Showing 50 of 25357 papers

Features of Solving Accelerator Technology Problems on Analog Computers

V. A. KOCHEGUROV, B. A. RYZHKOV, N. V. TRIKHANOVA, V. P. IVANCHENKOV
1974 SovietRxiv: ru-197401.12493

This paper discusses the use of analog computers for accelerator engineering calculations involving charged-particle trajectories in nonlinear, time-dependent electromagnetic fields. It presents modeling and programming features through examples including electron motion in a microtron, extraction o…

Studies of the Motion of Charged Particles in a Cyclotron Using an Analog Computer

A. A. KOMOV, B. A. RYZHKOV, N. V. TRIKHANOVA, S. N. YUZHAKOVA
1974 SovietRxiv: ru-197401.12492

This paper examines the calculation of charged-particle trajectories in the central region of a cyclotron as a means of improving the energy monochromaticity of extracted ion beams. It formulates the ion motion in and outside the accelerating gap as systems of differential equations and describes th…

Investigation Using an Analog Computer of the Focusing of an Intense Electron Beam by Quadrupole Fields

N. V. TRIKHANOVA, L. V. PILGER, P. M. SHCHANIN
1974 SovietRxiv: ru-197401.12491

The study examines whether quadrupole magnetic fields can focus high-current electron beams when space-charge repulsion must be included. Beam-envelope equations for parallel beams were solved on analog computers for systems made from straight current-carrying quadrupole conductors and for a helical…

Photometric determination of small amounts of titanium in high-purity iron

L. L. Skripova, G. A. Chervenchuk
1974 SovietRxiv: ru-197401.12061

This paper examines photometric determination of trace titanium in high-purity iron using diantipyrylmethane, addressing interference from ferric iron coloration and complex formation. Three analytical variants are developed and compared: extraction-based preliminary separation of iron, direct deter…

Sorption-photometric method for the determination of trace titanium in an alcohol-water medium

R. D. Glukhovskaya, Yu. L. Lel’chuk, L. L. Skripnova
1974 SovietRxiv: ru-197401.12060

This study examines the sorption of titanium on the KU-2 cation exchanger in aqueous and aqueous alcohol media in order to enable trace determination where organic solvent is present. Distribution coefficients were measured under static and dynamic conditions at different hydrochloric acid concentra…

Photometric Determination of Aluminum with Xylenol Orange in High-Purity Iron

V. B. Sokolovich, V. A. Malevannyi, Yu. L. Lelchuk
1974 SovietRxiv: ru-197401.12059

A photometric procedure is described for determining trace aluminum in high-purity iron using xylenol orange, selected for its high sensitivity in aluminum complex formation. The method dissolves the iron sample in hydrochloric acid, oxidizes and extracts iron as chloride complexes with diethyl ethe…

Determination of Free Ammonia, Ammonium Carbonate, and Total Ammonia Content in the Presence of Nitrite and Nitrate Ions

E. A. GUBER, G. A. CHERVENCHUK, Yu. L. LELCHUK
1974 SovietRxiv: ru-197401.12058

This paper addresses the analytical determination of free ammonia, ammonium carbonate, and total ammonium content in industrial solutions containing ammonium hydroxide, ammonium carbonate, ammonium nitrite, and ammonium nitrate, where conventional titrimetric methods are hindered by indicator instab…

Quantitative determination of tellurium by reduction with galactose

E. S. NOVIKOVA, T. S. GURNITSKAYA
1974 SovietRxiv: ru-197401.12057

This paper addresses the quantitative determination of tellurium and the difficulty of separating tellurium from selenium in conventional gravimetric and volumetric procedures. It compares the reducing action of several organic compounds on tellurite and selenite ions in alkaline solution, followed …

On the Calculation of Heat Exchanger Dynamics

A. F. Fedorov, P. A. Andriyanov
1974 SovietRxiv: ru-197401.12056

This paper examines how variations in heat exchanger load affect the coefficients in a dynamic model whose parameters depend on the heat transfer coefficient and flow velocity. Using a coil heat exchanger as an example, the authors compare time characteristics calculated for several flow rates in bo…

On Clinker Formation Processes in Mixtures Based on Nepheline Sludge

V. A. BUTKEVICH, N. S. DUBOVSKAYA
1974 SovietRxiv: ru-197401.12054

This study examines clinker formation in cement raw mixes using nepheline sludge from the Uzhur deposit as the clay component. Limestone and sludge mixtures with saturation coefficients from 0.64 to 0.95 were fired with two-hour holds, and the products were analyzed for loss on ignition, free calciu…

On the possibility of using products of zircon interaction with calcium carbonate in the production of capacitor ceramics

P. G. Usov, E. P. Solomatina
1974 SovietRxiv: ru-197401.12053

This study examines whether products formed by the reaction of zircon concentrate with calcium carbonate can be used as crystalline components in capacitor ceramics. Using thermodynamic calculations, high-temperature X-ray analysis, chemical kinetic treatment, and microscopy, the authors analyze pha…

Kinetics of Improvement of the Structure of Magnesium Metasilicate Formed as a Result of Talc Decomposition

P. G. Usov, N. V. Sobora
1974 SovietRxiv: ru-197401.12052

This study examines the ordering kinetics of protoenstatite, the magnesium metasilicate phase formed during thermal decomposition of talc, because structural defects in this phase influence dielectric losses in steatite ceramics. Pressed samples from two talc deposits were fired between 1200 and 138…

Influence of Colloids on the Technological Properties of Loams

P. G. Usov, N. F. Voronova, E. A. Guber
1974 SovietRxiv: ru-197401.12051

This paper examines how colloidal components in Tomsk Region loams affect properties important for red construction brick production. Colloids were removed from loam samples either chemically, using 0.5 N hydrochloric acid, or physically, by repeated decantation of fine clay suspensions, and the tre…

Overfiring of barium steatite ceramic products and its causes

P. G. Usov, V. I. Vereshchagin
1974 SovietRxiv: ru-197401.12050

This paper examines overfiring in barium steatite ceramic products, a defect that narrows the firing interval and causes swelling, pore expansion, reduced density, and deterioration of mechanical and electrical properties. The authors analyze possible sources of gas formation during firing and argue…

Effect of Calcium Impurities on the Properties of Steatite Ceramics

P. G. Usov, V. I. Vereshchagin
1974 SovietRxiv: ru-197401.12049

This paper examines how calcium impurities affect steatite ceramics, with particular attention to the stability of magnesium metasilicate phases that influence aging of dielectric products. Talc specimens and steatite bodies with varying calcium oxide contents were fired and analyzed by X-ray diffra…

Effect of the Dispersity of Magnesium Metasilicate Crystals on the Stabilization of Protoenstatite

P. G. Usov, V. N. Gurina
1974 SovietRxiv: ru-197401.12048

This study examines how crystal size affects polymorphic transformations of magnesium metasilicate relevant to the aging of steatite ceramics. Clinoenstatite fractions of different particle sizes were synthesized, dispersed, and analyzed by differential thermal analysis and high-temperature X-ray ph…

Effect of Polyacrylonitrile Additive on the Filtration Properties of an Asbestos-Cement Suspension

S. L. BABENKO, V. M. VITYUGIN, A. P. VEROZHSKII, N. S. DUBOVSKAYA
1974 SovietRxiv: ru-197401.12047

This study examines polyacrylonitrile as a flocculating additive for improving the filtration properties of asbestos-cement suspensions used in product forming. Using Portland cement and an industrial asbestos mixture, the authors compare polyacrylonitrile with polyacrylamide through tests of cement…

Treatment of Wastewater from the Kemerovo Coke-Chemical Plant for Oil Removal by Flotation Using Cationic Surfactants

S. A. BABENKO, L. F. PROSEKOVA, O. I. POPOVA
1974 SovietRxiv: ru-197401.12046

This study addresses the need for preliminary oil removal from wastewater at the Kemerovo Coke-Chemical Plant before biological phenol treatment, especially in view of planned dry coke quenching and discharge requirements. Laboratory flotation experiments were conducted on wastewater containing abou…

Studies on the Treatment of Wastewater from Coke Chemical Plants to Remove Phenols and Oils Using Lignin-Based Sorbents

S. A. BABENKO, L. F. PROSEKOVA, V. P. ZHUCHKOV, L. A. PERSHINA
1974 SovietRxiv: ru-197401.12045

This study evaluates a lignin-based sorbent for removing phenols and oils from wastewater from the Kemerovo Coke-Chemical Plant, addressing the lack of inexpensive sorbents capable of simultaneously extracting dissolved organic contaminants over varied conditions. Static experiments examined sorbent…

Decomposition of Spent Emulsions Used for Drawing Copper Wire

S. A. Babenko, N. T. Bolotkina
1974 SovietRxiv: ru-197401.12043

This paper investigates methods for decomposing spent oil in water emulsions used in copper wire drawing, with the aim of recovering oil and copper from waste streams. The authors compare demulsifier ANP, copper sulfate, alkali treatment, and sulfuric acid, examining their effects on separation of c…

Study of the Effect of Humic Acids and Insoluble Humates on the Compaction and Strengthening of Granules

A. F. KARPOVICH, V. M. VITYUTIN
1974 SovietRxiv: ru-197401.12040

This study examines how humic acids and insoluble calcium, iron, and aluminum humates affect the agglomeration, compaction, and strength of marshallite granules. Humic substances prepared from peat were mixed directly with the material before granulation on a laboratory pan granulator, and the densi…

Pelletizing of Ferruginous Sludge Waste from Aniline Dye Production

V. M. VITUGIN, A. S. BOGMA, V. V. SHVETSOV
1974 SovietRxiv: ru-197401.12039

This paper examines the pelletizing of ferruginous sludge waste from aniline production at the Kemerovo Aniline-Dye Plant, a highly dispersed magnetite-rich material unsuitable for direct use in layered metallurgical processes because of poor gas permeability. The authors characterize the sludge com…

On Some Features of Determining the Agglomerability Index of Disperse Materials Containing Water-Soluble Components

V. M. Vityugin, L. G. Lotova, L. N. Serdyuk
1974 SovietRxiv: ru-197401.12038

This paper examines why standard moisture-capacity methods can give erroneous agglomerability indices for disperse materials containing substantial water-soluble components. Using a high-boron glass batch as an example, the authors compare conventional thermal drying with low-temperature isothermal …

Granulation of Powdered Concentrated Phosphorus Fertilizers

V. M. VITYUTIN, V. A. TROFIMOV, T. G. LEONTYEVA, V. V. TIKHONOV
1974 SovietRxiv: ru-197401.12037

This paper evaluates the granulation behavior of a newly synthesized concentrated phosphate fertilizer composed mainly of calcium, magnesium, iron, and aluminum metaphosphates with calcium pyrophosphate. Using moisture capacity measurements, the authors calculate a lump-forming index of 0.9 and an o…

On the Issue of Improving the Technology for Forming Catalyst Supports

V. M. Vitogin, I. I. Lozbina, V. P. Koshintsev, E. P. Vole
1974 SovietRxiv: ru-197401.12036

This paper examines the replacement of conventional extrusion-based forming of catalyst supports with wet granulation on an inclined pan granulator, followed by drying and calcination in fluidized-bed reactors. Using alumina-based GIAP-3 and zinc oxide-based 481-Zn supports, the authors determine mo…

Ways to Improve the Production Technology of Artificial Corundum Abrasive Materials

V. M. Vityugin, V. V. Karlin, V. A. Lyutov, I. P. Chashchin
1974 SovietRxiv: ru-197401.12035

This paper addresses limitations in conventional electrofused corundum production for rough grinding wheels, including high energy use, batch operation, raw material sensitivity, dust losses, and weakening of grains during crushing. It proposes a calibrated abrasive grain technology based on wet gri…

Improving the Grade of Ammonium Sulfate Using Microadditives of Chromium Ion

V. M. Vityugin, I. N. Nozhkina, L. M. Zhitkova
1974 SovietRxiv: ru-197401.12034

This paper examines the use of chromium ion microadditives to improve the granulometric composition and crystal habit of ammonium sulfate produced from coke-chemical saturator liquors. Laboratory crystallization experiments with pure ammonium sulfate and with liquors from the Kemerovo Coke-Chemical …

Study of the Effect of Preliminary Heat Treatment of the Raw Material Charge on the Formation of Chrome Fused Alumina

V. M. Vityugin, V. V. Koyain, V. I. Vereshchagin
1974 SovietRxiv: ru-197401.12031

This study addresses nonuniformity and chromium oxide segregation in the conventional arc furnace production of chrome fused alumina from alumina and chromium oxide powders. The authors investigate whether preliminary heat treatment of a charge containing 98.5% alumina and 1.5% chromium oxide can in…

Investigation of the Effect of Magnetic Treatment on the Aggregate Properties of Moist Dispersed Materials

V. M. Vitotin, V. P. Podkova
1974 SovietRxiv: ru-197401.12030

This study examines whether magnetic treatment can alter the aggregate-forming properties of moist dispersed materials by changing the state of water associated with their particles. Kaolin, limestone, iron-ore concentrate, alumina, and coal slurry were exposed to a permanent magnetic field while dr…

Study of the Mechanism of the Effect of Surfactants on the Kinetics of Zinc Discharge-Ionization

V. E. Gorodovykh, O. S. Stepanova, and A. A. Ovcharenko
1974 SovietRxiv: ru-197401.12029

This study examines how the surfactants camphor and n-amyl alcohol influence the kinetics of zinc discharge and ionization in sulfate electrolytes, a problem relevant to improving electrodeposited zinc coatings. Polarographic and voltammetric measurements were carried out on dropping and stationary …

Study of the Mechanism of the Influence of Surfactants on the Kinetics of Copper Ionization Discharge

V. E. GORODOVYKH, O. S. STEPANOVA, N. G. BROSHNIKOVA
1974 SovietRxiv: ru-197401.12028

This study examines how the molecular surfactants n-amyl alcohol and camphor influence the kinetics of copper discharge and ionization in sulfate electrolyte. Using polarography with linearly varying potential on dropping mercury, stationary mercury drop, and solid copper electrodes, the authors mea…

Studies on the Compilation of Spectra of a Series of Elements in Various Electrolytes by Amalgam Accumulation Polarography

A. A. KAPLIN, V. M. PICHUGINA, R. F. ZARUBINA
1974 SovietRxiv: ru-197401.12027

This study addresses the selection of supporting electrolytes for amalgam accumulation polarographic determination of trace amounts of Zn, Cd, Pb, Cu, Bi, Sb, Sn, In, and Tl. Using a silver film electrode with a mercury film under standardized electrolysis, purging, stirring, and recording condition…

Studies on the Determination of 10(-10) - 10(-8) g Cu, Bi, Cd, Sb in Zinc and Cadmium Sulfide

A. A. Kaplin, Z. S. Mikhailova, V. M. Pichugina
1974 SovietRxiv: ru-197401.12026

This paper develops amalgam polarographic procedures with accumulation for determining trace impurities in semiconductor-grade zinc sulfide and cadmium sulfide. Using a 1 N hydrochloric acid background, the authors study the dependence of anodic peak currents on electrolysis potential, accumulation …

Polarographic Determination of Organic Impurities in Water

A. A. KAPLIN, L. M. POSKREBYSHEVA
1974 SovietRxiv: ru-197401.12025

This paper proposes an alternating-current polarographic method for determining surface-active organic microimpurities in water without preliminary concentration. The approach uses changes in the cathodic cadmium peak at a stationary mercury-film electrode, with tetrabutylammonium bromide as a refer…

Application of the Method of Amalgam or Film Stripping Polarography for Determining Low Concentrations of a Number of Organic Substances

A. A. KAPLIN, T. F. RYASHENTSEVA, N. P. SOROKINA
1974 SovietRxiv: ru-197401.12024

This paper examines the use of amalgam and film stripping polarography to determine very low concentrations of organic compounds that form sparingly soluble salts or complexes with metals at an electrode surface. The authors propose expanding earlier mercury electrode approaches by first concentrati…

Studies on the Development of Methods for Determining 10(-6)% of Certain Inorganic Impurities in Solutions Simulating Biological Objects

A. A. Kaplin, V. F. Yankauskas, A. S. Zharkikh
1974 SovietRxiv: ru-197401.12023

This study examines the extension of amalgam polarographic analysis to solutions simulating biological materials and food industry objects for trace determination of inorganic impurities. Using a film cathode, saturated calomel reference electrode, nitrogen deaeration, controlled acidity, and select…

Study of the acylation reaction of N-substituted arylalkylureas in the presence of various acid chlorinating agents

A. G. PECHENKIN, L. G. TIGNIBIDINA, T. V. ANTONOVA
1974 SovietRxiv: ru-197401.12021

This study compares acid chloride forming agents for the acylation of benzhydrylurea with propionic acid, a reaction relevant to the preparation of acylated ureas with potential anticonvulsant activity. Benzhydrylurea was reacted under identical conditions in benzene with propionic acid in the prese…

Infrared Absorption Spectra and Structure of Urea Derivatives

L. G. Tignibidina, A. G. Pechenkin, V. E. Chistyakov, M. M. Kaganskii
1974 SovietRxiv: ru-197401.12020

Infrared absorption spectra were recorded and systematized for 24 monosubstituted urea derivatives of the general type RNHCONH2 in Vaseline oil and in benzene and chloroform solutions. The study compares alkyl, arylalkyl, and diarylalkyl substituent classes with urea, assigning characteristic NH, NH…

On the Structure of Diacyl Derivatives of Benzylurea

N. S. DOBYCHINA
1974 SovietRxiv: ru-197401.12019

The paper examines the structural assignment of diacyl derivatives formed by acylation of benzylurea with para substituted benzoic acids, focusing on which amide nitrogen receives the second acyl group. Infrared spectra were found to be insufficiently diagnostic, so the study interprets proton magne…

Synthesis and pharmacological activity of some derivatives of benzalbisurea and 1-(?-ureidobenzyl)-2-naphthols

A. G. PECHENKIN, L. I. BUGAEVA, E. V. MAST, T. V. MIKHAILOVA
1974 SovietRxiv: ru-197401.12018

This study describes the synthesis and preliminary pharmacological evaluation of substituted benzalbisureas and 1-alpha-ureidobenzyl-2-naphthols in a search for anticonvulsant agents. Benzalbisureas were prepared by acid-catalyzed condensation of substituted benzaldehydes with urea, and selected pro…

Synthesis and Study of Some Ureido Acids and Their Derivatives

A. G. PECHENKIN, A. V. EVSEEVA, A. P. GILEV, T. V. MIKHAILOVA
1974 SovietRxiv: ru-197401.12017

This study examines whether introducing a urea fragment into amino acids associated with anticonvulsant activity preserves or modifies their biological effect. Seven ureido acids were synthesized from corresponding amino acids by reaction either with urea or with sodium cyanate, and the products wer…

Setup for Studying the Kinetics of Fast Reversible Reactions by the Field Dissociation Effect Method Using a Rectangular Pulse

V. I. IVASENKO, V. T. NOVIKOV, V. P. LOPATINSKII
1974 SovietRxiv: ru-197401.12016

This paper describes an apparatus for studying the kinetics of fast reversible reactions in solution using the field dissociation effect produced by a rectangular high-voltage pulse. The design adapts relaxation-method instrumentation for measuring protonation constants of carboxylic acids, with a s…

Research in the Chemistry of Carbazole Derivatives

Unknown
1974 SovietRxiv: ru-197401.12015

This study examines the dipole moments of a homologous series of monoacetyl derivatives of 9-alkylcarbazoles and evaluates the electronic state and polarity of their carbonyl bonds. Dipole moments were calculated from concentration dependences of dielectric constants and specific volumes in benzene …

Research in the Chemistry of Carbazole Derivatives

Unknown
1974 SovietRxiv: ru-197401.12014

This study examines how anthracene and phenanthrene impurities in carbazole affect the revinylation synthesis of 9-vinylcarbazole oligomers and their electrophotographic properties. Oligomers were prepared from synthetic carbazole with added anthracene, from reagent-grade carbazole, from recrystalli…

Kinetics of the Direct Iodination of Fluorenecarboxylic Acid-5 in the Presence of a Sulfuric-Nitric Acid Mixture

A. N. Novikov, V. T. Slyusarchuk
1974 SovietRxiv: ru-197401.12013

This study examines the kinetics of direct iodination of fluorene-5-carboxylic acid using iodine in the presence of a sulfuric and nitric acid mixture, a method proposed for preparing otherwise difficult aromatic iodo derivatives. Reaction progress was followed by sampling, quenching with water, ext…

Differential Method for Determining the Activation Energy of Thermal Decomposition of Solids

S. I. Smolyaninov, V. I. Lozyn
1974 SovietRxiv: ru-197401.12012

This paper proposes a simplified differential method for estimating the activation energy of thermal decomposition of solids from derivative thermogravimetric curves. Starting from the standard rate law with Arrhenius temperature dependence under constant heating, the authors derive an expression us…

Effect of Iron Oxide Additives on the Process of Volatile Release from Peat

S. I. Smol’yaninov, V. I. Lozbin, Ya. A. Belikhmaer
1974 SovietRxiv: ru-197401.12009

This study examines how hematite additions affect the thermal decomposition of peat, a question relevant to possible chemical and metallurgical uses of peat. Peat samples containing varying amounts of iron oxide were semicoked in nitrogen on a derivatograph to 600°C, while weight loss and the evolut…