Showing 50 of 25456 papers

Equilibrium in the $\mathrm{V}_2\mathrm{C}$ – $\mathrm{H }_2$ – $\mathrm{CH}_4$ – $\mathrm{V}$ System

Unknown
1960 SovietRxiv: ru-196001.98707

This study addresses the limited and uncertain thermodynamic data for transition metal carbides by measuring the equilibrium involving vanadium, hydrogen, methane, and vanadium carbide close to the composition V2C. The authors determined the equilibrium constant for the reaction V2C + 2H2 = CH4 + 2V…

Investigation of the Catalytic Decomposition of Hydrazine on Nickel Sulfide and Its Solid Solutions

HUANG Yu-Mei, N. P. KEIER, and Corresponding Member of the Academy of Sciences of the USSR S. Z. ROGINSKY
1960 SovietRxiv: ru-196001.98534

This study examines the catalytic decomposition of hydrazine on nickel sulfide and on solid solutions of nickel sulfide containing small additions of lithium or indium sulfides, with comparison to analogous nickel oxide systems. The authors prepared and characterized the sulfide catalysts by X-ray a…

Radiation Measurements During the Flight of the Second Space Rocket

Corresponding Member of the Academy of Sciences of the USSR S. N. VERNOV, A. E. CHUDAKOV, P. V. VAKULOV,
1960 SovietRxiv: ru-196001.98199

This paper reports preliminary radiation measurements from the second Soviet cosmic rocket, launched toward the Moon in September 1959, using gas-discharge and scintillation counters mounted both inside and outside the spacecraft container. The data are used to compare the Earth’s outer radiation be…

Linear partially ordered topological space

S. N. SLUGIN
1960 SovietRxiv: ru-196001.98025

The paper introduces linear partially ordered topological spaces, defined as linear lattices equipped with a topology having a monotone neighborhood basis, thereby generalizing partially ordered Banach spaces without requiring bounds for infinite bounded sets. It establishes basic structural and con…

On the Measurement of Energy Losses by Plasma

Yu. G. PROKHOROV
1960 SovietRxiv: ru-196001.97964

The paper describes an optical radiation detector for measuring energy losses from plasma to the wall of a toroidal discharge chamber in a strong longitudinal magnetic field. A heated platinum foil coupled by a light guide to a photomultiplier was calibrated by capacitor discharge and used to record…

Complexes in the series of aromatic organozinc compounds of the $\mathrm{ArZnX}$ class

N. I. Sheverdina, L. V. Abramova
1960 SovietRxiv: ru-196001.97871

This paper examines mixed aromatic organozinc compounds of the type ArZnX, whose preparation had been complicated by the use of Grignard reagents and associated magnesium salts. The authors describe syntheses based on disproportionation of diarylzinc compounds with zinc halides in dry ether, followe…

On the Number of $3d$ Electrons in Transition Metals

F. M. GAL’PERIN
1960 SovietRxiv: ru-196001.97804

This paper examines the relation between crystal structure and the number of 3d electrons in transition-metal atoms in the solid state, following x-ray studies that indicated different electronic configurations for close-packed and body-centered cubic metals. It proposes a simple formula for the tot…

On the Measurement of the Condensation Coefficient

R. Ya. KUCHEROV and L. E. RIKENGLAZ
1960 SovietRxiv: ru-196001.97643

This paper examines the measurement of the condensation coefficient in evaporation and condensation experiments, focusing on limitations of the Hertz-Knudsen formula commonly used at higher vapor pressures. The authors argue that this formula is valid only in the limiting case of a small condensatio…

Approximate Solution of a System of Ordinary Differential Equations with a Small Parameter at the Derivatives

Academician **L. S. Pontryagin** and **L. V. Rodygin
1960 SovietRxiv: ru-196001.97451

This paper studies singularly perturbed systems of ordinary differential equations in which the fast subsystem, for each value of the slow variable, has a unique rough stable limit cycle. The authors formulate an averaged equation for the slow variables by integrating the slow vector field over the …

Catalytic Transformations of Alcohols and Cyclic Hydrocarbons on Titanium Dioxide

A. A. TOLSTOPYATOVA, A. A. BALANDIN, and I. R. KONENKO
1960 SovietRxiv: ru-196001.97426

This study examines the catalytic behavior of titanium dioxide prepared by several methods in the conversion of alcohols and cyclic hydrocarbons, including dehydrogenation, dehydration, isomerization, and related transformations. Using a differential thermocouple combined with chemical analysis, the…

Dehydrogenation of Five-Membered Cyclenes in the Presence of Activated Carbon

N. I. Shuikin and T. I. Naryshkina
1960 SovietRxiv: ru-196001.97392

This study examines the catalytic behavior of several activated carbons in the dehydrogenation of five-membered cyclenes under elevated temperature and reduced pressure. Cyclopentene and 1-methylcyclopentene-1 were passed over birch activated carbon, fine-grained BAU carbon, and bone charcoal at 450…

Boundedness of Singular Integrals in Orlicz Spaces

I. B. SIMONENKO
1960 SovietRxiv: ru-196001.97358

This paper proves boundedness of a class of singular integral operators on Orlicz spaces over a bounded measurable domain. The kernel is assumed to satisfy cancellation, continuity, a Dini-type modulus condition in the angular variable, and Hölder continuity in the spatial variable, while the defini…

Reaction of Fluoroolefins with Hydrazoic Acid and Rearrangement of Perfluoroalkenyl Azides

I. L. KNUNYANTS and E. G. BYKHOVSKAYA
1960 SovietRxiv: ru-196001.97171

This paper examines the reaction of perfluoroolefins with hydrazoic acid and azide salts, focusing on the competition between addition to the double bond and vinylic fluorine substitution. Experiments with perfluoropropylene and perfluoroisobutylene in alcoholic and nonpolar media show formation of …

On a Multidimensional Integral Equation on a Half-Space with a Kernel Depending on the Difference of the Arguments and Its Discrete Analogue

L. S. GOLDENSHTEIN and I. Ts. GOKHBERG
1960 SovietRxiv: ru-196001.97107

This note studies multidimensional convolution integral equations on a half-space and corresponding lattice difference equations, with data in standard Banach spaces of functions or sequences. For the continuous equation, the authors use a Wiener type factorization of the Fourier transform under a n…

On the Theory of Superconductivity

Unknown
1960 SovietRxiv: ru-196001.97027

This paper applies the method of two-time temperature Green functions to the thermodynamics of the superconducting state for the Frohlich electron-phonon Hamiltonian. By decoupling higher-order Green functions while allowing anomalous pair averages, it derives coupled equations for normal and anomal…

The Influence of Hydrocarbon Structure on Their Solubilization in Solutions of Sodium Soaps of Saturated Fatty Acids

Unknown
1960 SovietRxiv: ru-196001.96859

This study examines how hydrocarbon structure affects colloidal solubilization in 0.1 M aqueous solutions of sodium soaps of saturated fatty acids from caprylate to stearate. Using a direct experimental method, the authors compare limiting solubilization of aromatic and aliphatic hydrocarbons and re…

On approximation on sets of analytic capacity zero

Unknown
1960 SovietRxiv: ru-196001.96634

This paper studies approximation near the boundary of a domain whose boundary has analytic capacity zero. Using dual extremal formulations for analytic capacity and function-space duality, it proves criteria relating zero analytic capacity to approximation in boundary integrals by functions in Hardy…

ON THE PHENOMENON OF EJECTION BY AN ELECTRIC DISCHARGE

§ 1. The equations of magnetic hydrodynamics for the case of a plane discharge in an incompressible medium have the form
1960 SovietRxiv: ru-196001.96626

This paper develops a magnetohydrodynamic treatment of electric discharge in a conducting medium, focusing on stationary plane and axisymmetric discharges in an incompressible fluid. It shows that, unlike the plane case, a finite axisymmetric discharge cannot remain hydrostatic and must induce motio…

On the Indefinite \(A\)-Integral

Unknown
1960 SovietRxiv: ru-196001.96558

The paper studies the indefinite form of the \(A\)-integral, defined through truncated Lebesgue integrals under a tail condition, and compares it with improper Lebesgue and Denjoy integration. It shows that existence of definite \(A\)-integrals on intervals does not generally yield well behaved inde…

PS-isomorphism of an ordered group

K. M. KUTYEV
1960 SovietRxiv: ru-196001.96508

This paper studies PS-isomorphisms, isomorphisms between the lattices or structures of subsemigroups, for torsion-free and ordered groups. It develops a sequence of lemmas on separable elements, isolated normal divisors, semi-Dedekind subsemigroups, and proper PS-isomorphisms, using these to show th…

On the Interaction of Some Arylated Ethylenic Hydrocarbons with Iodine Monochloride and on the Pinacolone-Type Rearrangement of Their 1-Iodo-2-Methoxy Derivatives

Unknown
1960 SovietRxiv: ru-196001.96413

This study examines the reactions of iodine chloride with several arylated ethylenic hydrocarbons, especially diphenyl- and tolyl-substituted ethenes and propenes, to clarify whether the observed chlorinated products reflect abnormal addition or subsequent substitution and elimination processes. On …

Studies in the series of derivatives of phosphinic and phosphinous acids. Synthesis and properties of dibutyl allylphosphonite

Unknown
1960 SovietRxiv: ru-196001.96379

This paper reports the synthesis and characterization of the dibutyl ester of allylphosphonous acid, an unsaturated phosphonous acid ester previously little studied. The compound was prepared by reacting allylmagnesium bromide with dibutyl chlorophosphite in dry ether at low temperature under nitrog…

On the Theory of Locally Stable Groups of Automorphisms

Unknown
1960 SovietRxiv: ru-196001.96358

This paper studies when local stability, an external condition on a group of automorphisms, implies local nilpotency of the automorphism group itself. After formulating stability and local stability for automorphism groups, the authors prove that every finitely stable group of automorphisms of a fre…

ON THE EXISTENCE OF APERIODIC FLOWS WITH A FREE BOUNDARY

The motion is assumed to be plane, steady, and irrotational; the liquid is ideal and incompressible.
1960 SovietRxiv: ru-196001.96339

This paper studies plane, steady, irrotational flows of an ideal incompressible liquid with a free boundary having horizontal asymptotes, focusing on flow over a locally uneven bottom and on solitary waves. The free-boundary problem is transformed by conformal mapping to an infinite strip and reduce…

Investigation of normal paraffins in the gasoline fraction of the Chinese karamaia petroleum

Academician A. V. TOPCHIEV, GU QI-WEI, and I. A. MUSAEV
1960 SovietRxiv: ru-196001.96327

This study examines the normal paraffin hydrocarbons in the 175 to 300°C kerosene fraction of Karamai petroleum from China, motivated by their potential use as feedstocks for organic synthesis. The kerosene fraction was prepared by removal of gasoline, deasphalting, deresining, vacuum distillation, …

Structure of the Electrostatic Field in the Free Atmosphere Based on Research Data from the International Geophysical Year

Unknown
1960 SovietRxiv: ru-196001.96295

This paper examines the vertical structure of the atmospheric electrostatic field using aircraft soundings carried out in Leningrad, Kiev, and Tashkent during the International Geophysical Year and International Geophysical Cooperation. Measurements of field strength with height were integrated to e…

Azobenzene as a Hydride Hydrogen Acceptor

Unknown
1960 SovietRxiv: ru-196001.96168

This paper investigates the acid-catalyzed reactions of azobenzene with a range of organic compounds and relates them to reductions observed in reactions of phenyldiazonium borofluoride in ketones. Experiments with sulfuric acid and other strong acids show that azobenzene is converted chiefly into b…

On the Relationship Between the Electrical Conductivity and Work Function of Modified Zinc Oxide

V. I. VLADIMIROVA, E. Kh. ENIKEEV, G. M. ZHABROVA, and L. Ya. MARGOLIS
1960 SovietRxiv: ru-196001.96164

This study examines whether electrical conductivity measurements reliably indicate shifts in the surface Fermi level of modified zinc oxide, a question relevant to interpreting semiconductor catalyst behavior. The authors constructed an apparatus for simultaneous measurement of electrical conductivi…

CONDITION FOR THE STABILITY OF A PLANE INTERFACE BETWEEN SOLID AND LIQUID PHASES DURING CRYSTALLIZATION OF A BINARY ALLOY

Unknown
1960 SovietRxiv: ru-196001.96104

This paper derives a stability condition for a planar solid-liquid interface during steady crystallization of a binary alloy, treating instability as the accelerated growth of a small hemispherical protrusion on the front. By solving approximate heat and solute diffusion problems in a moving frame, …

Free-radical addition of alkylbenzenes to $\alpha$ -olefins

Unknown
1960 SovietRxiv: ru-196001.96098

This study examines whether free-radical addition and telomerization can be used to synthesize alkylaromatic hydrocarbons relevant to alkylbenzenesulfonate surfactants. Using tert-butyl peroxide as initiator, toluene, ethylbenzene, cumene, p-xylene, and alpha-methylnaphthalene were reacted with alph…

Heats of wetting of Aerosil by aliphatic alcohols

V. F. Kiselev, K. G. Krasil'nikov, V. V. Murina
1960 SovietRxiv: ru-196001.96077

This study examines how the surface hydration of nonporous silica Aerosil affects its heats of wetting by a homologous series of aliphatic alcohols. Aerosil samples were calcined at different temperatures to vary structural water content, their surface areas were measured by nitrogen adsorption, and…

Effect of Tunneling Transitions on the Line Shape of the Nuclear Magnetic Resonance Signal in Crystals

Unknown
1960 SovietRxiv: ru-196001.96054

This paper analyzes how tunneling reorientation of a pair of magnetically equivalent spin one half nuclei affects the line shape of a nuclear magnetic resonance signal in a crystal. A quantum mechanical model is formulated for two nuclei moving between two equivalent potential minima, with the secul…

Relative Yield and Energy Distribution of Photodeuterons from Copper

Academician of the Academy of Sciences of the Ukrainian SSR A. P. KOMAR, E. D. MAKHNOVSKII, and V. P. PODDUBNOV
1960 SovietRxiv: ru-196001.95986

This study measured the relative yield of photodeuterons and photoprotons from copper, together with the energy distribution of emitted deuterons, under irradiation by bremsstrahlung gamma rays with a maximum energy of 70 MeV. Particles emitted at forward angles were recorded in nuclear emulsions pl…

Existence Theorems for Nonlinear Mixed Problems

Yu. I. NEIMARK and V. N. GOLDBERG
1960 SovietRxiv: ru-196001.95936

This paper establishes existence results for nonlinear mixed initial boundary value problems for second order hyperbolic and parabolic equations in a strip, with nonlinear boundary conditions depending on boundary traces of derivatives and on a parameter. Under smoothness, Lipschitz, nondegeneracy, …

Conjugate Manifolds and Their Applications

S. E. Karapetyan
1960 SovietRxiv: ru-196001.95934

This paper develops the notion of conjugate manifolds on the Klein quadric representing lines of projective three-space and relates it to asymptotic manifolds defined by higher order contact with tangent hyperplanes. Using Cartan’s exterior forms and Grassmann products, the author applies this frame…

Study of the Packing Density of Macromolecules in Various Cellulose Preparations

V. I. SHARKOV and V. P. LEVANOVA
1960 SovietRxiv: ru-196001.95914

This study examines the packing density of macromolecules in cellulose preparations by measuring true specific gravity, proposed as a more direct indicator than adsorption, wetting, or reactivity methods. Using a modified Hermans suspension method, the authors measured dried cellulose samples before…