Showing 50 of 25456 papers

A New Method for the Synthesis of 3-Aryl-1,4,5,6-tetrahydropyridazines. $n$ -Diphenylylcyclobutane

Yu. S. Shabarov, N. I. Vasil’ev, N. K. Mamaeva, and R. Ya. Levina
1960 SovietRxiv: ru-196001.01182

A new synthesis of 3-aryl-1,4,5,6-tetrahydropyridazines is described, addressing the limited accessibility of arylbutadienes required in the earlier azodicarboxylic ester route. The method reduces readily available 6-aryl-4,5-dihydropyridazin-3-ones, prepared from beta-aroylpropionic acids and hydra…

SIMULTANEOUS REDUCTION OF A PAIR OF BILINEAR FORMS TO CANONICAL FORM

A pair of bilinear forms is considered
1960 SovietRxiv: ru-196001.01069

The paper studies the simultaneous reduction of two bilinear forms whose matrices are symmetric or skew-symmetric, over the real or complex numbers. It gives a canonical decomposition of any such pair into a direct sum of explicitly listed elementary pairs, with uniqueness up to the order of summand…

Critical regions of concentration in soap solutions

P. A. DEMCHENKO and Corresponding Member of the USSR Academy of Sciences A. V. DUMANSKY
1960 SovietRxiv: ru-196001.00997

This paper examines critical concentration regions in sodium laurate and potassium laurate solutions, extending beyond the commonly recognized critical concentration of micelle formation. Using the solubilization of toluene as an experimental measure, the authors identify an initial threshold near 0…

X-ray spectral study of titanium beryllides

È. E. Vainstein, E. A. Zhurakovskiy, I. B. Staryi
1960 SovietRxiv: ru-196001.00895

This study examines the nature of interatomic bonding in titanium beryllides through the fine structure of titanium X-ray absorption spectra and K beta 5 emission bands. Alloys close to TiBe and TiBe2 were prepared by powder sintering, compositionally and structurally checked, and compared with meta…

Physicochemical Study of the Formation Process of Furfural-Aniline Resins

M. S. Barvinok, V. S. Kuprin, V. V. Mazurek, and G. I. Semenov
1960 SovietRxiv: ru-196001.00865

This study examines the chemistry of furfural-aniline resin formation, a process previously known in application but insufficiently characterized mechanistically. Using physicochemical analysis together with spectrophotometry, viscosity measurements, calorimetry, chemical analysis, hydrogenation, an…

On the Composition and Stability of Calcium Hydrosilicates under Hydrothermal Treatment Conditions at 700 atm Gauge and $200^\circ$

P. P. BUDNIKOV, S. M. ROYAK, L. Ya. LOPATNIKOVA and A. M. DMITRIEV
1960 SovietRxiv: ru-196001.00688

This study examines the composition, crystallization, and mechanical stability of calcium hydrosilicates formed during hydrothermal treatment relevant to cementing ultradeep oil wells at 200°C and pressures up to 700 atm. Mixtures of lime and quartz sand with CaO:SiO2 ratios of 2, 1, and 0.8 were au…

Inhibition of Hydrocarbon Cracking in Molten Sodium and Potassium Hydroxide

A. V. TOPCHIEV, Ya. M. PAUSHKIN, A. V. NEPRYAKHINA, P. G. ANAN’EV, and N. N. DMITREVSKII
1960 SovietRxiv: ru-196001.00685

This study examines the behavior of n-heptane and cyclohexene under high-temperature conditions in contact with molten sodium, potassium hydroxide, and, for comparison, molten aluminum. Experiments were conducted in flow apparatuses at atmospheric pressure and in an autoclave under elevated pressure…

Polarographic Study of the Nitro-Aci Tautomerism of Nitrocyclohexane

Ya. I. Tur’yan, Yu. M. Tyurin, and P. M. Zaitsev
1960 SovietRxiv: ru-196001.00649

This paper reports a polarographic investigation of the nitro-aci tautomerism of nitrocyclohexane in buffered aqueous media at controlled ionic strength. By following the polarographic wave of the nitro form over pH 3 to 12 and at 25 to 50°C, the authors measured the rates of conversion in both dire…

On Boundary Conditions in the Method of Spherical Harmonics

Unknown
1960 SovietRxiv: ru-196001.00391

This paper examines the choice of boundary conditions at a vacuum boundary in the spherical harmonics approximation to the particle transport equation. Using a variational principle for the transport problem, it derives boundary conditions that are optimal in the sense of minimizing the correspondin…

Reactions of Diphenylmercury with Benzene

Unknown
1960 SovietRxiv: ru-196001.00300

This paper examines the thermal and photochemical reactions of diphenylmercury in benzene, with particular attention to the role of oxygen and to phenyl group exchange between the organomercury compound and the solvent. Using carbon-14 labeled benzene or labeled diphenylmercury, the authors compare …

Phosphine oxides containing a vinyl group at the phosphorus atom

M. I. KABACHNIK, T. Ya. MEDVED’, and Yu. M. POLIKARPOV
1960 SovietRxiv: ru-196001.00299

This paper reports the synthesis of tertiary phosphine oxides containing a vinyl group attached to phosphorus, a class of organophosphorus compounds of interest as potential monomers for nonflammable polymers. The authors prepare diethylvinylphosphine oxide, dipropylvinylphosphine oxide, and ethylph…

Analysis of Some Inelastic $p$–$n$ Interactions at an Energy of $9$ BeV

Zh. S. Takibaev, V. A. Botvin, I. Ya. Chasnikov
1960 SovietRxiv: ru-196001.00255

This paper analyzes selected inelastic proton-neutron interactions at 9 BeV recorded in nuclear emulsion exposed to the internal proton beam of the Joint Institute for Nuclear Research synchrophasotron. From 72 three-prong events, 22 cases with full identification of secondary charged particles were…

Catalytic Dehydrogenation of Isopropylbenzene

O. K. BOGDANOVA, A. A. BALANDIN, and I. P. BELOMESTNYKH
1960 SovietRxiv: ru-196001.00250

This paper investigates the catalytic dehydrogenation of isopropylbenzene to alpha-methylstyrene, with emphasis on reaction kinetics and the influence of hydrocarbon structure on reaction rate. Experiments were conducted in a flow system over a mixed oxide catalyst with steam dilution, measuring hyd…

Synthesis of Peptides and Polyphosphates of Adenylic Acid from $\mathrm{N}$ -(Adenosinephospho)-phenylalanine

Z. A. SHABAROVA, L. G. ANDRONOVA, M. BEZDEK
1960 SovietRxiv: ru-196001.00228

This study examines N-adenosinephosphoric derivatives of phenylalanine as model compounds for possible peptide nucleotide linkages involving a phosphorus nitrogen bond. The authors synthesized and compared benzyl-protected and deprotected derivatives, testing their reactions with protected amino aci…

On R. N. Khadzhikov's Book Rock Mechanics

B. M. TITOV, V. S. UDUT
1959 SovietRxiv: ru-195901.14508

This review evaluates R. N. Khadzhikov’s revised textbook Mining Mechanics, approved for mining technical schools, in light of its pedagogical structure, technical coverage, and suitability for professional training. The authors note significant improvements over earlier editions, including clearer …

Analysis of the Theoretical Accuracy of Operation of a Certain Group of Spatial Mechanisms for Generating an Ellipse

E. I. TOROPYGIN
1959 SovietRxiv: ru-195901.14485

This article analyzes the theoretical accuracy of a class of spatial mechanisms used to generate ellipses, specifically mechanisms that form a conchoid by laying off constant segments along the radius vectors of a prescribed ellipse. The author derives formulas for the deviation between the generate…

Technical and Economic Determination of the Service Life of Machines

V. F. Vasyutin
1959 SovietRxiv: ru-195901.14452

This article examines how the service life of industrial machines should be determined by combining technical wear with economic indicators, rather than relying only on fixed calendar periods or uniform depreciation norms. Focusing on mining equipment in the Soviet coal industry, it argues that exis…

Some Issues in the Design of Main Fan Installations for Kuzbass Mines

O. M. Kolyshkin
1959 SovietRxiv: ru-195901.14408

This paper examines the design and operation of main fan installations in Kuzbass coal mines, where ventilation requirements vary widely as workings move to lower horizons and mine networks become more complex. Using survey data from 1955 to 1957 and comparisons of operating ranges for axial and cen…

On saving electric power by increasing the efficiency of fans

A. G. BYCHKOV
1959 SovietRxiv: ru-195901.14397

This paper estimates the potential reduction in Soviet electricity consumption that could be achieved by raising the efficiency of fans during the 1960 to 1969 period. Using approximate national data and engineering assumptions, it evaluates mine ventilation fans, thermal power station draft and bla…

On the Issue of Automatic Control of Skip Hoisting Installations

V. S. Udut
1959 SovietRxiv: ru-195901.14374

This paper examines automatic control of skip hoisting installations with asynchronous drives, focusing on how loading, unloading, and landing devices affect static resistance and rope tension during a hoisting cycle. Using analytical expressions, grapho-analytical estimates, and operating observati…

On Speed Indicators for Hoisting Machines

V. D. Petunov
1959 SovietRxiv: ru-195901.14363

The paper discusses the need to replace mercury-float speed meters used on Soviet mine hoisting installations, focusing on their inadequate recording scale, operational unreliability, and high cost. It reviews practical shortcomings of instruments made by Karlik, Logan, and the Tomsk Manometer Plant…

Design Methodology for an Induction Drive of a Mine Hoisting Machine

V. D. Petunov
1959 SovietRxiv: ru-195901.14341

This paper proposes a coordinated design methodology for asynchronous drives of mine hoisting machines, addressing the interdependent selection of the speed diagram, starting rheostat, magnetic station, and motor. The method derives rotor resistance stages from actual hoist operating conditions, rel…

Regulation of the Length of Hoisting Ropes

N. I. Klykov
1959 SovietRxiv: ru-195901.14308

This paper addresses the periodic adjustment of rope length in mine hoisting installations, where plastic elongation produces slack that can affect safe operation. It derives formulas for the permissible adjustment step from rope deformation, unloading overtravel, hoisting height, drum geometry, and…

Monitoring Rope Slack in Hoisting Installations

N. I. Klykov
1959 SovietRxiv: ru-195901.14297

This paper examines the problem of rope slack in mine hoisting installations, distinguishing emergency slack caused by a jammed descending conveyance from operating slack produced when a vessel is set down for loading. It reviews continuous monitoring methods based on sensing slack in the upper or l…

On the Elastic and Plastic Elongation of Hoisting Ropes

N. I. KLYKOV
1959 SovietRxiv: ru-195901.14286

This paper analyzes the elastic and plastic elongation of steel hoisting ropes used in mine hoists, emphasizing that unstretched ropes undergo plastic elongation at stresses below the elastic limit of their wires because of rope structure and wire displacement. It replaces the rope tensile diagram w…

Selection of Rational Cutter Geometry for Drilling Blastholes in Rock

M. K. TSEKHIN
1959 SovietRxiv: ru-195901.14241

This paper examines the poor performance and high cutter consumption associated with rotary electric drilling of blastholes in Kuzbass rock workings, particularly in strong and abrasive sandstones. On the basis of mine observations and analysis of cutter wear, it argues that standard cutter geometri…

The Problem of Combating Sudden Outbursts of Coal and Gas and Degassing in the Mines of the Eastern Coal Basins of the USSR

O. I. CHERNOV
1959 SovietRxiv: ru-195901.14230

This paper reviews sudden coal and methane outbursts and preliminary seam degassing in eastern Soviet coal basins, drawing on recorded mine cases from 1947 to 1956 and operational experience in Kuzbass, the Urals, the Far East, and Vorkuta. It summarizes outburst frequency, locations, and intensity,…

Some Research Results on Moisture-Resistant Inert Dust

Z. M. Guseva
1959 SovietRxiv: ru-195901.14219

This study examines moisture-resistant inert dust for coal-mine shale barriers, addressing the rapid hygroscopic caking of ordinary limestone dust and the resulting need for frequent replacement. Limestone was jointly ground with hydrophobizing additives such as mylonaphthene, rosin, and oleic acid,…

Determination of the Safe Height of Mine Conical Waste Rock Dumps (Spoil Tips) for the Conditions of Kuzbass

P. A. LEONOV
1959 SovietRxiv: ru-195901.14208

This paper examines the determination of a safe height for conical mine waste rock dumps under Kuzbass conditions, where economic advantages of taller dumps must be balanced against deformation and accident risks. It analyzes dump stability through equilibrium considerations, reviews existing calcul…

On a Profile for Fiberglass Reinforcement

E. A. Bober
1959 SovietRxiv: ru-195901.14186

This paper examines the design of portable chock supports for mine roof control, focusing on the limitations of rail, I-beam, and channel-section metal cribs, which are either too heavy or insufficiently stable under high rock pressure. It reports laboratory model tests of several bent sheet-steel s…

Mining System for Thick Coal Seams of the Tom-Usinsk District of Kuzbass

V. V. Proskurin, V. S. Evseev, G. E. Posokhov
1959 SovietRxiv: ru-195901.14163

The article addresses the problem of mining thick, gently dipping coal seams in the Tom-Usa district of Kuzbass, where existing inclined-slice methods with roof caving produced low output, high timber consumption, significant coal losses, and frequent roof-control difficulties. It proposes a system …

Main Directions for Improving Methods of Mining Thick Coal Seams

T. F. GORBACHEV
1959 SovietRxiv: ru-195901.14152

This paper examines ways to improve mining methods for thick coal seams in Kuzbass, where labor productivity had stagnated despite increased mechanization. It argues that manual timber support is the main obstacle and reviews alternative systems suited to varied geological conditions, including shie…