Showing 50 of 25456 papers

Development of the Mining Industry of the USSR over 40 Years

G. E. Bakanov
1959 SovietRxiv: ru-195901.14141

This article surveys the development of the USSR mining industry from its prerevolutionary origins through the first four decades after the October Revolution. Using historical production figures, examples of mine reconstruction, and comparisons across periods, it contrasts the low mechanization, sm…

Study of the Oxidation of Ammonia Under Pressure in the Presence of Cobalt-Aluminum Oxide Catalysts

N. P. Kurin, M. S. Zakharov
1959 SovietRxiv: ru-195901.14010

This study examines ammonia oxidation under elevated pressure over cobalt aluminum oxide catalysts, focusing on how aluminum oxide addition and mechanical pressing affect nitric oxide formation. Catalysts containing 5, 10, and 15% aluminum oxide were prepared by coprecipitation, with selected compos…

Binder from Solid Fuel Ash and Processes During Its Hardening

N. S. Dubovskaya, P. G. Usov
1959 SovietRxiv: ru-195901.13899

This paper investigates the production and hardening behavior of a binder made from solid fuel ash activated by simultaneous grinding with unslaked lime. Using compressive strength tests, chemical analysis, and thermal analysis, the authors examine the effects of fineness, curing time, and water or …

Probable Mechanism of Ammonia Oxidation Under Pressure in the Presence of Iron-Bismuth-Manganese Oxide and Cobalt Catalysts

N. P. KURIN, P. E. BOGDANOV
1959 SovietRxiv: ru-195901.13788

The paper proposes a mechanistic interpretation of ammonia oxidation under elevated pressure over iron, bismuth, manganese oxide and cobalt-containing catalysts. Using the hydroxylamine hypothesis, it explains previously observed dependencies of nitric oxide yield on space velocity, temperature, pre…

Effect of Lead on the Reduction of Tellurium

V. B. Sokolovich, I. P. Onufrienok
1959 SovietRxiv: ru-195901.13455

This study examines why established titrimetric methods for determining tellurium by reduction of tellurite to elemental tellurium fail in lead-containing alloys. Experiments with pure tellurium, artificial mixtures, and tellurium alloys tested lactose and several alternative reducing agents, includ…

Determination of Antimony and Tellurium in an Antimony-Tellurium Master Alloy

V. M. Aksenenko, I. P. Onufrienok
1959 SovietRxiv: ru-195901.13343

This paper addresses the titrimetric determination of antimony and tellurium in antimony tellurium master alloys without preliminary separation. The authors compare permanganate, bromate, and dichromate oxidants in hydrochloric sulfuric acid media using methyl red and related endpoint procedures, th…

Gravimetric determination of mercury as sulfide

I. P. ONUFRIENOK, Z. N. TERESHCHOVA
1959 SovietRxiv: ru-195901.13232

This paper proposes a simplified gravimetric method for determining mercury as mercuric sulfide by replacing sulfur extraction with carbon disulfide with oxidation by hydrogen peroxide in alkaline solution. The authors show that, under these conditions, excess sulfur associated with thiosulfate or s…

On the question of a new titrimetric method for determining iodide, bromide, and chloride ions

Yu. L. LEL’CHUK, O. V. CHASHCHINA, T. V. SONINA, F. V. DITRIKH
1959 SovietRxiv: ru-195901.13121

This study experimentally evaluates a proposed titrimetric method for determining iodide, bromide, and chloride ions in mixtures using potassium iodate in an aqueous acetone medium. The authors test the reproducibility of iodide titration, the effects of bromide and chloride ions, and the feasibilit…

On the Problem of Solubility in Analytical Chemistry

Yu. L. Lel’chuk
1959 SovietRxiv: ru-195901.13010

This paper examines how external electrolytes affect the solubility, solubility product, and activity coefficient of silver bromate, a problem presented as important for improving analytical precipitation methods. Using iodometric determination of bromate ions and gravimetric determination of silver…

Gravimetric Determination of Potassium and Sodium in Low-Mineralized Waters

M. E. Effendi, V. B. Sokolovich
1959 SovietRxiv: ru-195901.12899

This paper examines gravimetric methods for determining sodium and potassium in low-mineralized natural waters, where conventional alkali-metal determinations are hindered by the high solubility of their salts and often replaced by calculation. The authors develop and test procedures using magnesium…

Laboratory setup for producing hydrogen by water electrolysis

S. I. SMOLYANINOV
1959 SovietRxiv: ru-195901.12788

This paper describes a laboratory apparatus for producing hydrogen by electrolysis of water as a practical alternative to generating hydrogen from metals and acids when regular or substantial quantities are needed. It presents the construction and operation of a multi-cell glass electrolyzer using n…

Laboratory Setup for Producing Carbon Monoxide

S. I. Smolyaninov
1959 SovietRxiv: ru-195901.12677

This paper describes a compact laboratory installation for producing carbon monoxide in quantities suitable for synthesis work, addressing the cost and purity limitations of common acid decomposition methods. The proposed setup generates carbon monoxide by passing carbon dioxide through electrically…

Study of the Effect of Heating Temperature on the Distribution of Sulfur in Coal Pyrolysis Products

N. M. Smolyaninova, N. E. Smolyutin, S. I. Smolyaninov
1959 SovietRxiv: ru-195901.12566

This study examines how heating temperature and secondary pyrolysis conditions affect the distribution of sulfur among the products of high-sulfur Kizel coal pyrolysis. Experiments were conducted at 500 to 800°C in an enlarged laboratory unit with separately controlled furnace heating and fractional…

On the Role of Humic Acids in the Genesis of Coals

Generalization of humic acids and their salts
1959 SovietRxiv: ru-195901.12232

This study examines how humic acids may contribute to coal genesis through selective dehydration and decarboxylation under conditions simulating metamorphism. Peat humic acids from the Tagan Bog were heated as dry substances, aqueous gels, and sodium, ammonium, calcium, and barium humates at 170 to …

Indicator Scale for Determining the Color of Dark Petroleum Products

I. V. Gebler, S. I. Smolyaninov, D. A. Popov, D. D. Yodvorov
1959 SovietRxiv: ru-195901.12121

This paper proposes a simple indicator scale for visually determining the color intensity of dark petroleum products, a task not adequately served by existing colorimeters or solution standards designed mainly for light-colored products. The authors describe a ten-standard scale made from sodium sal…

Synthesis of Some Derivatives of 4(5)-Nitro- and 4(5)-aminoimidazole-5-(4)-carboxylic Acid

R. N. Gireva, N. S. Dobychina
1959 SovietRxiv: ru-195901.12010

This paper reports the preparation of several previously little studied derivatives of 4(5)-nitroimidazole-5(4)-carboxylic acid and the corresponding amino compounds. Nitroimidazolecarboxylic acid was obtained from oxymethylimidazole sulfate by a modified nitration procedure using potassium nitrate,…

Application of the Formaldehyde Method for the Isolation of Carbazole and Anthracene from Crude Anthracene

L. P. Kulev, V. P. Lopatinskii
1959 SovietRxiv: ru-195901.11899

This study examines the use of the formaldehyde method to separate carbazole and anthracene from crude anthracene, addressing limitations of existing potassium melt and pyridine processes. Experiments with pure carbazole, artificial carbazole and anthracene mixtures, and enriched crude anthracene ev…

Study in the Series of Pyrazolone Monoazo Dyes

L. P. Kulev, G. M. Stepanova
1959 SovietRxiv: ru-195901.11788

This study examines pyrazolone monoazo dyes prepared from previously synthesized 2-, 3-, and 4-aminobenzoylaminoantipyrines as diazo components. The authors diazotized the hydrochlorides of these acylaminoantipyrines and coupled them with several azo components, then characterized selected products …

On the Dependence of the Physiological Activity of Acyl Derivatives of 4-Aminoantipyrine on the Rate of Their Hydrolysis

L. P. Kutev, G. M. Stepnova
1959 SovietRxiv: ru-195901.11677

This study examines whether the antipyretic activity of acyl derivatives of 4-aminoantipyrine is related to their hydrolysis rate, on the assumption that physiological action depends on cleavage of the molecule in the organism. Several derivatives were prepared or selected, hydrolyzed under controll…

On the Direct Iodination of Monoiodobenzoic Acids

A. N. Novikov
1959 SovietRxiv: ru-195901.11455

This study examines the direct iodination of monoiodobenzoic acids in the presence of a nitrating mixture, extending earlier work on halogenation of aromatic compounds. Experiments with p-iodobenzoic acid gave 3,4-diiodobenzoic acid in about 47 to 48 percent yield under optimized conditions using io…

Effect of Pyridine on the Iodination of Phenols

L. A. Pershina, I. M. Borodina
1959 SovietRxiv: ru-195901.11344

This study examines the iodination of phenol and resorcinol by iodine and iodine chloride in ether, both alone and in the presence of pyridine, in light of pyridine’s activating effect in related halogenation reactions. Comparative experiments using different reagent ratios showed that free iodine w…

Study of Complex Compounds of Benzidine and p-Anisidine with Some Salts of Divalent Copper

I. I. Molodykh, A. I. Borodulina
1959 SovietRxiv: ru-195901.11121

This study reports the synthesis and preliminary characterization of complex compounds formed by benzidine and p-anisidine with divalent copper salts, including chloride, nitrate, sulfate, and acetate. The compounds were prepared by mixing cold saturated aqueous and alcoholic solutions of the compon…

Complexes of Amines with Some Bromonitrophenols and Their Bactericidal Properties

I. M. Bortovoi, G. L. Ryzhova, L. I. Potekhina
1959 SovietRxiv: ru-195901.10899

This study examines the preparation and antibacterial activity of amine complexes with 2-bromo-4-nitrophenol and 2,6-dibromo-4-nitrophenol. Seventeen previously undescribed crystalline complexes were synthesized, characterized by composition, nitrogen analysis, melting point, solubility, and color, …

Comparative Anti-Brucellosis Activity of Some Trypaflavine Derivatives

L. P. Kulev, A. G. Pechenkin
1959 SovietRxiv: ru-195901.10566

This study examines whether chemical modification of trypaflavine can produce derivatives with useful activity against brucella organisms, particularly through protection of amino groups by azo, acetyl, benzoyl, or benzylidene substituents. The authors synthesized a series of trypaflavine derivative…

Complex Compounds of Trypaflavine and Their Anti-Brucellosis Activity

L. P. Kulev, A. G. Pechenkin
1959 SovietRxiv: ru-195901.10455

This study investigates complex compounds of trypaflavine as potential anti-brucellosis agents, motivated by the limited therapeutic effectiveness of trypaflavine despite its strong in vitro bactericidal action. A series of metal salt and iodide complexes was synthesized, characterized by elemental …

Setup and Monitoring of the Operation of Balancing Machines

V. T. Tikhonov
1959 SovietRxiv: ru-195901.10234

This paper addresses the practical setup and verification of balancing machines used for rapidly rotating parts in mining and electrical machinery, focusing on DB-3, DB-4, and similar machines. It proposes using a dynamically balanced control rotor and a circular traverse with a known check weight i…

Complex Compounds of Uric Acid with Amines

L. I. Kulev, A. V. Boldyreva
1959 SovietRxiv: ru-195901.10233

This study examines salt-like complex compounds formed between uric acid and selected amines and amino alcohols, motivated by the possible relevance of such reactions to increasing uric acid solubility and identifying anti-gout agents. Using electrical conductivity, viscosity, density measurements, …

Factors Determining the Productivity of Raise-Boring Machines

D. N. Malikov
1959 SovietRxiv: ru-195901.10222

This paper examines the factors governing the productivity of crosscut, or raise-boring, drilling machines used for making raise holes in coal. It derives productivity equations for two drilling technologies, drilling followed by tool lowering and drilling with enlargement on the return stroke, by d…

Energy Performance Indicators of Rotary-Percussive Blast-Hole Drilling

Ya. A. Serov
1959 SovietRxiv: ru-195901.10200

This paper examines the power and energy characteristics of rotary-percussive blast-hole drilling, focusing on how feed force, drill rotation speed, impact frequency, air pressure, rock strength, and bit geometry affect the rotator, hammer, and feed mechanism. Using experimental comparisons across s…

Development of a rotary drilling machine with hydraulic drive for open-pit operations

O. D. Alimov, I. G. Basov, V. F. Gorbunov
1959 SovietRxiv: ru-195901.10178

The article addresses the need for mobile rotary drilling equipment for scattered or frequently changing work sites where supplying electric or pneumatic power is inefficient. It proposes a hydraulic-drive rotary drilling machine mounted on a tractor or excavator boom, using the carrier’s hydraulic …

Some Results of Production Tests of Long-Stroke Electric Drills

I. G. Basov, N. S. Kolodyazhnyi, V. I. Pogorelov
1959 SovietRxiv: ru-195901.10167

This paper reports production tests of a lightweight long-stroke electric drill developed to reduce the labor intensity and improve the productivity of rotary blasthole drilling in coal mines and weak to medium-strength rocks. The authors describe the drill’s supporting and feeding attachment, guide…

Application of the Method of Similarity and Dimensions to the Calculation of Solenoid Hammers

P. M. Alabuzhev, N. P. Ryashentsev
1959 SovietRxiv: ru-195901.10145

This paper applies similarity theory and dimensional analysis to the design calculation of multi-coil solenoid hammers, using a smaller Sintron hammer as a model for scaling to a more powerful machine. The authors derive similarity coefficients for impact energy, striker mass, velocity, stroke, blow…

On Reducing Losses in the Steel of a Solenoid Hammer

N. P. Ryashentsev, A. V. Frolov
1959 SovietRxiv: ru-195901.10134

This paper examines losses in the steel magnetic circuit of a solenoid hammer, with emphasis on eddy current heating of the striker and ways to improve efficiency without adding cooling equipment. Using calorimetric measurements on an MS-5 hammer, the authors compare striker materials, heat treatmen…

Calculation and Selection of Parameters for a Solenoid Hammer

N. P. Ryashentsev
1959 SovietRxiv: ru-195901.10123

This paper develops a calculation procedure for selecting the electrical and geometrical parameters of a multi-coil solenoid hammer, motivated by the limited applicability of standard electromagnet design methods to nonsinusoidal coil currents and dynamic hammer operation. It derives relations for s…

Study of the Dynamics of Solenoid Hammers

N. P. Ryashentsev
1959 SovietRxiv: ru-195901.10110

This paper examines the dynamics of solenoid hammers, focusing on the limitations of earlier designs whose impact energy, efficiency, and thermal behavior were constrained by electrical and magnetic braking effects. Using oscillographic recording of striker displacement, coil current, and voltage, t…