocenylene

A. N. Nesmeyanov, A. M. Rubinshtein, G. L. Slonimskii, A. A. Slinkin, N. S. Kochetkova, and R. B. Materikova
1961 SovietRxiv: ru-196101.73051

This study examines the magnetic susceptibility of polyalkanopolyferrocenes and polyferrocenylenes in relation to the spacing and bonding of ferrocene residues in polymer molecules. Static susceptibility was measured for solid polymers by the Faraday method and for benzene solutions by the Gouy meth…

ON SOME SPACES WITH AFFINE CONNECTION ADMITTING MOTIONS

Unknown
1961 SovietRxiv: ru-196101.72922

This paper studies spaces with affine connection that admit simply transitive or Abelian groups of affine collineations, with particular attention to torsion-free connections and their extensions. It derives the general form of a torsion-free affine connection admitting a simply transitive group of …

Extraction of Long Waves in Hydrodynamic Forecasting of Pressure Fields in the Middle and Upper Troposphere over the Northern Hemisphere

M. B. GALIN
1961 SovietRxiv: ru-196101.72855

This paper examines long-range hydrodynamic forecasting of pressure fields in the middle and upper troposphere over the Northern Hemisphere using a linearized two-level atmospheric model for the 700 and 300 millibar isobaric surfaces. The method expands initial absolute topography fields in spherica…

Spaces of Functions Analytic in $(p,q)$-Circular Domains

L. A. AIZENBERG
1961 SovietRxiv: ru-196101.72744

The paper studies spaces of functions analytic in bounded complete circular domains in two complex variables, more specifically \((p,q)\)-circular domains containing the origin. It constructs polynomial bases homogeneous with respect to \(w^{1/p}\) and \(z^{1/q}\), proves a convergence criterion for…

On the embedding in $E^4$ of certain monotone images of $E^3$

Lyudmila KELDYSH
1961 SovietRxiv: ru-196101.72545

This paper gives a sufficient criterion for embedding certain monotone images of three-dimensional Euclidean space in four-dimensional Euclidean space. It considers continuous decompositions of Euclidean 3-space into points and smooth continua whose nondegenerate elements have zero-dimensional compa…

Alkylation of tetrahydrofuran with ethylene

N. I. Shuikin and B. L. Lebedev
1961 SovietRxiv: ru-196101.72464

This paper reports the thermal alkylation of tetrahydrofuran with ethylene at elevated temperature and pressure, addressing an unexplored extension of alkane alkylation to saturated oxygen-containing rings. Experiments in a rotating autoclave examined the effects of temperature, reaction time, and e…

Potential functions of molecules of the $(\mathrm{CH}_3)_n\mathrm{SiCl}_{4-n}$ series ( $n=1-4$ )

I. F. KOVALEV
1961 SovietRxiv: ru-196101.72436

This paper investigates the potential functions of the methylchlorosilane series (CH3)nSiCl4-n, for n from 1 to 4, a set for which detailed force field analysis had previously been limited. Using published infrared and Raman spectra, together with earlier results for methylsilanes, the author calcul…

Experimental determination of the enthalpy of molybdenum at temperatures $700-2337^\circ$

Corresponding Member of the Academy of Sciences of the USSR V. A. KIRILLIN, A. E. SHEINDLIN
1961 SovietRxiv: ru-196101.71837

This paper reports experimental measurements of the enthalpy of molybdenum from about 700 to 2337 degrees Celsius, extending available data for this refractory metal beyond the previously studied range. The authors used a mixture-method calorimetric apparatus with a massive calorimeter and isotherma…

On Equations of Parabolic Type in a Banach Space with an Unbounded Variable Operator Whose Fractional Power Has a Constant Domain of Definition

P. E. SOBOLEVSKII
1961 SovietRxiv: ru-196101.71811

The paper extends earlier results on parabolic equations to Banach spaces for time dependent unbounded operators whose fractional powers satisfy uniform domain and continuity conditions. It proves existence of an evolution operator for the homogeneous problem, including semigroup composition, differ…

On the Quasi-Stationary Theory of Thermal Explosion

Unknown
1961 SovietRxiv: ru-196101.71749

This paper extends the quasi-stationary theory of thermal explosion to forced dynamic regimes in which the ambient temperature rises linearly with time, rather than remaining constant or changing through reaction self-acceleration. Starting from heat balance and conversion equations, the analysis fo…

Synthesis of $\alpha$-furylnitroethylene and study of its ability to polymerize

A. V. TOPCHIEV, V. P. ALANIYA, and V. A. SOPRANO
1961 SovietRxiv: ru-196101.71726

This study examines the synthesis of alpha-furylnitroethylene and its capacity to form heterocyclic nitro-containing polymers, a class described as insufficiently investigated. The monomer was prepared by condensation of furfural with nitromethane in the presence of an anion-exchange resin, giving y…

On the stability of solutions of second-order equations

A. Yu. LEVIN
1961 SovietRxiv: ru-196101.71508

This paper studies stability and asymptotic stability of solutions of second order ordinary differential equations, with emphasis on linear equations with variable coefficients. It first proves comparison theorems and derives amplitude estimates for solutions, then applies these estimates to the lin…

The Simplest Model of Halos

D. O. MOKHNACH
1961 SovietRxiv: ru-196101.71430

This paper develops a simple model for cometary halos as thin spherical layers produced by a short, isotropic ejection of particles from a point source under an approximately constant solar repulsive acceleration. It derives expressions for the projected particle density, locates the maximum apparen…

Homolytic isomerization of 2-bromo-3,3-dichlorobut-1-ene

M. Ya. Khorlina and V. N. Kost
1961 SovietRxiv: ru-196101.71404

This paper investigates the isomerization behavior of 2-bromo-3,3-dichlorobutene-1, prepared from 1-bromo-3,3-dichlorobutane through dehydrobromination, bromination, and further elimination. The compound is shown to isomerize on standing or under ultraviolet irradiation to 1-bromo-2,3-dichlorobutene…

Angular distribution of sputtered particles during irradiation of a single crystal with an ion beam

V. A. MOLCHANOV, V. G. TELKOVSKII, and V. M. CHICHEROV
1961 SovietRxiv: ru-196101.71325

This study examines the angular distribution of atoms sputtered from single-crystal copper under ion bombardment, focusing on the formation of characteristic Wehner, or Venus, spots along crystallographic directions. Using an argon ion beam and x-ray film collectors placed at varying distances, the …

Chemical Reactions in Chromatographic Mode

S. Z. ROGINSKII, M. I. YANOVSKII, and G. A. GAZIEV
1961 SovietRxiv: ru-196101.71285

This paper examines chemical reactions carried out in a chromatographic regime, where differential distribution of reactants, products, or impurities between phases causes their separation during flow through a reactor. Using a pulse introduction model and assuming mass exchange is faster than react…

Some Observations on the Crystallization of Beryllium Oxide from the Gas Phase

P. P. BUDNIKOV and N. V. SHISHKOV
1961 SovietRxiv: ru-196101.70892

This paper reports observations on the crystallization of beryllium oxide from the gas phase at temperatures of 1600 to 1900°C in an argon atmosphere using compact polycrystalline BeO in a graphite resistance furnace. The authors describe the formation of plate, rod, prism, dendritic, and whisker-li…

Effect of Various Types of Radiation on the Catalytic Dehydration of n-Decyl Alcohol

Academician Vikt. I. SPITSYN, ION MAXIM, G. N. PIROGOVA,
1961 SovietRxiv: ru-196101.70832

This study compares the effects of several forms of radiation on the catalytic dehydration of n-decyl alcohol over high-purity aluminum oxide. Alumina catalysts were irradiated in a reactor with neutrons and gamma rays for different durations, modified by introducing radioactive cerium-144 chloride …

Resistance of Polymeric Plastics to Cavitation Erosion

Unknown
1961 SovietRxiv: ru-196101.70666

This paper examines the resistance of selected polymer plastics to cavitation erosion, a property for which comparative data were lacking in contrast to established scales for metals. Experiments were conducted in a hydrodynamic tube under controlled cavitation conditions using plate and cylindrical…

Interaction of Some Rare-Earth Elements with Dibutyl Phosphate and Their Extraction Separation

E. E. Kriss and Z. A. Sheka
1961 SovietRxiv: ru-196101.70505

This study examines the interaction of selected rare-earth elements with dibutyl phosphate and evaluates its use for extractive separation. Using distribution measurements, fractional extraction, isolation and analysis of solid compounds, solubility experiments in carbon tetrachloride, conductivity …

STUDY OF PLASTIC DEFORMATION OF A METAL WITH DEFORMATION ANISOTROPY CREATED IN THE PROCESS OF PRELIMINARY LOADING

Unknown
1961 SovietRxiv: ru-196101.70351

This paper investigates the initial stages of secondary plastic deformation in metals whose deformation anisotropy is produced by prior plastic loading and subsequent partial or complete unloading. Using combined tension and torsion tests on thin-walled tubular specimens of technically pure nickel, …

Effect of Radioactive Radiation from $\mathrm{Y}^{90}$ and $\mathrm{Y}^{91}$ on the Solubility of Yttrium Hydroxide

---------
1961 SovietRxiv: ru-196101.70277

This study examines how beta radiation from yttrium isotopes affects the dissolution and apparent solubility of yttrium oxide, which hydrates in water to yttrium hydroxide. Radioactive yttrium oxide preparations containing Y-90 or Y-91 over a range of specific activities were prepared under identica…

On the expansion in eigenfunctions of a non-self-adjoint system of second-order differential equations

Unknown
1961 SovietRxiv: ru-196101.70210

The paper studies expansions in eigenfunctions for a nonselfadjoint second order system of differential equations on the half-line in the space of vector-valued square integrable functions, with a matrix potential and a boundary condition at the origin. Using matrix solutions with prescribed asympto…

APPROXIMATE EQUATIONS OF THE COUPLED OSCILLATIONS OF WATER AND A VESSEL IN THE CHAMBERS OF TRANSPORT SHIP LIFTS AND LOCKS

Unknown
1961 SovietRxiv: ru-196101.70152

This paper develops approximate equations for the coupled oscillations of water and a vessel in the chambers of transport ship lifts and locks. Using linearized long wave theory, it formulates water motion together with equations for the vessel’s vertical and longitudinal pitching oscillations, incl…